28 results on '"Mančić, Lidija T"'
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2. PEG and PVP assisted solvothermal synthesis of NaYF4:Yb3+/Er3+ up-conversion nanoparticles
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Dinic, Ivana Z., Rabanal, Maria Eugenia, Yamamoto, Kazuhiro, Tan, Zhenquan, Ohara, Satoshi, Mancic, Lidija T., and Milosevic, Olivera B.
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- 2016
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3. Spherical assemblies of titania nanotubes generated through aerosol processing
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Jovanović, Dragana J., Dugandžić, Ivan M., Ćirić-Marjanović, Gordana, Radetić, Tamara, Ahrenkiel, Scott P., Milošević, Olivera B., Nedeljković, Jovan M., Šaponjić, Zoran V., and Mancic, Lidija T.
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- 2015
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4. Hydrothermal synthesis of optically active fluoride particles doped with rare earth ions in the presence of ethylenediaminetetra acetic acid (EDTA)
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Dinić Ivana Z., Mančić Lidija T., and Milošević Olivera B.
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NaYF4:Yb3+/Er3+ ,EDTA ,hydrothermal synthesis ,luminescence ,Engineering (General). Civil engineering (General) ,TA1-2040 - Abstract
Fluorescent nanoparticles have an important role in biological analyzes, and in the last ten years they are successfully applied in a visualization and characterization of biological processes at the cellular and molecular level, as well as, in the development of fluorescent lamps, displays, plasma screens and protective labels. The great interest is directed towards the development and implementation of the light up - converters containing rare earth ions which have the ability of a intense luminescence. In this paper we described the process of EDTA assisted hydrothermal synthesis of rare earth doped fluorides. Different structural forms of materials were obtained by changing the time of the hydrothermal reaction. Comparison of a structure, morphology and optical properties of NaYF4:Yb3+/Er3+ powders were done based on X-ray powder diffraction analysis (XRPD), scanning and transmission electron microscopy (SEM and TEM) and through measuring of the luminescence in a visible part of spectrum. It was shown that the transformation from cubic to hexagonal phase is affected by the reaction time, while the up - conversion luminescence is dependent of the particles morphology and the crystal structure.
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- 2016
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5. Ultrasonic spray pyrolysis of surface modified TiO2 nanoparticles with dopamine
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Dugandžić, Ivan M., Jovanović, Dragana J., Mančić, Lidija T., Milošević, Olivera B., Ahrenkiel, Scott P., Šaponjić, Zoran V., and Nedeljković, Jovan M.
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- 2013
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6. The synthesis: Structure relationship in the ZnO-Cr2O3 system
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Mančić Lidija T., Marinković Zorica V., Vulić P., and Milošević Olivera B.
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spinel ,ZnCr2O4 ,spray pyrolysis ,mechanical activation ,structural analysis ,Chemical technology ,TP1-1185 - Abstract
In this work the development of the spinel phase in the ZnO-Cr2O3 system was discussed from the viewpoint of the synthesis-structure relationship. The nanostructure evolution in particles obtained either via solution-based (spray pyrolysis) or solid-state (mechanical activation) synthesis procedures were investigated by XRD analysis. A detailed structural analysis of the spinel phase lattice parameters, average primary crystallite sizes and micro strains were performed in accordance with a procedure based on the Koalariet-Xfit program. Due to the importance of spinel-phase cat ion distribution for chemical and physical properties, a study of the site occupation factors, i.e. changes in the stoichiometric, of ZnCr2O4 spinals was undertaken. The calculation based on atomistic methods for the description of both perfect and defect spinel ZnCr2O4 crystal lattices has been applied and the presence of individual structural defects was determined.
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- 2004
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7. Nanocrystalline functional materials and nanocomposites synthesis through aerosol routes
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Milošević Olivera B., Mančić Lidija T., Marinković Zorica V., Ohara Saloshi, Fukui Takehisa, Varez Alejandro, and Torralba Jose Manuel
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aerosol ,nanocrystals ,nanocomposites ,ultrasonic atomisation ,functional materials ,Chemical technology ,TP1-1185 - Abstract
This paper represents the results of the design of functional nanocrystalline powders and nanocomposites using chemical reactions in aerosols. The process involves ultrasonic aerosol formation (mist generators with the resonant frequencies of 800 kHz, 1.7 and 2.5 MHz) from precursor salt solutions and control over the aerosol decomposition in a high-temperature tubular flow reactor. During decomposition, the aerosol droplets undergo evaporation/drying, precipitation and thermolysis in a single-step process. Consequently, spherical, solid, agglomerate-free submicronic particles are obtained. The particle morphology, revealed as a composite structure consisting of primary crystallites smaller than 20 nm was analysed by several methods (XRD, DSC/DTA, SEM, TEM) and discussed in terms of precursor chemistry and process parameters. Following the initial attempts, a more detailed aspect of nanocrystalline particle synthesis was demonstrated for the case of nanocomposites based on ZnO-MeO (MeO=Bi Cr+), suitable for electronic applications, as well as an yttrium-aluminum base complex system, suitable for phosphorus applications. The results imply that parts of the material structure responsible for different functional behaviour appear through in situ aerosol synthesis by processes of intraparticle agglomeration, reaction and sintering in the last synthesis stage.
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- 2003
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8. Synthesis of thin films by the pyrosol process
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Tucić Aleksandar, Branković Goran O., Marinković Zorica V., Mančić Lidija T., and Milošević Olivera B.
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ultrasonic atomizing ,pyrosol ,SnO2 ,thin films ,Chemical technology ,TP1-1185 - Abstract
Among many aerosol routes, the Pyrosol process, due to its simplicity, low cost and quality of obtained films, represents a promising technique for the synthesis of thin films. The pyrosol process is based on the transport and pyrolysls of an aerosol of processor solution, generated in an ultrasonic atomizer, on a heated substrate. The theoretical principles of the pyrosol process are presented in this paper, as well as the influence of some synthesis parameters on the deposition of SnO2 thin films.
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- 2002
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9. Kinetics of nanocrystalline phase transformations in spray pyrolysed ZnO particles
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Mančić Lidija T., Marinković Zorica V., and Milošević Olivera B.
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nanocrystalline ZnO powders ,structural changes ,JMA equation ,Mining engineering. Metallurgy ,TN1-997 - Abstract
The thermal behavior of ZnO powder obtained by ultrasonic spray pyrolysis of nitrate solution (c=0.8mol/dm3, D0=2.695µm, Tmax=6000C, FG=1.2dm3/min) was investigated using non-isothermal differential scanning calorimetry (DSC, heating rates 5, 10, 15, 20O/min). The exothermic heat effects at the temperature range from 350 to 5000C were linked to particles structural data obtained by XRD, SEM and TEM analysis. Produced particles are characterized by uniform submicronic size (D=800nm, BET=4.94m2/g), high phase purity and granular or circular “open” surface due to the presence of primary crystallites (d= 20nm). Observed structural changes during heating of this powder were attributed to simultaneous processes of nucleation and growth of primary crystallites inside the produced particles.
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- 2002
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10. Surface modification of submicronic TiO2 particles prepared by ultrasonic spray pyrolysis for visible light absorption
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Dugandžić, Ivan M., Jovanović, Dragana J., Mančić, Lidija T., Zheng, Nan, Ahrenkiel, Scott P., Milošević, Olivera B., Šaponjić, Zoran V., and Nedeljković, Jovan M.
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- 2012
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11. Structural, electrical and magnetic properties of nickel manganite obtained by a complex polymerization method
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Savić, Slavica M., Tadic, M., Jaglicic, Z., Vojisavljević, Katarina, Mančić, Lidija T, Branković, Goran, Savić, Slavica M., Tadic, M., Jaglicic, Z., Vojisavljević, Katarina, Mančić, Lidija T, and Branković, Goran
- Abstract
Structural, electrical and magnetic properties of nickel manganite ceramics obtained by sintering fine powders prepared by a complex polymerization method are given in this work. The phase composition of the synthesized material was examined by x-ray powder diffraction (XRPD). Field-emission scanning electron microscopy (FE-SEM) was used to analyze the obtained powder morphology. Scanning electron microscopy (SEM) was used to analyze the microstructure of sintered ceramics. The activation energy of conduction E-a and the coefficient of temperature sensitivity B-25/100 were calculated from direct current (DC) resistivity measurements. The magnetization dependence of temperature M(T) and alternating current (AC) susceptibility data obtained from SQUID measurements clearly demonstrate that quadruple magnetic phase transitions can be readily detected at T-M1 similar to 115 K, T-M2 similar to 105 K, T-M3 similar to 38 K and T-M4 similar to 7 K. These findings suggest a novel magnetic transition for nickel manganite at low temperature T-M4.
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- 2014
12. Dirigovana sinteza nanostrukturnih oksidnih prahova sa gledišta razvoja materijala zadatih svojstava
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Mančić, Lidija T., Ristić, Momčilo, Minić, Dragica, Stojanović, Biljana, Adnađević, Borivoje, and Blagojević, Nikola
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sinteza-struktura-svojstvo ,synthesis-structure-properties ,spinel ,superconductor ,superprovodljivost ,Bi1.8Pb0.2Sr2Ca2Cu3Ox ,ZnCr2O4 ,nanostructured powders ,nanostrukturni prah ,reakciono raspršivanje ,spray pyrolysis - Abstract
Razvoj novih materijala, kao i nastojanja za iskorišćenjem njihovih tehnološki atraktivnih karakteristika doveli su do intenzivnije sinteze novih ultrafinih struktura i nanofaznih prahova. Istraživanja obuhvaćena radom fokusirana su na dirigovanu sintezu nanostrukturnih oksidnih prahova iz sistema koje odlikuje izrazita jonska (ZnCr2O4) i elektronska provodnost(Bi1.8Pb0.2Sr2Ca2Cu3Ox) primenom metode reakcionog raspršivanja. Akcenat je stavljen na nastanak faza koje su potencijalni nosioci svojstava značajnih za tehničku primenu materijala. Primenjena strategija rezultat je razvoja metode sa stanovišta definisanja odnosa u trijadi sinteza-struktura-svojstvo i izvodjenja procesa kontrolisane sinteze. Proces sinteze ZnCr2O4 praha izveden je u uslovima ultrazvučnog reakcionog raspršivanja rastvora nitrata koncentracije 0.03mol/dm3 pri unapred definisanim parametrima procesa i za različito vreme zadržavanja kapi/čestice na Tmax uz dodatan boravak u reakcionim zonama sa nižom temperaturom. Čestice nastaju procesom zapreminskom precipitacije, nukleacije, rasta kristala i obrazovanja primarnih nanočestica koje nisu u slobodnom stanju vec izgradjuju agregate sferičnog oblika i srednje veličine 470nm. Za prah iz filtra karakterističan je nastanak čestica ZnCr2O4 na čijoj se površini jasno uočavaju primarne čestice veličine nekoliko desetina nanometra. Strukturna analiza ovog praha pokazuje prisustvo primarnih kristalita veličine 44nm, i najveću utvrdjenu vrednost mikronaprezanja, 0.638%. Produženje vremena boravka čestica u reakcionoj zoni dovodi do promene morfologije prahova, pri čemu je za čestice praha zone I karakteristično nastajanja punih čestica, glatke površine i homogenog sastava. Veličina primarnih kristalita odredjena na bazi strukturne difraktometrijske analize iznosi 33nm. Na bazi faktora okupiranosti katjonskih položaja u jediničnoj ćeliji spinela utvrdjeni odnos katjona Zn i Cr blizak je zadatoj vrednosti (0.5) i iznosi: 0.496 (prah zone I), 0.481 (prah zone II) i 0.518 (prah iz filtra), dok su nešto više vrednosti ovog odnosa dobijene na bazi EDS analize. Dodatni termički tretman prahova (2h,1000 0C), dovodi do stabilisanja spinelne faze sa odnosom Zn/Cr=0.52 uz izdvajanje ZnO (1,9 %mas.). Na osnovu analize termodinamički ostvarivih defekata u spinelu pokazano je da je favorizovani nastanak faze u kojoj egzistira višak Zn2+ jona posledica obrazovanja Cr4+ grupe defekata. Ostvarena morfologija čestica spinelne faze odgovara kristalnim formama za koje se modelom predvidjaju poboljšana senzorska svojstva. Razvoj faza i obrazovanje Bi1.8Pb0.2Sr2Ca2Cu3Ox (2223 faza) u postupku reakcionog raspršivanja rastvora nitrata ukupne koncentracije 1mol/dm3 praćen je sa aspekta modifikacije prekursora (2 %mas. uree), odnosno iniciranja egzotermne reakcije u kapi/ čestici. Pokazano je da proces kontrolisane hidrolize uz intenzivno oslobadjanje toplote dovodi do procesa termičke eksplozije kapi/čestice, što prividno ubrzava proces razlaganja nitrata zbog smanjenja zapremine u kojoj se reakcija odvija što ima za posledicu i promenu faznog sastava čestica. Morfologija čestica ostaje nepromenjena, te prah karakteriše prisustvo sferičnih čestica srednje veličine 140nm. Difraktometrijska analiza ukazuje na dobru kristaliničnost prahova, uz karakterističnu koegzistenziju ortorombične 2212 i tetragonalne 2223 faze, kao i prisustvo malih količina Sr14Cu24O41, Ca2PbO4 i Ca2CuO3. Sastav praha odredjen je na bazi semi-kvantitativne analize površine i definisan je stehiometrijom Bi1.9Sr1.56Ca2.23Cu3.18Ox. Za prah dobijen reakcionim raspršivanjem osnovnog prekursorskog rastvora nitrata karakteristično je prisustvo dve različite morfološke forme čestica, i to: submikronskih (400 nm) sferičnih čestica glatke površine, karakterističnih za proces reakcionog raspršivanja i čestica poligonalnog oblika čija dimenzija iznosi i do 15 m u pravcu duže ose. Po svom hemijskom sastavu čestice poligonalnog oblika odlikuje izuzetno visok sardžaj stroncijuma i kiseonika, i njihovo prisustvo u prahu je verovatno posledica nepotpunog rastvaranja polazne stroncijumove soli koja konverzijom u procesu sinteze daje čestice stroncijum oksida. Difraktometrijska analiza je potvrdila prisustvo SrO a nađeno je i par refleksija Sr(NO3)2. Po svom faznom sastavu prah je okarakterisan maksimalnim udelom 2212 faze, dok se 2223 faza i Ca2PbO4 u uzorku nalaze kao prateće faze. Na bazi semi-kvantitativne analize ukupnog uzorka definisana je stehiometrija Bi2.02Sr1.71Ca2.23Cu3.01Ox. Karakteristično in-situ obrazovanje 2223 faze u procesu sinteze reakcionim raspršivanjem kao i izostajanje stvaranja bizumutata tipa (Ca,Sr)-Bi-O omogućava olakšanu konverziju pratećih faza u 2223 fazu tokom dodatnog termičkog tretmana sintetisanih prahova. Dvočasovni tretman u kiseoniku pri 845 °C dovodi do promene stehiometrije čestica i ukazuje na značaj funikularnih i pendularnih stupnjeva aglomeracije u daljem procesu obrazovanja koherentnih struktura 2223 faze. Development of advanced materials, together with the efforts invested in the optimization of their current properties result today in the opening of a new field: design of ultra-fine structure materials. Nanostructured materials with new and improved properties could be prepared through different techniques. Investigations presented here are focused on conducted synthesis of nanostructured oxide powders in ZnCr2O4 and Bi1.8Pb0.2Sr2Ca2Cu3Ox systems using the spray pyrolysis method. The main emphasis is on controlled evolution of specific phases characterized with properties suitable for potential technical application. The strategy used is the result of methodology development from the viewpoint of establishing synthesis-structure-properties relations. Because of that, investigation of phase thermal stability, particle morphology - shape, size and agglomeration, crystal structure - grain boundary and defects concentration, homogeneity of chemical composition are of special interest. As a result of ZnCr2O4 powder conduction synthesis using spray pyrolysis of nitrate salts, spherical particles with uniform size around 470 nm are obtained. Synthesized dense particles are uniform in shape and posses small differences in crystallinity and stoichiometry. Effect of droplet/particle residence time on final powder morphology is established through investigation of precursor decomposition, nucleation and growth of primary crystallites in nanoporous precipitated particles. It was shown that increase of the residence time indicates growth of nanocrystallites with mean sizes around 40nm leading to dense particle evolution. Also, formation of a spinel phase with high homogeneity and uniformity of chemical composition in all produced samples are characterized with the cation ratio of Zn/Cr=0.68. Constant mismatching in stoichiometry from the assigned value, as well as additional changes in particle morphology after their thermal treatment at 1000 °C (2h) is the consequence of ZnO dissolution in a spinel cell and is explained by a model, which is based on computing of crystal surface formation energy and surfaces attachment energy. It was shown that the achieved particle morphology is predicted by a model as an unique surface structure which posses improved sensor and catalytic properties. Specific phase development in the Bi1.8Pb0.2Sr2Ca2Cu3Ox system synthesized through conducted spray pyrolysis process is estimated from the viewpoint of nitrate precursor modification due to in situ existence of a thermal source in every droplet. The effect of controlled hydrolysis as well as thermal explosion of droplets on 2223 phase formation is defined based on the investigation of salt precipitation and the decomposition process. Additional reduction in particle size from 400 to 140 nm and maintenance of structural and compositional homogeneity result in intensification of different phase conversions and orthorhombic 2223 phase formation. Coexistence of both, 2212 and 2223 phase is determined for all samples. Their further conversion is favorized due to the presence of liquid phase rich in Ca2+ and Cu3+ ions during additional thermal treatment in oxygen. Shortening of the time needed for vacancy distribution during orthogonal-tetragonal transition results in phase intercalation and formation of a 2223 phase richer in strontium content. Initial sintering and coherent phase development in thermally treated samples are related to the presence of funicular and pendulum agglomeration states. Establishing of conducted nanostructured oxide synthesis through spray pyrolysis process classify this method as one that is successful in production of advanced functional materials.
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- 2004
13. Mechanochemical synthesis of bismuth ferrite
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Marinković Stanojević, Zorica, Mančić, Lidija T, Srećković, Tatjana, Stojanović, Biljana D, Marinković Stanojević, Zorica, Mančić, Lidija T, Srećković, Tatjana, and Stojanović, Biljana D
- Abstract
A powder mixture of Bi2O3 and Fe2O3 was mechanically treated in a planetary ball mill in an air from 30 to 720 minutes. It was shown that the mechanochemical formation of BiFeO3 (BFO) phase was initiated after 60 min and its amount increased gradually with increasing milling time. A detailed XRPD structural analysis is realized by Rietveld's structure refinement method. The resulting lattice parameters, relative phase abundances, crystallite sizes and crystal lattice microstrains were determined as a function of milling time. Microstructural analysis showed a little difference in morphology of obtained powders. The primary particles, irregular in shape and smaller than 400 nm are observed clearly, although they have assembled together to form agglomerates with varying size and morphology. Dense BFO ceramics were prepared by conventional solid-state reaction at the temperature of 810oC for 1h followed immediately by quenching process.
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- 2013
14. Structural and magnetic properties of nanocrystalline bismuth manganite obtained by mechanochemical synthesis
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Marinković Stanojević, Zorica, Branković, Zorica, Jaglicic, Zvonko, Jagodic, M, Mančić, Lidija T, Bernik, Slavko, Recnik, Aleksander, Branković, Goran, Marinković Stanojević, Zorica, Branković, Zorica, Jaglicic, Zvonko, Jagodic, M, Mančić, Lidija T, Bernik, Slavko, Recnik, Aleksander, and Branković, Goran
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We have studied the formation of BiMnO3 (BMO) nanocrystalline perovskite powder produced by high-energy milling of the constituent oxides. The crystal structure and the amount of crystalline and amorphous phases in the powder as a function of the milling time were determined with XRPD using Rietveld refinement. BMO perovskite formed directly from highly activated nano-sized constituent oxides after 240 min of milling and subsequently grew during prolonged milling. The morphology, structure, and chemical composition of the powder were investigated by SEM and TEM. A clear ferromagnetic transition was observed at T (C) similar to 66 K for a sample milled for 240 min and increased with milling time. The magnetic hysteresis behavior is similar to that of a soft ferromagnet. The magnetic properties of the obtained BMO powders were found to change as a function of milling time in a manner consistent with variations in the nanocomposite microstructure.
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- 2011
15. Microstructural and electrical changes in nickel manganite powder induced by mechanical activation
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Savić, Slavica M., Mančić, Lidija T, Vojisavljević, Katarina, Stojanović, Goran M, Branković, Zorica, Aleksić, Obrad, Branković, Goran, Savić, Slavica M., Mančić, Lidija T, Vojisavljević, Katarina, Stojanović, Goran M, Branković, Zorica, Aleksić, Obrad, and Branković, Goran
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Nickel manganite powder synthesized by calcination of a stoichiometric mixture of manganese and nickel oxide was additionally mechanically activated in a high energy planetary ball mill for 5-60 min in order to obtain a pure NiMn2O4 phase. The as-prepared powders were uniaxially pressed into disc shape pellets and then sintered for 60 min at 1200 degrees C. Changes in the particle morphology induced by mechanical activation were monitored using scanning electron microscopy, while changes in powder structural characteristics were followed using X-ray powder diffraction. The ac impedance spectroscopy was performed on sintered nickel manganite samples at 25 degrees C, 50 degrees C and 80 degrees C. It was shown that mechanical activation intensifies transport processes causing a decrease in the average crystallites size, while longer activation times can lead to the formation of aggregates, defects and increase of lattice microstrains. The observed changes in microstructures were correlated with measured electrical properties in order to define optimal processing conditions.
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- 2011
16. Multiferroic bismuth manganite prepared by mechanochemical synthesis
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Branković, Zorica, Marinković Stanojević, Zorica, Mančić, Lidija T, Vukotić, Vesna M, Bernik, Slavko, Branković, Goran, Branković, Zorica, Marinković Stanojević, Zorica, Mančić, Lidija T, Vukotić, Vesna M, Bernik, Slavko, and Branković, Goran
- Abstract
Multiferroic bismuth manganite (BiMnO3) is known as a material that exhibits both ferromagnetic and ferroelectric properties making it interesting for various technological applications. Unfortunately, preparation of BiMnO3 is not possible by a conventional solid-state reaction and it can form only from mixture of oxides at high pressures (>40 kbar). In this work single-phased BiMnO3 was prepared for the first time by mechanochemical synthesis in a planetary ball mill. A mixture of Bi2O3 and Mn2O3 was intensively milled in air atmosphere, using stainless steel vials and balls. According to analysis of XPRD results BiMnO3 obtained after milling for 240 min has a tetragonal structure with lattice parameters a = 3.9230 angstrom, c = 3.920 angstrom and a crystallite size of 16.8 nm. The cumulative energy introduced into the system during milling for 240 min was 401 kJ/g. It was found that the obtained powders were agglomerated. Corresponding agglomeration factors were calculated from the results of BET and particle size distribution analysis.
- Published
- 2010
17. Infrared reflection spectroscopy of Zn2SnO4 thin films deposited on silica substrate by radio frequency magnetron sputtering
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Nikolić, Maria Vesna, Satoh, K., Ivetić, Tamara B., Paraskevopoulos, K.M., Zorba, T.T., Blagojević, V., Mančić, Lidija T, Nikolić, Pantelija M., Nikolić, Maria Vesna, Satoh, K., Ivetić, Tamara B., Paraskevopoulos, K.M., Zorba, T.T., Blagojević, V., Mančić, Lidija T, and Nikolić, Pantelija M.
- Abstract
Single-phase zinc-stannate thin films of different thickness values were prepared by radio frequency magnetron sputtering on a silica substrate. Rietveld analysis of X-ray diffraction data confirmed that the films had an inverse spinel structure, with a cation inversion parameter of 0.8. Room temperature far and mid infrared reflectivity spectra were measured in the range 50-4000 cm(-1). The reflectivity diagrams were analyzed using the four-parameter model of coupled oscillators for optical phonons with a standard multi-layer technique taking into account the thin-film layer and the substrate. The optical parameters were determined for seven oscillators belonging to the spinel structure. Their origin was discussed in relation to non-stoichiometry of the thin film and cation disorder in the crystal lattice. Bom effective charges were calculated from the transversal/ longitudinal splitting.
- Published
- 2008
18. Phase evolution in Ce-doped yttrium-aluminum-based particles derived from aerosol
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Mančić, Lidija T, Del, Rosario, G., Marinković Stanojević, Zorica, Milošević, Olivera, Mančić, Lidija T, Del, Rosario, G., Marinković Stanojević, Zorica, and Milošević, Olivera
- Abstract
The common nitrates precursor solution leading to the Y3Al5O12:Ce3+ (YAG:Ce) composition with 2 at.% of cerium, is ultrasonically atomised and introduced into the tubular flow reactor at 320 degrees C. Having in mind that extremely high heating rates and short residence time are associated with spray pyrolysis, the low temperature regime is used for aerosol decomposition for the production of segregation-free precursor powder that is additionally heated at 900 and 1000 degrees C (2-6h) for the purpose to determine the phase evolution. Formation of uniform and submicron-sized spherical particles with nano-clustered inner structure is proved by different analysing techniques (X-ray powder diffraction, scanning electron microscopy and energy dispersive spectroscopy). The effect of processing parameters and post-annealing treatment is discussed from the viewpoint of the targeted garnet phase formation.
- Published
- 2007
19. Microstructural characterization of mechanically activated ZnO-Cr2O3 system
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Marinković Stanojević, Zorica, Mančić, Lidija T, Vulić, Predrag, Milošević, Olivera, Marinković Stanojević, Zorica, Mančić, Lidija T, Vulić, Predrag, and Milošević, Olivera
- Abstract
An equimolar mixtures of starting ZnO and Cr2O3 powders were mechanically activated by grinding using a planetary ball mill for various periods of time (40-320min). Formation of nanocrystalline ZnCr2O4 as normal spine] structure at room temperature is detected in all samples-after ball-milling. A detailed XRD structural analysis (the relative phase abundances of different phases, lattice parameter changes, site occupancy, the average primary crystallite sizes, crystal lattice microstrains) is realized by the pattern decomposition technique, performed in accordance with the procedure based on Rietveld software KOALARIET-XFIT. Due to the importance of cation distribution on the chemical and physical properties of spinels, a study of site occupation factors of ZnCr2O4 spinels has been undertaken. The calculation based on the atomistic methods for the description of the perfect and defect spinel ZnCr2O4 crystal lattice is applied and the presence of the individual structural defects is determined.
- Published
- 2005
20. Dirigovana sinteza nanostrukturnih oksidnih prahova sa gledišta razvoja materijala zadatih svojstava
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Ristić, Momčilo, Minić, Dragica, Stojanović, Biljana, Adnađević, Borivoje, Blagojević, Nikola, Mančić, Lidija T., Ristić, Momčilo, Minić, Dragica, Stojanović, Biljana, Adnađević, Borivoje, Blagojević, Nikola, and Mančić, Lidija T.
- Abstract
Razvoj novih materijala, kao i nastojanja za iskorišćenjem njihovih tehnološki atraktivnih karakteristika doveli su do intenzivnije sinteze novih ultrafinih struktura i nanofaznih prahova. Istraživanja obuhvaćena radom fokusirana su na dirigovanu sintezu nanostrukturnih oksidnih prahova iz sistema koje odlikuje izrazita jonska (ZnCr2O4) i elektronska provodnost(Bi1.8Pb0.2Sr2Ca2Cu3Ox) primenom metode reakcionog raspršivanja. Akcenat je stavljen na nastanak faza koje su potencijalni nosioci svojstava značajnih za tehničku primenu materijala. Primenjena strategija rezultat je razvoja metode sa stanovišta definisanja odnosa u trijadi sinteza-struktura-svojstvo i izvodjenja procesa kontrolisane sinteze. Proces sinteze ZnCr2O4 praha izveden je u uslovima ultrazvučnog reakcionog raspršivanja rastvora nitrata koncentracije 0.03mol/dm3 pri unapred definisanim parametrima procesa i za različito vreme zadržavanja kapi/čestice na Tmax uz dodatan boravak u reakcionim zonama sa nižom temperaturom. Čestice nastaju procesom zapreminskom precipitacije, nukleacije, rasta kristala i obrazovanja primarnih nanočestica koje nisu u slobodnom stanju vec izgradjuju agregate sferičnog oblika i srednje veličine 470nm. Za prah iz filtra karakterističan je nastanak čestica ZnCr2O4 na čijoj se površini jasno uočavaju primarne čestice veličine nekoliko desetina nanometra. Strukturna analiza ovog praha pokazuje prisustvo primarnih kristalita veličine 44nm, i najveću utvrdjenu vrednost mikronaprezanja, 0.638%. Produženje vremena boravka čestica u reakcionoj zoni dovodi do promene morfologije prahova, pri čemu je za čestice praha zone I karakteristično nastajanja punih čestica, glatke površine i homogenog sastava. Veličina primarnih kristalita odredjena na bazi strukturne difraktometrijske analize iznosi 33nm. Na bazi faktora okupiranosti katjonskih položaja u jediničnoj ćeliji spinela utvrdjeni odnos katjona Zn i Cr blizak je zadatoj vrednosti (0.5) i iznosi: 0.496 (prah zone I), 0.481 (prah zone I, Development of advanced materials, together with the efforts invested in the optimization of their current properties result today in the opening of a new field: design of ultra-fine structure materials. Nanostructured materials with new and improved properties could be prepared through different techniques. Investigations presented here are focused on conducted synthesis of nanostructured oxide powders in ZnCr2O4 and Bi1.8Pb0.2Sr2Ca2Cu3Ox systems using the spray pyrolysis method. The main emphasis is on controlled evolution of specific phases characterized with properties suitable for potential technical application. The strategy used is the result of methodology development from the viewpoint of establishing synthesis-structure-properties relations. Because of that, investigation of phase thermal stability, particle morphology - shape, size and agglomeration, crystal structure - grain boundary and defects concentration, homogeneity of chemical composition are of special interest. As a result of ZnCr2O4 powder conduction synthesis using spray pyrolysis of nitrate salts, spherical particles with uniform size around 470 nm are obtained. Synthesized dense particles are uniform in shape and posses small differences in crystallinity and stoichiometry. Effect of droplet/particle residence time on final powder morphology is established through investigation of precursor decomposition, nucleation and growth of primary crystallites in nanoporous precipitated particles. It was shown that increase of the residence time indicates growth of nanocrystallites with mean sizes around 40nm leading to dense particle evolution. Also, formation of a spinel phase with high homogeneity and uniformity of chemical composition in all produced samples are characterized with the cation ratio of Zn/Cr=0.68. Constant mismatching in stoichiometry from the assigned value, as well as additional changes in particle morphology after their thermal treatment at 1000 °C (2h) is the consequence of ZnO d
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- 2004
21. The influence of mechanical activation on the stoichiometry and defect structure of a sintered ZnO-Cr2O3 system
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Marinković Stanojević, Zorica, Mančić, Lidija T, Vulić, P., Milošević, Olivera, Marinković Stanojević, Zorica, Mančić, Lidija T, Vulić, P., and Milošević, Olivera
- Abstract
Mixtures of starting ZnO and Cr2O3 powders in equimolar quantities were mechanically activated by grinding using a high energy vibro-mill for 0, 40 and 80 minutes. Qualitative X-ray diffraction analysis made after sintering at 900degreesC for 240 min showed the presence of a well-crystallized spinel-type phase, ZnCr2O4, in all examined samples. A detailed structural analysis of lattice parameters, average primary crystallite sizes, and crystal lattice microstrains was made by the pattern decomposition technique, performed in accordance with the procedure based on the KOALARIET-XFIT program. Due to importance of cation distributions for the chemical and physical properties of spinels, a study of site occupation factors of ZnCr2O4 spinels, i.e. changes in the stoichiometry, was conducted. Calculations based on atomistic methods for the simulation and description of perfect and defect spinel ZnCr2O4 crystal lattices were made, and the presence of individual structural defects was determined.
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- 2004
22. Nature of structural changes in LSM-YSZ nanocomposite material during thermal treatments
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Marinković Stanojević, Zorica, Mančić, Lidija T, Cribier, JF, Ohara, S, Fukui, T, Milošević, Olivera, Marinković Stanojević, Zorica, Mančić, Lidija T, Cribier, JF, Ohara, S, Fukui, T, and Milošević, Olivera
- Abstract
Nanocomposite powders in the system (La1-xSx)(a)MnO3-YSZ((1-y)) [LSM-YSZ], as an attractive cathode material for high operating solid oxide fuel cell (SOFC), were obtained through ultrasonic spray pyrolysis (1.7 MHz) method. The principle of the synthesis is based on a single-step high temperature aerosol decomposition of atomized precursor solutions composed from yttria stabilized ZrO2 sol (average particle size similar to 60 nm) and corresponding aqueous nitrate and hydrogen peroxide solutions of La, Sr and Mn. Two starting systems were examined: (a) (La0.76Sr0.24)(0.93)MnO3 with 0% YSZ, and (b) (La0.77Sr0.23)(0.92)MnO3-YSZ(0.81) with corresponding molar ratio LSM/YSZ = 48:52. X-ray diffraction analysis of as-prepared powders showed the presence of a lanthanum magnesium oxide and yttrium zirconium oxide. Compositional homogeneity and particle morphology were determined by SEM analysis. LSM-YSZ obtained particles are spherical in shape, submicron in size and composed of primary subgrains. TEM analysis of ultra-cross section revealed dense-packed nanosized grains, several tens of nanometers in diameter. After powders calcination TEM observations confirmed dense particle structure composed of primary grains, with a mean diameter of around 100 nm. The structural changes expressed through the crystallite growth were analyzed by nonisothermal differential scanning calorimetry (DSC).
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- 2004
23. The nature of structural changes in nanocrystalline ZnO powders under linear heating conditions
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Marinković Stanojević, Zorica, Mančić, Lidija T, Milošević, Olivera, Marinković Stanojević, Zorica, Mančić, Lidija T, and Milošević, Olivera
- Abstract
The nature of exothermal and irreversible structural changes observed during linear heating of nanocrystalline ZnO powders was investigated using differential scanning calorimetry, X ray, SEM and TEM analysis. Nanocrystalline ZnO powders were obtained by ultrasonic spray pyrolysis of 0.8 mol/dm(3) zinc nitrate solution and subsequent decomposition of 2.7 mum sized droplets in the temperature range up to 600 degreesC, F-air = 1.2 dm(3)/min. Produced particles are characterized by uniform and submicronic size, BET = 4.94 m(2)/g, high phase purity and granular or circular "open" surface as the consequence of primary crystallites presence with average size of d = 20 nm. The observed quasi nucleation-growth process during heating of this powder was discussed in the terms of primary crystallites structural changes.
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- 2004
24. Pyrosol preparation and structural characterization of SnO2 thin films
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Tucić, Aleksandar, Marinković Stanojević, Zorica, Mančić, Lidija T, Cilense, Mario, Milošević, Olivera, Tucić, Aleksandar, Marinković Stanojević, Zorica, Mančić, Lidija T, Cilense, Mario, and Milošević, Olivera
- Abstract
Polycrystalline tin oxide thin films were prepared from ethanol solution Of SnCl2.H2O (concentrations: 0.05, 0.1, 0.2 and 0.4 mol/dm(3)) at different substrate temperatures ranging from 300 to 450 degreesC. The kinetic deposition processes were studied in terms of various process parameters. The crystal phases, crystalline structure, grain size and surface morphology are revealed in accordance to X-ray diffractometry and scanning electron microscopy (SEM). Texture coefficients (TCs) for (110), (2 0 0), (2 11) and (3 0 1) reflections of the tetragonal SnO2 were calculated. Structural characteristics of deposited films with respect to varying precursor chemistry and substrate temperature are presented and discussed.
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- 2003
25. Synthesis of thin films by the pyrosol process [Sinteza prevlaka pirolizom]
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Tucić, Aleksandar, Branković, Goran, Marinković Stanojević, Zorica, Mančić, Lidija T, Milošević, Olivera, Tucić, Aleksandar, Branković, Goran, Marinković Stanojević, Zorica, Mančić, Lidija T, and Milošević, Olivera
- Abstract
Among many aerosol routes, the Pyrosol process, due to its simplicity, low cost and quality of obtained films, represents a promising technique for the synthesis of thin films. The pyrosol process is based on the transport and pyrolysis of an aerosol of processor solution, generated in an ultrasonic atomizer, on a heated substrate. The theoretical principles of the pyrosol process are presented in this paper, as well as the influence of some synthesis parameters on the deposition of SnO2 thin films.
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- 2002
26. Preparation of nanostructured Zn-Cr-O spinel powders by ultrasonic spray pyrolysis
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Marinković Stanojević, Zorica, Mančić, Lidija T, Maric, R, Milošević, Olivera, Marinković Stanojević, Zorica, Mančić, Lidija T, Maric, R, and Milošević, Olivera
- Abstract
Ultrasonic spray pyrolysis (1.7 MHz) has been applied for the generation of zinc chromium oxide submicronic (470 nm) particles from the corresponding metal nitrate solution. Heterogeneous gas-liquid/solid chemical reactions occurred in dispersed systems (aerosols) at 1173 K with the residence time ranging from 3 to 6 s. Such a synthesis method enables a high surface reaction and stoichiometric retention at the droplet scale that is of special importance when functional materials with sensing properties are considered. Consequently, homogeneous distributions of the constituting elements and zinc to chromium atomic ratio of about 0.7 are proved by EMAX analysis. The particle morphology, revealed mostly as a composite structure, comprised of primary crystallites smaller than 70 nm. The particle crystalline structure, phase content and decomposition behavior were analyzed in accordance with various methods of analysis (X-ray powder diffraction (XRD). differential scanning calorimetry (DSC). differential thermal analysis (DTA), scanning electron microscopy with X-ray microanalyser (SEM-EMAX)) and discussed in terms of precursor chemistry and process parameters.
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- 2001
27. Synthesis and characterization of the Me–HTSC composite
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Stanković, Zvonimir D, primary and Mančić, Lidija T, additional
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- 1997
- Full Text
- View/download PDF
28. Ultrasonic spray pyrolysis of surface modified TiO2 nanoparticles with dopamine.
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Dugandžić, Ivan M., Jovanović, Dragana J., Mančić, Lidija T., Milošević, Olivera B., Ahrenkiel, Scott P., Šaponjić, Zoran V., and Nedeljković, Jovan M.
- Subjects
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TITANIUM dioxide nanoparticles , *SPRAYING , *SURFACE chemistry , *DOPAMINE , *PYROLYSIS , *CHEMICAL preparations industry - Abstract
Abstract: Spherical, submicronic TiO2 powder particles were prepared in the low temperature process of ultrasonic spray pyrolysis (150 °C) by using as a precursor aqueous colloidal solutions consisting of surface modified 45 Å TiO2 nanoparticles with dopamine. Detailed structural and morphological characterization of colored submicronic TiO2 spheres was performed by X-ray powder diffraction (XRPD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), laser particle size analysis and FTIR techniques. Also, optical characterization of both dopamine-modified TiO2 precursor nanoparticles and submicronic TiO2 powder particles was performed using absorption and diffuse reflectance spectroscopy, respectively. A significant decrease of the effective band gap (1.9 eV) in dopamine-modified TiO2 nanoparticles compared to the band gap of bulk material (3.2 eV) was preserved after formation of submicronic TiO2 powder particles in the process of ultrasonic spray pyrolysis under mild experimental conditions. Due to the nanostructured nature, surface-modified assemblage of TiO2 nanoparticles preserved unique ability to absorb light through charge transfer complex by photoexcitation of the ligand-to-TiO2 band, conventionally associated with extremely small TiO2 nanoparticles (d < 20 nm) whose surface Ti atoms, owing to the large curvature, have penta-coordinate geometry. [Copyright &y& Elsevier]
- Published
- 2013
- Full Text
- View/download PDF
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