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Massive colliding-wind binaries that host a Wolf-Rayet (WR) star present a potentially important source of dust and chemical enrichment in the interstellar medium (ISM). However, the chemical composition and survival of dust formed from such systems is not well understood. The carbon-rich WR (WC) binary WR~140 presents an ideal astrophysical laboratory for investigating these questions given its well-defined orbital period and predictable dust-formation episodes every 7.93 years around periastron passage. We present observations from our Early Release Science program (ERS1349) with the James Webb Space Telescope (JWST) Mid-Infrared Instrument (MIRI) Medium-Resolution Spectrometer (MRS) and Imager that reveal the spectral and spatial signatures of nested circumstellar dust shells around WR~140. MIRI MRS spectroscopy of the second dust shell and Imager detections of over 17 shells formed throughout the past $\gtrsim130$ years confirm the survival of carbonaceous dust grains from WR~140 that are likely carriers of "unidentified infrared" (UIR)-band features at 6.4 and 7.7 $\mu$m. The observations indicate that dust-forming WC binaries can enrich the ISM with organic compounds and carbonaceous dust., Comment: Published in Nature Astronomy on Oct 12, 2022; 21 pages, 5 figures, 2 tables

The massive, luminous Population I Wolf-Rayet stars can be considered as stars with the highest known sustained mass loss rates. Around 10% of WR stars may form carbon-rich dust in their dense and inhomogeneous winds. Though we are yet to find how dust is formed in such an extremely hostile environment, we have made substantial progress over the past decade. Here we discuss the results of recent high-resolution mid-infrared imaging of a sample of the most prodigious WR 'dustars'. This allows one to map rapidly changing dust-forming regions and derive some basic properties of the freshly formed dust., Comment: 6 pages, 3 figures; Proceedings of the Workshop "Massive Stars in Interacting Binaries", eds. N. St-Louis and A. F. J. Moffat, ASP Conference Series, in press

We describe the new version 3.0 NASA Ozone Monitoring Instrument (OMI) standard nitrogen dioxide (NO2) products (SPv3). The products and documentation are publicly available from the NASA Goddard Earth Sciences Data and Information Services Center (https://disc.gsfc.nasa.gov/datasets/OMNO2_V003/summary/). The major improvements include (1) a new spectral fitting algorithm for NO2 slant column density (SCD) retrieval and (2) higher-resolution (1° latitude and 1.25° longitude) a priori NO2 and temperature profiles from the Global Modeling Initiative (GMI) chemistry–transport model with yearly varying emissions to calculate air mass factors (AMFs) required to convert SCDs into vertical column densities (VCDs). The new SCDs are systematically lower (by ∼10-40%) than previous, version 2, estimates. Most of this reduction in SCDs is propagated into stratospheric VCDs. Tropospheric NO2 VCDs are also reduced over polluted areas, especially over western Europe, the eastern US, and eastern China. Initial evaluation over unpolluted areas shows that the new SPv3 products agree better with independent satellite- and ground-based Fourier transform infrared (FTIR) measurements. However, further evaluation of tropospheric VCDs is needed over polluted areas, where the increased spatial resolution and more refined AMF estimates may lead to better characterization of pollution hot spots.

The Ozone Monitoring Instrument (OMI) onboard NASA's Aura satellite has been providing global observations of the ozone layer and key atmospheric pollutant gases, such as nitrogen dioxide (NO2) and sulfur dioxide (SO2), since October 2004. The data products from the same instrument provide consistent spatial and temporal coverage and permit the study of anthropogenic and natural emissions on local-to-global scales. In this paper, we examine changes in SO2 and NO2 over some of the world's most polluted industrialized regions during the first decade of OMI observations. In terms of regional pollution changes, we see both upward and downward trends, sometimes in opposite directions for NO2 and SO2, for different study areas. The trends are, for the most part, associated with economic and/or technological changes in energy use, as well as regional regulatory policies. Over the eastern US, both NO2 and SO2 levels decreased dramatically from 2005 to 2015, by more than 40 and 80 percent, respectively, as a result of both technological improvements and stricter regulations of emissions. OMI confirmed large reductions in SO2 over eastern Europe's largest coal-fired power plants after installation of flue gas desulfurization devices. The North China Plain has the world's most severe SO2 pollution, but a decreasing trend has been observed since 2011, with about a 50 percent reduction in 2012-2015, due to an economic slowdown and government efforts to restrain emissions from the power and industrial sectors. In contrast, India's SO2 and NO2 levels from coal power plants and smelters are growing at a fast pace, increasing by more than 100 and 50 percent, respectively, from 2005 to 2015. Several SO2 hot spots observed over the Persian Gulf are probably related to oil and gas operations and indicate a possible underestimation of emissions from these sources in bottom-up emission inventories. Overall, OMI observations have proved valuable in documenting rapid changes in air quality over different parts of the world during last decade. The baseline established during the first 11 years of OMI is indispensable for the interpretation of air quality measurements from current and future satellite atmospheric composition missions.