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With the help of the one-dimensional random Potts-like model, we study the origins of fine structures observed on differential melting profiles of double-stranded DNA. We theoretically assess the effects of sequence arrangement on DNA melting curves through the comparison of results for random, correlated, and block sequences. Our results re-confirm the smearing out of the fine structure with the increase in chain length for all types of sequence arrangements and suggest that the fine structure is a finite-size effect. We have found that the fine structures on melting curves of chains comprised of blocks with correlations in sequence are more persistent, probably because of increased sequence disorder the blocks introduce. Many natural DNAs show a well-expressed fine structure of melting profiles. Our results for block sequences may suggest the existence of such sequence motifs in natural DNA sequences. [ABSTRACT FROM AUTHOR]

Homogenous melting at superheating temperature is commonly described by classical nucleation theory (CNT), but the atomic mechanism of the formation and development of critical liquid nuclei is still unclear. Molecular dynamics simulations were conducted to analyze the melting process of Ta. It is found that the process of subcritical liquid clusters evolving into critical liquid nucleus occupies most of the melting time, and merging between neighboring liquid clusters is the main path for subcritical liquid clusters to grow in size. Total melting time is strongly affected by the distribution of formation sites of subcritical liquid clusters, which has been considered random in homogenous melting. This work depicts a clear picture of the formation and development of liquid phase during the homogeneous melting process at superheating temperature and suggests an internal factor of melting mechanism. [ABSTRACT FROM AUTHOR]

Glaciologist Rob DeConto's research on polar climate change, specifically focusing on glaciers and ice sheets, is discussed in this article. DeConto explains the differences between Antarctica and Greenland and the challenges of understanding how the Antarctic ice sheet will behave in a warmer world. He also discusses the potential dangers of marine ice sheet instability and the impact of melting ice shelves on sea-level rise. The article emphasizes the uncertainties surrounding the rate of sea-level rise and the need for further research in this area. It highlights the term "deep uncertainty" used by the Intergovernmental Panel on Climate Change (IPCC) to describe the situation and the conservative nature of current projections. The author emphasizes the need for action to address the melting of ice sheets, as it poses a threat to infrastructure worldwide. [Extracted from the article]

Body-centered cubic bismuth (bcc-Bi) has long been considered an ideal pressure standard/calibrant; thus, the accurate knowledge of both its equation of state (EOS) and melting curve is of primary importance for future high pressure and high temperature experiments. However, its melting curve has never been measured experimentally beyond 5 GPa, and several theoretical calculations do not agree with each other and, in fact, differ by as much as a factor of 2 with regard to the bcc-Bi melting point at 50 GPa. Here, we present the calculation of the melting curve of bcc-Bi to 400 GPa via quantum molecular dynamics simulations using the Z method implemented with VASP. We also present the ab initio EOS of bcc-Bi as well as its principal Hugoniot, which both appear to be in excellent agreement with the available experimental data. At 100 GPa, the temperature extent (from zero to melt) of bcc-Bi is comparable to that of gold. At pressures of $\stackrel {\gt }{ \sim }500$ GPa, the melting curve of bcc-Bi is (quasi-)parallel to, being ${\sim } 1000$ K below that of rhenium, the highest melter above ${\sim } 30$ GPa among the elements of the third row of the periodic table, which makes bcc-Bi the second highest melter behind Re. [ABSTRACT FROM AUTHOR]

The elasticity of polymer networks, formed by cross-linking high molecular mass polymers in the melt state and then swollen by a solvent, involves contributions from both the presence of cross-link network junctions and the interchain interactions associated with the combined effect of excluded volume interactions and topological constraints that become modified when the network is swollen. We test the capacity of the previously developed localization model of rubber elasticity, a mean field "tube model," to describe changes in elasticity observed in classical experimental studies of the mechanical properties of this type of network. In order to obtain a satisfactory comparison to the experiments, it was found to be necessary to account for the independently observed tendency of the network junctions to become localized in the network with appreciable swelling, as well as the interchain interactions emphasized in previous discussions of the localization model. [ABSTRACT FROM AUTHOR]

The melting temperature is important for materials design because of its relationship with thermal stability, synthesis, and processing conditions. Current empirical and computational melting point estimation techniques are limited in scope, computational feasibility, or interpretability. We report the development of a machine learning methodology for predicting melting temperatures of binary ionic solid materials. We evaluated different machine-learning models trained on a dataset of the melting points of 476 non-metallic crystalline binary compounds using materials embeddings constructed from elemental properties and density-functional theory calculations as model inputs. A direct supervised-learning approach yields a mean absolute error of around 180 K but suffers from low interpretability. We find that the fidelity of predictions can further be improved by introducing an additional unsupervised-learning step that first classifies the materials before the melting-point regression. Not only does this two-step model exhibit improved accuracy, but the approach also provides a level of interpretability with insights into feature importance and different types of melting that depend on the specific atomic bonding inside a material. Motivated by this finding, we used a symbolic learning approach to find interpretable physical models for the melting temperature, which recovered the best-performing features from both prior models and provided additional interpretability. [ABSTRACT FROM AUTHOR]

Water can be vitrified if it is cooled at high rates, which makes it possible to outrun crystallization in so-called no man's land, a range of deeply supercooled temperatures where water crystallizes rapidly. Here, we study the reverse process in pure water samples by flash melting amorphous ice with microsecond laser pulses. Time-resolved electron diffraction reveals that the sample transiently crystallizes despite a heating rate of more than 5 × 106 K/s, even though under the same conditions, vitrification can be achieved with a similar cooling rate of 107 K/s. Moreover, we observe different crystallization kinetics for amorphous solid water and hyperquenched glassy water. These experiments open up new avenues for elucidating the crystallization mechanism of water and studying its dynamics in no man's land. They also add important insights into the laser melting and revitrification processes that are integral to the emerging field of microsecond time-resolved cryo-electron microscopy. [ABSTRACT FROM AUTHOR]

By employing brute-force molecular dynamics, umbrella sampling, and seeding simulations, we investigate homogeneous nucleation during melting and freezing of hard spheres. We provide insights into these opposing phase transitions from the standpoint of classical nucleation theory. We observe that melting has both a lower driving force and a lower interfacial tension than freezing. The lower driving force arises from the vicinity of a spinodal instability in the solid and from a strain energy. The lower interfacial tension implies that the Tolman lengths associated with melting and freezing have opposite signs, a phenomenon that we interpret with Turnbull's rule. Despite these asymmetries, the nucleation rates for freezing and melting are found to be comparable. [ABSTRACT FROM AUTHOR]

Titanium (Ti) is one of the most important metals used in several industrial applications, and the presence of spherical defect reduces its strength and stability. We simulate the melting of Ti crystals with a spherical void of radii 0.6, 0.8, 1.0, and 1.5 nm and also of the crystal without it. Ti is modeled using embedded atom method ,and all crystals are heated at 1 atm from 300 to 2200 K till it melts completely. All molecular dynamics trajectories are analyzed using radial distribution functions, bond-orientational order parameters, Voronoi tessellation, and velocity auto-correlation functions. The results show that 0.6, 0.8, 1.0, and 1.5 nm voids fill before the crystals melt and they fill immediately within few picoseconds; thereafter, atoms rearrange/order to crystal like arrangements, wherein overall crystallinity remains hcp for crystals with 0.6 and 0.8 nm void and changes to bcc for the crystals with 1.0 and 1.5 nm voids. For all crystals with and without void, melting takes place with the loss of both long- and short-range orders and not from liquid like nuclei as proposed by classical nucleation theory. [ABSTRACT FROM AUTHOR]

With the aim of producing realistic coarse-grained models of homopolymers, we introduce a tabulated backbone-oriented anisotropic potential. The parameters of the model are optimized using statistical trajectory matching. The impact of grain anisotropy is evaluated at different coarse-graining levels using cis-polybutadiene as a test case. We show that, at the same time, tuning the aspect ratio of the grains can lead to a better density and structure and may reduce the unphysical bond crossings by up to 90%, without increasing the computation time too much and thereby jeopardizing the main advantage of coarse-grained models. [ABSTRACT FROM AUTHOR]

Polyrotaxanes, which consist of mechanically interlocked bonds with rings threaded onto soft polymer chains, exhibit unique mechanical properties and find applications in diverse fields. In this study, we investigate the anomalous segmental dynamics of supercooled polyrotaxane melts using coarse-grained molecular dynamics simulations. Our simulations reveal that the presence of rings effectively reduces the packing efficiency, resulting in well-contained local motion even below the glass transition temperature. We also observe variations in dynamical free volume, characterized by the Debye–Waller factor, which shows a minimum at a ring coverage of 0.1 on threading chains. Such a non-monotonic dependence on coverage shows great consistency in structural relaxation time and dynamic heterogeneity. Specifically, the high segmental mobility of threading linear chains at large coverage can be attributed to the increased dynamical free volume due to supported rigid rings. However, such anomalous segmental dynamics is limited to length scales smaller than one ring size. Beyond this characteristic length scale, the diffusion is dominated by topological constraints, which significantly reduce the mobility of polyrotaxanes and enhance the dynamic heterogeneity. These findings offer microscopic insights into the unique packing structures and anomalous segmental dynamics of supercooled polyrotaxane melts, facilitating the design of advanced materials based on mechanical interlocking polymers for various applications. [ABSTRACT FROM AUTHOR]

From the perspective of a bond-order-length-strength correlation, we put forward an analytical solution to describe the size, shape, and wall thickness dependency of melting temperature, entropy, and enthalpy for metallic nanostructures. Theoretical reproduction of measurements clarified that (i) when the crystal size reduces, the atomic coordination number lowers, the atomic cohesive energy decreases, and the surface-to-volume ratio increases; (ii) at the same equivalent radius, with the decrease in the number of sides for polyhedral nanoparticles and polygonal nanowires or nanotubes, the melting temperature, entropy, and enthalpy depress; and (iii) the melting temperature, entropy, and enthalpy of nanotubes are always lower than those of nanowires with the same cross-sectional radius. The present formulation is accurate and convenient, which not only shows deeper insight into the physical origins of a melting thermodynamic property response to perturbations but also provides guidance for the design and optimization of electronic nanodevices. [ABSTRACT FROM AUTHOR]

Boron phosphide (BP) is a (super)hard semiconductor constituted of light elements, which is promising for high demand applications at extreme conditions. The behavior of BP at high temperatures and pressures is of special interest but is also poorly understood because both experimental and conventional ab initio methods are restricted to studying refractory covalent materials. The use of machine learning interatomic potentials is a revolutionary trend that gives a unique opportunity for high-temperature study of materials with ab initio accuracy. We develop a deep machine learning potential (DP) for accurate atomistic simulations of the solid and liquid phases of BP as well as their transformations near the melting line. Our DP provides quantitative agreement with experimental and ab initio molecular dynamics data for structural and dynamic properties. DP-based simulations reveal that at ambient pressure, a tetrahedrally bonded cubic BP crystal melts into an open structure consisting of two interpenetrating sub-networks of boron and phosphorous with different structures. Structure transformations of BP melt under compressing are reflected by the evolution of low-pressure tetrahedral coordination to high-pressure octahedral coordination. The main contributions to structural changes at low pressures are made by the evolution of medium-range order in the B-subnetwork and, at high pressures, by the change of short-range order in the P-subnetwork. Such transformations exhibit an anomalous behavior of structural characteristics in the range of 12–15 GPa. DP-based simulations reveal that the Tm(P) curve develops a maximum at P ≈ 13 GPa, whereas experimental studies provide two separate branches of the melting curve, which demonstrate the opposite behavior. Analysis of the results obtained raises open issues in developing machine learning potentials for covalent materials and stimulates further experimental and theoretical studies of melting behavior in BP. [ABSTRACT FROM AUTHOR]

The possible existence of a liquid–liquid critical point in deeply supercooled water has been a subject of debate due to the challenges associated with providing definitive experimental evidence. The pioneering work by Mishima and Stanley [Nature 392, 164–168 (1998)] sought to shed light on this problem by studying the melting curves of different ice polymorphs and their metastable continuation in the vicinity of the expected liquid–liquid transition and its associated critical point. Based on the continuous or discontinuous changes in the slope of the melting curves, Mishima [Phys. Rev. Lett. 85, 334 (2000)] suggested that the liquid–liquid critical point lies between the melting curves of ice III and ice V. We explore this conjecture using molecular dynamics simulations with a machine learning model based on ab initio quantum-mechanical calculations. We study the melting curves of ices III, IV, V, VI, and XIII and find that all of them are supercritical and do not intersect the liquid–liquid transition locus. We also find a pronounced, yet continuous, change in the slope of the melting lines upon crossing of the liquid locus of maximum compressibility. Finally, we analyze the literature in light of our findings and conclude that the scenario in which the melting curves are supercritical is favored by the most recent computational and experimental evidence. Although the preponderance of evidence is consistent with the existence of a second critical point in water, the behavior of ice polymorph melting lines does not provide strong evidence in support of this viewpoint, according to our calculations. [ABSTRACT FROM AUTHOR]

We investigated the melting behavior of four CPs with one-dimensional structures from a thermodynamic point-of-view. The difference in melting points depending on the crystal structures is observed. The interactions within the crystals were analyzed using DFT calculations. These analyses suggest that entropic terms dominate the melting points. [ABSTRACT FROM AUTHOR]

Three‐dimensional architecture of segregated network can significantly influence thermal behaviors of polymer composites, such as the melting temperature (Tm) and degradation temperature. However, there have been few systematic studies on the thermal behaviors of polypropylene (PP) composites with a segregated network that the fillers were selectively located in the polymeric particle interfaces. In this study, we found that introduction of the segregated graphene nanoplatelet (GNP) network induced the maximum Tm of 177.6°C, extending the operating temperature by 11.5°C compared to the Tm of composites with randomly dispersed GNPs. In contrast, the thermal degradation temperature of polymer composites varied insignificantly regardless of introduction of the segregated network because the thermal degradation of the polymer matrix occurred after the PP chains melted and the segregated GNP network collapsed at temperatures above the Tm. Therefore, the incorporation of a segregated network can be an effective option for enhancing the Tm and extending the operating temperature of the polymer composites. Highlights: Segregated network induced the remarkable increase in melting temperature.Meanwhile, the segregated network had little effect on decomposition temperature.Segregated composite was efficient strategy for expanding operating temperature. [ABSTRACT FROM AUTHOR]

In fusion‐based metal additive manufacturing (MAM), the high‐intensity energy input leads to serious evaporation, but how evaporation induces composition evolution and variation and further impacts microstructure and mechanical properties remain a knowledge gap. Here a model integrating composition evolution with molten pool dynamics is developed to reproduce temperature‐ and composition‐dependent evaporative losses and subsequent transport during laser melting. Together with comprehensive experimental characterizations and tests, the simulation results illustrate varying evaporation rates of different elements altering compositions, resulting in a 3D cirrus‐shaped concentration distribution, which significantly impacts the mechanical properties. The simulations reproduce the detailed composition evolution from surface evaporation to molten pool transport and reveal underlying mechanisms relating the composition, temperature, fluid flow, and cracking, which is challenging to observe experimentally. This study elucidates the critical role of evaporation‐induced composition evolution in determining microstructure and mechanical properties. In future alloy design for MAM, integrating initial composition and manufacturing parameters is imperative, where composition evolution simulation offers valuable guidance. [ABSTRACT FROM AUTHOR]

Disorder‐induced electronic localization is responsible for the OFF state of the Ovonic threshold switching (OTS) device, which is an indispensable component in the present 3D‐crossbar‐architecture phase‐change memory circuit. However, the atomic mechanism of the OTS device, especially the role of thermal effect, remains a long‐term open question. Recent researches suggest that the working current of the OTS ON‐state is often large enough to melt the adjacent phase‐change memory material in the OTS+PCM devices. Thus, Joule heating‐induced atomic/electronic structure transition in OTS materials must be seriously considered. Taking the typical OTS material GeSe as an example, first‐principles calculations reveal an unexpected electronic delocalization induced by the enhanced structural disorder upon solid‐liquid transition. Meanwhile, as the temperature rises, the band gap decreases or even closes, leading to an increase in carrier concentration. Therefore, the melting filament with high conductivity could be responsible for the holding‐ON state of OTS materials. The results in this study may provide possible explanations for some puzzles of OTS devices, such as the reasons for holding‐ON state and limited endurance. [ABSTRACT FROM AUTHOR]

In view of the health concerns associated with high sugar intake, this study investigates methods to enhance sweetness perception in chocolate without increasing its sugar content. Using additive manufacturing, chocolate structures were created from masses with varying sugar and fat compositions, where hazelnut oil served as a partial cocoa butter replacement. The study found that while variations in sugar content minimally affected the physical properties of the chocolate masses, hazelnut oil significantly modified melting behavior and consumption time. Chocolate masses with higher hazelnut oil content but similar sugar content exhibited a 24% increase in sweetness perception, likely due to accelerated tastant (i.e., sucrose) release into saliva. Multiphase structures, designated as layered, cube-in-cube, and sandwich structures, exhibited less sensory differences compared to the homogeneous control. Nonetheless, structures with hazelnut oil-rich outer layers resulted in an 11% increase in sweetness perception, even without sugar gradients. This suggests that tastant release plays a more critical role than structural complexity in modifying sweetness perception. This research highlights the efficacy of simpler multiphase structures, such as sandwich designs, which offer sensory enhancements comparable to those of more complex designs but with reduced manufacturing effort, thus providing viable options for industrial-scale production. [ABSTRACT FROM AUTHOR]

The temperature of melt blowing (MB) and melt spun fibers is frequently measured using infrared thermography (IRT). However, measurements are affected by the size and curvature of the fiber and by reflected radiation from the nozzle. A procedure was developed to obtain accurate measurements of fiber temperature, which corrects fiber size, fiber curvature, and reflected radiation. This procedure is more general than the ones used so far to correct fiber temperature because it corrects the three abovementioned factors using a single correction formula, this being the first time that fiber temperature correction for reflected radiation has been accounted for. It is also more accurate because it uses the local fiber diameter to correct fiber curvature, instead of mean fiber diameter. The procedure was used to measure the temperature of MB adhesive fibers produced by two multi-hole nozzle designs, the results indicating that, in melt blowing applications, the distortion caused by fiber curvature and reflected radiation on the measurement proves to be far more significant than that caused by fiber size, while correction generally leads to an increase in fiber temperature. Considerations as to the effect of different parameters on temperature correction, as well as the quality of thermographic images, are also provided throughout the text. The conclusions emerging from this study allow more accurate temperature measurements of melt blown and melt spun fibers to be obtained. [ABSTRACT FROM AUTHOR]

This paper describes secondary crystallized melt inclusions trapped in magnesiochromite of lherzolite xenolith from the V. Grib kimberlite pipe (Arkhangelsk diamondiferous province). It is shown that the inclusions are microportions of melt related to magmatism, which was further formed this pipe. Daughter minerals assemblage of inclusions in magnesiochromite contain Na‒K‒Ca-, Na‒Mg-, Ca‒Mg-, Mg-, and Ca-bearing carbonates; Na–Mg carbonates with additional PO , Cl–, and SO anions; chlorides; sulfate; phosphate; and silicate. The mineral assemblage of daughter phases, the amount of carbonates (77 vol %) and silicates (tetraferriphlogopite) (15 vol %) and Ca : Na : K ratios within the inclusions indicate that this melt was an alkali-enriched carbonate liquid with a low content of SiO2 (≤6 wt %) and H2O (≤0.6 wt %). As is known, serpentine in kimberlites is a major H2O-bearing mineral, but the problem of water sources during serpentinization of kimberlites and an actual H2O content in kimberlite melts is a controversial issue. The absence of serpentine and the low H2O content (≤0.6 wt %) of the studied melt inclusions in comparison with those of kimberlites of the V. Grib kimberlite pipe (10‒14 wt %) indicate the key role of external fluids during serpentinization of these kimberlites. [ABSTRACT FROM AUTHOR]

A controlled fragmentation method, by deep laser melting, for a multi-purpose projectile (penetrator) is presented, using a full-sized projectile with 1100 mm long, 148 mm diameter, and 17.8 mm wall thickness. Effects on penetration and fragmentation performance, for various laser melting parameters, are explored through penetration and fragmentation field tests. It is shown that it is possible to attain an optimal local microstructure, in the melted regions, that ensures a pre-defined fragmentation pattern upon explosion without compromising on the penetration capabilities. [ABSTRACT FROM AUTHOR]

A revisiting of the Lindemann criterion under the recently established minimal viscosity formulation is proposed which uncovers intriguing insights into the melting process. The approach suggests that melting involves competition between the electron rest energy and the thermal one caused by temperature increase when considering a defect-free crystal structure. However, when accounting for the role of vacancies in the melting process, the analysis suggests that the key competing factors are the thermal energy and the one needed for vacancy migration. The estimated value of the Lindemann constant, in this case, is close to the reported values and with recent simulations studying the correlation between Born and Lindemann melting criteria. [ABSTRACT FROM AUTHOR]

The effect of varying amounts (1.0–5.0 wt %) of TiO 2 as an additive on the interfacial behavior between the MgAl 2 O 4 crucible materials and molten K417G superalloys during the vacuum induction melting has been characterized. Experimental results indicate that the phases of the TiO 2 -doped MgAl 2 O 4 materials were identified as MgAl 2 O 4 and minor amounts of MgTiO 3 after sintering at 1680°C for 1 h. When the TiO 2 -doped MgAl 2 O 4 crucibles were in contact with K417G melt, a reaction layer of MgTiO 3 was formed at the inner wall of the crucible. Moreover, some Al3+ and O2- were expelled toward the alloy side from MgTiO 3 near the interface to form Al 2 O 3 phases, and even form a continuous aluminum oxide layer in the 5 wt %TiO 2 -doped crucible after the melting experiment. Furthermore, only MC carbide with MgAl 2 O 4 as the core (MgAl 2 O 4 -(Ti, Mo)C hybrid-type) in the K417G alloy after the melting experiment can be observed, indicating that physical erosion predominates. [ABSTRACT FROM AUTHOR]

The structures and dynamical properties of core–shell bimetallic Ni-Ag nanoalloys varying with different sizes and compositions have been studied using Monte Carlo (MC) and Molecular Dynamic (MD) simulations. We have considered the compositions in which the size of the core increases while the total number of atoms is fixed. In this sense, two (Ni13Ag134, Ni55Ag92), three (Ni13Ag296, Ni55Ag254, Ni147Ag162) and four (Ni13Ag548, Ni55Ag506, Ni147Ag414 and Ni309Ag252) compositions were considered for 147, 309 and 561 atoms, respectively. Highly symmetric Mackay icosahedral structures with centred symmetric cores appear for these specific sizes and compositions. Also, smaller Ni atoms tend to occupy the core and Ag atoms prefer to segregate to the surface of the nanoalloy due to its lower surface and cohesive energy. Then, the lowest energy structures obtained by Basin Hopping MC simulations were used as initial configurations for melting simulations. The transitions between different chemical ordering patterns with increasing temperature are possible in these systems while they are still in the solid state. Although there are clear differences in the melting process of the compositions with increasing size of the core, for all cases, surface melting occurs indicating that the Ag shell melts before the inner Ni core. [ABSTRACT FROM AUTHOR]

Heat transfer analysis of Casson nanofluid flow with single and multi-walled carbon nanotubes and Al 2 O 3 or GO nanoparticles, which are suspended in kerosene oil, is elucidated. The impact of second slip conditions on the flow system's velocity, temperature, and solutal is considered, along with the effect of melting heat transfer and nanoparticle shape factor. The appraisal's novelty is the incorporation of second slip conditions on kerosene oil flow containing with new three distinct nanoparticles. Similar variables are used to convert the governing equations into ordinary equations which are then solved using homotopy perturbation method (HPM). The profiles of velocity, temperature, concentration, and Bejan number are estimated for various values of relevant parameters. Results demonstrate that the Bejan number declines due to enhance the first thermal parameter and second velocity parameter, while the contrary tendency is examined by raising the Casson fluid parameter and first velocity parameter. Al 2 O 3 -SWCNT-MWCNT TNF responds more strongly than GO-SWCNT-MWCNT TNF when the temperature is coupled with (nanoparticles volume fraction, first thermal parameter), axial velocity with (nanoparticles volume fraction, first velocity parameter, first thermal parameter), and Bejan number with melting parameter. This study is to help rocket engine designers identify the optimal nanofluids for cooling and fuel. [ABSTRACT FROM AUTHOR]

Complex formulations based on poly(hydroxybutyrate) (PHB) and poly(hydroxybutyrate-co-valerate) (PHBV) were studied to statistically assess the effect of formulation (i.e., hydroxyvalerate (HV) content, plasticiser chemistry and content, filler type and content) on their thermal properties and degree of crystallinity (Xc). In binary systems, thermal properties were mainly influenced by filler type rather than its content, while for plasticised systems the changes were dependent on both increasing plasticiser content and PHB-plasticiser compatibility. Variations in HV content affected the ability of the polymer chain to fold, leading to significant changes in both thermal properties and Xc. In ternary systems, presence of multiple additives and consequent changes in intermolecular interactions lead to multifaceted behaviours that were not easily predicted by results from binary systems alone. For example, melting temperature did not show dependence on filler presence in PHBV systems despite introducing variations in pure PHB systems. In general, thermal properties and Xc are affected by all parameters studied, with changes in system free volume (i.e. changes in HV content and plasticisation) playing the most significant role. These results expand the understanding of factors controlling crystallisation in complex polymer systems and can be used to control matrix properties in new generations of packaging materials. [ABSTRACT FROM AUTHOR]

Marine‐terminating glacier fjords play a central role in the transport of oceanic heat toward ice sheets, regulating their melt. Mixing processes near glacial termini are key to this circulation but remain poorly understood. We present new summer measurements of circulation and mixing near a marine‐terminating glacier with active sub‐glacial discharge. 65% of the fjord's vertical overturning circulation is driven by the buoyant plume, however we newly report intense vertical and horizontal mixing in the plume's horizontal spreading phase, accounting for the remaining 35%. Buoyant plume theory supports 2%–5% of total glacial melt. Thus, most of the heat associated with vertical overturing short‐circuits the glacial front. We find however that turbulence in the horizontal spreading phase redistributes the short‐circuited heat back into the surface waters of the near‐glacial zone. Our findings highlight the need for further research on the complex mixing processes that occur near the glacier terminus. Plain Language Summary: Melting of glacial ice is the single largest contributor to global sea‐level rise. Many glaciers flow into the ocean where the near‐vertical ice wall is bathed in relatively warm sea water. Freshwater from ice surface melting seeps down through cracks and crevasses in the glacier to be discharged at the base of the ice wall, many tens to hundreds of meters below the sea surface. This fresh water rises from the depths as a highly turbulent plume, drawing in and pushing upwards the surrounding seawater, eventually spreading horizontally as a mixture of fresh discharge and mixed‐in seawater. Few measurements exist in the dangerous zone where iceberg often calve. Using data from a robotic platform we show that the vertical rise and the horizontal spreading of fresh water both play important roles in the total ocean‐induced melting of the glacial face in this type of system. Key Points: Entrainment into the buoyant plume drives ∼65% of fjord vertical overturning circulationIntense turbulent mixing in the horizontal spreading phase of the plume drives the remaining ∼35%95%–98% of the heat in the rising plume short‐circuits the glacier, to be redistributed into glacial proximal waters by horizontal mixing [ABSTRACT FROM AUTHOR]

Bright‐band defects frequently occur on as‐cast strips in the twin‐roll strip‐casting process, particularly at low‐casting speeds, with intervals of ≈200 mm. Additionally, the cast‐rolling force also exhibits minor fluctuations. With increasing casting speeds, the spacing between bright‐band defects widens, and the severity of these defects diminishes. When the casting speed reaches a certain threshold, defects almost entirely disappear. Detailed analysis of the underlying causes of this phenomenon is essential for effectively preventing defect formation. In this study, the numerical simulation method is employed to analyze casting rolls’ thermal deformation and the melt pool's solidification behavior, based on the production site equipment and process conditions. The causes of defects in as‐cast strips are thoroughly analyzed based on simulation results, in conjunction with variations in the cast‐rolling force. In this study, it is demonstrated that the thermal deformation of casting rolls and the position of the solidification endpoints collectively contribute to the fluctuations in cast‐rolling force and are the primary causes of bright‐band defects. Fundamental principles for preventing defects are provided based on actual on‐site production. Furthermore, simulation results contribute to establishing a theoretical basis for selecting process parameters and controlling cast‐rolling force during production. [ABSTRACT FROM AUTHOR]

With the ongoing decline in Arctic sea ice extent, the accurate simulation of Arctic sea ice in coupled models remains an important problem in climate modelling. In this study, the substantial CMIP6 model spread in Arctic sea ice extent and volume is investigated using a novel, process-based approach. An observational dataset derived from the Arctic Ice Mass Balance buoy (IMB) network is used to evaluate the thermodynamic and mass balance diagnostics produced by a subset of CMIP6 models, to better understand the model processes that underlie the large-scale sea ice states. Due to the sparse nature of the IMB observations, the evaluation is performed by comparing distributions of modelled and observed fluxes in the densely sampled regions of the North Pole and Beaufort Sea. We find that all fluxes are routinely biased high in magnitude with respect to the IMB measurements by nearly all models, with too much melt in summer, and too much conduction and growth in winter, even as a function of ice thickness. We also show that choices of thermodynamic parameterisation substantially influence particular fluxes in physically realistic ways, and that these effects likely modulate the large-scale relationship between ice thickness and ice growth and melt in the CMIP6 models. [ABSTRACT FROM AUTHOR]

The article explores the connection between melting permafrost and heavy metals in mountain lakes. It explains that as permafrost melts and glaciers retreat, heavy metals can become more concentrated in streams and lakes, especially in areas with sulfide-containing bedrock. This is due to acid mine drainage, which lowers the pH of the water and causes heavy metals to dissolve. The article also presents a series of experiments that can be used in classrooms to demonstrate the effects of acid mine drainage on water quality. These experiments allow students to observe the pH changes and increased copper content in water samples exposed to pyrite. The experiments provide a hands-on learning experience for high school chemistry and environmental science classes. [Extracted from the article]

The memory of crystalline phase in the melt of isotactic polypropylene (iPP) in regiodefective samples of iPP characterized by different concentrations regiodefects, constituted by secondary 2,1 propene units, is studied. The self‐nucleation (SN) experiments have demonstrated that the presence of 2,1 regiodefects produces a strong memory of the crystalline phase in the melt that persists up to temperatures much higher than the melting temperature. The extension of the heterogeneous melt (domain II) containing self‐nuclei increases with increasing the concentration of regiodefects. The higher the concentration of regiodefects the higher the temperature at which the self‐nuclei are dissolved and the homogeneous melt is achieved. This demonstrates that a strong memory of the crystalline phase of iPP in the melt exists not only in copolymers with noncrystallizable bulky comonomeric units rejected from the crystals but even when small defects are largely included in the crystals. [ABSTRACT FROM AUTHOR]

In this study, tubes filled with PCM as a thermal energy storage unit with an indirect air heater are used to store and recover solar thermal energy. Two different configurations of PCM-filled tubes (inline and staggered) in the unit are considered and compared with the PCM-filled plate unit. In all cases, the amount of the PCM is the same. The effects of airflow rate, diameter of tubes and inlet temperature on the charging and discharging rates are studied. Results showed that the PCM tube unit is more efficient than the PCM plate unit. The thermal performance is enhanced with the increase of the air mass flow rate. Results also revealed that the phase change rate in staggered configurations is between 7% and 36% (depending on the airflow rate) greater than that in the inline ones. By reducing the tube diameter, the melting and solidification processes are performed more quickly due to the rise of the overall heat transfer surface area. The influence of the temperature difference between the inlet air and PCM is more effective than the other considered effects where the 10 °C increase of the temperature difference enhances the charging rate by a factor of 2. [ABSTRACT FROM AUTHOR]

A 3-D Finite Element (FE) model was established to simulate the laser cladding of nickel powder for in situ repairing AISI 410 stainless steel. The temperature distribution field was estimated at six different points using low laser power of 450 W and a scanning speed of 2 mm/s. This study used a moving laser heat source in COMSOL to simulate the laser cladding process. The proposed FE model investigated the temperature field in two cases: (1) in situ repairing the defect by laser cladding without preheating and (2) in situ repairing the defect by laser cladding technique after preheating the cavity made on the substrate. A time-temperature profile was obtained after the simulation in both cases. The results of both cases were compared and analyzed. When the cladding material is poured into the preheated cavity, its temperature rises due to the heating effect obtained from the cavity, resulting in a higher maximum temperature after the cladding process. It was observed that after the cladding process, the maximum temperature was higher in the case of laser cladding after preheating the substrate (2400.49 K) compared to the maximum temperature in cladding without preheating the substrate (1770 K). Therefore, a molten pool is formed, solidifying rapidly to form a clad coating with better metallurgical bonding and enhanced surface properties. [ABSTRACT FROM AUTHOR]

In this paper, a numerical model is presented for the simulation of melting and microstructure formation during a layer-by-layer laser melting process. The model couples the solution of thermal and species transport with a sharp-interface enthalpy-based phase change model to track the melting and solidification in each layer. The effect of the moving laser energy source is implemented through a transient moving heat flux boundary condition. Transition from the completion of a layer to the start of a new layer is implemented using a domain translation technique, keeping the size of the computational domain constant. The model captures the remelting of a previous layer during the formation of a new layer. Simulations are performed to predict the segregation and grain structure formation during multi-layered laser melting of Al-10%Cu alloy. It is seen that the laser scan direction governs the grain orientation with grains growing in the direction of laser travel. Also, the remelting of the previously formed grains in the adjacent layer affects the species concentration and grain structure in the subsequent layer. Higher power, lower laser scan speed, and smaller laser radius leads to the formation of longer grains with larger aspect ratio spanning multiple layers. [ABSTRACT FROM AUTHOR]

AbstractThe meltdown of a fuel rod is a severe accident resulting from the overheating of the reactor core. In the present study, a numerical investigation of this process, focusing on the loss of coolant has been conducted. The objective of this study is to conduct a numerical simulation of transient heat conduction and melting at various points within a typical pressurized water reactor fuel rod. In this analysis, heat conduction in the radial direction of a fuel rod, including the UO2 fuel pellet, the gap, and the zircaloy cladding, is investigated. The FRAPCON steady-state code is employed to calculate the operational parameters of the fuel rod. The calculated parameters, such as coolant and fuel temperatures, fission gas fraction, gap heat transfer coefficient, and burnup, are utilized to evaluate and compare the melting phenomena at different time intervals.In the investigation of the phase change in various parts of the pellet and fuel rod, the explicit finite difference (FD) method is utilized with enthalpy instead of temperature-dependent equations. Finally, the temperature history, phase change, and melting map at different points along the radial and axial directions of the fuel rod during coolant loss and heat transfer coefficient reduction are evaluated based on various operating parameters of the core. To enhance the quality of the results, an uncertainty analysis of effective parameters is conducted.According to this analysis, the heat transfer coefficient of the coolant under accident conditions (0.2 ± 5% kWm−2K−1) and the thermal conductivity of the fuel have the most significant impact on the temperature history and melting process. Highlights include the following:1. The meltdown of a nuclear fuel rod is analyzed under a loss-of-coolant accident.2. The enthalpy formula is discretized by the explicit FD numerical method.3. Effective parameters in melting, such as coolant temperature, burnup, and gap heat transfer coefficient, are obtained by FRAPCON.4. The temperature history, phase changes, and melting map of various radial points within the fuel pellet and cladding along the axial direction of the fuel rod are determined. [ABSTRACT FROM AUTHOR]

The exploration of nonlinear optical crystals with ultraviolet (UV) transparent ranges and easy-to-grow large-size crystals is one of the current research interests. Herein, by combining borate and phosphate groups, a novel congruently melting alkali-mixed metal borophosphate, Li3Na7B4P6O26 (LNBPO) with UV transparency was successfully designed and synthesized using a high-temperature flux method. LNBPO crystallizes in the non-centrosymmetric (NCS) and polar orthorhombic space group Pca21 (no. 29), showcasing interesting (B2P3O13)∞ chains along the c axis. Notably, LNBPO has a moderate second harmonic generation (SHG) response (∼0.38 × KDP) and displays a wide transmission ranging from 0.22 to 3.68 μm, as measured by a [001]-oriented crystal wafer. Furthermore, a high-quality single crystal of LNBPO with sizes up to 14 × 14 × 12 mm3 was grown using the top-seeded solution growth method. The refractive indices of LNBPO were determined by applying the minimum deviation angle method. These results show that LNBPO possesses a phase-matching wavelength as short as 483 nm, indicating its potential as a new UV NLO crystal. [ABSTRACT FROM AUTHOR]

This study reviews existing simulation models and describes a selected model for analysing combustion dynamics in hydrogen and natural gas mixtures, specifically within non-ferrous melting furnaces. The primary objectives are to compare the combustion characteristics of these two energy carriers and assess the impact of hydrogen integration on furnace operation and efficiency. Using computational fluid dynamics (CFD) simulations, incorporating actual furnace geometries and a detailed combustion and NOx emission prediction model, this research aims to accurately quantify the effects of hydrogen blending. Experimental tests on furnaces using only natural gas confirmed the validity of these simulations. By providing precise predictions for temperature distribution and NOx emissions, this approach reduces the need for extensive laboratory testing, facilitates broader exploration of design modifications, accelerates the design process, and ultimately lowers product development costs. [ABSTRACT FROM AUTHOR]

This article presents the results of U–Pb (ID-TIMS) geochronological, geochemical, and Sm–Nd isotopic-geochemical studies of metavolcanic rocks of the Djagdagle Formation, which belong to the key elements of the Bureya continental massif. It was established that the age of metavolcanic rocks of the Djagdagle Formation is 217 ± 7 Ma and corresponds to the Late Triassic. This fact contradicts the traditional ideas, according to which the Djagdagle formation is the Early Precambrian in age. The results of Sm–Nd isotope studies of the metavolcanic rocks indicate the melting of rocks of continental crust with Paleoproterozoic model ages during the formation of initial melts. The new geochronological data and previously published data allow us to distinguish at least two stages of magmatic activity in the Triassic within the northwestern part of the Bureya massif: ~243 and 219–201 Ma. On the basis of synchronous of Neoproterozoic, Early Paleozoic, Late Paleozoic, and Early Mesozoic magmatic events in the geologic history of the Bureya and Songnen–Zhangguangcai Range massifs, an assumption about their common geological history at least since the Late Neoproterozoic has been proposed. The close spatial position of metavolcanic rocks of the Djagdagle Formation and the Mongol–Okhotsk Orogenic Belt, their Late Triassic age (217 ± 7 Ma), and geochemical features allow us to link the formation of initial melts of metavolcanic rocks of this formation with within-plate magmatism in the rear part of subduction zone of the Mongol–Okhotsk Ocean beneath the northern (in modern coordinates) margin of the Bureya continental massif. [ABSTRACT FROM AUTHOR]

The list of standard abbreviations for JDS is available at adsa.org/jds-abbreviations-24. Nonstandard abbreviations are available in the Notes. Diarrheagenic Escherichia coli (DEC) is a kind of foodborne pathogen that poses a significant threat to both food safety and human health. To address the current challenges of high prevalence and difficult subtyping of DEC, this study developed a method that combined multiplex PCR with high-resolution melting (HRM) analysis for subtyping 5 kinds of DEC. The target genes are amplified by multiplex PCR in a single well, and HRM curve analysis was applied for distinct amplicons based on different melting temperature (Tm) values. The method enables discrimination of different DEC types based on characteristic peaks and distinct Tm values in the thermal melting curve. The assay exhibited 100% sensitivity and 100% specificity with a detection limit of 0.5 to 1 ng/μL. The results showed that different DNA concentrations did not influence the subtyping results, demonstrating this method owed high reliability and stability. In addition, the method was also used for the detection and subtyping of DEC in milk. This method streamlines operational procedures, shorts the detection time, and offers a novel tool for subtyping DEC. [ABSTRACT FROM AUTHOR]

Aircraft encounters with volcanic ash have caused significant damage over the past 40 years, resulting in particular attention being given to the issue. We analyzed the volcanic ash-aircraft encounter database published by the USGS. We added new volcanic eruptions and parameters such as eruption types, and dry–wet. Then, we applied standard and advanced statistical methods. Over 130 encounters have been documented in the mentioned database, with volcanic ash causing severe abrasions to the windshield, airframe, wings, and engine components. In nine cases, aircraft engines failed. We applied the binary regression analysis and some laboratory melting experiments on volcanic ash. Besides phreatomagmatism, we use the term external water in this work to describe meteoric water that enters volcanic plumes through precipitation or melting ice on ice-capped volcanoes. We demonstrated that engine failure occurs when our regression analyses undergo dry-to-wet conditions. In other words, statistically, there is a positive correlation between wet ash encounters with aircraft and engine failure incidents. Moreover, experiments conducted at 900 °C and under 40 bar pressure showed increased sintering in the dry sample, while melting textures were more prevalent in hydrated samples. We concluded that despite the various eruptive dynamics of volcanic ash, the introduction of external water into the volcanic plumes, probably causing instantaneous hydration of volcanic ash, is a common factor in engine failure incidents. Thus, we have identified the reasons behind engine failures during encounters between aircraft and volcanic ash and the specific damage that can occur depending on the type of eruption involved. [ABSTRACT FROM AUTHOR]

The results of theoretical and experimental studies of convective vortex currents formed during ice melting, as well as physical modeling of the phenomenon of spontaneous rotation of an ice disk on the water surface, are presented. It is shown that the cause of the observed movements on the surface of initially quiescent water is a cellular convective flow generated by the process of ice melting at the lower boundary of the disk, and a new physical model of such rotation is constructed. [ABSTRACT FROM AUTHOR]

Recent seismological studies of the Martian core revealed its relatively low density, suggesting the presence of large amounts of light elements including oxygen and carbon in addition to sulfur. In order to reveal crystallizing solids in the light-element-rich core of Mars, we performed high-pressure melting experiments on Fe-S-O-C alloys at 26–49 GPa using a laser-heated diamond-anvil cell. The liquidus phase relations in the Fe-S-O-C system were determined based on textural and chemical characterizations of recovered samples. The results show that Fe-S-O-C liquids crystallize FeO or Fe 3 C in the presence of small amounts of O or C in liquids. Accordingly the liquidus fields of Fe 3 S and Fe 2 S are small, and the quaternary eutectic point is found to be close to the Fe-Fe 3 S binary eutectic point. Under Martian core conditions, S-rich liquids have low liquidus temperatures to crystallize FeO or Fe 3 C compared to S-poor liquids. The pressure dependence of liquidus temperatures suggests that crystallization of Mars' core starts at the center upon cooling. According to the FeO-Fe 3 C cotectic surfaces and their liquidus temperatures, an FeO and/or Fe 3 C inner core is predicted unless the Martian core remains entirely liquid. [ABSTRACT FROM AUTHOR]

The magmatic controls on the formation of giant epithermal Au deposits genetically associated with alkaline magmatic systems are not well understood. The general model, which attributes the generation of alkaline magmas to low-degree partial melting of metasomatized lithospheric mantle in a post-subduction tectonic setting cannot easily explain why some of these magmas are highly fertile for Au mineralization while others are not. This knowledge gap hampers the effective exploration of this economically important deposit type. In this study, we focused on the alkaline magmatism on Lihir Island and the Conical Seamount, Papua New Guinea, that gave birth to the Ladolam deposit and investigated the composition of silicate melt inclusions (SMIs) hosted in primitive volcanic rocks. Our findings offer important and novel insights into the early and deep magmatic processes that controlled the ore fertility of the melts that produced the largest known alkalic-type epithermal Au deposit on Earth. Olivine- and clinopyroxene-hosted primitive SMIs reveal nepheline-normative ankaramitic melt compositions derived from high-degree partial melting of metasomatized clinopyroxene-dominated lithologies, presumably amphibole-bearing clinopyroxenitic cumulates and metasomatically overprinted lithospheric mantle, both produced during earlier active subduction. These ultra-calcic parental melts are relatively low in H 2 O, S, and Cl, but enriched in Cu and highly oxidized. Due to their low water contents, significant clinopyroxene crystallization over a narrow temperature interval drove melt evolution from ankaramitic to alkaline compositions by strongly increasing incompatible element concentrations. Despite initially low H 2 O concentrations, evidence for high-temperature degassing is present in the form of low-density single-phase fluid inclusions co-existing with SMIs in clinopyroxene. This degassing event led to a strong decrease of S concentrations in the melt, whereas Cl and chloride-complexing elements remained largely unaffected. We propose that high-temperature volatile saturation as consequence of significant clinopyroxene crystallization is a key process for subsequent epithermal Au mineralization and can explain the efficient separation of Au from Cu. The complex tectonic setting of Lihir Island, marked by a reversal of subduction polarity, a tear in the slab beneath the island, and trans-lithospheric extensional structures, facilitated the generation and ascent of highly oxidized and relatively dry ankaramitic melts that ultimately exsolved a vapor-like, S- and presumably Au-rich fluid phase and might thus represent a prerequisite for alkalic-type epithermal Au mineralization. [ABSTRACT FROM AUTHOR]

Sedimentary‐derived (S‐type) granites are an important product of orogenic metamorphism, and a range of subtypes can be recognized by differences in field occurrence, mineralogy and geochemistry. These subtypes can reflect variations of initial protolith composition, partial melting reactions, pressure and temperature of anatexis, or magmatic processes that occur during ascent through the crust (e.g. mineral fractional crystallization or crustal assimilation). Together, these diverse factors complicate geological interpretation of the history of peraluminous felsic melt fractions in orogenic settings. To assess the influence of these factors, we performed integrated field investigation, petrology, geochemistry, geochronology and phase equilibrium modelling on a series of leucosomes within migmatite associated with different S‐type granites within the Khondalite belt, North China craton (NCC), which is an archetypal collisional orogen. Three types of leucosome are recognized in the east Khondalite belt: leucogranitic leucosome, K‐feldspar (Kfs)‐rich granitic leucosome and garnet (Grt)‐rich granitic leucosome. Phase equilibrium modelling of partial melting and fractional crystallization processes indicate that the leucogranitic leucosomes were mostly produced through fluid‐present melting, Kfs‐rich granitic leucosomes are produced through muscovite dehydration melting with 3 vol.% garnet fractional crystallization, and Grt‐rich granitic leucosomes are produced through biotite dehydration melting with 20–40 vol.% K‐feldspar fractional crystallization and up to 20 vol.% peritectic garnet entrainment. Mineral fractional crystallization and peritectic mineral entrainment occur in the source during melting, and play equally important roles in partial melting mechanisms in terms of affecting the geochemical compositions of granitic melts. Thus, we suggest that peraluminous felsic magmas preserved in collisional orogens are dominantly produced by fluid‐absent melting in the middle to deep continental crust, although extraction of low‐volume melt fractions from an anatectic source region at shallower depths during fluid‐present melting can also generate small amounts of S‐type granites that subsequently crystallize at high structural levels in the crust. [ABSTRACT FROM AUTHOR]

This paper employed a scaling analysis to represent the processing parameters, affecting the melting process in the dimensionless numbers, identify the relationships of these dimensionless numbers, and develop semi-empirical correlations to predict the width and depth of the melt pool. To develop the correlations, Ti-6Al-4V powder was used to print 38 tracks at various processing conditions. The correlations were then fit into this experimental data using python code to find the constants of the correlations. The correlations were then used to predict the depth and width of the melt pools. It was found that the mean discrepancy between the predicted melt pool dimensions and the experiment is 7%. To evaluate the accuracy of the correlation in predicting the melt pool dimensions of the materials never used during the development of the correlations, the melt pool depth of some tracks made out of stainless steel 316L printed at various conditions was predicted using the model, and it was found that the mean discrepancy between the predicted melt pool depth and experiment is 11%. [ABSTRACT FROM AUTHOR]

Experiments on titanium partitioning between zircon and silicate melt were conducted at temperatures 1300 and 1400°С at 1 atm total pressure. Additionally, the Ti content in zircons of a few experimental series from (Borisov and Aranovich, 2019) was measured and a critical analysis of experimental literature was carried out. It was demonstrated that at high temperatures (1200–1450°С) DTi values lie in the range from 0.02 to 0.04 regardless of pressure, melt composition, and water content. Based on obtained data, the impossibility of zircon crystallization from high temperature basic melts once more was shown. It was shown that "Ti in zircon" geothermometer cannot describe Ti content in our experimental zircons and, possibly, cannot be applied to dry high-titanium melts at 1 atm total pressure. [ABSTRACT FROM AUTHOR]

In this study, a new control of the heat transport process utilizing phase-change materials (PCMs), as latent thermal energy storage, and nanofluid flow in a thermal system is explored numerically. The proposed model comprises PCM domain divided square enclosure, filled with two different nanofluids (TiO2 and CuO) heated and cooled, respectively, at the left and right sides of the enclosure. Horizontal walls are adiabatic. The coupled mathematical model comprises phase-change materials, nanofluids, and thermal gradients, which are solved numerically following the finite volume-based approach. The enthalpy-porosity technique is adopted to assess the melting behavior of the PCM domain. The thermo-hydraulic performance of the complex system of nanofluids and the melting process of PCM is assessed for the set of control variables such as Grashof numbers (Gr) and nanoparticle concentration (ϕ). Analysis revealed that the melting performance of the PCM domain is significantly influenced by the concentration of the nanoparticles on both sides. The results revealed that, for the early stage of the melting process, the thickness of the melted layer strongly depends on the interaction of the thermal gradient inside the cavity. Higher Gr value and ϕ lead to higher thermal convection in the heated section, which allows the faster melting process of the PCM domain and more amount of thermal energy storage inside the PCM. This transport process further enhances with the increase in the nanoparticles concentrations. A higher Gr value with higher nanoparticle concentrations is always beneficial for the higher amount of thermal energy storage and storage goes up to 35.80%. [ABSTRACT FROM AUTHOR]

Knowledge gaps about how the ocean melts Antarctica's ice shelves, borne from a lack of observations, lead to large uncertainties in sea level predictions. Using high-resolution maps of the underside of Dotson Ice Shelf, West Antarctica, we reveal the imprint that ice shelf basal melting leaves on the ice. Convection and intermittent warm water intrusions form widespread terraced features through slow melting in quiescent areas, while shear-driven turbulence rapidly melts smooth, eroded topographies in outflow areas, as well as enigmatic teardrop-shaped indentations that result from boundary-layer flow rotation. Full-thickness ice fractures, with bases modified by basal melting and convective processes, are observed throughout the area. This new wealth of processes, all active under a single ice shelf, must be considered to accurately predict future Antarctic ice shelf melt. [ABSTRACT FROM AUTHOR]