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We investigate the glassy-state properties of Mg2Ca, Al2Ca, and Al4Ca from the grafting application viewpoint. We employed classical molecular dynamics to examine the phase transition, structural, thermodynamic, transport, and mechanical properties in the amorphous state. All properties suggest successful simulations of the glass phase at and below the glass transition temperature, ranging between 550 and 689 K for Mg2Ca, Al2Ca, and Al4Ca. Computed results are compared and discussed with the reported findings and known mechanical and thermal properties of the various parts of the human bones and biocomposites. The comparison establishes that the mechanical, thermal, and transport properties significantly improve in the glass phase compared to its crystalline alloy form. At 300 K, studied glasses have densities in close agreement with human bone density. Structural analysis and heat capacity show the second-order phase transition, verifying the formation of the glass structure. The targeted glasses exhibit excellent thermal conductivity and thermal diffusivity compared to other commonly used biocomposites for bone grafting. Furthermore, the simulated elastic properties, viz., the Poisson ratio, G/B ratio, Cauchy's pressure, and yield strength, are in close agreement with the mechanical properties of various parts of human bone. The predicted ductility nature, contrary to the brittle character of Mg2Ca, Al2Ca, and Al4Ca crystalline alloys, proves the superiority of the glassy form for the implant's functioning. The minimum enthalpy of formation and thermodynamic stability of studied compounds benefit the synthesis process; hence, we propose that the studied glasses are persuasive materials for experimental synthesis aimed at bone grating applications. [ABSTRACT FROM AUTHOR]

Hydrogen is a promising candidate for green energy sources for future endeavors because of its abundance on Earth. Although its storage is a major challenge for the researchers of this era because of its unsafe and highly explosive nature. The structural, optoelectronic, thermoelectric, vibrational, thermodynamic properties and hydrogen storage capacity of XMgH3 (X = Sr , Ba) are carried out by using the full potential linearized augmented plane wave (FP-LAPW) method in the DFT framework. The theoretical study about these magnesium-based metal hydride perovskites, i.e., SrMgH3 and BaMgH3, declares them structurally stable compounds in space group Pm-3m. The optimization graph for SrMgH3 and BaMgH3 reflects the lowest ground state energy, i.e., −6759 Ry and −16683 Ry, respectively. Comparatively, BaMgH3 seems to be more stable. The electronic band structures and density of states declare them pure metallic due to zero band gap and overlapping of electronic states of the valence and the conduction bands. The electrical conductivity of BaMgH3 increases up to 4. 5 × 1 0 2 0 (Ω ⋅ m ⋅ s) − 1 and thermal conductivity 1. 2 5 × 1 0 1 6 (Ω ⋅ m ⋅ s) − 1 in the temperature range 100 K to 1000 K revealing the good metallic character of BaMgH3. The optical analysis portrays the absorption of compounds in the visible range along with valance shell electrons to the weak bond of hydrogen and dissociates hydrogen molecules at a certain intensity of light. BaMgH3 compound shows minimum scattering and maximum absorption of light in the visible region up to 3 eV. The reflectivity peaks in the visible region 3.0 eV show that 40% of light energy is absorbed due to the opaque nature of BaMgH3. Both these compounds are declared thermodynamically stable due to negative free energy such as −1.20 eV for SrMgH3 and −1.50 eV energy for BaMgH3 at 1000 K, respectively. Moreover, the three acoustic modes showing zero imaginary phonon frequencies at Γ symmetry points predict these compounds' structural and thermodynamical stability. The gravimetric hydrogen storage concentration of SrMgH3 and BaMgH3 is determined as 2.637% and 1.836%, respectively. [ABSTRACT FROM AUTHOR]

Optimization for hydrogen storage properties of Mg-based alloy is mainly restricted by coarse α-Mg grains and uneven catalytic phases. In this study, a strategy of melt-spinning rapid solidification is proposed to fabricate one-dimensional Mg 97 Ni 2 Y 1 alloy fiber with submicron-sized α-Mg grains and uniform microstructure. After heat treatment and activation process, ultrafine Mg 2 Ni and YH 2 phases are in-situ generated and uniformly distributed. The results indicate that 5.24 wt% H 2 is absorbed at 305 °C in 30 min, higher than the as-cast alloy powder of 4.49 wt% H 2. Meanwhile, the dehydrogenation rate is accelerated at lower temperatures. Based on the DSC curve, the hydrogen pumping effect in the fiber alloy powder is more significant, reducing the dehydrogenation temperature of MgH 2. The fiber alloy powder absorbs more hydrogen in stage 1, leading to enhanced hydrogenation kinetics. The uniform and refined microstructure formed by the rapid-solidified fiber is the key factor for enhanced de-/hydrogenation properties. • Submicron α-Mg grains are formed in Mg–Ni–Y alloy fiber by melt-spinning. • Nano Mg 2 Ni and YH 3 multiphases are uniformly precipitated by H-induced reaction. • The F-powder absorbs 5.24 wt% H 2 at 305 °C since more absorbed H 2 in stage 1. • The initial decomposition temperature of F-powder hydrides is reduced to 243.8 °C. [ABSTRACT FROM AUTHOR]

In this study, we utilized Selective Laser Melting (SLM) technology to fabricate a magnesium alloy, and subsequently subject it to micro-arc oxidation treatment. We analyzed and compared the microstructure, elemental distribution, wetting angle, and corrosion resistance of the SLM magnesium alloy both before and after the micro-arc oxidation process. The findings indicate that the SLM magnesium alloy exhibits surface porosity defects ranging from 2% to 3.2%, which significantly influence the morphology and functionality of the resulting film layer formed during the micro-arc oxidation process. These defects manifest as pores on the surface, leading to an uneven distribution of micropores with varying sizes across the layer. The surface roughness of the 3D-printed magnesium alloy exhibits a high roughness value of 180 nanometers. The phosphorus (P) content is lower within the film layer compared to the surface, suggesting that the Mg3(PO4)2 phase predominantly resides on the surface, whereas the interior is primarily composed of MgO. The micro-arc oxidation process enhances the hydrophilicity and corrosion resistance of the SLM magnesium alloy, thereby potentially endowing it with bioactivity. Additionally, the increased surface roughness post-treatment promotes cell proliferation. However, certain inherent defects present in the SLM magnesium alloy samples negatively impact the improvement of their corrosion resistance. [ABSTRACT FROM AUTHOR]

Although rare-earth magnesium (Mg-RE) alloys are widely used in various industries, they show much poorer machinability for shaping into desired dimensions than conventional magnesium ones. The most critical issues associated with cutting Mg-RE alloys are high risk of chip ignition and short tool life dominating the chip removal process. The present paper aims to address the tool performances on the machinability of Mg-RE alloys under dry cutting. Four types of tools covering uncoated and diamond-coated ones were examined, and a special focus was devoted to explore the effects of various tool parameters on the milling responses of Mg-RE alloys as well as the underlying wear mechanisms. The experiments reveal that the cutting tools with larger rake, clearance, and helix angles can achieve high-quality milling of Mg-RE alloys at controllable cutting temperatures. The cutting parameters can be maintained at a certain level, such as the cutting speed of 120–240 m/min and the feed per tooth of 0.1–0.2 mm/z, to meet the requirements of safe milling of Mg-RE alloys without ignition risk. [ABSTRACT FROM AUTHOR]

The fabrication of hydroxyapatite (HAP)/MgO composite coatings on Mg alloy is crucial for enhancing the corrosion resistance and biocompatibility of biomedical implants. In this study, we aimed to investigate the effects of two different surface modification methods, i.e., electrochemical (electrodeposition, ED) and chemical (solution treatment, ST), on the phase structure, degradation properties, and biocompatibility of the composite coatings in comparison to the anodized coating. The surface morphologies and crystalline structures of the coatings were characterized by scanning electron microscopy (SEM) and X-ray diffraction (XRD). Subsequently, the degradation rate of the coatings in simulated body fluid were comprehensively evaluated by using electrochemical impedance spectroscopy (EIS), potentiodynamic polarization and scanning electrochemical microscopy (SECM) tests. Additionally, in-vitro cell proliferation assays were employed to quantitatively assess the biocompatibilities of the coatings. The results showed that both ED and ST methods were effective in depositing HAP on anodized Mg alloy, resulting in different surface morphologies with hydroxyapatite layer thicknesses of 2.71 μm and 3.56 μm, respectively. In this way, the HAP-deposited coatings exhibited improved corrosion resistances and biocompatibilities compared with those of the anodized coating. Specifically, the ST-deposited composite film displayed superior degradability and biocompatibility which was attributed to its filiform surface morphology and thicker HAP layer. Overall, the present study demonstrates the potential of HAP/MgO composite coatings for biomedical applications, with implications for the development of advanced implant materials with improved performance and biocompatibility. [ABSTRACT FROM AUTHOR]

Alloying represents an effective approach for addressing challenges related to over stable thermodynamics and slow kinetics in magnesium alloys. The incorporation of Y dopant served to enhance the quantity of grain boundaries and phase boundaries, thereby addressing the issue of high dehydrogenation temperature observed in Mg85–Ni10–La5, which can be decreased to 273.3 °C after the addition of 0.5 wt% Y additive. In addition, the initial hydrogenation rate of Mg85–Ni10–La4.5-Y0.5 reached up to 3.42 wt% H 2 at 260 °C and the apparent activation energy for dehydriding was decreased from 115.31 to 86.05 kJ/mol. Theoretical calculations suggested that the hydrogen adsorption energy of Mg85–Ni10–La4.5-Y0.5 was dramatically lower than that of Mg85–Ni10–La5, improving hydrogenation properties. The consistency between theoretical calculations and experimental outcomes provided a valuable reference for the selection of suitable magnesium-based hydrogen storage materials. [Display omitted] • Mg85–Ni10–La4.5-Y0.5 can absorb 3.42 wt% H 2 at 260 °C within a minute and release 4.67 wt% H 2 at 300 °C within 5 min. • The peak desorption temperature of Mg85–Ni10–La4.5-Y0.5 is 273.3 °C. • The activation energy of dehydrogenation of Mg85–Ni10–La4.5-Y0.5 is 86.05 kJ/mol. • The diffusion rate of H is faster in Mg85–Ni10–La4.5-Y0.5, therefore Mg85–Ni10–La4.5-Y0.5 is easier to adsorb hydrogen. [ABSTRACT FROM AUTHOR]

Biodegradable materials such as magnesium and its alloys have significant potential for realizing biomedical advancements; however, their rapid degradation in biological settings restricts their widespread use. A metal–organic-like metallic ion-integrated tannic acid (TA) complex coating was immobilized on the surface of the rare earth element-free Mg–2Zn–1Mn (ZM21) magnesium (Mg) alloy for improving the corrosion resistance. The TA was first immobilized on an Mg substrate, followed by an alternating dip-coating process of Ce ions and TA to build a complex coating. Such immobilization process was executed by the chelation reaction between TA molecules and metallic ion. The EIS results show that after 7 days of immersion in SBF solution, the impedance module value of the Mg–TA/Ce coating at 0.01 Hz still remains at 104 Ω cm2, and its tensile strength decreased by 2.1%, demonstrating its excellent corrosion resistance. This metal–organic coating also induces the proliferation of osteoblast and fibroblasts cells. This metal–organic complex coating can serve as a viable means for modifying magnesium-based orthopedic implants. [ABSTRACT FROM AUTHOR]

There has been a good deal of research on improving the corrosion behavior of magnesium (Mg) by polycaprolactone (PCL) coating, albeit with destroying bioactivity and hydrophilicity. The adhesion of a polymeric layer to the surface of the metal is also a knotty problem. On the other hand, the micro-arc oxidation (MAO) process is a new method that can create thin films with desirable adhesion to the surface of the implants although these films could hardly control the degradation of Mg. In this research, a multifunctional nanocomposite coating showing significant adhesion to the surface of the substrate has been fabricated that can enhance not only the corrosion but also the bioactivity of Mg-based biomaterials. It can also improve their biological, antibacterial, and osteogenesis properties. The fabrication process of this multifunctional composite coating with these desirable features can be broadly separated into three main stages beginning with synthesizing strontium (Sr) and copper (Cu) doped bioactive glass nanoparticles (BGNs), applying micro-arc oxidation (MAO) nanocomposite coating on the surface of pure Mg, and finally sealing the pores of MAO layer by PCL with BGNs containing Sr and Cu at concentrations of 5, 10, and 15 wt%. After this process, the corrosion resistance, bioactivity, antibacterial, and cytotoxicity of Mg-based samples were assessed. It was found that the addition of 10 wt% of BGNs in the MAO-PCL nanocomposite enhanced corrosion resistance (78,343.358 KΩ.Cm2), bioactivity, cellular viability and antibacterial property (99%) of Mg-based scaffolds, which can be widely used in bone tissue engineering. [ABSTRACT FROM AUTHOR]

The biodegradability of magnesium (Mg) metal implants necessitates surface modification to mitigate the high corrosion rate in the body's physiological environment. This study focuses on synthesizing and applying a nanocomposite coating of polydimethylsiloxane-nanosized bioactive glass (PDMS-nBG) on the surface of a plasma electrolytic oxidation (PEO)-modified AZ91 Mg alloy. The PDMS-1 wt% nBG nanocomposite coating was deposited on the PEO-treated substrate using the dip-coating method. Surface and cross-sectional morphologies of the nanocomposite coatings were examined using field emission scanning electron microscopy (FESEM). Corrosion behavior of the AZ91 substrate, PEO coating, and double-layer PEO/PDMS-nBG coating was investigated using electrochemical impedance spectroscopy (EIS) and potentiodynamic polarization (PDP) tests. Results showed that the corrosion resistance and corrosion current density of Mg substrates increased and decreased from 4815 Ω.cm2 and 8.96 µA.cm− 2 to 18 MΩ.cm2 and 0.00016 µA.cm− 2 for AZ91 and PEO/PDMS-nBG coating, respectively. Additionally, the morphology and adhesion of cultured human mesenchymal cells on the PEO-modified AZ91 substrates with a single PDMS polymer coating and a PDMS-nBG nanocomposite coating were investigated using fluorescent light microscopy and FESEM. The PEO/PDMS-nBG bilayer coating effectively addressed the limitations of magnesium alloys and holds potential for biomedical applications, particularly in orthopedic implants, due to the enhanced biocompatibility and bioactivity of Mg alloys. [ABSTRACT FROM AUTHOR]

This document is a summary of a special issue of the journal "Materials" titled "Development of Advanced Aluminum and Magnesium Alloys: Microstructure, Mechanical Properties and Processing." The special issue focuses on the latest progress in the development of advanced aluminum alloys, magnesium alloys, and their composites. Thirteen articles are included in the special issue, with six papers on aluminum alloys, two papers on magnesium alloys, and five papers on light metal composite materials. The articles cover a range of topics including optimization of aluminum alloys for casting processes, the effect of torch angle on the properties of aluminum alloys fabricated using additive manufacturing, and the development of high-strength aluminum metal-matrix composites. The special issue provides valuable insights into the relationships between microstructure, mechanical properties, and processing conditions, and aims to contribute to the future development and industrial applications of lightweight alloys. [Extracted from the article]

Zr-containing rare earth magnesium alloys have garnered considerable attention due to their exceptional properties, making them highly desirable for various engineering applications (Chen et al. in Mater Rev 30(9):1–9, 2016). However, flow line defects have been observed to impact the mechanical performance of these alloys, warranting a thorough investigation into their origin and impact. Utilizing advanced analytical techniques, such as scanning electron microscopy and non-destructive testing, we elucidate the microstructural characteristics of these defects and their underlying formation mechanisms by numerical simulation and experiment. Subsequently, the influence of flow line defects on the mechanical properties, such as tensile strength and ductility, is thoroughly assessed. Furthermore, this work outlines practical strategies to mitigate the formation of flow line defects during processing and fabrication, thereby enhancing the overall mechanical integrity of Zr-containing rare earth magnesium alloys. This research contributes valuable insights to the field of advanced magnesium alloys, offering guidelines for engineering design and industrial implementation. [ABSTRACT FROM AUTHOR]

In order to study the effects of REs (Ce, Y and Gd) on the grain size and the grain refinement mechanism of AZ91 as-cast magnesium alloy at different cooling rates, the AZ91-xRE(Ce, Y, Gd, x = 0, 0.3, 0.6, 0.9) alloys with different cooling rates were prepared by die casting. The results show that the addition of REs to AZ91 magnesium alloy and the increase in cooling rate both can refine the grain size of the alloy, but the grain refinement effects of REs on AZ91 magnesium alloy will be weakened when the alloy is solidified at a faster cooling rate. The grain refinement effects of REs on AZ91 magnesium alloy are mainly due to the rare earth compounds of Al4Ce, Al2Y and Al2Gd which can act as heterogeneous nucleation particle to promote nucleation and the inhibitory effects of rare earth compounds distributed near grain boundaries on the grain growth. Increasing the cooling rate of the alloy will reduce the effective constitutional supercooling zone and increase the proportion of nucleation-free zone, which will weaken the heterogeneous nucleation particle effect of Al4Ce, Al2Y and Al2Gd, thereby weakening the grain refinement effects of REs on the AZ91 magnesium alloy at a faster cooling rate. [ABSTRACT FROM AUTHOR]

In this study, pure and hexagonal boron nitride (hBN)-doped zinc oxide (ZnO) nanoparticles with different doping ratios (1, 5 and 10 wt%) were synthesized and their structural morphological properties were investigated. ZnO-hBN nanocomposite particles were used as reinforcement material in AZ91 magnesium alloy. AZ91 powder reinforced with ZnO-hBN nanocomposite particles was combined by powder metallurgy. Hardness of AZ91 matrix composites was measured at 5 different points on each sample and averaged. The specimens were subjected to wear tests in a pin-on-disk test apparatus. As a result of the tests, the hardness value of pure AZ91 alloy was found to be 62 HB, while the hardness value of AZ91-ZnO-10 hBN sample was found to be up to 85 HB. In the wear tests, it was observed that ZnO-hBN additives resulted in low weight losses in wear losses and also decreased the friction coefficient of the hBN additive in the friction coefficient graphs. A hybrid GA (genetic algorithm)-SVR (support vector regression) model was proposed for the prediction of wear quantities of composites. The purpose of using a hybrid system combining SVR and GA is to improve the wear prediction by optimizing the hyperparameters of t and GA. The results are observed using four different kernel functions in the SVR algorithm, and then, a hybrid GA-SVR structure is proposed and compared. With the proposed method, 98.80% prediction success of the wear quantities of the composite is achieved by the hybridized GA. [ABSTRACT FROM AUTHOR]

In this work, AZ31 and AZ31-1 wt.% RE (RE = Nd, Dy, Nd+Dy) alloys were prepared by conventional casting. The effect of single and co-addition of rare earth (RE) on the microstructure, mechanical properties and corrosion behavior of as-cast AZ31 magnesium alloys were investigated at ambient temperature, and after heat treatment at 400 °C for 1 h. The addition of 1 wt.% RE (RE = Nd, Dy, Nd+Dy) preferentially formed the Al2RE phase and completely suppressed the formation of the intermetallic β-Mg17Al12 phase. An excellent ultimate tensile strength (UTS)/ductility combination of 209 MPa/21% and 192 MPa/17% with an adequate yield strength (YS) of 90 MPa was observed for AZ31+Nd sample in as-cast and annealed states, respectively. The work-hardening rate of the AZ31 alloy containing Nd and Dy increased significantly after annealing compared to those of the as-cast state. Fracture analysis indicated that the additive RE did not obviously change the fracture mechanism of the Mg alloy. All specimens exhibit a hybrid fracture with cleavages and dimples. The weight loss test showed that the corrosion resistance of the AZ31 Mg alloy was improved with added RE as it interacts with Al to form Al-RE phase, which upgraded the corrosion resistance of the alloys. The co-addition of RE (RE = Nd+Dy) was proven to enhance corrosion resistance, and also stabilized the corrosion rate. In brief, the co-addition of Nd and Dy significantly improved the corrosion resistance of the AZ31 magnesium alloys than the counterpart of the mechanical properties. [ABSTRACT FROM AUTHOR]

The demands of next-generation transportation such as electric and hybrid vehicles as well as computing and renewable energy applications require new alloys with high castability, high electrical and thermal conductivity, and moderate strength. Aluminum and Mg alloys offer respectable electrical and thermal conductivity with high specific properties unlike Cu and precious metals. However, traditional light alloy systems rely on significant alloying content for solid solution strengthening and to generate short freezing ranges for high castability that is associated with a large decrease to electrical and thermal conductivity. Aluminum alloys based on transition metal and rare earth additions (Fe, Ni, Co and Ce) as well as Mg alloys with additions of Zn, Ca and Ce are potential highly castable alloys with high electrical and thermal conductivity. These new conductive light alloys rely on alloy additions that have low solid solubility but provide short freezing ranges. Results indicate that these Al and Mg alloys can have electrical conductivities ~ 80% of their pure counterparts and castability similar to traditional cast Al–Si and Mg–Al alloys. [ABSTRACT FROM AUTHOR]

A high strength and toughness AZ63 cast magnesium alloy whose ultimate tensile strength, yield strength and elongation at room temperature respectively reached 319 MPa, 160 MPa and 7.6%, was developed by combining the alternating-temperature ultrasonic melt treatment and T6 heat treatment. The high as-aged tensile properties of the alloy with the alternating-temperature ultrasonic melt treatment are mainly attributed to the remarkable increase of the β-prismatic precipitates with orientation relationships (ORs) of ( $ \bar{3}\bar{3} $ 3 ¯ 3 ¯ 0)β // (1 $ \bar{1} $ 1 ¯ 00)α, [ $ \bar{1} $ 1 ¯ 11]β // [11 $ \bar{2} $ 2 ¯ 0]α, thereinto the mentioned-increase is possibly related to that the solute-vacancy clusters along {0 $ \bar{1} $ 1 ¯ 11} plane might serve as the nucleation points of the β-prismatic precipitates. [ABSTRACT FROM AUTHOR]

The performance of aluminum alloys can be affected by the element of magnesium. Therefore, it is necessary to realize fast and accurate quantitative analysis of magnesium in aluminum alloys. Herein, high repetition rate spark discharge assisted laser-induced breakdown spectroscopy based on microchip lasers (HRR SD-LIBS) was applied to quantitatively analyze magnesium elements in aluminum alloys. Baseline correction was performed using the moving median method to obtain the net spectral data. Multivariate calibration models such as back-propagation neural network (BP), support vector machine (SVM), and random forest (RF) were established, respectively. Compared with the conventional univariate calibration model, the correlation coefficients (RP²) of BP,SVM and RF models increased from 0. 810 to 0.985, 0.997 and 0.994, while the root mean square error (RMSEP) decreased from 0.283 to 0.059 8, 0.041 0 and 0.054 2, the average relative error decreased from 26.62% to 3.13%, 2.82%, and 3.61%. It indicated that machine earning combined microchip laser-based HRR SD-LIBS significantly improved the quantitative analysis ability of LIBS. In conclusion, it is promising to achieve portable, fast, and accurate quantitative elemental analysis of alloy sample and other materials. [ABSTRACT FROM AUTHOR]

In view of the importance of metal coatings, this study addresses the ion concentration of the anti‐corrosive coating's immersion solution. The physical properties of the coating surface, such as molecular characteristics, smoothness, and structural strength, were changed by adding nano‐SiO2 in the immersion solution to formulate the best scheme for anti‐corrosive performance. The composite coating was prepared on the surface of AZ31B magnesium alloy by electroless plating. Besides, the surface coating based on AZ31B substrate has high‐quality corrosion resistance to different types of contaminated media. The experimental results demonstrate that the nanocomposite coating can form an ultrafine particle‐filling effect on the metal surface, which is lower than the drag force of the conventional metal surface. Considering the slip velocity gradient in the contact coating area, we reduce the shear stress and drag force, verifying the nanocomposite coating's effect on reducing the reaction force. The contact angle of water droplets in the composite coating is greater than 158.7°. The study finally verifies that the prepared coating has good self‐cleaning potential which can prevent the corrosion of different polluted media. [ABSTRACT FROM AUTHOR]

Magnesium (Mg) and its alloys have received much attention in the aerospace, transportation, automotive industry, and military equipment fields due to their unique chemical and physical properties, such as their low density and high specific strength, particularly as the lightest structural metal materials, with the opportunity to achieve the design of lighter engineering systems. With the continuous improvement of processing technology, the application scope of magnesium alloy is rapidly expanding, and market demand is increasing. However, because of its significant electronegativity (2.37 V) and loose naturally formed oxide coating, magnesium has low corrosion resistance in comparison to other structural metal elements, severely limiting its large‐scale use. This review summarizes several typical anticorrosion methods for magnesium alloys, including chemical conversion coating treatment, anodic oxide film treatment, micro‐arc oxidation treatment, laser surface treatment, ion implantation, physical vapor deposition, and superhydrophobic coating. In most cases, the corrosion resistance of magnesium and its alloys has improved, but it has a certain degree of environmental damage. It is hoped that this review will contribute to further developing magnesium alloy materials in the field of preservative coating. [ABSTRACT FROM AUTHOR]

Magnesium alloys have a huge market and broad prospects due to their high specific strength, good ductility, and strong thermal conductivity. However, the active chemical properties of elemental magnesium and the negative standard electrode potential result in magnesium alloys being highly susceptible to corrosion and failure. Chemical conversion treatment of magnesium alloy can improve its corrosion resistance by preparing a chemical conversion film on its surface. Rare earth conversion treatment has the advantages of effortless process, moderate price, no pollution, good corrosion resistance, and synergistic effect with inorganic or organic additives, which is in line with the pursuit of “green chemical” in industrial production. At present, there is little research and application on lanthanum-based rare earth conversion coatings (La-RECC). This paper selects rare earth element lanthanum (La) to prepare La-RECC on the surface of AZ91D magnesium alloy through chemical conversion treatment. The microstructure, chemical composition, and protective properties of La-RECC were discovered, as well as their interrelationships, revealing the degradation process of La-RECC in 3.5% NaCl solution. La-RECC is composed of La(OH)3 and Mg(OH)2, exhibiting a crystal cluster structure with cracks, and there are a large number of needle-like crystals on the crystal cluster of La-RECC, with a thickness of 2.14 μm. The degradation process of La-RECC can be divided into three stages: Rapid degradation, slow degradation, and complete degradation. The complete degradation time of La-RECC in 3.5% NaCl solution is 82.5h. [ABSTRACT FROM AUTHOR]

“Anodeless” electrodes for all‐solid‐state batteries (ASSBs) have been attracting attention as a solution for achieving high energy density. Recent studies on anodeless electrodes have shown improvements in cycle life and energy density through the stabilization of plated lithium (Li) using Li‐soluble metals (e.g., Ag, Zn, etc.). In this study, magnesium‐based materials (MgF2@C) are introduced for use as an anodeless electrode. Nanodot magnesium fluoride (MgF2) is synthesized onto a carbon black surface via sonochemical synthesis. MgF2 is converted to a Mg‐Li alloy and LiF during lithiation. The Mg‐Li alloy from the MgF2@C anodeless electrode reduces lithiation overpotential and provides a uniform and dense Li layer between the current collector and the anodeless electrode. The ASSB cell assembled with the MgF2@C anodeless electrode exhibits 81.4% capacity retention after 200 cycles at 30 °C. [ABSTRACT FROM AUTHOR]

The formation of intermetallic compounds (IMCs) is a primary factor that affects the welding joint between dissimilar materials. In this study, experiments were performed using Al/Mg friction stir welding (FSW) and ultrasonic vibration enhanced FSW (UVeFSW) with varying thicknesses of Sn interlayer. Detailed characterization and tests were conducted to explore the effect of Sn interlayer with or without ultrasonic vibration on weld surface morphology, macro-micro structure, generation of IMCs, and joint tensile strength. The study discusses the effect of ultrasonic vibration coupled with Sn interlayer and provides ideas for IMCs regulation when joining dissimilar materials. The study showed that adding a Sn interlayer cannot eliminate the generation of Al-Mg IMCs, but it can significantly reduce their thickness. Applying ultrasonic vibration with Sn interlayer can further reduce the thickness of Al-Mg IMCs and improve the interface microstructure from 'IMC + matrix +IMC + matrix' multilayer structures to simple IMCs structures. Furthermore, the highest joint strength was achieved when the Sn interlayer thickness was 0.1 mm during FSW. UVeFSW's joint strength can be further improved with 0.05 mm and 0.1 mm Sn interlayer. [ABSTRACT FROM AUTHOR]

Within the scope of these investigations, the feasibility of a material bond between Ti-6Al-4V and the magnesium alloy AZ91 is analyzed. Ti-6Al-4V is frequently used for implants due to its biocompatibility, corrosion resistance, and specific strength. However, depending on the surface quality, the attachment behavior of the bone to the implant varies. Magnesium implants promote the regeneration of bone tissue and biodegrade as the bone tissue heals. Combining the properties of both materials in one implant enables a reduced implant volume and increased stability. For this reason, this study aims to demonstrate the feasibility of creating a material bond between the materials Ti-6Al-4V and AZ91. For this purpose, Ti-6Al-4V truncated cones and AZ91 sleeves were produced using the additive manufacturing process of laser powder bed fusion (L-PBF). The as-built sleeves were then pressed onto machined truncated cones. Since zinc serves as a lubricant and has good diffusion properties with the materials used as a result of heat treatment, a comparison was made between zinc-coated and the as-built Ti-6Al-4V samples. This showed that a bond was created after hot isostatic pressing and that the push-out force could be increased by more than 4.5 times. Consequently, a proof of feasibility was demonstrated, and a high potential for applications in medical technology was shown. [ABSTRACT FROM AUTHOR]

The synergic effects of activated carbon and transition metals on the hydrogenation characteristics of commercial ZK60 magnesium alloy were investigated. Severe plastic deformation was performed using equal-channel angular pressing with an internal die angle of 120° and preheating at 300 °C. The ZK60 alloy samples were processed for 12 passes using route BA. The deformed ZK60 alloy powder was blended with activated carbon and different concentrations of transition metals (Ag, Pd, Co, Ti, V, Ti) using high-energy ball milling for 20 h at a speed of 1725 rpm. The amount of hydrogen absorbed and its kinetics were calculated using Sievert's apparatus at the higher number of cycles at a 300 °C ab/desorption temperature. The microstructure of the powder was analyzed using an X-ray diffractometer and scanning electron microscope. The results indicated that 5 wt% activated carbon presented the maximum hydrogen absorption capacity of 6.2 wt%. The optimal hydrogen absorption capacities were 7.1 wt%, 6.8 wt%, 6.7 wt%, 6.64 wt%, 6.65 wt%, and 7.06 wt% for 0.5 Ag, 0.3 Co, 0.1 Al, 0.5 Pd, 2 Ti, and 0.5 V, respectively. The hydrogen absorption capacities were reduced by 35.21%, 26.47%, 41.79%, 21.68%, 26.31%, and 26.34% after 100 cycles for 5C0.5Ag, 5C0.3Co, 5C0.1Al, 5C0.5Pd, 2Ti, and 5C0.5V, respectively. Hydrogen absorption kinetics were significantly improved so that more than 90% of hydrogen was absorbed within five minutes. [ABSTRACT FROM AUTHOR]

The AZ91 magnesium alloy was subjected to a complex treatment involving age hardening (supersaturation and artificial aging) and simultaneous surface layer modification. The specimens were supersaturated in contact with a mixture containing varying concentrations of zinc chloride, followed by cooling either in air or water. After supersaturation, the specimens were subjected to artificial aging and then air-cooled. This process resulted in the formation of a surface layer made of zinc-rich phases. The thickness and microstructure of the surface layer were influenced by the process parameters, namely, the zinc chloride content in the mixture and the cooling rate during supersaturation. The treated specimens exhibited favorable tensile strength and greater elongation compared to the as-cast AZ91 alloy, with values comparable to those of the alloy subjected to standard T6 tempering. No cracking of the layer was observed under moderate deformation, though greater deformation resulted in the formation of cracks, primarily in the areas containing the Mg5Al2Zn2 intermetallic phase. The produced layer demonstrated strong metallurgical bonding to the AZ91 substrate. [ABSTRACT FROM AUTHOR]

Excessive cooling of air is required in conventional air conditioning systems to reduce the humidity, leading to the development of desiccant wheel-based air conditioning systems. The desiccant wheel consists of desiccant material which is deposited on matrix material. In this study, aluminum, magnesium alloy, Teflon, and fiberglass have been considered matrix materials of the desiccant wheel. A one-dimensional mathematical model has been developed to evaluate the effect of these matrix materials. The results show that fiberglass can be selected as a suitable matrix material for drying applications because it has maximum moisture removal (MR; 1.92 g/kg) and temperature difference (4.72 °C) at optimal rotational speed, which are desirable for drying. While aluminum can be selected as a suitable matrix material for air conditioning applications because, at the optimal rotational speed, it has lower maximum MR (1.26 g/kg) and temperature difference (3.14 °C) as compared to other matrix materials. As moderate maximum MR and lower temperature difference are the requirements for air conditioning. A similar trend of results has been also obtained for other parameters (volume ratio, regeneration velocity, regeneration temperature, etc.) of this study. [ABSTRACT FROM AUTHOR]

Europium-hydroxyapatite (Eu-HA) nanocomposite was developed via continuous hydrothermal synthesis. Eu+3 ions partially replaced the Ca+2 ions within hydroxyapatite molecular structure. High quality Eu-HA nanorods of 20 nm width and 6 μm lengths were verified via TEM micrographs. Eu-HA maintained the crystalline structure of HA with minimum change; material studio software confirmed the partial replacement of Ca+2 by Eu+3. XPS analysis demonstrated Eu+3 content of 6.91 atom %. Ca/P ratio was found to be 1.405 and 0.118 for virgin HA and Eu-HA respectively; this was ascribed to the partial replacement of Ca+2 with Eu +3. The EDAX mapping verified the uniform dispersion of Eu ions within Eu-HA structure. Eu-HA nanocomposite was uniformly distributed in silica sol-gel matrix; subsequently it was applied on AZ31 magnesium alloy. The corrosion performance of Eu-HA sol-gel coating nanocomposite (Eu–S) was evaluated using different electrochemical techniques including Potentiodynamic Polarization (PDP), Electrochemical Impedance Spectroscope (EIS), and Electrochemical Noise (EN) in aerated 0.1 M NaCl solution. Corrosion protection was assessed to that of neat silica sol-gel coating (NSG). Pitting was detected over the whole NSG coated sample, after few hours of immersion in the corrosive solution. EuS coated AZ31 withstand up to 144 h without any sign of corrosion or delamination. EIS analysis with PDP parameters suggested the formation of protective layer; that is responsible for the corrosion resistance. Europium has unique ability to form a protective oxide layer acting as a barrier layer that could prevent the penetration of corrosive electrolyte to the underlying metal substrate. [ABSTRACT FROM AUTHOR]

To reveal the influences of solution temperature and Nd addition on microstructures and mechanical properties of Mg-12Gd-2Zn-xNd-0.4Zr (x = 0, 0.5, and 1 wt.%) alloys, optical microscope, scanning electron microscope, tensile testing machine, nano-indentation tester, and Vickers hardness tester were used to study the microstructures and mechanical properties of the solution-treated alloys. The results show that with the increase in solution temperature, the alternating α-Mg and β-(Mg, Zn)3Gd eutectic phase and the stacking faults (SFs) and long-period stacking ordered (LPSO) structures gradually decrease and disappear, accompanied by the increased needle-like precipitated phase. The β-(Mg, Zn)3Gd and needle-like precipitated phases increase with increasing Nd addition under the same solution temperature. The yield strength and elongation are both enhanced with increasing solution temperature, the yield strength is also improved but the elongation is reduced with increasing Nd addition. Most importantly, the comprehensive mechanical property, called product of strength and elongation, is significantly improved by increasing solution temperature for the three alloys, but overall, it is reduced with increasing Nd addition solution treated at the same temperature. The Mg-12Gd-2Zn-0.5Nd-0.4Zr solution treated at 515 °C shows the highest product of strength and elongation (4498.4 MPa%) with the ultimate tensile strength of 335.7 MPa and elongation of 13.4%. [ABSTRACT FROM AUTHOR]

Magnesium alloys are widely used for orthopedic implants due to their biocompatibility and biodegradability. However, their low corrosion resistance limits their application, particularly in physiological environments. The goal of this study is to examine how a three-layer coating, consisting of MOF/3D rGO/PCL, affects the corrosion resistance and in vitro biocompatibility of a biodegradable Mg–Mn–Zn alloy in a simulated body fluid (SBF). Corrosion behavior was evaluated using potentiodynamic polarization and electrochemical impedance spectroscopy. The results demonstrate a significant enhancement in the corrosion resistance of the modified alloy. Additionally, cell culture experiments were conducted to investigate the biocompatibility of the coatings. The data from the methylthiazole tetrazolium (MTT) and alkaline phosphatase (ALP) bioassays indicate a substantial improvement in the growth process of MC3T3-E1 osteoblastic cells and an increase in ALP activity in SBF. This confirms the non-toxicity and biocompatibility of the synthesized coating in the SBF solution. The findings of this study will be valuable for the development of biodegradable materials in biomedical applications. [ABSTRACT FROM AUTHOR]

The commercialization of magnesia–air batteries (Mg–air) necessitates the development of highly efficient, cost-effective, and durable electrocatalysts for the oxygen reduction reaction (ORR), replacing expensive and unstable precious metal electrocatalysts. A hard template-assisted synthesis of FeCo nanoparticles immobilized on N-doped porous carbon (Fe–Co–C–N) for the ORR is reported. The half-wave potential of Fe–Co–C–N for ORR (E1/2 = 0.88 V vs. RHE) is elevated by 40 mV compared to that of 20 wt% Pt/C (E1/2 = 0.84 vs. RHE). The catalyst exhibits exceptional catalytic performance and remarkable stability. The discharge voltage of the Mg–air battery, utilizing Fe–Co–C–N as the cathode catalyst (1.29 V), surpasses that of the battery employing 20 wt% Pt/C as the cathode catalyst (1.28 V). The Mg–air battery with Fe–Co–C–N as the cathode catalyst exhibited excellent discharge stability and maintained a stable discharge for over 200 hours. The present study offers valuable insights into the structural design and regulatory mechanisms governing the performance of M–N–C catalysts in Mg–air batteries. [ABSTRACT FROM AUTHOR]

Porous hexagonal nanoplatelets of mixed metal oxide (MMO) derived from the calcination of MgAl layered double hydroxide exhibits a CO2 sorption capacity of 1.99 mmol g−1 at 30 °C, with a retention of 87% sorption capacity over 10 carbonation–decarbonation cycles and a CO2 sorption capacity of 1 mmol g−1 at 200 °C with a 40% increase in capacity over 10 cycles. The high sorption capacity is attributed to the porous nanoplatelet structure of the MMO with a BET surface area of 115 m2 g−1, which enables increased CO2 diffusion. Upon partially replacing magnesium with calcium (33, 50 and 66 mol%), the CO2 sorption capacity of the MMO increases with an increase in temperature. MMO derived from LDH, in which 66% of magnesium is replaced by calcium (MgCaAl-66), delivers CO2 sorption capacities of 1.38, 1.31, 2.50, 4.85 and 7.75 mmol g−1 at 200, 300, 350, 400 and 600 °C, respectively, which is significant for application in the sorption-enhanced water gas shift (SEWGS) process. MgCaAl-66 MMO exhibits a sorption capacity of 1 mmol g−1, which is stable over 10 cycles at 200 °C, and a sorption capacity of 3.68 mmol g−1 at 400 °C with 85% capture efficiency retention over 10 cycles. While the incorporation of Ca2+ serves multiple purposes such as increasing basic defect sorption sites and improving stability to repress the sintering-induced limitation of MMO over sorption cycles, the porous nanoplatelets act as individual sorbent units resisting volume changes through carbonation–decarbonation cycles. [ABSTRACT FROM AUTHOR]

Magnesium borate whiskers were used to prepare a hierarchical microstructure on cordierite ceramic substrate through the precipitation-molten salt method. The La 2-X Ce X Zr 2 O 7 catalyst was then loaded onto the magnesium borate whiskers to form the hierarchical microstructure. The Ce-doped catalysts exhibited a significant improvement in the catalytic activity of soot combustion compared to the La 2 Zr 2 O 7 catalyst. The study employed various techniques to characterize the structural morphology and phase composition, including scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDS), Fourier transform-infrared spectroscopy (FT-IR), and X-ray diffraction (XRD). The growth of Magnesium borate whiskers (Mg 2 B 2 O 5) with diameters of 100–200 nm and lengths of 2–5 μm were grown and tightly bonded to the cordierite ceramic substrate to mimic the structure of human respiratory system cilia. This could improve the filtration efficiency of soot in car exhaust. BET analysis showed that the specific surface area of cordierite increased from 0.684 m2/g to 1.363 m2/g after whisker growth. The study confirmed that the whiskers were firmly attached to the cordierite ceramic substrate, as demonstrated by the binding strength experiments. The addition of Ce metal has been found to significantly enhance soot combustion due to the presence of more active oxygen species and superior mobility of lattice oxygen species with more oxygen vacancies. The catalyst's intrinsic redox property was characterized using X-ray photoelectron spectroscopy (XPS) and H 2 temperature-programmed reduction (H 2 -TPR). The semi-quantitative thermogravimetric analysis (TG-DTG) and the temperature-programmed oxidation (TPO) of catalysts showed that Z-La 1.9 Ce 0 · 1 Zr 2 O 7 exhibited the highest catalytic activity for soot combustion, with an ignition temperature of 268 °C, a peak temperature of 418 °C, and a temperature of 90 % soot conversion of 464 °C. Furthermore, cyclic stability experiments demonstrate that the Z-La 1.9 Ce 0 · 1 Zr 2 O 7 catalyst exhibits excellent structural stability and consistent catalytic performance. This distinctive microstructure holds great potential for applications in the field of DPF. [ABSTRACT FROM AUTHOR]

Aluminum and magnesium are the lightest structural metals, and therefore, various alloys based on them are widely used in both, automotive and aerospace industries. However, aluminum and magnesium are very easily affected by atmospheric and aqueous corrosion, and, therefore, the alloying elements should enhance their corrosion stability. In this work, the thermodynamic analysis of phase and chemical equilibria involving aluminum and magnesium alloys doped with silicon in oxygen–containing air environments, as well as the analysis of chemical and electrochemical equilibria involving these alloys in aqueous environments is conducted. The phase and chemical equiliibria in the Al–Mg, Al–Si, Mg–Si, and Al–Mg–Si systems at 298 K are considered, and the thermodynamic activities of the components of common Al–Mg–Si system alloys are calculated. The invariant chemical equilibria in the systems Al–Mg–O, Al–Si–O, Mg–Si–O at 298 K are considered, the isothermal section of the state diagrams of these systems are plotted, and the oxidation scheme of the Al–Mg–Si system alloys in excess oxygen is proposed. The chemical and electrochemical equilibria in the Al–Mg–Si–H2O system at 298 K are considered and presented in form of the activity – pH and the potential – pH diagrams, and the oxidation of the Al–Mg–Si system alloys in aqueous environments is discussed. [ABSTRACT FROM AUTHOR]

Traditional chemotherapy drugs for cervical cancer often cause significant toxic side effects and drug resistance problems, highlighting the urgent need for more innovative and effective treatment strategies. Magnesium alloy is known to be degradable and biocompatible. The release of degradation products Mg2+, OH−, and H2 from magnesium alloy can alter the tumor microenvironment, providing potential anti-tumor properties. We explored the innovative use of magnesium alloy biomaterials in the treatment of cervical cancer, investigating how various concentrations of Mg2+ on the proliferation and cell death of cervical cancer cells. The results revealed that varying concentrations of Mg2+ significantly inhibited cervical cancer by arresting the cell cycle in the G0/G1 phase and inducing apoptosis in SiHa cells, effectively reducing tumor cell proliferation. In vivo experiments demonstrated that 20 mM Mg2+ group had the smallest tumor volume, exhibiting a potent inhibitory effect on the biological characteristics of cervical cancer. This enhances the therapeutic potential of this biomaterial as a local anti-tumor therapy and lays a theoretical foundation for the potential application of magnesium in the treatment of cervical cancer. [ABSTRACT FROM AUTHOR]

An investigation has been performed to study the compatibility of machining AZ91 magnesium alloy in dry conditions using uncoated and CVD diamond-coated WC-Co inserts. The machining characteristics such as built-up edge (BUE) formation, surface roughness, cutting forces and chip morphology were studied at the cutting speeds, 350, 650 and 950 m/min. The results revealed severe adhesion of the AZ91 Mg alloy on the uncoated WC-Co inserts with increasing cutting speed and contributed to an increase in surface roughness and cutting forces. The CVD diamond-coated inserts have shown negligible built-up edges at various cutting speeds due to their unique properties like low coefficient of friction, low chemical affinity and high thermal conductivity. Snarled types of long continuous chips were observed while machining with CVD diamond-coated WC-Co inserts, whereas short continuous chips were observed with uncoated WC-Co inserts. [ABSTRACT FROM AUTHOR]

Segregation is a serious defect in alloy ingots which severely deteriorates materials performance. The segregation defect in Mg-6Gd alloy is studied by coupling macro thermal-solutal-convection transport and micro dendrite growth. The macroscopic fluid dynamics and mass transfer equations are resolved to forecast the segregation behavior under conditions of continuous temperature variation during the solidification process. The numerical model is validated by testing double-diffusive natural convection in a closed square cavity. A phase field model is then applied to simulate the micro dendrite growth, using macro undercooling and liquid flow velocity as boundary conditions. Results show that the multiscale segregation behavior, including macro solute distribution and micro dendritic morphology, is strongly dependent on the temperature condition and the liquid convection, which provides guidance for reducing and eliminating the segregation defect. [ABSTRACT FROM AUTHOR]

In order to effectively reduce energy consumption and increase range mile, new energy vehicles represented by Tesla have greatly aroused the application of integrated magnesium (Mg) alloy die casting technology in automobiles. Previously, the application of Mg alloys in automobiles, especially in automotive cockpit components, is quite extensive, while it has almost disappeared for a period of time due to its relatively high cost, causing a certain degree of information loss in the application technology of Mg alloy parts in automobiles. The rapid development of automotive technology has led to a higher requirement for the automotive components compared with those traditional one. Therefore, whatever the components themselves, or the Mg alloy materials and die casting process have to face an increasing challenge, needing to be upgraded. In addition, owing to its high integration characteristics, the application of Mg alloy die casting technology in large-sized and thin-walled automotive parts has inherent advantages and needs to be expanded urgently. Indeed, it necessitates exploring advance Mg alloys and new product structures and optimizing die casting processes. This article summarizes and analyzes the development status of thin-walled and large-sized die casting Mg alloy parts in passenger car cockpit and corresponding material selection methods, die casting processes as well as mold design techniques. Furthermore, this work will aid researchers in establishing a comprehensive understanding of the manufacture of thin-walled and large-sized die casting Mg alloy parts in automobile cockpit. It will also assist them in developing new Mg alloys with improved comprehensive performance and new processes to meet the high requirements for die casting automotive components. [ABSTRACT FROM AUTHOR]

High-performance magnesium alloys are moving towards a trend of being produced on a large scale and in an integrated manner. The foundational key to their successful production is the high-quality cast ingots. Magnesium alloys produced through the conventional semi-continuous casting process inevitably contain casting defects, which makes it challenging to manufacture high-quality ingots. The integration of external field assisted controlled solidification technology, which combines physical fields such as electromagnetic and ultrasonic fields with traditional semi-continuous casting processes, enables the production of high-quality magnesium alloy ingots characterized by a homogeneous microstructure and absence of cracks. This article mainly summarizes the technical principles of those external field assisted casting process. The focus is on elaborating the refinement mechanism of different types of electromagnetic fields, ultrasonic fields, and combined physical fields during the solidification of magnesium alloys. Finally, the development prospects of producing highquality magnesium alloy ingots through semi-continuous casting under the external field were discussed. [ABSTRACT FROM AUTHOR]

The fabrication of dissimilar metal joints, particularly between AA 6061 aluminum alloy (Al) and AZ31B magnesium alloy (Mg), poses significant technical challenges due to their distinct metallurgical characteristics and the inherent difficulties associated with welding such materials. These challenges include the propensity for intermetallic compound formation, thermal cracking, and differences in thermal and mechanical properties between the two alloys. Cold Metal Transfer (CMT) welding, known for its low heat input and controlled metal transfer, offers a potential solution to these issues. However, optimizing the process parameters to ensure strong, defect-free joints requires a systematic approach. This study aims to optimize CMT welding parameters using parametric mathematical modeling (PMM) to produce high-strength Al and Mg dissimilar joints and to study the effects of CMT parameters on tensile strength (TS) and weld metal hardness (WMH), as well as the microstructural features of AA 6061 aluminum alloy/AZ31B magnesium alloy (Al/Mg) dissimilar joints. Al/Mg dissimilar butt joints were produced by the CMT process using ER4043 as filler wire. CMT, a low-heat input welding technique, was used to mitigate issues such as intermetallic compounds (IMCs), wider heat-affected zone (HAZ), and distortion. The CMT parameters, particularly wire feed speed (WFS), welding speed (WS), and arc length correction (ALC), were optimized using response surface methodology (RSM) to maximize the TS and WMH of the Al/Mg dissimilar joints. Polynomial regression was employed to create PMMs that integrated these CMT parameters to forecast the TS and WMH of the joints. An analysis of variance (ANOVA) was applied to assess the feasibility of the PMMs. The results indicated that the Al/Mg dissimilar joints, produced using a WFS of 4700 mm/min, a WS of 280 mm/min, and an ALC of 10%, exhibited higher TS and WMH values of 33 MPa and 95.8 HV, respectively. The PMMs provided precise forecasts for the TS and WMH of the Al/Mg joints with an error rate of less than 1% and a confidence level of 97%. [ABSTRACT FROM AUTHOR]

The automotive and aerospace sectors are progressively employing the magnesium (Mg) alloy of the grade AZ31B because of its excellent castability, low density, and high ratio of strength to weight. Nevertheless, the limited ability of AZ31B alloy to withstand corrosion limits their use in several fields of technology. In order to solve this problem, the AZ31B alloy is coated utilizing an AA2024/Al2O3 metal matrix composite (MMC) coating that is applied by the cold spray coating (CS) method. The primary goal of this work is the parametric optimization of CS process for maximizing adhesive strength of MMC-coated Mg-alloy substrate. Response surface methodology (RSM) is implemented to find the optimum CS parameters, including feed rate of powder -- FRP (g/min), standoff distance of gun -- SDG (mm) and processing temperature -- TEMP (°C). The regression-based parametric adhesion strength prediction (ASP) model was formulated using the RSM and statistically validated using analysis of variance (ANOVA). Employing 3D surface of responses, the influence of CS parameters on the adhesion strength of an MMC-coating was assessed. The findings revealed that when the MMC-coating was cold sprayed on the Mg-alloy using FRP of 22 g/min, SDG of 12 mm, and TEMP of 520 °C, the maximum adhesion strength of MMC-coating was 70 MPa (actual). Given less than 2% error at 95% confidence, the parametric ASP model correctly predicted the adhesion strength of the MMC-coating. The ANOVA findings showed that FRP (g/min) had significant effect on adhesive strength of MMC-coating followed by SDG (mm) and TEMP (°C). The MMC-coating applied using the RSM optimized CS parameters showed 70.73% superior adhesive strength owing to the lower porosity formation of 2 vol% which offers greater interfacial area. The ASP equation was formulated using the "best fitting line" approach and validated using ANOVA for predicting the adhesive strength (MPa) from the porosity formation (vol%) in the MMC-coating. [ABSTRACT FROM AUTHOR]

Mg-Gd-Y-Zn-Mn (MVWZ842) is a kind of high rare earth magnesium alloy with high strength, high toughness and multi-scale strengthening mechanisms. After heat treatment, the maximum tensile strength of MVWZ842 alloy is more than 550 MPa, and the elongation is more than 5%. Because of its great mechanical properties, MVWZ842 has broad application potential in aerospace and rail transit. However, the addition of high rare earth elements makes the deformation resistance of MVWZ842 alloy increase to some extent. This leads to the difficulty of direct plastic processing forming and large structural part shaping. Friction stir welding (FSW) is a convenient fast solid-state joining technology. When FSW is used to weld MVWZ842 alloy, small workpieces can be joined into a large one to avoid the problem that large workpieces are difficult to form. In this work, a high-quality joint of MVWZ842 alloy was achieved by FSW. The microstructure and properties of this high-strength magnesium alloy after friction stir welding were studied. There was a prominent onion ring characteristic in the nugget zone. After the base was welded, the stacking fault structure precipitated in the grain. There were a lot of broken long period stacking order (LPSO) phases on the retreating side of the nugget zone, which brought the effect of precipitation strengthening. Nano-α-Mn and the broken second phase dispersed in the matrix in the nugget zone, which made the grains refine. A relatively complete dynamic recrystallization occurred in the nugget zone, and the grains were refined. The welding coefficient of the welded joint exceeded 95%, and the hardness of the weld nugget zone was higher than that of the base. There were a series of strengthening mechanisms in the joint, mainly fine grain strengthening, second phase strengthening and solid solution strengthening. [ABSTRACT FROM AUTHOR]

The present work involves in a novel approach of studying the material characteristics of AZ31 alloy by varying the cooling method in powder metallurgy and particle size of the matrix material. It also has a novel approach of reinforcing AZ31 alloy with quarry dust and providing self oxide coating to the material in a distinct way for corrosion resistance. The alloy is prepared through powder metallurgy with a pressure of 675 MPa, sintered at 540 ºC, with one hour of soaking. The Scanning Electron Microscopy images are taken to analyse the microstructure. Wear and corrosion studies are done to analyse the effect of parameters. Optimisation for wear is also done with Taguchi method. The AZ31 samples reinforced 5, 10 and 15% of quarry dust are prepared and studied for mechanical properties. The material prepared using 75–150 micron range, cooled in still air cooling and with 5% reinforcement has shown higher values of compressive strength and microhardness. The alloy provided with self-oxide coating has shown higher resistance to corrosion than that of uncoated alloy and the composite. [ABSTRACT FROM AUTHOR]

The replacement of traditional materials like steel and Fe with lightweighted solutions, such as Al, Mg and composites has rapid development in science and technology. This study looks into Mg alloys which is expected to have rising impact on industrial trends in the future with material consumption, balanced performance and economic effects. Joining dissimilar materials together has never been easy and so the paper gives a brief theory of the advanced joining methods, laser beam welding (LBW) of distinct lightweight materials like Mg alloys, and its influences on laser parameters. Additionally, all experimental analyses of interlayer or filler materials reinforced by the weld joint of Mg alloys are studied. Their imitating results on the Mg alloys’ microstructure and properties to advance the weldability of the joint to repel failure, as well as their knowledge of the fundamentals, current trends and future approaches in the advanced joining of lightweight materials. [ABSTRACT FROM AUTHOR]

Shot peening is a commonly used method of finishing machine elements in the manufacturing process. One variation of shot peening is the impulse shot peening. This paper presents the influence of impulse shot peening technological conditions on the surface roughness (parameters Ra and Rt), topography, and microhardness. The FEM was used to determine the S11 stresses. In the experiment and simulation tests, AZ31 and AZ91HP magnesium alloy samples were used. Variable parameters in the impulse shot peening process were impact energy E (15–185 mJ), ball diameter d (3–15 mm), and impact density j (3–44 mm−2). As a result of the tests carried out, it was found that after impulse shot peening, the surface topography is change, microirregularities are flattened, and numerous depressions are formed, which can be potential lubrication pockets. The 2D surface roughness parameters for most impulse shot peening conditions are lower than for the pre-machining. The roughness parameters for magnesium alloy AZ91HP are lower than for AZ31. This is most likely due to the lower elongation A. The microhardness after impulse shot peening increased by 20 to 87 HV. As a result of FEM of the impulse shot peening, compressive stresses S11 were created in the surface layer. The depth of occurrence of S11 stresses is from 1.5 to 3.5 mm, and their values for the AZ91HP magnesium alloy samples are 10 to 25% lower than for the AZ31 alloy samples. The most favorable results of the tested properties of the surface layer were obtained for E = 100 mJ, d = 10 mm, and j = 11 mm−2. The abstract serves both as a general introduction to the topic and as a brief, non-technical summary of the main results and their implications. [ABSTRACT FROM AUTHOR]

Purpose: To improve the corrosion resistance of magnesium alloys, the construction of protective coatings is necessary to extend the service life of Mg-based materials. Design/methodology/approach: SiO2 nanoparticles modified by dodecyltrimethoxysilane (DTMS) were added to the PP and a superhydrophobic Mg(OH)2/PP-60mSiO2 composite coating was fabricated on the surface of AZ31 magnesium alloy via the hydrothermal method and subsequently the immersion treatment. Findings: Hydrophilic SiO2 nanoparticles become hydrophobic after modified by DTMS, showing a higher dispersibility in xylene. By incorporating modified SiO2 nanoparticles into the composite PP coating, the hydrophobicity of the layer was enhanced, resulting in a contact angle of 166.3° and a sliding angle of 3.4°. It also improved the water repellency and durability of the coating. Furthermore, the intermediate layer of Mg(OH)2 significantly strengthened the bond between the PP layer and the substrate. The Mg(OH)2/PP-60mSiO2 composite coating significantly enhances the corrosion resistance of the magnesium alloy by effectively blocking the infiltration of the corrosion anions during corrosion. The corrosion current density of the Mg(OH)2/PP-60mSiO2 composite coating is approximately 8.23 × 10–9 A·cm-2, which can achieve a magnitude three times lower than its substrate, making it a promising surface modification for the Mg alloy. Originality/value: The composite coating effectively and durably enhances the corrosion resistance of magnesium alloys. [ABSTRACT FROM AUTHOR]

Magnesium-based alloys and composites have potential as biodegradable materials due to their moderate biodegradability, biocompatibility, and usefulness, but their mechanical strength limits their clinical use. The study synthesised a WE43-based alloy with calcium (Ca) and zinc (Zn), then reinforced it with nano reinforcements (hydroxyapatite, beta-tricalcium phosphate, graphene, and bioglass) through stir casting to create four nanocomposites. The microstructural and mechanical properties were examined to assess Ca and Zn's influence and determine the most effective reinforcement. The result showed that Ca and Zn-modified alloys and all nanocomposite materials have two additional phases, LPSO and Ca 2 Mg 6 Zn 3 , compared to the monolithic WE43 alloy. With the addition of Ca and Zn, S-2 saw significant increases in ultimate tensile strength (UTS), tensile yield strength (TYS), and uniform elongation (U.El), reaching ∼246 MPa, ∼144 MPa, and ∼8 %, respectively, while maintaining an elastic modulus of ∼19 GPa. This resulted in improvements of ∼29 %, ∼25 %, and ∼9 % compared to the as-cast WE43. Graphene-reinforced S-4 demonstrated superior mechanical properties with a UTS of 294 MPa, TYS of 194 MPa, U.El of ∼8 %, and an elastic modulus of 24 GPa, representing increases of ∼52 %, ∼69 %, and 6.05 %, respectively, compared to as-cast WE43. Additionally, S-4 exhibited impressive compressive properties, with an ultimate compressive strength (UCS) of 370 MPa, a compressive yield strength (CYS) of ∼185 MPa, and an U.El of ∼26 %. The bioglass-reinforced nanocomposites had a maximum hardness of 74.8 HV, whereas the as-cast WE43 had a maximum toughness of ∼4 J. These enhancements in mechanical properties are attributed to strengthening processes, including thermal mismatch, orowan, and grain refinement mechanisms. Graphene reinforcement shows promise for biodegradable applications. [ABSTRACT FROM AUTHOR]

Bone fractures often require internal fixation using plates or screws. Normally, these devices are made of permanent metals like titanium providing necessary strength and biocompatibility. However, they can also cause long-term complications and may require removal. An interesting alternative are biocompatible degradable devices, which provide sufficient initial strength and then degrade gradually. Among other materials, biodegradable magnesium alloys have been developed for craniofacial and orthopaedic applications. Previously, we tested implants made of magnesium hydroxide and RS66, a strong and ductile ZK60-based alloy, with respect to biocompatibility and degradation behaviour. Here, we compare the effects of dissolving magnesium hydroxide and RS66 cylinders on bone regeneration and bone growth in rabbit condyles using microtomographical and histological analysis. Both magnesium hydroxide and RS66 induced a considerable osteoblastic activity leading to distinct but different spatio-temporal patterns of cancellous and periosteal bone growth. Dissolving RS66 implants induced a prominent periosteal bone formation on the medial surface of the original condyle whereas dissolving magnesium hydroxide implants enhance mainly cancellous bone formation. Especially periosteal bone formation was completed after 6 and 8 weeks, respectively. The observed bone promoting functions are in line with previous reports of magnesium stimulating cancellous and periosteal bone growth and possible underlying signalling mechanisms are discussed. Biodegradable magnesium based implants are promising candidates for use in orthopedic and traumatic surgery. Although these implants are in the scientific focus for a long time, comparatively little is known about the interactions between degrading magnesium and the biological environment. In this work, we investigated the effects of two degrading cylindrical magnesium implants (MgOH 2 and RS66) both on bone regeneration and on bone growth. Both MgOH 2 and RS66 induce remarkable osteoblastic activities, however with different spatio-temporal patterns regarding cancellous and periosteal bone growth. We hypothesize that degradation products do not diffuse directionless away, but are transported by the restored blood flow in specific spatial patterns which is also dependent on the used surgical technique. [Display omitted] [ABSTRACT FROM AUTHOR]

Magnesium as a biodegradable material offers promising results in recent studies of different maxillo-facial fracture models. To overcome adverse effects caused by the fast corrosion of pure magnesium in fluid surroundings, various alloys, and surface modifications are tested in animal models. In specified cases, magnesium screws already appeared for clinical use in maxillofacial surgery. The present study aims to compare the bone healing outcome in a non-load-bearing fracture scenario of the forehead in sheep when fixed with standard-sized WE43 magnesium fixation plates and screws with plasma electrolytic oxidation (PEO) surface modification in contrast to titanium osteosynthesis. Surgery was performed on 24 merino mix sheep. The plates and screws were explanted en-bloc with the surrounding tissue after four and twelve weeks. The outcome of bone healing was investigated with micro-computed tomography, histological, immunohistological, and fluorescence analysis. There was no significant difference between groups concerning the bone volume, bone volume/ total volume, and newly formed bone in volumetric and histological analysis at both times of investigation. The fluorescence analysis revealed a significantly lower signal in the magnesium group after one week, although there was no difference in the number of osteoclasts per mm2. The magnesium group had significantly fewer vessels per mm2 in the healing tissue. In conclusion, the non-inferiority of WE43-based magnesium implants with PEO surface modification was verified concerning fracture healing under non-load-bearing conditions in a defect model. Titanium implants, the current gold standard of fracture fixation, can lead to adverse effects linked to the implant material and often require surgical removal. Therefore, degradable metals like the magnesium alloy WE43 with plasma electrolytic oxidation (PEO) surface modification gained interest. Yet, miniplates of this alloy with PEO surface modification have not been examined in a fracture defect model of the facial skeleton in a large animal model. This study shows, for the first time, the non-inferiority of magnesium miniplates compared to titanium miniplates. In radiological and histological analysis, bone healing was undisturbed. Magnesium miniplates can reduce the number of interventions for implant removal, thus reducing the risk for the patient and minimizing the costs. [Display omitted] [ABSTRACT FROM AUTHOR]