Search

Data from 6000 geothermal areas worldwide are analyzed with a machine learning approach. The analysis suggests and confirms a dominant role of the terrestrial heat flow, topography, volcanism and extensional tectonics.

Abstract An evaluation of the feasible development of geothermal energy in Mozambique is proposed based on some thermal springs geochemical characterization in the Tete region. Chemical and isotopic data suggest that the springs have a meteoric origin and do not show connection with any active magmatic system. The proposed circulation model suggests high depths infiltration of meteoric waters along faults and fractures in a system characterised by discrete permeability and reservoir temperature between 90 and 120 °C. These results, jointly with low salinity fluids and corrosive components absence suggest that the geothermal system may be conveniently exploited for direct and indirect uses.

Abstract Recurring discoveries of abiotic methane in gas seeps and springs in ophiolites and peridotite massifs worldwide raised the question of where, in which rocks, methane was generated. Answers will impact the theories on life origin related to serpentinization of ultramafic rocks, and the origin of methane on rocky planets. Here we document, through molecular and isotopic analyses of gas liberated by rock crushing, that among the several mafic and ultramafic rocks composing classic ophiolites in Greece, i.e., serpentinite, peridotite, chromitite, gabbro, rodingite and basalt, only chromitites, characterized by high concentrations of chromium and ruthenium, host considerable amounts of 13C-enriched methane, hydrogen and heavier hydrocarbons with inverse isotopic trend, which is typical of abiotic gas origin. Raman analyses are consistent with methane being occluded in widespread microfractures and porous serpentine- or chlorite-filled veins. Chromium and ruthenium may be key metal catalysts for methane production via Sabatier reaction. Chromitites may represent source rocks of abiotic methane on Earth and, potentially, on Mars.

The chemical composition of volatile organic compounds (VOCs) in interstitial soil gases from hydrothermal areas is commonly shaped by both deep hydrothermal conditions (e.g., temperature, redox, sulfur fugacity) and shallow secondary processes occurring near the soil-atmosphere interface. Caldara di Manziana and Solfatara di Nepi, i.e., two hydrothermal systems characterized by diverse physicochemical conditions located in the Sabatini Volcanic District and Vicano-Cimino Volcanic District, respectively (Central Italy), were investigated to evaluate the capability of VOCs in soil gases to preserve information from the respective feeding deep fluid reservoirs. Hierarchical cluster analyses and robust principal component analyses allowed recognition of distinct groups of chemical parameters of soil gases collected from the two study areas. The compositional dissimilarities from the free-gas discharges were indeed reflected by the chemical features of soil gases collected from each site, despite the occurrence of shallow processes, e.g., air mixing and microbial degradation processes, affecting VOCs. Four distinct groups of VOCs were recognized suggesting similar sources and/or geochemical behaviors, as follows: (i) S-bearing compounds, whose abundance (in particular that of thiophenes) was strictly dependent on the sulfur fugacity in the feeding system; (ii) C 4,5,7+ alkanes, n-hexane, cyclics and alkylated aromatics, related to relatively low-temperature conditions at the gas source; (iii) C 2,3 alkanes, benzene, benzaldehyde and phenol, i.e., stable compounds and thermal degradation products; and (iv) aliphatic O-bearing compounds, largely influenced by shallow processes within the soil. However, they maintain a chemical speciation that preserves a signature derived from the supplying deep-fluids, with aldehydes and ketones becoming more enriched after intense interaction of the hypogenic fluids with shallow aquifers. Accordingly, the empirical results of this study suggest that the chemical composition of VOCs in soil gases from hydrothermal areas provides insights into both deep source conditions and fluid circulation dynamics, identifying VOCs as promising geochemical tracers for geothermal exploration., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023 The Authors. Published by Elsevier B.V. All rights reserved.)

Here we present digitization and analysis of the thermal springs of the world dataset compiled by Gerald Ashley Waring in 1965 into a collection of analog maps. We obtain the geographic coordinates of ~6,000 geothermal spring areas, including complementary data (e.g., temperature, total dissolved solids, flow rate), making them available in electronic format. Using temperature and flow rate, we derive the heat discharged from 1483 thermal spring areas (between ~10 -5 and ~10 3  MW, with a median value of ~0.5 MW and ~8300 MW in total). We integrate this data set with other global data sets to study the relationship between thermalism and endogenous and exogenous factors with a supervised machine learning algorithm. This analysis confirms a dominant role of the terrestrial heat flow, topography, volcanism and extensional tectonics. This data set offers new insights and will boost future studies in geothermal energy exploration., (© 2022. The Author(s).)

Earth's hydrocarbon degassing through gas-oil seeps, mud volcanoes and diffuse microseepage is a major natural source of methane (CH 4 ) to the atmosphere. While carbon dioxide degassing is typically associated with extensional tectonics, volcanoes, and geothermal areas, CH 4 seepage mostly occurs in petroleum-bearing sedimentary basins, but the role of tectonics in degassing is known only for some case studies at local scale. Here, we perform a global scale geospatial analysis to assess how the presence of hydrocarbon fields, basin geodynamics and the type of faults control CH 4 seepage. Combining georeferenced data of global inventories of onshore seeps, faults, sedimentary basins, petroleum fields and heat flow, we find that hydrocarbon seeps prevail in petroleum fields within convergent basins with heat flow ≤ 98 mW m -2 , and along any type of brittle tectonic structure, mostly in reverse fault settings. Areas potentially hosting additional seeps and microseepage are identified through a global seepage favourability model.

We develop KAM theory close to an elliptic fixed point for quasi-linear Hamiltonian perturbations of the dispersive Degasperis-Procesi equation on the circle. The overall strategy in KAM theory for quasi-linear PDEs is based on Nash-Moser nonlinear iteration, pseudo differential calculus and normal form techniques. In the present case the complicated symplectic structure , the weak dispersive effects of the linear flow and the presence of strong resonant interactions require a novel set of ideas. The main points are to exploit the integrability of the unperturbed equation, to look for special wave packet solutions and to perform a very careful algebraic analysis of the resonances. Our approach is quite general and can be applied also to other 1d integrable PDEs. We are confident for instance that the same strategy should work for the Camassa-Holm equation., (© The Author(s) 2020.)

659 water samples from springs and wells in the Sabatini and Vicano-Cimino Volcanic Districts (central Italy) were analyzed for arsenic (As), fluoride (F - ) and radon ( 222 Rn) concentrations. Waters mostly sourced from a shallow and cold aquifer hosted within volcanic rocks, which represents the main public drinking water supply. Cold waters from perched aquifers within sedimentary formations and thermal waters related to a deep hydrothermal reservoir were also analyzed. The highest concentrations of As and F - were measured in the thermal waters and attributed to their enhanced mobility during water-rock interaction processes at hydrothermal temperatures. Relatively high concentrations of As and F - were also recorded in those springs and wells discharging from the volcanic aquifer, whereas waters hosted in the sedimentary units showed significantly lower contents. About 60% (As) and 25% (F - ) of cold waters from the volcanic aquifer exceeded the maximum allowable concentrations for human consumption. Such anomalously high levels of geogenic pollutants were caused by mixing with fluids upwelling through faulted zones from the hydrothermal reservoir. Chemical weathering of volcanic rocks and groundwater flow path were also considered to contribute to the observed concentrations. Cold waters from the volcanic aquifer showed the highest 222 Rn concentrations, resulting from the high contents of Rn-generating radionuclides in the volcanic units. Approximately 22% of these waters exceeded the recommended value for human consumption. A specific Quality Index (QI), comprised between 1 (very low) and 4 (very high), was computed for each water on the basis of As, F - and 222 Rn concentrations and visualized through a spatial distribution map processed by means of geostatistical techniques. This map and the specific As, F - and 222 Rn maps can be regarded as useful tools for water management by local authorities to both improve intervention plans in contaminated sectors and identify new water resources suitable for human consumption., (Copyright © 2019 Elsevier Ltd. All rights reserved.)

Recurring discoveries of abiotic methane in gas seeps and springs in ophiolites and peridotite massifs worldwide raised the question of where, in which rocks, methane was generated. Answers will impact the theories on life origin related to serpentinization of ultramafic rocks, and the origin of methane on rocky planets. Here we document, through molecular and isotopic analyses of gas liberated by rock crushing, that among the several mafic and ultramafic rocks composing classic ophiolites in Greece, i.e., serpentinite, peridotite, chromitite, gabbro, rodingite and basalt, only chromitites, characterized by high concentrations of chromium and ruthenium, host considerable amounts of 13 C-enriched methane, hydrogen and heavier hydrocarbons with inverse isotopic trend, which is typical of abiotic gas origin. Raman analyses are consistent with methane being occluded in widespread microfractures and porous serpentine- or chlorite-filled veins. Chromium and ruthenium may be key metal catalysts for methane production via Sabatier reaction. Chromitites may represent source rocks of abiotic methane on Earth and, potentially, on Mars.