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The ubiquity of microplastics (MPs) in the various environment is of increasing concern. Although micro Fourier Transform Infrared Spectroscopy (μ-FTIR) represents an ideal method for the detection of MPs, this technique lacks a standardized mode to be followed for MPs in diverse environmental matrices. The study focused on the optimization, application, and validation of μ-FTIR techniques for the identification of smaller-sized MPs (20 μm-1 mm). In order to assess the validity of the various detection modes in μ-FTIR (reflection and transmission), a confirmatory test with known standard polymers, viz., polyethylene (PE), polypropylene (PP), polystyrene (PS), polyamide (PA), and polyvinyl chloride (PVC) were executed. Subsequently, for the validation and accuracy of the method, the polymer spectra of standard polymers acquired in μ-FTIR (smaller-sized) were compared with spectra of larger-sized particles (same standards) in FTIR-ATR (Attenuated Total Reflectance). The spectra were comparable and highlighted the similar pattern of the polymeric composition. The spectral quality and matching score (>60 %) with the reference library was taken into account to accentuate the authenticity of the different methods. This study highlighted the reflection mode (particularly diffuse reflection) as more effective for the quantification of smaller-sized MPs in complex environmental samples. The same method was successfully applied to a representative environmental sample (sand), supplied by the EURO-QCHARM for inter-laboratory study. Two polymers (PE and PET) were correctly identified out of three spiked polymers (PE, PET, and PS) in the given sample. Similarly, in terms of matching algorithms, the results for diffuse reflection (PE-71.7 % and PET-89.1 %) were found satisfactory as compared to micro-ATR (PE-67 % and PET-63.2 %) reflection mode. Overall, this study illustrates an extensive perspective of different μ-FTIR techniques, recommending the most reliable, easy, and non-destructive method to unambiguously characterize diverse types of polymers of smaller MPs in complex environmental matrices.

Microplastics (MPs) are ubiquitous in the marine environment, yet information regarding their occurrence in the food web is limited. We investigated the concentration and composition of MPs in water and diverse zooplankton groups from the Arabian Sea basin. Forty-one zooplankton tows were collected with a bongo net (330 μm mesh) from the Arabian Sea in January 2019. MPs in the surface water varied between 0 and 0.055 particles/m

Due to the increasing concerns on global ecosystems and human health, the environmental risks posed by microplastics (MPs) and nanoplastics (NPs) have become an important topic of research. Their ecological impacts on various faunal species have been extensively researched and reviewed. However, the majority of those studies perceive these micro(nano)-plastics (MNPs) as a single entity rather than a collective term for a group of chemically distinct polymeric particulates. Each of the plastic polymers can possess unique physical and chemical behavior, which, in turn, can determine the possible environmental impacts. Furthermore, many studies explore the adsorption, absorption, and release of other environmental pollutants by MNPs. But only a handful of them explore the leaching of additives possessed by these polymers. Data on the environmental behavior and toxicity of individual additives associated with different polymer particulates are scarce. Knowledge about the leachability and ecotoxicity of the additives associated with environmental MNPs (unlike large plastic particles) remains limited. The ecological impacts of different MNPs together with their additives and the basis of their toxicity have not been explored yet. The present review systematically explores the potential implications of environmentally predominant polymers and their associated additives and discusses their physicochemical characteristics. The review ultimately aims to provide novel insights on what components precisely make MNPs hazardous to the fauna. The paper also discusses the major challenges proposed in the available literature along with recommendations for future research to throw light on possible solutions to overcome the hazards of MNPs.

This paper characterize microplastics (MPs) in the heavily urbanized, brackish water Vembanad Lake (India), focussing on some commercially important bottom-feeding fishes and shellfish (Arius maculatus, Etroplus suratensis, E. maculatus and Villorita sp.). The average abundance of MPs was higher in the water column (872 ± 573 nos./m3) than in finfishes (15 ± 13 particles per fish) and shellfish (23 ± 20 nos./ind.). Fibre was the most abundant MP type in the water and the organisms examined. The size of MPs obtained from finfishes ranged between 0.04 and 4.73 mm (4 ± 3 mm), with a majority of particles being

International audience; Polybrominated diphenyl ethers (PBDEs) were measured in plastic resin pellets collected from 65 beaches across 27 countries worldwide. They were detected at 49 locations at concentrations of the sum of 49 congeners of up to 46 ng/g-pellet and a median of 2 ng/g-pellet. These values are one to two orders of magnitude lower than those of polychlorinated biphenyls (PCBs) (median, 51 ng/g-pellet). This difference can be attributed to lower production of the Penta-BDE technical mixture, which is used extensively in some countries, and lower availability of brominated flame retardants for equilibrium partitioning than PCBs. Tetra-, penta-, and hexa-brominated congeners (BDE-47, 99, 100, 153, 154) were dominant over a deca-substituted congener (BDE-209) in many samples; this was significantly detected in pellets from some locations. Results indicate that pellets reflect the pollution status of PBDEs in the dissolved phase in seawater. From the ranking of the summed concentrations of six major PBDE congeners (Σ6PBDEs), we propose five levels of pollution categorization (ng/g-pellet): no (8.5) local pollution. The USA and neighboring countries were categorized as extreme (17–36 ng/g-pellet), western Europe and Japan were categorized as high (≤8.8), and most Asian and African countries were categorized as slight (

The versatile use of various synthetic polymers, including plastics, generates a large volume of non-degradable waste, which is eventually responsible for forming microplastics (MPs) in aquatic environments. The present study describes the significant spatial and seasonal variation on the abundance of MPs and their physiochemical nature along the Mandovi-Zuari estuarine system of Goa, west coast of India. During the wet season (September), the average abundance of MPs was found relatively higher in water (0.107 particles/m3) and sediment (7314 particles/kg) than those found in the dry season (April) (0.099 particles/m3 in water and 4873 particles/kg in sediment). During the wet season, heavy rain and excessive riverine freshwater influx carry more terrestrial plastic debris in the estuarine system which causes higher averages MPs density in surface water and sediment.

Accumulation of plastic litter exerts pressure on the environment. Microplastics (MPs) pollution has become a universal challenge due to the overexploitation of plastic products and unsystematic dumping of plastic waste. Initial studies on MPs and their implications had been confined to aquatic and terrestrial ecosystems, but recent research has also focused on MPs in the air. Their impacts on urban air quality and atmospheric transport to pristine habitats have emerged to be a serious concern. However, the extent and the significance of impacts of airborne particulate matter (PM) MPs on human health are not clearly understood. Further, the influence of airborne MPs on indoor and outdoor air quality remains unknown. We highlight the human health impacts of airborne PM-MPs with a special focus on the occupational safety of the industry workers, their possible influence on Air Quality Index (AQI), their potential exposure, and accumulation in the canopy/arboreal, above-canopy and atmospheric (aerial) habitats. The present review emphasizes the data limitations and knowledge gaps on the atmospheric transport and contribution of particulate plastics to the worsening of overall urban air quality and throws critical perspectives on whether atmospheric MPs pollution is trivial or an actual matter of concern.

The most prevalent pollutant, polycyclic aromatic hydrocarbons (PAHs) is now plenteously distributed in the global atmosphere. We recently quantified 36 polycyclic aromatic hydrocarbons (PAHs) associated with aerosols (particulate matter: PM) in five Asian cities: Tokyo (Japan), Beijing (China), Kolkata (India), Hanoi (Vietnam), and Kuala Lumpur (Malaysia). Average atmospheric PAH concentrations (Σ12 PAHs-ng m^(–3)) increased in the order of Kuala Lumpur (2.99) ≈ Tokyo (3.95) ＜ Hanoi (7.99) ＜＜ Kolkata (63.5) ＜＜ Beijing (142.8). The most abundant PAHs in PM samples in these cities were chrysene, benz[a]anthracene, benzofluoranthenes, benzo[a]pyrene, and benzo[e]pyrene. We used the PAH compositions, especially the relative abundances of alkylated PAHs, and hopanes to determine vehicle exhaust-derived PAHs, and levoglucosan as a tracer for biomass burning, especially from wood combustion. Vehicle exhaust contributed to atmospheric PAHs in all cities, indicated by higher ratios of (C_(30)17α)/total PAHs and MPAHs/PAHs than coal and wood combustion products. Coal combustion contributed also in winter aerosols in Beijing, indicated by higher abundance of β isomers i.e., 17β21β (H)-C30hopane (C_(30)17β) and 17β21β (H)-C_(29)hopane (C_(29)17β) signifying mass use of coal for heating. The ratio of levoglucosan/PAHs was high in Kuala Lumpur and Hanoi, suggesting greater inputs of PAHs from biomass burning there.

The present study exhibits the occurrence of MPs in different matrices (water, sediment and biota) from the Sal estuary, Goa, situated on the central west coast of India. The average numbers of MPs in the water column and sediment were 48 ± 19 MP particles/L (MPs/L) and 3950 ± 930 MP particles/kg (MPs/kg), respectively. In shellfish (whole soft tissue), the average concentrations of MPs were 4 ± 2 (Crassostrea sp.), 3.2 ± 1.8 (Perna viridis) and 0.7 ± 0.3 (Paphia malbarica) MPs/g body weight (bw), respectively. The highest MPs were recorded in finfish (gastro-intestinal tract) (Mugil cephalus)7.8 ± 4, followed by (Gerres filamentosus) 5.3 ± 4.9, (Arius jella) 4.6 ± 2.6, and (Etroplus suratensis)1.4 ± 0.3 MP/g bw. MP fibres were predominant in all matrices. Interestingly, a dominance of small sized (10–300 μm) MPs was recorded in biota. Among the 37 polymer types identified by μ-FTIR, the most prevalent ones were, polyacrylamide (PAM) , polyacetylene, ethylene vinyl alcohol (EVOH), polyvinyl chloride (PVC) and polyamide (nylon). Notably, the polymers dominant in the gut of finfish and in whole shellfish were equally prominent in sediment and the water column. This study highlights the presence of MPs in commercially important shellfish and finfish samples from the Sal estuary. This study clearly shows the presence of MPs in various types of marine organisms in the Sal estuary. As shellfish is locally consumed as a delicacy and plays a major role in the seafood industry, the MPs may pose a hazard for human health. There is also an ecological risk as MPs are also found in water and sediment and in the digestive tract of finfish.

Considering the magnitude of pollution caused by marine plastics, the present study assessed their abundance, distribution, surface morphology and polymer type in ten sandy beaches spread across three states (Maharashtra, Karnataka and Goa) along the west coast of India (WCI). The total abundance of plastics (∼1–100 mm) in the studied beaches ranged from 4.1 to 23.4% (19±1–346 ± 2 items/m2). Location-wise, the abundances of both micro (43.6 ± 1.1–346 ± 2 items/m2) and macroplastics (21.6±3–195 ± 6 items/m2) were relatively higher in beaches along the Maharashtra coast. Surface morphology-wise, fragments were predominantly abundant in both micro (76±2–346 ± 2 items/m2) and macroplastics (50.6 ± 1.5–195 ± 6 items/m2) followed by pellets (43.3 ± 2.5–245.6 ± 2 items/m2). Fourier-transform infrared spectroscopy (FT-IR) analysis of plastics revealed a dominance of polyethylene (PE) followed by polypropylene (PP). IR spectra of the collected plastics at absorption band at 1750–1700 cm−1 reflect minimal surface oxidation. White-colored plastics were observed most frequently, followed by pale-yellow, dark-brown, green, blue, transparent and red. A short-term (72 h) experimental study to assess the toxicity of PE microbeads (∼1 mm) in a commercially important shrimp species, Litopenaeus vannamei revealed toxicological changes. An elevated level of lipid peroxidation (LPX)—the tagged biochemical marker, was recorded only at the maximum dose (0.15 mg/L) of PE microbeads. A moderate increase in the levels of enzymatic antioxidants (catalase and glutathione S-transferase) was also recorded at the same dose. Comprehensive information on marine plastics, including ecotoxicity provided in this study, would help in evolving strategies in minimizing plastic pollution along the WCI.

In June 2016, a cruise vessel was grounded in the Mormugao Port, resulting in unnoticed oil spill. The surface water and sediment samples were collected from the vicinity of the ship, and also an oil sample from the ship (OIL). These samples were subject to petroleum biomarker such as pentacyclic triterpenes (hopanes) and compound specific carbon isotopic (?13C) analyses to assess the source of hydrocarbon pollution in the Mormugao Port. While no clear trend was observed in water samples, the bottom surface sediments did show an identical pattern of hopanes with the oil. The chemometric analyses of hopane Diagnostic Ratios (DRs) and ?13C ratios confirmed the ship oil as the source of oil pollution in sediments. Whereas the water is comparatively more dynamic than the sediment, the physical processes arising out of winds, waves, tides and currents might have dispersed the oil away from the grounded ship. - 2019 Elsevier Ltd We thank the Director, CSIR-NIO, Goa, for his constant support and interest in this study. We thank the Goa State Pollution Control Board for funding this project. Thanks to the GSPCB officials for their kind support during sample collection. Thanks to Dr Aninda Mazumdar and Dr Siby Kurian for providing ASE and Sample concentrator facilities. We also thank Sonam and Adarsh for their assistance during sample processing. This is CSIR-NIO contribution number 6400. Appendix A Scopus

Following the Fukushima Dai-ichi Nuclear Power Station accident, regional road dust, heavily contaminated with radiocesium, now represents a potential source of radiocesium pollution in river water. To promote effective countermeasures for reducing the risk from radiocesium pollution, it is important to understand its sources. This study evaluated the utility of metals, including Al, Fe, and Zn as road dust tracers, and applied them to analyze sources of 137Cs in rivers around Fukushima during wet weather. Concentrations of Zn in road dust were higher than agricultural and forest soils, whereas concentrations of Fe and Al were the opposite. Concentrations of Zn were weakly but significantly correlated with benzothiazole, a molecular marker of tires, indicating Zn represents an effective tracer of road dust. Al, Fe, and Zn were frequently detected in suspended solids in river water during wet weather. Distribution coefficients of these metals and 137Cs exceeded 104, suggesting sorptive behavior in water. Although concentrations of Al, Fe, Zn, and 137Cs were higher in fine fractions of road dust and soils than in coarse fractions, use of ratios of 137Cs to Al, Fe, or Zn showed smaller differences among size fractions. The results demonstrate that combinations of these metals and 137Cs are useful for analyzing sources of radiocesium in water. These ratios in river water during wet weather were found to be comparable with or lower than during dry weather and were closer to soils than road dust, suggesting a limited contribution from road dust to radiocesium pollution in river water.

Oil pollution in the marine environment is an unavoidable problem due to chronic input from local sources, particularly in urban areas and oil spills. Oil pollution not only causes immediate physical damages to surrounding wildlife but also some components, including higher molecular weight PAHs, can persist in the environment for many years and pose insidious threats to the ecosystem. Long-term and nontargeted monitoring of oil pollution is important. This paper examines the ability of International Pellet Watch (IPW) for initial identification and monitoring of oil pollution by analysing PAHs and hopanes in plastic pellet samples collected globally by volunteers. PAH concentrations with the sum of 28 parent and methyl PAHs vary geographically, ranging from 0.035 to 24.4 µg/g-pellet, in line with the presence or absence of local oil pollution sources, such as oil refineries or oil spill sites. This suggests that PAHs can be used to monitor petroleum pollution in IPW. A colour-coded categorization for PAH concentrations within IPW monitoring also is established to facilitate data presentation and understanding. PAH concentrations are generally higher in Western Europe, especially around the North Sea shorelines, moderate in East Asia and North America, and lower in South East Asia, Oceania, South America, and Africa. Hopane concentrations, with a smaller spatial variation (1.7–101 µg/g-pellet), showed no spatial pattern. This result and the poor correlation between hopanes and PAHs suggest that hopane concentrations alone are unsuited to identify petroleum pollution. However, hopane compositions can be used for fingerprinting sources of oil pollution. Thus, both PAHs and hopanes in IPW allow for low cost, remote monitoring of global oil pollution.

Seven sulfonamides, trimethoprim, five macrolides, lincomycin and three tetracyclines were measured in 150 water samples of sewage, livestock and aquaculture wastewater, and river and coastal waters, in five tropical Asian countries. The sum of the concentrations of the target antibiotics in sewage and heavily sewage-impacted waters were at sub- to low-ppb levels. The most abundant antibiotic was sulfamethoxazole (SMX), followed by lincomycin and sulfathiazole. The average concentration of SMX in sewage or heavily sewage-impacted waters was 1720 ng/L in Vietnam (Hanoi, Ho Chi Minh, Can Tho; n=15), 802ng/L in the Philippines (Manila; n=4), 538 ng/L in India (Kolkata; n=4), 282 ng/L in Indonesia (Jakarta; n=10), and 76 ng/L in Malaysia (Kuala Lumpur; n=6). These concentrations were higher than those in Japan, China, Europe, the US and Canada. A predominance of sulfonamides, especially SMX, is notable in these tropical countries. The higher average concentrations, and the predominance of SMX, can be ascribed to the lower cost of the antibiotics. Both the concentration and composition of antibiotics in livestock and aquaculture wastewater varied widely. In many cases, sulfamethazine (SMT), oxytetracycline (OTC), lincomycin, and SMX were predominant in livestock and aquaculture wastewater. Both human and animal antibiotics were widely distributed in the respective receiving waters (i.e., the Mekong River and Manila Bay). SMT/SMX ratios indicate a significant contribution from livestock wastewater to the Mekong River and nearby canals, with an estimated ~10% of river water SMX derived from such wastewater. Mass flow calculations estimate that 12 tons of SMX is discharged annually from the Mekong River into the South China Sea. Riverine inputs of antibiotics may significantly increase the concentration of such antibiotics in the coastal waters.

Microplastic pellets (MPPs) are ubiquitous contaminants, recognised as a serious threat to the biota in coastal, estuarine and marine environment. The distribution, abundance, weathering and chemical characteristics of MPPs on the beaches of Goa, and their transport to the coast during the southwest (SW) monsoon are discussed in this paper. MPP samples collected from six sandy beaches were categorised based on colour and polymer types using Stereoscope microscope and FTIR-ATR spectroscopy, respectively. White colour MPPs were the most abundant, and Polyethylene (PE) and Polypropylene (PP) were the dominant polymer types of MPPs deposited on all the beaches. Carbonyl index values showed that MPPs collected in June 2015 (representing SW monsoon) were ‘new’, whereas the MPPs collected in January 2015 were ‘aged’, showing that MPPs are arriving at Goa coast only during SW monsoon due to conducive hydrodynamic conditions. Characteristics of MPPs suggest that they could be originated primarily from ocean-based sources. The winds and surface currents during SW monsoon are the driving forces for the transportation and deposition of MPPs on the Goa beaches. The results of this study will be useful to the National ‘Clean India’ program for effective plastic debris removal management.

Made available in DSpace on 2018-12-11T16:41:34Z (GMT). No. of bitstreams: 0 Previous issue date: 2016-01-01 Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq) High spatial variability in polycyclic aromatic hydrocarbons (PAHs), polychlorinated biphenyls (PCBs), organochlorine pesticides, such as DDTs, and polybrominated diphenylethers was observed in plastic pellets collected randomly from 41 beaches (15 cities) in 2010 from the coast of state of São Paulo, southeastern Brazil. The highest concentrations ranged, in ng g-1, from 192 to 13,708, 3.41 to 7554 and

The utility of ginkgo leaves as biomonitors of airborne polycyclic aromatic hydrocarbons (PAHs) was evaluated. We investigated PAH concentrations among tree species, the effect of variations in leaf position in a tree, tissue distributions, correlations between ginkgo leaves and air, and seasonal variations. Among the five species examined ( Ginkgo biloba L., Zelkova serrata Makino, Liriodendron tulipifera L., Prunus yedoensis Matsum, and Magnolia kobus DC.), ginkgo accumulated the greatest amount of PAHs from roadside air. Most PAHs (∼80%) were accumulated in the wax fraction, and most of the remainder (17%) penetrated the inner tissues of the leaves. PAH concentrations in ginkgo leaves decreased with increasing height and distance from the road, reflecting the derivation of PAHs from vehicle emissions. Seasonal time-series sampling showed that PAH concentrations in ginkgo leaves increased with time, attributable to the effects of temperature and accumulation through long-term exposure. Concentrations in ginkgo leaves collected from various roads showed a strong and significant correlation with those in air collected by a high-volume air sampler ( r 2 = 0.68, P

Various source materials such as crude oil, automobile exhaust, coal, and wood combustion products were analyzed for polycyclic aromatic hydrocarbons (PAHs) and hopanes. Hopanes were detected in coal combustion-derived soot, along with petrogenic sources. Based on the correlation between the alkylated PAHs/parental PAHs ratio with their respective C30 hopane/PAHs ratio in these source materials, the criteria for differentiating the petrogenic and pyrogenic sources of PAHs were established. This study concluded that sediments contained exclusively pyrogenic PAHs when the following conditions were met: MP/P (methylphenanthrenes to phenanthrene) = 0.5, MPy/Py [(methylpyrenes + methylfluoranthenes) to (pyrene + fluoranthene)] = 0.15, and MC/C [(methylchrysenes + methylbenz[a]anthracenes) to (chrysene + benz[a]anthracene)] = 0.2. By contrast, the sediments contained exclusively petrogenic PAHs when the ratios of MP/P, MPy/Py, MC/C, and methyl PAHs (MPAHs)/PAHs exceeded 3.5, 1.5, 2.0, and 2.2, respectively. Bas...

Perfluorinated surfactants (PFSs) in Asian freshwater fish species were analyzed to investigate tissue distribution, temporal trends, extent of pollution, and level of PFS exposure through food intake. Freshwater fish species, namely carp, snakehead, and catfish, were collected in Japan, Vietnam, India, Malaysia, and Thailand, and 10 PFSs, including perfluorooctanesulfonate (PFOS) and perfluorooctanoate, were analyzed by liquid chromatography–tandem mass spectrometry. PFSs in carp in Tokyo were more concentrated in kidneys (Σ10 PFSs = 257 ± 95 ng/g wet weight [ww]) and livers (119 ± 36 ng/g ww) than in ovaries (43 ± 2 ng/g ww) and muscles (24 ± 17 ng/g ww). Concentrations of PFOS and its precursor, perfluorooctane sulfonamide, in livers of carp and in waters in Tokyo showed a dramatic decrease during the last decade, probably because of 3 M’s phasing-out of the manufacture of perfluorooctanesulfonyl-fluoride-based products in 2000. In contrast, continuing contamination by long-chain perfluorocarboxylates (PFCAs) with ≥ 9 fluorinated carbons was seen in multiple media, suggesting that these compounds continue to be emitted. PFS concentrations in freshwater fish species in tropical Asian countries were generally lower than those in developed countries, such as Japan, e.g., for PFOS in muscle, Vietnam < 0.05–0.3 ng/g ww; India < 0.05–0.2 ng/g ww; Malaysia < 0.05–0.2 ng/g ww; Thailand < 0.05 ng/g ww; and Japan (Tokyo) = 5.1–22 ng/g ww. Daily intake of short-chain PFCAs with ≤ 8 fluorinated carbons from freshwater fish species in Japan was approximately one order of magnitude lower than that from drinking water, whereas daily intake of PFOS and long-chain PFCAs with ≥ 9 fluorinated carbons from freshwater fish species was comparable with or greater than that from drinking water. Because the risk posed by exposure to these compounds through intake of fish species is a matter of concern, we recommend the continued monitoring of PFS levels in Asian developing countries.

Plastics debris in the marine environment, including resin pellets, fragments and microscopic plastic fragments, contain organic contaminants, including polychlorinated biphenyls (PCBs), polycyclic aromatic hydrocarbons, petroleum hydrocarbons, organochlorine pesticides (2,2′-bis( p- chlorophenyl)-1,1,1-trichloroethane, hexachlorinated hexanes), polybrominated diphenylethers, alkylphenols and bisphenol A, at concentrations from sub ng g –1 to µg g –1 . Some of these compounds are added during plastics manufacture, while others adsorb from the surrounding seawater. Concentrations of hydrophobic contaminants adsorbed on plastics showed distinct spatial variations reflecting global pollution patterns. Model calculations and experimental observations consistently show that polyethylene accumulates more organic contaminants than other plastics such as polypropylene and polyvinyl chloride. Both a mathematical model using equilibrium partitioning and experimental data have demonstrated the transfer of contaminants from plastic to organisms. A feeding experiment indicated that PCBs could transfer from contaminated plastics to streaked shearwater chicks. Plasticizers, other plastics additives and constitutional monomers also present potential threats in terrestrial environments because they can leach from waste disposal sites into groundwater and/or surface waters. Leaching and degradation of plasticizers and polymers are complex phenomena dependent on environmental conditions in the landfill and the chemical properties of each additive. Bisphenol A concentrations in leachates from municipal waste disposal sites in tropical Asia ranged from sub µg l –1 to mg l –1 and were correlated with the level of economic development.

The lower tidal stretch of the river Ganges, known as Hugli (ca. 280 km), flows southward before entering the Bay of Bengal forming a vast mangrove-enriched estuarine delta called Sunderbans. Hugli estuary is a typical example of tide-dominated sink for contaminants from multifarious sources. This major important river is subjected to anthropogenic stress due to the socio-economic importance of these areas based on growth of industry, agriculture, aquaculture, port activities, fishing and tourism. The living resources have been degraded recently due to increases in population pressure, pollution and natural resource consumption to the extent of overexploitation. The present paper critically examines the physicochemical characteristics and level of dissolved heavy metals at three ecologically distinct zones along the course of the river – Babughat located in the eastern part of the metropolitan megacity Calcutta (140 km upstream from seaface), Diamond Harbor (70 km upstream from sea face) and Gangasagar positioned at the mouth of the Ganges estuary. Physicochemical characteristics of this partially mixed estuary are largely influenced by the interaction of seawater and discharge of riverine freshwater, annual precipitation and surface runoff. The levels of salinity, total dissolved solids, hardness and conductivity showed an increasing downward trend. Marked increase in biochemical oxygen demand (BOD) values (2.20–5.95 mg/l) was recorded in Babughat whereas correspondingly low values (0.75–2.82 mg/l) were noticed at Gangasagar. This can be attributed mainly due to huge organic load of untreated sewage from the twin city Howrah and Calcutta situated in the east and west of the river. Spatiotemporal distribution of heavy metals reveals a wide range of variations reflecting input of huge anthropogenic inputs associated with a number of physical and chemical processes. Levels of metals registered a seasonal pattern, with an increase during late monsoon months (September–October), a period characterized by low salinity and relatively low pH of the water. Elevated levels of dissolved Hg and Pb were also recorded in Babughat, with values ranging from 0.16 to 0.95 μg/ml and 0.017 to 0.076 μg/ml, respectively, this high values for Hg can be attributed to the discharge from pulp and paper manufacturing units and to atmospheric input and runoff of automobile emission for Pb. It was revealed that the socio-economic development of Calcutta, the most potential economic zone in India situated on the east bank of Hugli river, has had a significant impact on the water quality of this major river. The deterioration of water quality is directly related to nonfunctioning and malfunctioning of wastewater treatment plants and lack of environmental planning and coordination. To restore the ecological stability and economic vitality of this river, the following measures have been suggested: (i) strong vigilance programme is to be undertaken towards installation and maintenance of the wastewater treatment plants to check the flow of persistent contaminants in the river water and (ii) execution of legislation and mass awareness programmes are to be enacted to restore the sound health of the river. The authors urge that environmental education should be used as an effective tool for water resource management dealing with intricate and complex problems in the interaction between nature, technology and human beings.

The coastal environment of West Bengal, recognized as the most diversified and productive ecosystem among all the maritime states of India, faces organic pollution from domestic sewage and urban and industrial effluents leading serious impacts on biota. The present paper aims at providing information on concentration level of heavy metals among the tissues of benthic polychaetes, bivalve molluscs and finfishes collected from Sundarban mangrove wetland, northeast coast of India. An overall common trend in bioaccumulation was revealed with the following decreasing order: Zn>Mn>Cu>Cr>Se>Hg with few exceptions. Both species dependent variability and temporal variations were pronounced. A high degree of organ specificity was evident in the bivalves where gill and mantle exhibited higher metal accumulation due to ion exchange property of the mucous layer covering these organs. Variability between closely related species is a reflection of different uptake rates, physiology and impact of environmental factors. The results of this analysis suggest that mollusks can play a significant role in trace metal trophic transfer studies, especially as their representatives are intertidally and subtidally ubiquitous. Keywords: Heavy metal, Body concentrations, Marine biota, Sunderban mangrove complex

Detailed analyses of persistent organic pollutants (POPs) such as hexachlorocyclohexane (HCH) isomers (HCHs), dichlorodiphenyltrichloro ethane (DDT) and its metabolites (DDTs), hexachlorobenzene (HCB) and congeners of polychlorinated biphenyls (PCBs) and polycyclic aromatic hydrocarbons (PAHs) in surface sediments from the coastal estuarine environment of West Bengal, northeast India allowed the evaluation of the contamination status, distribution and possible pollution sources. HCH, DDT, HCB, PCB and PAH were identified compounds in all the samples, whereas the concentrations of chlorinated pesticides (trans-eptachlorepoxide, dieldrin, endrin, metaoxychlor and mirex) were below the detection limits and were not of great concern. The pesticides did demonstrate markedly different distributions reflecting different agricultural and domestic usage in the region. The range of concentrations of HCH, HCB, DDT and PCBs in the sediments were 0.11–0.40

The present paper is the first document of a detailed geochemical and mineralogical study of estuarine sediments (0-5 cm, of 30% as reflected from XRD patterns) whereas, the labile sodic and potassic feldspar species (albite and microcline) are quite inconsistent at different stations. Albite is present in the range 30%. Microcline was either not detected or present from about 5-10%. The flaky mica group of minerals is also inconsistent in patterns but the content is higher than found for albite. Chlorite group of minerals is present in all sediments from

We analyzed polychlorinated biphenyls (PCBs), dichlorodiphenyl dichloroethane and its metabolites, hexachlorocyclohexanes (HCHs), polycyclic aromatic hydrocarbons (PAHs), and hopanes, in plastic resin pellets collected from nine locations along the Portuguese coast. Concentrations of a sum of 13 PCBs were one order of magnitude higher in two major cities (Porto: 307. ng/g-pellet; Lisboa: 273. ng/g-pellet) than in the seven rural sites. Lower chlorinated congeners were more abundant in the rural sites than in the cities, suggesting atmospheric dispersion. At most of the locations, PAH concentrations (sum of 33 PAH species) were ∼100 to ∼300. ng/g-pellet; however, three orders of magnitude higher concentrations of PAHs, with a petrogenic signature, were detected at a small city (Sines). Hopanes were detected in the pellets at all locations. This study demonstrated that multiple sample locations, including locations in both urban and remote areas, are necessary for country-scale pellet watch. This research was financially supported by Mitsui and Co. Ltd., Environment Fund for their financial support (Project R11-G4-1053) and Grants-in-Aid from the Ministry of Education and Culture of Japan (Project No. 22254001). We also appreciate to be supported by Fundação para a Ciência e Tecnologia, Portugal for their financial support through the project POIZON reference PTDC/MAR/102677/2008 and fellowship reference SFRH/BD/74772/2010. published

Polybrominated diphenyl ethers (PBDEs) are extensively used as flame retardants in many consumer products, and leachates from landfills have been identified as one of the possible sources of PBDEs in the environment. Meanwhile, the unprecedented economic and population growths of some Asian countries over the last decade have led to significant increases in the amount of waste containing PBDEs in that region. This study investigates the status of PBDEs in leachates from municipal solid waste dumping sites (MSWDS) in tropical Asian countries. A total of 46 PBDE congeners were measured, both in the adsorbed (n = 24) and dissolved (n = 16) phases, in leachate samples collected, from 2002 to 2010, from ten MSWDS distributed among the eight countries of Lao PDR, Cambodia, Vietnam, India, Indonesia, Thailand, the Philippines, and Malaysia. PBDEs were predominantly found in the adsorbed phase. Partitioning of PBDEs in the dissolved phase was associated with the presence of dissolved organic matter; the apparent organic carbon-normalized partition coefficients (K′oc) of the BDE congeners were lower by two to four orders of magnitude than the K oc predicted from the octanol–water partition coefficients (K ow). The total PBDE concentrations from mono- to deca-BDEs ranged from 3.7 to 133,000 ng/L, and showed a trend toward higher concentrations in the more populous and industrialized Asian countries. The congener profiles in the leachates basically reflected the composition of PBDE technical mixtures. The occurrence of congeners not contained, or in trace concentrations, in technical products (e.g., BDEs 208, 207, 206, 202, 188, 179, 49, 17/25, 8, 1) was observed in most of the leachate samples, suggesting the debromination of technical mixtures, including BDE-209, in the MSWDS of tropical Asian countries. Moreover, the temporal trend indicated the reduction of BDE-209 over time, with a corresponding increase in and/or emergence of lower brominated PBDE congeners. The results indicated that MSWDS of tropical Asian countries are potential sources of environmental PBDEs, which may be transported to the aquatic environment via dissolution with dissolved organic matter. MSWDS could be amplifiers of PBDE toxicity in the environment, possibly through debromination.

We determined concentrations of polycyclic aromatic hydrocarbons (PAHs), polychlorinated biphenyls (PCBs), linear alkylbenzenes (LABs), and hopanes in coastal sediments collected from Jakarta Bay and Tokyo Bay. PAH concentrations in sediments from Jakarta Bay (257-1511 ng/g-dry) were lower than or comparable to those from Tokyo Bay (1372-1615 ng/g-dry). Ratios of alkyl-PAHs to parent PAHs showed a greater contribution of petrogenic inputs in Jakarta Bay than in Tokyo Bay. This difference is consistent with the higher ratio of hopanes to PAHs in Jakarta Bay. LAB concentrations in Jakarta Bay (geometric mean, 1400 ng/g-dry) were higher than those in Tokyo Bay (661 ng/g-dry). The internal to external (I/E) ratios of LABs in Jakarta Bay (0.92-2.88) were lower than those in Tokyo Bay (2.8-4.8), indicating that Jakarta Bay receives untreated or poorly treated sewage. Significant amounts of tetrapropylene-based alkylbenzenes were detected in several locations in Jakarta Bay, suggesting current usage of the non-degradable surfactants alkylbenzene sulfonates that are banned in many countries. The PCB concentration in Jakarta Bay was 1 order of magnitude lower than in Tokyo Bay, suggesting minimal usage of PCBs in industrial or commercial products in Jakarta. Analyses of a sediment core indicate increasing inputs of PAHs, hopanes, and LABs into Jakarta Bay during recent decades.

To understand the spatial variation in concentrations and compositions of organic micropollutants in marine plastic debris and their sources, we analyzed plastic fragments (∼10 mm) from the open ocean and from remote and urban beaches. Polychlorinated biphenyls (PCBs), polycyclic aromatic hydrocarbons (PAHs), dichloro-diphenyl-trichloroethane and its metabolites (DDTs), polybrominated diphenyl ethers (PBDEs), alkylphenols and bisphenol A were detected in the fragments at concentrations from 1 to 10,000 ng/g. Concentrations showed large piece-to-piece variability. Hydrophobic organic compounds such as PCBs and PAHs were sorbed from seawater to the plastic fragments. PCBs are most probably derived from legacy pollution. PAHs showed a petrogenic signature, suggesting the sorption of PAHs from oil slicks. Nonylphenol, bisphenol A, and PBDEs came mainly from additives and were detected at high concentrations in some fragments both from remote and urban beaches and the open ocean.

We collected surface sediment samples from 174 locations in India, Indonesia, Malaysia, Thailand, Vietnam, Cambodia, Laos, and the Philippines and analyzed them for polycyclic aromatic hydrocarbons (PAHs) and hopanes. PAHs were widely distributed in the sediments, with comparatively higher concentrations in urban areas (Sigma PAHs: approximately 1000 to approximately 100,000 ng/g-dry) than in rural areas ( approximately 10 to approximately 100g-dry), indicating large sources of PAHs in urban areas. To distinguish petrogenic and pyrogenic sources of PAHs, we calculated the ratios of alkyl PAHs to parent PAHs: methylphenanthrenes to phenanthrene (MP/P), methylpyrenes+methylfluoranthenes to pyrene+fluoranthene (MPy/Py), and methylchrysenes+methylbenz[a]anthracenes to chrysene+benz[a]anthracene (MC/C). Analysis of source materials (crude oil, automobile exhaust, and coal and wood combustion products) gave thresholds of MP/P=0.4, MPy/Py=0.5, and MC/C=1.0 for exclusive combustion origin. All the combustion product samples had the ratios of alkyl PAHs to parent PAHs below these threshold values. Contributions of petrogenic and pyrogenic sources to the sedimentary PAHs were uneven among the homologs: the phenanthrene series had a greater petrogenic contribution, whereas the chrysene series had a greater pyrogenic contribution. All the Indian sediments showed a strong pyrogenic signature with MP/P approximately 0.5, MPy/Py approximately 0.1, and MC/C approximately 0.2, together with depletion of hopanes indicating intensive inputs of combustion products of coal and/or wood, probably due to the heavy dependence on these fuels as sources of energy. In contrast, sedimentary PAHs from all other tropical Asian cities were abundant in alkylated PAHs with MP/P approximately 1-4, MPy/Py approximately 0.3-1, and MC/C approximately 0.2-1.0, suggesting a ubiquitous input of petrogenic PAHs. Petrogenic contributions to PAH homologs varied among the countries: largest in Malaysia whereas inferior in Laos. The higher abundance of alkylated PAHs together with constant hopane profiles suggests widespread inputs of automobile-derived petrogenic PAHs to Asian waters.

7 páginas, 3 tablas, 1 figura, The effect of metals - among other contaminations - on aquatic organisms are of increasing concern as greater amount of potential pollutants are mobilized to the environment by human activities. Anthropogenic sources of metals, including urban runoff, sewage, traffic emissions, coal and oil combustion, industrial production, mining and the smelting of ores (Eisler 1981; Moore and Ramamoorthy 1993), have lead to a signicant enhancement of metal concentrations in coastal areas with its inherent toxic threat. The present collaborative work has been set out to evaluate the status of metal concentrations in the representative biota inhabiting the Sundarban wetland environment (NE India) and to assess their potential for the biomonitoring of metal contaminations.

This paper reports the result of sewage pollution monitoring conducted in South and Southeast Asia during 1998-2003 using linear alkylbenzenes (LABs) as molecular tracers of sewage contamination. Eighty-nine water samples collected from Malaysia, Vietnam, and Japan (Tokyo), and 161 surface sediment samples collected from Tokyo, Thailand, Malaysia, Philippines, Vietnam, Cambodia, Indonesia, and India were analyzed for alkylbenzenes. The concentration range of SigmaLABs in river water particles in Southeast Asia (0.005-0.913 microg/L) was comparable to or higher than those found in Tokyo (0.005-0.638 microg/L). I/E ratios (a ratio of internal to external isomers of LABs) in tropical Asian waters were close to the value of LABs in raw sewage ( approximately 1) and much lower than those in secondary effluents (3-5). This suggests that untreated or inadequately treated sewage is discharged into the water. SigmaLABs concentrations in sediments from South and Southeast Asia ranged from0.002-42.6 microg/g-dry with the highest concentration occurring at several populous cities. Low I/E ratios of the sediments with high SigmaLABs concentrations suggest a heavy load of untreated sewage. Clearly in view of the current data and evidence of the implications of sewage pollution, this paper highlights the necessity of the continuation of water treatment system improvement in tropical Asia.