1. Quadratic Zeeman and Electric Quadrupole Shifts in Highly Charged Ions
- Author
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Gilles, Jan, Fritzsche, Stephan, Spieß, Lukas J., Schmidt, Piet O., and Surzhykov, Andrey
- Subjects
Physics - Atomic Physics - Abstract
Recent advances in high-precision spectroscopy of highly charged ions necessitate an understanding of energy shifts of ionic levels caused by external electric and magnetic fields. Beyond the well-known Stark and linear Zeeman shifts, trapped ions may also exhibit quadratic Zeeman and electric quadrupole shifts. In this contribution, we present a systematic approach for the theoretical analysis of these shifts for arbitrary many-electron ions. Based on the derived expressions and making use of the multiconfigurational Dirac-Fock approach, we performed calculations of quadratic Zeeman shift coefficients and quadrupole moments for various ionic states in Ca$^{14+}$, Ni$^{12+}$ and Xe$^{q+}$ ions. These ions attract particular interest for ongoing and future experiments in optical clocks and tests of fundamental physics., Comment: 14 pages, 1 figure
- Published
- 2024