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Quantum control allows a wide range of quantum operations employed in molecular physics, nuclear magnetic resonance and quantum information processing. Thanks to the existing microelectronics industry, semiconducting qubits, where quantum information is encoded in spin or charge degree freedom of electrons or nuclei in semiconductor quantum dots, constitute a highly competitive candidate for scalable solid-state quantum technologies. In quantum information processing, advanced control techniques are needed to realize quantum manipulations with both high precision and noise resilience. In this review, we first introduce the basics of various widely-used control methods, including resonant excitation, adabatic passage, shortcuts to adiabaticity, composite pulses, and quantum optimal control. Then we review the practical aspects in applying these methods to realize accurate and robust quantum gates for single semiconductor qubits, such as Loss-DiVincenzo spin qubit, spinglet-triplet qubit, exchange-only qubit and charge qubit.

Repetitive Ramsey interferometry measurements (RIMs) are often used to measure qubit coherence, assuming that the environment remains unaffected after each measurement and the outcomes of all measurements are independent and identically distributed (i.i.d.). While this assumption is valid for a classical environment, it may not hold for a quantum environment due to the non-negligible backaction from qubit to environment. Here we present a general theoretical framework to incorporate the measurement backaction from qubit to environment in sequential RIMs. We show that a RIM of a qubit induces a quantum channel on the quantum environment, and sequential RIMs gradually steer the quantum environment to the fixed points of the channel. We reveal three distinct environment steering effects -- polarization, depolarization and metastable polarization, depending on the commutativity of the noise operator $B$ and the free environment Hamiltonian $H_e$: (1) if $B$ commutes with $H_e$, i.e., $[B,H_e]=0$, the quantum environment is gradually polarized to different eigenstates of $B$ as the number $m$ of repetitive RIMs increases; (2) When $[B,H_e]\neq 0$, the quantum environment is gradually depolarized to a maximally mixed state of its whole Hilbert space or a Hilbert subspace; (3) When $[B,H_e]\neq 0$ but one of $H_e$ and $B$ is a small perturbation on the other, metastable polarization can happen, such that the quantum environment is first polarized for a finite range of $m$ but becomes gradually depolarized as $m$ increases further. The environment steering also makes the measurement statistics of sequential RIMs develop non-i.i.d. features, such that the measurement result distribution can display multiple peaks for a small quantum environment, corresponding to different fixed points of the quantum channel.

Metastability in open system dynamics describes the phenomena of initial relaxation to longlived metastable states before decaying to the asymptotic stable states. It has been predicted in continuous-time stochastic dynamics of both classical and quantum systems. Here we present a general theory of metastability in discrete-time open quantum dynamics, described by sequential quantum channels. We focus on a general class of quantum channels on a target system, induced by an ancilla system with a pure-dephasing coupling to the target system and under Ramsey sequences. Interesting metastable behaviors are predicted and numerically demonstrated by decomposing the average dynamics into stochastic trajectories. Examples and applications are also discussed., Comment: 7 pages, 2 figures (+9 pages, 5 figures supplement)

We propose and demonstrate that the behaviors of long-range, two-site quantum resources can effectively diagnose quantum phases. In an XX spin chain with symmetry-breaking quantum phase transitions, we reveal that the asymptotic and oscillating decay modes of quantum coherence or quantum discord, along with two-site distance, can identify two spin-liquid phases. Furthermore, based on our analytical results of spin correlation functions, we confirm the existence of long-range entanglement in the system and establish a connection between two-site entanglement and quantum phases. Additionally, for the extended Ising model with topological phase transitions, we find that coherence and quantum discord behaviors can also signify topological quantum phases. In particular, we discover the quantum resource freezing phenomenon, where topologically protected long-range quantum resources may have potential applications in quantum information processing., Comment: 4.5 pages, 4 figures plus the supplemental material

Quantum phase estimation (QPE) of the eigenvalues of a unitary operator on a target quantum system is a crucial subroutine in various quantum algorithms. Conventional QPE is often expensive to implement as it requires a large number of ancilla qubits and the ability to perform quantum Fourier transform. Recent developments in iterative QPE reduce the implementation cost by repetitive uses of a single ancilla and classical post-processing. However, both conventional and iterative schemes often require preparation of the target system in an eigenstate of the unitary operator, while it remains ambiguous to achieve QPE of multiple eigenvalues with no need of initial state preparation. Here we clarify this issue by developing a theoretical framework based on sequential quantum channels for iterative QPE. We find that QPE of multiple eigenvalues can be efficiently realized for arbitrary initial target system state by actively utilizing the measurement backaction of iterative QPE on the target system with a long coherence time. Specifically, we investigate two iterative QPE schemes based on sequential Ramsey interferometry measurements (RIMs) of an ancilla qubit: (a) the repetitive scheme, which conducts repetitive RIMs to achieve the standard quantum limit in estimating the eigenvalues; (b) the adaptive scheme, which adjusts the parameters of each RIM based on prior measurement outcomes to attain the Heisenberg limit. In both schemes, sequential ancilla measurements generate sequential quantum channels on the target system, gradually steering it to the eigenstates of the estimated unitary operator, while the measurement statistics of the ancilla can reveal the embedded information about its eigenvalues with proper post-processing. We demonstrate the analysis by simulating a central spin model, and evaluate the performance and noise resilience of both schemes., Comment: 19 pages, 8 figures

The relation between projective measurements and generalized quantum measurements is a fundamental problem in quantum physics, and clarifying this issue is also important to quantum technologies. While it has been intuitively known that projective measurements can be constructed from sequential generalized or weak measurements, there is still lack of a proof of this hypothesis in general cases. Here we prove it from the perspective of quantum channels. We show that projective measurements naturally arise from sequential generalized measurements in the asymptotic limit. Specifically, a selective projective measurement arises from a set of typical sequences of selective generalized measurements. We provide an explicit scheme to construct projective measurements of a quantum system with sequential generalized measurements. Remarkably, a single ancilla qubit is sufficient to mediate sequential generalized measurements for constructing arbitrary projective measurements of a generic system., Comment: 8 pages, 2 figures (+6 pages supplement)

Path-independent (PI) quantum control has recently been proposed to integrate quantum error correction and quantum control [Phys. Rev. Lett. 125, 110503 (2020)], achieving fault-tolerant quantum gates against ancilla errors. Here we reveal the underlying algebraic structure of PI quantum control. The PI Hamiltonians and propagators turn out to lie in an algebra isomorphic to the ordinary matrix algebra, which we call the PI matrix algebra. The PI matrix algebra, defined on the Hilbert space of a composite system (including an ancilla system and a central system), is isomorphic to the matrix algebra defined on the Hilbert space of the ancilla system. By extending the PI matrix algebra to the Hilbert-Schmidt space of the composite system, we provide an exact and unifying condition for PI quantum control against ancilla noise., Comment: 9 pages, 2 figures

The electric dipole spin resonance (EDSR) combining strong spin-orbit coupling (SOC) and electric-dipole transitions facilitates fast spin control in a scalable way, which is the critical aspect of the rapid progress made recently in germanium (Ge) hole-spin qubits. However, a puzzle is raised because centrosymmetric Ge lacks the Dresselhaus SOC, a key element in the initial proposal of the hole-based EDSR. Here, we demonstrate that the recently uncovered finite k-linear Rashba SOC of 2D holes offers fast hole spin control via EDSR with Rabi frequencies in excellent agreement with experimental results over a wide range of driving fields. We also suggest that the Rabi frequency can reach 500 MHz under a higher gate electric field or multiple GHz in a replacement by [110]oriented wells. These findings bring a deeper understanding for hole-spin qubit manipulation and offer design principles to boost the gate speed., Comment: 11 pages, 3 figures

Bosonic modes have wide applications in various quantum technologies, such as optical photons for quantum communication, magnons in spin ensembles for quantum information storage and mechanical modes for reversible microwave-to-optical quantum transduction. There is emerging interest in utilizing bosonic modes for quantum information processing, with circuit quantum electrodynamics (circuit QED) as one of the leading architectures. Quantum information can be encoded into subspaces of a bosonic superconducting cavity mode with long coherence time. However, standard Gaussian operations (e.g., beam splitting and two-mode squeezing) are insufficient for universal quantum computing. The major challenge is to introduce additional nonlinear control beyond Gaussian operations without adding significant bosonic loss or decoherence. Here we review recent advances in universal control of a single bosonic code with superconducting circuits, including unitary control, quantum feedback control, driven-dissipative control and holonomic dissipative control. Various approaches to entangling different bosonic modes are also discussed., Comment: 23 pages, 9 figures, 1 table (+2 pages supplement with 1 figure)

Interactions are essential for the creation of correlated quantum many-body states. While two-body interactions underlie most natural phenomena, three- and four-body interactions are important for the physics of nuclei [1], exotic few-body states in ultracold quantum gases [2], the fractional quantum Hall effect [3], quantum error correction [4], and holography [5, 6]. Recently, a number of artificial quantum systems have emerged as simulators for many-body physics, featuring the ability to engineer strong interactions. However, the interactions in these systems have largely been limited to the two-body paradigm, and require building up multi-body interactions by combining two-body forces. Here, we demonstrate a pure N-body interaction between microwave photons stored in an arbitrary number of electromagnetic modes of a multimode cavity. The system is dressed such that there is collectively no interaction until a target total photon number is reached across multiple distinct modes, at which point they interact strongly. The microwave cavity features 9 modes with photon lifetimes of $\sim 2$ ms coupled to a superconducting transmon circuit, forming a multimode circuit QED system with single photon cooperativities of $\sim10^9$. We generate multimode interactions by using cavity photon number resolved drives on the transmon circuit to blockade any multiphoton state with a chosen total photon number distributed across the target modes. We harness the interaction for state preparation, preparing Fock states of increasing photon number via quantum optimal control pulses acting only on the cavity modes. We demonstrate multimode interactions by generating entanglement purely with uniform cavity drives and multimode photon blockade, and characterize the resulting two- and three-mode W states using a new protocol for multimode Wigner tomography., Comment: 5 pages of main text with 5 figures. 11 pages of supplementary information with 10 figures

The clock transitions (CTs) of central spins have long coherence times because their frequency fluctuations vanish in the linear order of external field noise (such as Overhauser fields from nuclear spin baths). Therefore, CTs are useful for quantum technologies. Also, the quadratic dependence of frequencies on noises makes the CT decoherence an interesting physics problem. Thus we are motivated to study the decoherence of CTs. We consider noise from spin baths, which is one of the most relevant mechanisms of qubit decoherence. Various quantum many-body methods have been developed to study the decoherence of a central spin in spin baths. In particular, the cluster-correlation expansion (CCE) systematically accounts for the many-body correlations that cause the central spin decoherence. However, the CCE can not be straightforwardly applied to CTs in spin baths, for the expansion may fail to converge due to the effective long-range interactions resulting from the quadratic term of the noise (e.g., the second-order interaction mediated by hyperfine interactions for a nuclear spin bath). In this work, we develop a modified CCE method to tackle this class of decoherence problems. By diagonalizing the central spin Hamiltonian for each bath eigenstate of the hyperfine interaction, we find that the effects of long-range interactions are absorbed as fluctuations of central spin eigenenergies in the form of single-spin correlations. We apply the method to two specific systems, namely, nitrogen vacancy center electron spins in near zero magnetic field and singlet-triplet transition of two electrons in a double quantum dot. The numerical simulation shows that the modified CCE converges rapidly for the CTs.

Ancilla systems are often indispensable to universal control of a nearly isolated quantum system. However, ancilla systems are typically more vulnerable to environmental noise, which limits the performance of such ancilla-assisted quantum control. To address this challenge of ancilla-induced decoherence, we propose a general framework that integrates quantum control and quantum error correction, so that we can achieve robust quantum gates resilient to ancilla noise. We introduce the path independence criterion for fault-tolerant quantum gates against ancilla errors. As an example, a path-independent gate is provided for superconducting circuits with a hardware-efficient design., Comment: 6 pages, 2 figures (+15 pages supplement)

To solve classically hard problems, quantum computers need to be resilient to the influence of noise and decoherence. In such a fault-tolerant quantum computer, noise-induced errors must be detected and corrected in real-time to prevent them from propagating between components. This requirement is especially pertinent while applying quantum gates, when the interaction between components can cause errors to quickly spread throughout the system. However, the large overhead involved in most fault-tolerant architectures makes implementing these systems a daunting task, which motivates the search for hardware-efficient alternatives. Here, we present a gate enacted by a multilevel ancilla transmon on a cavity-encoded logical qubit that is fault-tolerant with respect to decoherence in both the ancilla and the encoded qubit. We maintain the purity of the encoded qubit in the presence of ancilla errors by detecting those errors in real-time, and applying the appropriate corrections. We show a reduction of the logical gate error by a factor of two in the presence of naturally occurring decoherence, and demonstrate resilience against ancilla bit-flips and phase-flips by observing a sixfold suppression of the gate error with increased energy relaxation, and a fourfold suppression with increased dephasing noise. The results demonstrate that bosonic logical qubits can be controlled by error-prone ancilla qubits without inheriting the ancilla's inferior performance. As such, error-corrected ancilla-enabled gates are an important step towards fully fault-tolerant processing of bosonic qubits., Comment: 15 pages, 8 figures

Quantum measurements and phase transitions are seemingly uncorrelated topics, but here we show that phase transitions occur in sequential quantum measurements. We find that the probability distribution of the measurement results of a sequence of quantum measurements on a two-level system (e.g. a qubit) is equivalent to the Boltzmann distribution of a classical lattice spin model. So the measurement results present phase transitions similar to those in the lattice spin model. In sequential commuting positive-operator valued measurements, the probability distribution is mapped to a long-range Ising model in the weak-measurement regime, and a projective measurement emerges from a sequence of weak measurement when the strength or the number of measurements becomes above certain critical values, which correspond to a second-order ferromagnetic phase transition of the lattice spin model. These findings not only provide new insights on sequential quantum measurements, but may also have potential applications in quantum technologies., Comment: 19 pages,4 figures

Single-shot readout of qubits is required for scalable quantum computing. Nuclear spins are superb quantum memories due to their long coherence times but are difficult to be read out in single shot due to their weak interaction with probes. Here we demonstrate single-shot readout of a weakly coupled $^{13}$C nuclear spin, which is unresolvable in traditional protocols. We use dynamical decoupling pulse sequences to selectively enhance the entanglement between the nuclear spin and a nitrogen-vacancy center electron spin, tuning the weak measurement of the nuclear spin to a strong, projective one. A nuclear spin coupled to the NV center with strength 330 kHz is read out in 200 ms with fidelity 95.5\%. This work provides a general protocol for single-shot readout of weakly coupled qubits and therefore largely extends the range of physical systems for scalable quantum computing., Comment: 5 pages, 4 figures

Decoherence of electron spins in nanoscale systems is important to quantum technologies such as quantum information processing and magnetometry. It is also an ideal model problem for studying the crossover between quantum and classical phenomena. At low temperatures or in light-element materials where the spin-orbit coupling is weak, the phonon scattering in nanostructures is less important and the fluctuations of nuclear spins become the dominant decoherence mechanism for electron spins. Since 1950s, semiclassical noise theories have been developed for understanding electron spin decoherence. In spin-based solid-state quantum technologies, the relevant systems are in the nanometer scale and the nuclear spin baths are quantum objects which require a quantum description. Recently, quantum pictures have been established to understand the decoherence and quantum many-body theories have been developed to quantitatively describe this phenomenon. Anomalous quantum effects have been predicted and some have been experimentally confirmed. A systematically truncated cluster correlation expansion theory has been developed to account for the many-body correlations in nanoscale nuclear spin baths that are built up during the electron spin decoherence. The theory has successfully predicted and explained a number of experimental results in a wide range of physical systems. In this review, we will cover these recent progresses. The limitations of the present quantum many-body theories and possible directions for future development will also be discussed., Comment: 44 pages, 29 figures, corrected many typos and added some references

Nuclear magnetic resonance (NMR) has enormous applications. Two-dimensional NMR is an essential technique to characterize correlations between nuclei and, hence, molecule structures. Towards the ultimate goal of single-molecule NMR, dynamical-decoupling- (DD) enhanced diamond quantum sensing enables the detection of single nuclear spins and nanoscale NMR. However, there is still the lack of a standard method in DD-based quantum sensing to characterize correlations between nuclear spins in single molecules. Here we present a scheme of two-dimensional DD-based quantum sensing, as a universal method for correlation spectroscopy of single molecules. We design two-dimensional DD sequences composed of two sets of periodic DD sequences with different periods, which can be independently set to match two different transition frequencies for resonant DD. We find that under the resonant DD condition the sensor coherence patterns, as functions of the two independent pulse numbers of DD subsequences, can fully determine different types of correlations between nuclear spin transitions. This work offers a systematic approach to correlation spectroscopy for single-molecule NMR., Comment: 23 pages, 3 figures + 8 page supplement

Single-molecule sensitivity of nuclear magnetic resonance (NMR) and angstrom resolution of magnetic resonance imaging (MRI) are the highest challenges in magnetic microscopy. Recent development in dynamical-decoupling- (DD) enhanced diamond quantum sensing has enabled single-nucleus NMR and nanoscale NMR. Similar to conventional NMR and MRI, current DD-based quantum sensing utilizes the frequency fingerprints of target nuclear spins. The frequency fingerprints by their nature cannot resolve different nuclear spins that have the same noise frequency or differentiate different types of correlations in nuclear-spin clusters, which limit the resolution of single-molecule MRI. Here we show that this limitation can be overcome by using wave-function fingerprints of target nuclear spins, which is much more sensitive than the frequency fingerprints to the weak hyperfine interaction between the targets and a sensor under resonant DD control. We demonstrate a scheme of angstrom-resolution MRI that is capable of counting and individually localizing single nuclear spins of the same frequency and characterizing the correlations in nuclear-spin clusters. A nitrogen-vacancy-center spin sensor near a diamond surface, provided that the coherence time is improved by surface engineering in the near future, may be employed to determine with angstrom resolution the positions and conformation of single molecules that are isotope labeled. The scheme in this work offers an approach to breaking the resolution limit set by the frequency gradients in conventional MRI and to reaching the angstrom-scale resolution., Comment: 44 pages, 6 figures,1 table

We present a scheme of positioning a single electron spin with sub-nanometer resolution through multiple nitrogen-vacancy centers in diamond. With unwanted noise suppressed by dynamical decoupling, the spin coherence of each center develops characteristic oscillations due to a single electron spin located $4{\sim20}$ nm away from the centers. We can extract the position information from the characteristic electron spin-coherence oscillations of each center. This scheme is useful for high-resolution nanoscale magnetometry and spin-based quantum computing., Comment: 11 pages, 4 figures

Whether a quantum bath can be approximated as classical noise is a fundamental issue in central spin decoherence and also of practical importance in designing noise-resilient quantum control. Spin qubits based on bismuth donors in silicon have tunable interactions with nuclear spin baths and are first-order insensitive to magnetic noise at so-called clock-transitions (CTs). This system is therefore ideal for studying the quantum/classical nature of nuclear spin baths since the qubit-bath interaction strength determines the back-action on the baths and hence the adequacy of a classical noise model. We develop a Gaussian noise model with noise correlations determined by quantum calculations and compare the classical noise approximation to the full quantum bath theory. We experimentally test our model through dynamical decoupling sequence of up to 128 pulses, finding good agreement with simulations and measuring electron spin coherence times approaching one second - notably using natural silicon. Our theoretical and experimental study demonstrates that the noise from a nuclear spin bath is analogous to classical Gaussian noise if the back-action of the qubit on the bath is small compared to the internal bath dynamics, as is the case close to CTs. However, far from the CTs, the back-action of the central spin on the bath is such that the quantum model is required to accurately model spin decoherence., Comment: 5 pages, 3 figures

Many-body correlations can yield key insights into the nature of interacting systems; however, detecting them is often very challenging in many-particle physics, especially in nanoscale systems. Here, taking a phosphorus donor electron spin in a natural-abundance 29Si nuclear spin bath as our model system, we discover both theoretically and experimentally that many-body correlations in nanoscale nuclear spin baths produce identifiable signatures in the decoherence of the central spin under multiple-pulse dynamical decoupling control. We find that when the number of decoupling -pulses is odd, central spin decoherence is primarily driven by second-order nuclear spin correlations (pairwise flip-flop processes). In contrast, when the number of -pulses is even, fourth-order nuclear spin correlations (diagonal interaction renormalized pairwise flip-flop processes) are principally responsible for the central spin decoherence. Many-body correlations of different orders can thus be selectively detected by central spin decoherence under different dynamical decoupling controls, providing a useful approach to probing many-body processes in nanoscale nuclear spin baths.