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Introduction. Yellow wood anemone (Anemone ranunculoides L.) is a herbaceous perennial. This plant grows in the European parts of Russia, Ciscaucasia, Siberia, Central Europe and other regions. It has many different pharmacological activities: immunomodulatory, sedative, anti-inflammatory, antitoxic, diuretic, antibacterial, antioxidant, antitumor and antirheumatic activity. These various effects are due to their biologically active compounds, which include ephemeroids, protoanemonin, saponins, tannins, resins, ascorbic acid, ranunculin, oils lipids and triterpene glycosides. As to phenolic compounds, currently there is no sufficient information on flavonoids and hydroxycinnamic acids (HCAs) profiles in different species of genus Anemone. Because these groups of compounds are quite specific for yellow wood anemone, their detailed study seems to be relevant.Aim. The objective of this research is to identify and quantify flavonoids, HCAs, and their conjugates in Yellow wood anemone leaves, flowers and rhizomes with roots.Materials and methods. The identification was carried out by using ultra-high-performance liquid chromatography with diode array and electrospray ionization-mass spectrometric detection (UHPLC–DAD–ESI-MS) with quantification of individual compounds by external calibration method.Results and discussion. Among the 47 compounds, 30 flavonoids and 17 derivatives of HCAs were detected. Quercetin glycosides were found to be the major flavonoids in aerial parts whereas chalcone glycosides – in underground parts. The major HCA in rhizomes with roots was feruloyltartaric acid (1.18 mg/g) whereas chlorogenic acid was predominant in leaves and flowers (8.68 mg/g and 2.62 mg/g accordingly). The total content of phenolic compounds was estimated at 60 mg/g on a dry weight basis.Conclusion. As a result of the research a detailed profile of flavonoids and HCAs acids of anemon was described. The data obtained can serve to identify this species in the standardization of medicinal plant materials and taxonomic studies.

Purpose: to determine elements of irrigation technology for young vineyard plantations using the drip irrigation method on various types of soil in the Republic of Crimea and test them under the conditions of this region. Materials and methods. The research was carried out in the village of Pavlovka, Belogorsky district of the Republic of Crimea. The establishment of field experiments and observations were carried out using generally accepted methods for setting up and conducting field experiments. Results. As a result of the research, the water-physical properties of soils of the Republic of Crimea were analyzed and rational elements of the technology for irrigating young vineyard plantations using drip irrigation on various types of soils (limits of optimal soil moisture, dripper consumption, wetted depth, irrigation period and water application rate) were calculated. When calculating the irrigation regime for the drip irrigation method, it is necessary to take into account the wetted layer depth, the physical properties of soil, the planting pattern, the moisture contour shape, the dripper flow rate and pre-irrigation soil moisture. The elements of irrigation technology for young vineyard plantations vary significantly, for example, the recommended flow rate of drippers varies from 2–4 l/h on chernozems to 6–8 l/h on light chestnut soils and steppe solonetzes, while the duration of irrigation varies from 2–3 h on light chestnut soils up to 6–9 h on ordinary chernozems. Conclusions. When testing the results, it was found that the drip irrigation method has a positive effect on the survival rate of table grape cuttings. On average, this indicator for varieties was 98.8%. For soil and climatic conditions of the Republic of Crimea, the varieties Sport, Podarok to Irina, Baikonur and Zabava turned out to be the most responsive in terms of their morphological characteristics. During the growing season of the first year young table grapes (in a medium-dry year), 16 irrigations of 30 cubic m/ha with an irrigation rate of 480 cubic m/ha were carried out, while the total water consumption excluding the use of moisture from soil was 3740 cubic m/ha.

Improvement of the quality requirements for the herbal pharmaceutical substances is the basis for the safety and efficacy of drugs produced from it. Modern diagnostic methods made it possible to clarify and to elaborate the regulatory requirements for Fructus Carvi, Fructus Foeniculi and Fructus Anisi vulgaris and to create innovated pharmacopoeial articles.

A comparative study of the biologically active compounds (BAC) composition of alcoholic extracts of leaves and fruits was carried out by GLC-MS. It is shown that the BAC composition of leaves of Hedera caucasica is more extensive: the structure of 22 following compounds was determined: pinene, catechol, germacrene, sinapic alcohol, phytol, falkarinol, palmitic acid, oleic acid, linolenic acid and their esters; stigmasterol, lupeol, sitosterol, panaxadiol and panaxinon. The last three compounds - panaxidol, panaxinon and sitosterol - were not found in fruit extract.

The work is concerned with the Transfer Matrix Method for solving the steady-state Schrödinger equation applied for a unified evaluation of the emission current density from non-refractory cathodes. The method is applicable to arbitrary shapes of the potential barrier and its transmission probability is obtained without any analytical approximations. The Fermi-Dirac distribution for the free electrons in the metal is considered as a supply function. The results, obtained for a work function of the cathode material of 4.5 eV over a wide range of values of the surface temperature and the electric field strength, clearly show a growing deviation from those obtained by the classical Jeffreys-Wentzel-Kramers-Brillouin approximation with the increase of the electric field strength. Preliminary results are obtained to demonstrate the applicability of the Transfer Matrix method to the evaluation of the ion-assisted electron emission. A significant local enhancement of the emission current density is obtained as a result of the presence of an ion at a fixed position near the metal surface. The effect becomes very strongly pronounced at an appropriate value of the electric field strength, for which a resonant ion contribution appears.

The line spectra of emitted resonance radiation from mercury and the effective decay rates of the Hg 63P1 and 61P1 levels in mercury–argon discharges are simulated by a Monte Carlo method. The hyperfine splitting, the natural isotopic composition, collisional transfer of excitation, foreign gas collisions and quenching are considered to describe in detail the 253.7 nm and 184.9 nm lines. The calculations are performed for Hg vapor densities corresponding to coldest spot temperatures of 5–100°C, and discharge parameters typical for fluorescent lamp operation. The densities of the Hg 63P1 and 61P1 levels are consistently estimated by means of a set of balance equations for the Hg 63P0, 63P1, 63P2, and 61P1 excited states. The resulting uv radiation output of the discharge is then estimated for a tube radius of 18 mm, argon pressure of 400 Pa, discharge current 0.4 A, and wall temperatures of 20–80°C. The results obtained show a good agreement as compared with published experimental data. [ABSTRACT FROM AUTHOR]

Electrical measurements and numerical modelling of dc tungsten-inert gas arcs are carried out in order to determine the electric field and the voltage, and to study their importance to the plasma-electrode interaction. The configuration under consideration is very typical for tungsten-inert gas welding processes and includes a conically shaped cathode made of doped tungsten and atmospheric pressure argon as a shielding gas. The studies analyze the effects of the inter-electrode distance and the electric current over wide ranges of variation—currents from below 10 A up to 200 A, and distances from 20 mm down to 2 mm in the modelling and to the short-circuit in the experiment. The comparison of the experimentally obtained and the computed current–voltage and arc length-voltage characteristics clearly prove the predictive capability of the advanced non-equilibrium model of the arc and the electrodes. Moreover, the self-consistent model yields the structure of the electric potential and the electric field and is capable of describing the peculiarities of the plasma-electrode interaction. [ABSTRACT FROM AUTHOR]

The present work is concerned with the simulation analysis of a microwave plasma torch suitable for deposition applications prior to the admixture of any precursor. The self-consistent numerical model describes the electromagnetic field of the microwaves entering an R26 waveguide, the plasma generation, the gas flow through a tube crossing the waveguide, and the heat transfer in the gas. The plasma description avoids the assumption of quasi-neutrality and provides, therefore, a solution including the near-wall regions. The multiphysics model is applied to the source operated in argon at atmospheric pressure. Quasi-stationary solutions are obtained in a 2D Cartesian geometry and in a 3D geometry employing increasing degrees of complexity with respect to the physics, the reaction kinetics and the boundary conditions. The distribution of the electromagnetic field and the plasma parameters resulting from 2D fully coupled one- and two-ion models is analyzed for an incoming microwave power of 1 kW and a gas flow rate of 18 slm. The 2D model is capable of predicting the plasma parameters at a reasonable computational cost. The application of a 3D plasma-microwave model shows that the spatial distribution of the electromagnetic field and the plasma parameters is not, in general, axially symmetric. In the plane corresponding to the 2D work plane, the results of 3D one-ion plasma model show agreement with the 2D results, however, at significant computational costs. The 2D simulation analysis carried out allows us to draw up a decision-making with regard to the setup performance. [ABSTRACT FROM AUTHOR]

A collisional-radiative model for the ground state and fifty effective excited levels of atomic iron, and one level for singly-ionized iron, is set up for technological plasmas. Attention is focused on the population of excited states of atomic iron as a result of excitation, de-excitation, ionization, recombination and spontaneous emission. Effective rate coefficients for ionization and recombination, required in non-equilibrium plasma transport models, are also obtained. The collisional-radiative model is applied to a thermal arc plasma. Input parameters for the collisional-radiative model are provided by a magnetohydrodynamic simulation of a gas-metal welding arc, in which local thermodynamic equilibrium is assumed and the treatment of the transport of metal vapour is based on combined diffusion coefficients. The results clearly identify the conditions in the arc, under which the atomic state distribution satisfies the Boltzmann distribution, with an excitation temperature equal to the plasma temperature. These conditions are met in the central part of the arc, even though a local temperature minimum occurs here. This provides assurance that diagnostic methods based on local thermodynamic equilibrium, in particular those of optical emission spectroscopy, are reliable here. In contrast, deviations from the equilibrium atomic-state distribution are obtained in the near-electrode and arc fringe regions. As a consequence, the temperatures determined from the ratio of line intensities and number densities obtained from the emission coefficient in these regions are questionable. In this situation, the collisional-radiative model can be used as a diagnostic tool to assist in the interpretation of spectroscopic measurements. [ABSTRACT FROM AUTHOR]

The collisional–radiative model with an emphasis on the accurate treatment of the resonance radiation transport is developed and applied to the free-burning Ar arc plasma. This model allows for analysis of the influence of resonance radiation on the spatial density profiles of the atoms in different excited states. The comparison of the radial density profiles obtained using an effective transition probability approximation with the results of the accurate solution demonstrates the distinct impact of transport on the profiles and absolute densities of the excited atoms, especially in the arc fringes. The departures from the Saha–Boltzmann equilibrium distributions, caused by different radiative transitions, are analyzed. For the case of the DC arc, the local thermodynamic equilibrium (LTE) state holds close to the arc axis, while strong deviations from the equilibrium state on the periphery occur. In the intermediate radial positions the conditions of partial LTE are fulfilled. [ABSTRACT FROM AUTHOR]

A novel non-equilibrium model has been developed to describe the interplay of heat and mass transfer and electric and magnetic fields in a DC electric arc. A complete diffusion treatment of particle fluxes, a generalized form of Ohm’s law, and numerical matching of the arc plasma with the space-charge sheaths adjacent to the electrodes are applied to analyze in detail the plasma parameters and the phenomena occurring in the plasma column and the near-electrode regions of a DC arc generated in atmospheric pressure argon for current levels from 20 A up to 200 A. Results comprising electric field and potential, current density, heating of the electrodes, and effects of thermal and chemical non-equilibrium are presented and discussed. The current–voltage characteristic obtained is in fair agreement with known experimental data. It indicates a minimum for arc current of about 80 A. For all current levels, a field reversal in front of the anode accompanied by a voltage drop of (0.7–2.6) V is observed. Another field reversal is observed near the cathode for arc currents below 80 A. [ABSTRACT FROM AUTHOR]

A modified method for the solution of the Holstein-Biberman transport equation is proposed for cylindrical geometry, arbitrary absorption coefficient accounting for plasma inhomogeneity and a Lorentz spectral lineshape. The method is applied to the plasma generated by a free-burning arc in argon at atmospheric pressure in order to study the effect of trapping of resonance radiation on the population of the resonance state Ar(1s4). The results obtained are compared with those of a self-consistent nonequilibrium model of the arc including excited atomic levels. They show an enhanced (compared to the results of the nonequilibrium model) population of the resonance state outside of the arc core as an effect of the trapping of resonance radiation and almost negligible collisional de-excitation. In the arc core, the effect is negligible so that the calculated population of the Ar(1s4) state confirms the results obtained with the nonequilibrium model. [ABSTRACT FROM AUTHOR]

Edible coatings that have a recognized ecological effect are an alternative to retard the processes of moisture evaporation and mold growth in bakery products. The aim of the present research was to study the influence of Malva sylvestris L. (mallow) flowers' extract on the antimicrobial activity of edible coatings of three types of polysaccharides, pectin/P/, xanthan/X/ and carboxymethylcellulose/C/, as well as to analyze their effect on the freshness and microbiological status of coated small loaves during storage. It was found that the presence of a mallow extract had a positive effect on the fungicidal and yeasticidal activities of the X and C coatings. The loaves were evaluated for their physical (moisture, color), textural (firmness and crumb firming kinetics) and microbiological characteristics. The coatings (P, X and C) with mallow extract had the strongest moisture-retaining effect on the loaves' crumb. The coatings with X and with P (with/without mallow extract) significantly slowed down the crumb firming process, and the value of the rate constant for the crumb firming (k) is the lowest for the X coating-0.1815 day -1 . The smallest changes in the crust color were reported when mallow-based coatings were used. They have also been proven to have the lowest microbial load when they are stored for up to three days. This study shows that polysaccharide edible coatings with an active mallow component have significant potential to extend the shelf life of bakery products.

The architecture of transparent contacts is of utmost importance for creation of efficient flexible light-emitting devices (LEDs) and other deformable electronic devices. We successfully combined the newly synthesized transparent and durable silicone rubbers and the semiconductor materials with original fabrication methods to design LEDs and demonstrate their significant flexibility. We developed electrodes based on a composite GaP nanowire-phenylethyl-functionalized silicone rubber membrane, improved with single-walled carbon nanotube films for a hybrid poly(ethylene oxide)-metal-halide perovskite (CsPbBr 3 ) flexible green LED. The proposed approach provides a novel platform for fabrication of flexible hybrid optoelectronic devices.

Inorganic halides perovskite CsPbX 3 (X = Cl, Br, and I or mixed halide systems Cl/Br and Br/I) nanoparticles are efficient light-conversion objects that have attracted significant attention due to their broadband tunability over the entire visible spectral range of 410-700 nm and high quantum yield of up to 95%. Here, we demonstrate a new method of recrystallization of CsPbBr 3 nanoparticles inside the electrospun fluoropolymer fibers. We have synthesized nonwoven tetrafluoroethylene mats embedding CsPbBr 3 nanoparticles using inexpensive commercial precursors and syringe electrospinning equipment. The fabricated nonwoven mat samples demonstrated both down-conversion of UV light to 506 nm and up-conversion of IR femtosecond laser radiation to 513 nm green photoluminescence characterized by narrow emission line-widths of 35 nm. Nanoparticle formation inside nonwoven fibers was confirmed by TEM imaging and water stability tests controlled by fluorimetry measurements. The combination of enhanced optical properties of CsPbBr 3 nanoparticles and mechanical stability and environmental robustness of highly deformable nonwoven fluoropolymer mats is appealing for flexible optoelectronic applications, while the industry-friendly fabrication method is attractive for commercial implementations.

The present study evaluated the thermal properties of sponge cake batters with different functional ingredients, and the effects of their adding on starch gelatinization. Samples of sponge cake batter: with wheat flour (control batter), with a reduced quantity of wheat flour and addition of functional ingredients (sponge cake batter with 50% einkorn wholemeal flour, sponge cake batter with 20% Jerusalem artichoke powder, sponge cake batter with 35% cocoa husk powder) were investigated. Using the method of differential scanning calorimetry (DSC) the starch gelatinization temperature intervals (°C) and energies of the different batters during baking were evaluated. Based on the experimental results, it could be concluded that the addition of functional ingredients in the cake batter retard the starch gelatinization. The gelatinization occurs at higher temperature and with higher energy consumption. The retarding effect of the functional ingredients is related to the water binding capacity and the presence of dietary fiber., (Copyright © 2019 Elsevier Ltd. All rights reserved.)

This article reviews the normal postsurgical anatomy and appearance of PCL reconstructions on MDCT and MRI with the different operative techniques considering the type of tibial fixation, use of a single or double bundle, type of tendon graft and the fixation material. Tunnel positioning, appearance of the ligament graft and findings at the donor site are considered. Imaging signs of PCL graft failure and its possible causes are discussed. Imaging manifestations of other potential complications of both the PCL graft and donor sites are described, such as laxity, impingement, arthrofibrosis, ganglion cyst formation or complications related to the fixation material.

A two-dimensional model of microwave-induced plasma (field frequency 2.45 GHz) in argon at atmospheric pressure is presented. The model describes in a self-consistent manner the gas flow and heat transfer, the in-coupling of the microwave energy into the plasma, and the reaction kinetics relevant to high-pressure argon plasma including the contribution of molecular ion species. The model provides the gas and electron temperature distributions, the electron, ion, and excited state number densities, and the power deposited into the plasma for given gas flow rate and temperature at the inlet, and input power of the incoming TEM microwave. For flow rate and absorbed microwave power typical for analytical applications (200-400 ml/min and 20 W), the plasma is far from thermodynamic equilibrium. The gas temperature reaches values above 2000 K in the plasma region, while the electron temperature is about 1 eV. The electron density reaches a maximum value of about 4 × 10(21) m(-3). The balance of the charged particles is essentially controlled by the kinetics of the molecular ions. For temperatures above 1200 K, quasineutrality of the plasma is provided by the atomic ions, and below 1200 K the molecular ion density exceeds the atomic ion density and a contraction of the discharge is observed. Comparison with experimental data is presented which demonstrates good quantitative and qualitative agreement.

Most dermoid cysts in the oral cavity floor are derived from epithelial debris or rests, enclaved during midline closure of the bilateral first and second branchial arches. They may also result from ectodermal differentiation of multipotential cells, most likely pinched off at the time of anterior neuropore closure. Congenital epidermoid cysts and teratomata of the tongue may be explained in a similar manner. Only 6.9 per cent of dermoid cysts observed in humans involve the head and neck regions. Treatment consists in complete surgical removal, with excellent prognosis in cases free of complications. This is a report on a rare case of epidermoid cyst, described because of its unusual location and cell population variation of the epithelium lining the cystic cavity.

The litholytic effect of soluran and pharmalith on renal calculi was studied by X-ray diffraction analysis. It is shown that pharmalith is more effective in treating nephrolithiasis, than other drugs.