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Despite being one of the most important tropical biomes in the world, the Atrato River basin has experienced a critical ecological deterioration due to gold mining, posing a significant threat to wildlife and human health. In this study, we measured the concentrations of mercury (Hg) and arsenic (As) in sediments at various swamps within the basin. Classical indices were employed to assess the associated ecological and human health risks linked to exposure to these elements. The concentrations of Hg and As in the sediments ranged between 0.09 and 0.23 mg/kg and 0.59-2.68 mg/kg, respectively. The highest Hg values were found at upstream stations impacted by gold mining activities. For As, the highest levels were found near river mouth (except for station B), where agricultural practices are taken place. The contamination factor (CF) indicated that most of the sediments exhibited moderate contamination levels of Hg and As, depending on the specific sampling area. Conversely, the pollution load index (PLI) suggested a contamination level ranging from basic to moderate, with the exception of station B, which showed a progressive deterioration of the site. The geoaccumulation index (Igeo) indicated that the sediments were moderately contaminated with Hg, while showing signs of increasing contamination for As. According to the criteria for limiting effect concentrations (TEC), Hg concentrations exceeded the TEC at stations B and C, indicating a potential toxic risk to aquatic biota. A moderate potential ecological risk (PERI) was detected at downstream stations (D and E), and a high risk was detected at upstream stations (A, B and C). The hazard index (HI), used for non-carcinogenic risk assessment, suggested a risk of adverse effects on the population, particularly in children, with HI values exceeding 1. However, all lifetime cancer risk (TLCR) values fell within the acceptable range (1 × 10-6 to 1 × 10-4), indicating a negligible risk. Oral ingestion and inhalation wer

In this work, several binding gels were successfully prepared in Diffusive Gradient in Thin-film (DGT) that targeted the inclusion of novel biomass-derived materials for the determination of the labile fraction of mercury (Hg) in water. First, five biomass-derived materials were tested and the descending order as a function of the average percentage of Hg removal in solution was feathers > biochar > cork > canola meal > rice husk. The best two materials were treated and pulverized into powder to be embedded in a hydrogel; and so, feathers were pyrolyzed preserving the sulfur contained in their keratin structure (FBC), and biochar (BC) was modified and pyrolyzed with sublimated sulfur (SBC) to increase the Hg sorption sites in its structure. Analysis by Energy Dispersive X-ray fluorescence (EDXRF) spectrometry confirmed that the different pyrolysis procedures increased sulfur absorption successfully. The efficiency of the new gels (BC, SBC and FBC) in agarose was evaluated by comparative Hg uptake tests, showing a larger efficacy in the following order: SBC > BC > FBC. To assess the suitability of their application in freshwater environments, novel DGT devices were also evaluated to determine their diffusion coefficients (D). This test was conducted under controlled laboratory conditions, with particular focus on the potential competence of trace elements (Mn, Cu, Zn, Ni, Pb, Cd and As), which are commonly present in natural waters affected by mining. A stronger linear relationship between the Hg uptake by binding layers and the deployment time were obtained for the DGT devices with SBC (R2 = 0.948) vs. BC (R2 = 0.885). Therefore, the D obtained for Hg were 8.94 × 10-6 cm2 s-1 for DGT-SBC and 5.12 × 10-6 cm2 s-1 for DGT-BC devices at 25 °C, both within the same order of magnitude reported by previous studies. The good performance obtained by DGT-SBC devices is a promising result and indicates the potential for valorization of waste materials in the DGT technique.