1. Effect of rare earth site substitution on magnetic and transport properties of Ln2CoMnO6 (Ln = La, Sm and Gd) double perovskites.
- Author
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Sahoo, R.C., Das, Sananda, and Nath, T.K.
- Subjects
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COBALT alloys , *MAGNETIC properties of perovskite , *SUBSTITUTION reactions , *MAGNETIC properties of metals , *X-ray diffraction - Abstract
The influence of rare earth site substitution on structural, transport and magnetic characteristics of polycrystalline Ln 2 CoMnO 6 (Ln = La, Sm and Gd) has been systematically investigated in details. The room temperature X-ray diffraction data confirm the monoclinic crystal structure of the samples, having P2 1 /n space group. The magnetic study reveals that the ferromagnetic transition temperature (T C1 ∼ 233.2 K) of La 2 CoMnO 6 decreases very fast due to a decrease of ionic radii in Ln site and T C2 (∼150 K) disappears in the Gd 2 CoMnO 6 system due to the presence of only Co 2+ and Mn 4+ ion pair. The field dependent magnetization data at 5 K exhibit antiferromagnetic ordering induced in the Sm 2 CoMnO 6 and Gd 2 CoMnO 6 systems due to structural distortion and 4f-3d negative magnetic interactions. The temperature dependent resistivity data of La 2 CoMnO 6 display semiconductor like behavior in a temperature range of 150–300 K and this behavior has been best described by the variable range hopping conduction mechanism. On the other hand, the resistivity of Sm and Gd based samples follows variable range hopping model in the temperature range of 200–300 K. Large magnetoresistance of ∼−26.35% has been observed at 160 K at a magnetic field of 60 kOe in La 2 CoMnO 6 and it decreases to −8.28% for Sm 2 CoMnO 6 , and −1.01% for Gd 2 CoMnO 6 as ionic radii decrease at the Ln site. [ABSTRACT FROM AUTHOR]
- Published
- 2018
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