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1. Formation of binuclear pyrazolate-bridged palladium carboxylates in the reactions of [Pd(Hdmpz)4](OOCR2) (R = Me, Bu t, Ph) with heterometallic Pd-Co acetate

Author

F. M. Miloserdov, M. Ya. Yakovleva, Sergei E. Nefedov, and E. V. Perova

Subjects
Inorganic Chemistry, chemistry.chemical_compound, chemistry, Stereochemistry, Materials Science (miscellaneous), chemistry.chemical_element, Life Science, Physical and Theoretical Chemistry, Pyrazole, Medicinal chemistry, Palladium
Abstract

The reactions of [Pd(Hdmpz)4](OOCR)2 (R = Me, Bu t , Ph, Hdmpz = 3,5-dimethylpyrazole) with the heterometallic acetate Pd(μ-OOCMe)4Co(NCMe) gives pyrazolate-bridged dimers Pd2(μ-dmpz)2(Hdmpz)2(OOCR)2 (R = Me, Bu t , Ph), which were characterized by X-ray diffraction.

Published
2009

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