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1. Highly stereoselective ring expansion reactions mediated by attractive cation-n interactions

Author

Day, V.W., English, D.G., Katz, C.E., Aubé, J., Poutsma, J.L., Smith, S., Neuenswander, B., Ribelin, T., and Manukyan, A.K.

Abstract

Gaining control: An attractive electrostatic force stabilizes the conformation of an intermediate (see scheme; n=nonbonded electron), thus controlling the leaving group configuration to give superior diastereoselectivity in an asymmetric ring expansion.

Published
2008
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