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The ~2,000-km-long Central Range of New Guinea is a hotspot of modern carbon sequestration due to the chemical weathering of igneous rocks with steep topography in the warm wet tropics. These high mountains formed in a collision between the Australian plate and ophiolite-bearing volcanic arc terranes, but poor resolution of the uplift and exhumation history has precluded assessments of the impact on global climate change. Here, we develop a palinspastic reconstruction of the Central Range orogen with existing surface geological constraints and seismic data to generate time-temperature paths and estimate volumes of eroded material. New (U-Th)/He thermochronology data reveal rapid uplift and regional denudation between 10 and 6 Mya. Erosion fluxes from the palinspastic reconstruction, calibrated for time with the thermochronological data, were used as input to a coupled global climate and weathering model. This model estimates 0.6 to 1.2 °C of cooling associated with the Late Miocene rise of New Guinea due to increased silicate weathering alone, and this CO2 sink continues to the present. Our data and modeling experiments support the hypothesis that tropical arc-continent collision and the rise of New Guinea contributed to Neogene cooling due to increased silicate weathering.

The flooding record of North America has been used to infer patterns of global erosion and sea level in deep time. Here, we utilize the geospatial dimension of the stratigraphic record provided by the Macrostrat database, and patterns of erosion from thermochronology, to resolve local tectonic subsidence from global sea level. We show that the flooding history of North America correlates in space and time with continent-facing subduction along active margins, consistent with subduction-driven dynamic topographic subsidence of the continental interior. Nonetheless, the continentally aggregated flooding signal of North America is an exaggerated global M-curve of Phanerozoic sea level. This coincidence relates to the closing of the geodynamic loop of the supercontinent cycle: Subduction under North America accommodated both the makeup and breakup of Pangaea, which, coupled with changing ridge length, flattened hypsometry, and increased sea level both locally and globally. The sole Phanerozoic exception to this pattern of global sea level tracking North American near-field geodynamics is the Cambrian Sauk transgression. We argue that this is a far-field record of the inception of circum-Gondwanan subduction, independent of North America, which significantly flattened Earths hypsometry. This hypsometric flattening displaced ocean water globally, flooding tectonically passive North America to seal the Great Unconformity.

The Cryogenian Sturtian and Marinoan Snowball Earth glaciations bracket a nonglacial interval during which Demosponge and green-algal biomarkers first appear. To understand the relationships between environmental perturbations and early animal evolution, we measured sulfur and mercury isotopes from the Datangpo Formation from South China. Hg enrichment with positive Δ199Hg excursion suggests enhanced volcanism, potentially due to depressurization of terrestrial magma chambers during deglaciation. A thick stratigraphic interval of negative Δ33Spy indicates that the nonglacial interlude was characterized by low but rising sulfate levels. Model results reveal a mechanism to produce the Δ33S anomalies down to -0.284‰ through Rayleigh distillation. We propose that extreme temperatures and anoxia contributed to the apparent delay in green algal production in the aftermath of the Sturtian glaciation and the subsequent reoxygenation of the iron-rich and sulfate-depleted ocean paved the way for evolution of animals.

During the Cryogenian (720 to 635 Ma ago) Snowball Earth glaciations, ice extended to sea level near the equator. The cause of this catastrophic failure of Earth's thermostat has been unclear, but previous geochronology has suggested a rough coincidence of glacial onset with one of the largest magmatic episodes in the geological record, the Franklin large igneous province. U-Pb geochronology on zircon and baddeleyite from sills associated with the paleo-equatorial Franklin large igneous province in Arctic Canada record rapid emplacement between 719.86 ± 0.21 and 718.61 ± 0.30 Ma ago, 0.9 to 1.6 Ma before the onset of widespread glaciation. Geologic observations and (U-Th)/He dates on Franklin sills are compatible with major post-Franklin exhumation, possibly due to development of mafic volcanic highlands on windward equatorial Laurentia and increased global weatherability. After a transient magmatic CO2 flux, long-term carbon sequestration associated with increased weatherability could have nudged Earth over the threshold for runaway ice-albedo feedback.

Three Orosirian basins and associated foreland thrust-fold belts are preserved on the margins of the Slave craton. All three are related to orogenic belts where oceans opened and later closed, uniting new crustal partners. The Great Slave basin differs from the Kilhigok and Coronation basins in ways that have defied explanation. It lacks a passive margin sequence and hosts two discrete igneous suites, separated by large-scale thrusting, that occurred well after the adjacent paleocean had closed. Here we report U-Pb zircon geochronology by chemical abrasion isotope dilution thermal ionization mass spectrometry for a member of each suite to constrain the age and origin of postcollisional thrusting. A widespread pulse of mainly phreatic alkaline volcanism, coeval with renewed foredeep flexure, occurred at 1889.0 [+ or -] 0.7 Ma (2a internal error). A quartz-monzodiorite body one of a belt-parallel chain of laccoliths that postdate thrusting, was emplaced at 1866.9 [+ or -] 0.9 Ma. These ages bracket renewed foredeep sedimentation and thrusting that telescoped major facies zones and was rooted within the basin. The older age is 70 and 30--60 Myr younger than collision in the Thelon and Taltson orogens, respectively. We attribute postcollisional thrusting and foredeep subsidence to 'eduction'--the upward and outward ejection of partly subducted crust--and postulate that the top of the ejected wedge was a normal-sense detachment fault projecting beneath the Nonacho basin. We infer that eduction was triggered by slab failure, producing alkaline volcanism, and ended with delamination and laccolith emplacement. Eduction was facilitated by tradewind-driven erosion. Delamination was enabled by crustal transfer to the educted wedge, reducing footwall buoyancy. Slab failure and/or delamination removed the passive margin. Key words: eduction, slab failure, delamination, geochronology, Great Slave Lake, Introduction Remnants of three sedimentary basins and associated thrust-fold belts of Orosirian age (2.05--1.80 Ga) are preserved on the margins of the Slave craton (Fig. 1 and Table 1). Each [...]

The rise of complex macroscopic life occurred during the Ediacaran Period, an interval that witnessed large-scale disturbances to biogeochemical systems. The current Ediacaran chronostratigraphic framework is of insufficient resolution to provide robust global correlation schemes or test hypotheses for the role of biogeochemical cycling in the evolution of complex life. Here, we present new radio-isotopic dates from Ediacaran strata that directly constrain key fossil assemblages and large-magnitude carbon cycle perturbations. These new dates and integrated global correlations demonstrate that late Ediacaran strata of South China are time transgressive and that the 575- to 550-Ma interval is marked by two large negative carbon isotope excursions: the Shuram and a younger one that ended ca. 550 Ma ago. These data calibrate the tempo of Ediacaran evolution characterized by intervals of tens of millions of years of increasing ecosystem complexity, interrupted by biological turnovers that coincide with large perturbations to the carbon cycle.

The Tonian supercontinent Rodinia is hypothesized to have included almost all Proterozoic continental blocks. Competing models variably place South China at the core or periphery of Rodinia or separated from it entirely. Tonian paleogeographic models also vary in whether they incorporate hypothesized large and rapid oscillatory true polar wander associated with the ca. 810–795 Ma Bitter Springs Stage. Here, we present paleomagnetic data paired with U-Pb chemical abrasion isotope dilution thermal ionization mass spectrometry zircon geochronology from the Tonian Xiajiang Group in South China to establish the craton's position and test the Bitter Springs Stage true polar wander hypothesis. Fine-grained siliciclastic sediments and ashes of the Xiajiang Group post-date the Jiangnan Orogeny, which united the Yangtze and Cathaysia blocks. A U-Pb zircon date of 815.73 ± 0.18 Ma from a tuff near the base of the Xiajiang Group constrains the Jiangnan Orogeny to have ended between ca. 830 and 816 Ma. The paleomagnetic and geochronologic data constrain South China to high latitudes ca. 813 Ma and indicate a relatively stable high-latitude position from ca. 821 to 805 Ma. These high-latitude constraints either connect the craton to Rodinia along its periphery or disconnect it from the supercontinent entirely. The difference in pole position between the pre-Bitter Springs Stage Xiajiang Group pole and the syn-Bitter Springs Stage Madiyi Formation pole is significantly less than that predicted for the Bitter Springs Stage true polar wander hypothesis. If this pole difference is interpreted as true polar wander superimposed upon differential plate motion, it requires South China to have been separate from Rodinia.

One of the hypothesized effects of large igneous provinces (LIPs) is planetary cooling on million-year timescales associated with enhanced silicate weathering of freshly emplaced basalt. This study combines reconstructions of the original surface extent and emplacement ages of LIPs, a paleogeographic model, and a parameterization of LIP erosion to estimate LIP area in all latitudinal bands through the Phanerozoic. This analysis reveals no significant correlation between total LIP area, nor LIP area in the tropics, and the extent of continental ice sheets. The largest peaks in tropical LIP area are at times of non-glacial climate. These results suggest that changes in planetary weatherability associated with LIPs are not the fundamental control on whether Earth is in a glacial or non-glacial climate, although they could provide a secondary modulating effect in conjunction with other processes.

Steep topography, a tropical climate, and mafic lithologies contribute to efficient chemical weathering and carbon sequestration in the Southeast Asian islands. Ongoing arc-continent collision between the Sunda-Banda arc system and Australia has increased the area of subaerially exposed land in the region since the mid-Miocene. Concurrently, Earth's climate has cooled since the Miocene Climatic Optimum, leading to growth of the Antarctic ice sheet and the onset of Northern Hemisphere glaciation. We seek to evaluate the hypothesis that the emergence of the Southeast Asian islands played a significant role in driving this cooling trend through increasing global weatherability. To do so, we have compiled paleoshoreline data and incorporated them into GEOCLIM, which couples a global climate model to a silicate weathering model with spatially resolved lithology. We find that without the increase in area of the Southeast Asian islands over the Neogene, atmospheric pCO2 would have been significantly higher than preindustrial values, remaining above the levels necessary for initiating Northern Hemisphere ice sheets.

Changes in the geological sulfur cycle are inferred from the sulfur isotopic composition of marine barite. The structure of the 34S/32S record from the Mesozoic to present, which includes ∼50- and 100-Ma stepwise increases, has been interpreted as the result of microbial isotope effects or abrupt changes to tectonics and associated pyrite burial. Untangling the physical processes that govern the marine sulfur cycle and associated isotopic change is critical to understanding how climate, atmospheric oxygenation, and marine ecology have coevolved over geologic time. Here we demonstrate that the sulfur outgassing associated with emplacement of large igneous provinces can produce the apparent stepwise jumps in the isotopic record when coupled to long-term changes in burial efficiency. The record of large igneous provinces map onto the required outgassing events in our model, with the two largest steps in the sulfur isotope record coinciding with the emplacement of large igneous provinces into volatile-rich sedimentary basins. This solution provides a quantitative picture of the last 120 My of change in the oceans largest oxidant reservoir.

The Great Unconformity marks a major gap in the continental geological record, separating Precambrian basement from Phanerozoic sedimentary rocks. However, the timing, magnitude, spatial heterogeneity, and causes of the erosional event(s) and/or depositional hiatus that lead to its development are unknown. We present field relationships from the 1.07-Ga Pikes Peak batholith in Colorado that constrain the position of Cryogenian and Cambrian paleosurfaces below the Great Unconformity. Tavakaiv sandstone injectites with an age of ≥676 ± 26 Ma cut Pikes Peak granite. Injection of quartzose sediment in bulbous bodies indicates near-surface conditions during emplacement. Fractured, weathered wall rock around Tavakaiv bodies and intensely altered basement fragments within unweathered injectites imply still earlier regolith development. These observations provide evidence that the granite was exhumed and resided at the surface prior to sand injection, likely before the 717-Ma Sturtian glaciation for the climate appropriate for regolith formation over an extensive region of the paleolandscape. The 510-Ma Sawatch sandstone directly overlies Tavakaiv-injected Pikes granite and drapes over core stones in Pikes regolith, consistent with limited erosion between 717 and 510 Ma. Zircon (U-Th)/He dates for basement below the Great Unconformity are 975 to 46 Ma and are consistent with exhumation by 717 Ma. Our results provide evidence that most erosion below the Great Unconformity in Colorado occurred before the first Neoproterozoic Snowball Earth and therefore cannot be a product of glacial erosion. We propose that multiple Great Unconformities developed diachronously and represent regional tectonic features rather than a synchronous global phenomenon.

On multimillion-year time scales, Earth has experienced warm ice-free and cold glacial climates, but it is unknown whether transitions between these background climate states were the result of changes in carbon dioxide sources or sinks. Low-latitude arc-continent collisions are hypothesized to drive cooling by exhuming and eroding mafic and ultramafic rocks in the warm, wet tropics, thereby increasing Earth's potential to sequester carbon through chemical weathering. To better constrain global weatherability through time, the paleogeographic position of all major Phanerozoic arc-continent collisions was reconstructed and compared to the latitudinal distribution of ice sheets. This analysis reveals a strong correlation between the extent of glaciation and arc-continent collisions in the tropics. Earth's climate state is set primarily by global weatherability, which changes with the latitudinal distribution of arc-continent collisions.

Mafic intrusions, lava flows, and felsic plutons in southwestern Laurentia have been hypothesized to be associated with the emplacement of a late Mesoproterozoic (Stenian Period) large igneous province. Improved geochronologic data resolve distinct episodes of mafic magmatism in the region. The ca. 1,098 Ma main pulse of southwestern Laurentia large igneous province (SWLLIP) magmatism is recorded by mafic intrusions across southeastern California to central Arizona. A younger episode of volcanism resulted in eruptions that formed the ca. 1,082 Ma Cardenas Basalt, which is the uppermost unit of the Unkar Group in the Grand Canyon. With the updated geochronological constraints, we develop new paleomagnetic data from mafic sills in the SWLLIP. Overlapping poles between the Death Valley sills and rocks of similar age in the Midcontinent Rift are inconsistent with large‐scale Cenozoic vertical axis rotations in Death Valley. We also develop a new paleomagnetic pole from the ca. 1,082 Ma Cardenas Basalt (pole longitude = 183.9°E, pole latitude = 15.9°N, A95 ${\mathrm{A}}_{95}$ = 7.4°, N = 18). The new paleomagnetic data are consistent with the pole path developed from time‐equivalent rocks of the Midcontinent Rift, supporting interpretations that changing pole positions are the result of rapid equatorward motion. These data add to the record of Laurentia's rapid motion from ca. 1,110 to 1,080 Ma that culminated in collisional Grenvillian orogenesis and the assembly of Rodinia. Plain Language Summary: In Earth's geological record, voluminous magmatism over brief time frames are known as large igneous provinces. One such event took place approximately 1.1 billion years ago on the ancient North American continent (known as Laurentia) resulting in the formation of thick mafic sills. Previously, these intrusions across southwestern Laurentia were believed to have been emplaced simultaneously with the extrusive Cardenas Basalt lava flows in the Grand Canyon. We now know that the emplacement of the thick mafic intrusions represent a large igneous province, which predates the eruption of the Cardenas Basalt by 16 million years. By pairing this knowledge of the age with recorded magnetic directions in the lavas and intrusions, we can enrich our knowledge of Laurentia's motion leading up to the assembly of the supercontinent Rodinia. These data provide a new constraint on the position of the continent 1,082 million years ago and support the interpretation of rapid plate motion over the preceding 20 million years. Key Points: Paleomagnetic directions from mafic sills in Death Valley are consistent with ca. 1,098 Ma LIP‐style magmatism in southwestern LaurentiaA paleomagnetic pole from the ca. 1,082 Ma Cardenas Basalt of the Grand Canyon corresponds with time‐equivalent Midcontinent Rift polesChanging southwestern Laurentia LIP pole positions support rapid equatorward motion of the continent recorded by the Keweenawan Track [ABSTRACT FROM AUTHOR]

The evolution of the global carbon and silicon cycles is thought to have contributed to the long-term stability of Earth's climate.sup.1-3. Many questions remain, however, regarding the feedback mechanisms at play, and there are limited quantitative constraints on the sources and sinks of these elements in Earth's surface environments.sup.4-12. Here we argue that the lithium-isotope record can be used to track the processes controlling the long-term carbon and silicon cycles. By analysing more than 600 shallow-water marine carbonate samples from more than 100 stratigraphic units, we construct a new carbonate-based lithium-isotope record spanning the past 3 billion years. The data suggest an increase in the carbonate lithium-isotope values over time, which we propose was driven by long-term changes in the lithium-isotopic conditions of sea water, rather than by changes in the sedimentary alterations of older samples. Using a mass-balance modelling approach, we propose that the observed trend in lithium-isotope values reflects a transition from Precambrian carbon and silicon cycles to those characteristic of the modern. We speculate that this transition was linked to a gradual shift to a biologically controlled marine silicon cycle and the evolutionary radiation of land plants.sup.13,14. Analysis of shallow-water marine carbonate samples from 101 stratigraphic units allows construction of a record of lithium isotopes from the past 3 billion years, tracking the evolution of the global carbon and silicon cycles., Author(s): Boriana Kalderon-Asael [sup.1] , Joachim A. R. Katchinoff [sup.1] , Noah J. Planavsky [sup.1] , Ashleigh v. S. Hood [sup.2] , Mathieu Dellinger [sup.3] , Eric J. Bellefroid [sup.1] [...]

Geological evidence indicates that grounded ice sheets reached sea level at all latitudes during two long-lived Cryogenian (58 and ≥5 My) glaciations. Combined uranium-lead and rhenium-osmium dating suggests that the older (Sturtian) glacial onset and both terminations were globally synchronous. Geochemical data imply that CO2 was 102 PAL (present atmospheric level) at the younger termination, consistent with a global ice cover. Sturtian glaciation followed breakup of a tropical supercontinent, and its onset coincided with the equatorial emplacement of a large igneous province. Modeling shows that the small thermal inertia of a globally frozen surface reverses the annual mean tropical atmospheric circulation, producing an equatorial desert and net snow and frost accumulation elsewhere. Oceanic ice thickens, forming a sea glacier that flows gravitationally toward the equator, sustained by the hydrologic cycle and by basal freezing and melting. Tropical ice sheets flow faster as CO2 rises but lose mass and become sensitive to orbital changes. Equatorial dust accumulation engenders supraglacial oligotrophic meltwater ecosystems, favorable for cyanobacteria and certain eukaryotes. Meltwater flushing through cracks enables organic burial and submarine deposition of airborne volcanic ash. The subglacial ocean is turbulent and well mixed, in response to geothermal heating and heat loss through the ice cover, increasing with latitude. Terminal carbonate deposits, unique to Cryogenian glaciations, are products of intense weathering and ocean stratification. Whole-ocean warming and collapsing peripheral bulges allow marine coastal flooding to continue long after ice-sheet disappearance. The evolutionary legacy of Snowball Earth is perceptible in fossils and living organisms.

The Earth's climate cooled through the Ordovician Period leading up to the Hirnantian glaciation. Increased weatherability of silicate rocks associated with topography generated on the Appalachian margin during the Taconic orogeny has been proposed as a mechanism for Ordovician cooling. However, paleogeographic reconstructions typically place the Appalachian margin within the arid subtropics, outside of the warm and wet tropics where chemical weathering rates are highest. In this study, we reanalyze the paleomagnetic database and conclude that Ordovician constraints from cratonic Laurentia are not robust. Instead, we use paleomagnetic data from well-dated volcanic rocks in the accreting terranes to constrain Laurentia's position given that the Appalachian margin was at, or equatorward of, the paleolatitude of these terranes. To satisfy these allochthonous data, Laurentia must have moved toward the equator during the Ordovician such that the Appalachian margin was within 10° of the equator by 465 Ma. This movement into the tropics coincided with the collision and exhumation of the Taconic arc system, recorded by a shift in neodymium isotope data from shale on the Appalachian margin to more juvenile values. This inflection in detrital neodymium isotope values precedes a major downturn in global seawater strontium isotopic values by more than one million years, as would be predicted from a change in weathering input and the relatively long residence time of strontium in the ocean. These data are consistent with an increase in global weatherability associated with the tropical weathering of mafic and ultramafic lithologies exhumed during the Taconic arc-continent collision. A Taconic related increase in weatherability is a viable mechanism for lowering atmospheric CO2 levels through silicate weathering contributing to long-term Ordovician cooling.

New constraints on the tectonic evolution of the Neo-Tethys Ocean indicate that at ∼90-70 Ma and at ∼50-40 Ma, vast quantities of mafic and ultramafic rocks were emplaced at low latitude onto continental crust within the tropical humid belt. These emplacement events correspond temporally with, and are potential agents for, the global climatic cooling events that terminated the Cretaceous Thermal Maximum and the Early Eocene Climatic Optimum. We model the temporal effects of CO2 drawdown from the atmosphere due to chemical weathering of these obducted ophiolites, and of CO2 addition to the atmosphere from arc volcanism in the Neo-Tethys, between 100 and 40 Ma. Modeled variations in net CO2-drawdown rates are in excellent agreement with contemporaneous variation of ocean bottom water temperatures over this time interval, indicating that ophiolite emplacement may have played a major role in changing global climate. We demonstrate that both the lithology of the obducted rocks (mafic/ultramafic) and a tropical humid climate with high precipitation rate are needed to produce significant consumption of CO2 Based on these results, we suggest that the low-latitude closure of ocean basins along east-west trending plate boundaries may also have initiated other long-term global cooling events, such as Middle to Late Ordovician cooling and glaciation associated with the closure of the Iapetus Ocean.

After nearly a billion years with no evidence for glaciation, ice advanced to equatorial latitudes at least twice between 717 and 635 Mya. Although the initiation mechanism of these Neoproterozoic Snowball Earth events has remained a mystery, the broad synchronicity of rifting of the supercontinent Rodinia, the emplacement of large igneous provinces at low latitude, and the onset of the Sturtian glaciation has suggested a tectonic forcing. We present unique Re-Os geochronology and high-resolution Os and Sr isotope profiles bracketing Sturtian-age glacial deposits of the Rapitan Group in northwest Canada. Coupled with existing U-Pb dates, the postglacial Re-Os date of 662.4 ± 3.9 Mya represents direct geochronological constraints for both the onset and demise of a Cryogenian glaciation from the same continental margin and suggests a 55-My duration of the Sturtian glacial epoch. The Os and Sr isotope data allow us to assess the relative weathering input of old radiogenic crust and more juvenile, mantle-derived substrate. The preglacial isotopic signals are consistent with an enhanced contribution of juvenile material to the oceans and glacial initiation through enhanced global weatherability. In contrast, postglacial strata feature radiogenic Os and Sr isotope compositions indicative of extensive glacial scouring of the continents and intense silicate weathering in a post-Snowball Earth hothouse.