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Since its discovery, the Kamil crater (Egypt) has been considered a natural laboratory for studying small-scale impact cratering. We report on a previously unknown shock-related phenomenon observed in impact melt masses from Kamil; that is, the shock-triggered formation of skeletal quartz aggregates from silica-rich fluids. These aggregates are unshocked and characterized by crystallographically oriented lamellar voids and rounded vesicles. The distribution of the aggregates can be correlated with former H2O- and impurity-rich heterogeneities in precursor quartz; i.e., fluid inclusions. The heterogeneities acted as hot spots for local melting. Due to the presence of H2O and the high impact pressure and temperature, the formation of a localized supercritical fluid is plausible. Below the upper critical end point of the SiO2–H2O system (temperature

Fractionation effects related to evaporation and condensation had a major impact on the current elemental and isotopic composition of the Solar System. Although isotopic fractionation of moderately volatile elements has been observed in tektites due to impact heating, the exact nature of the processes taking place during hypervelocity impacts remains poorly understood. By studying Fe in microtektites, here we show that impact events do not simply lead to melting, melt expulsion and evaporation, but involve a convoluted sequence of processes including condensation, variable degrees of mixing between isotopically distinct reservoirs and ablative evaporation during atmospheric re-entry. Hypervelocity impacts can as such not only generate isotopically heavy, but also isotopically light ejecta, with δ56/54Fe spanning over nearly 5‰ and likely even larger variations for more volatile elements. The mechanisms demonstrated here for terrestrial impact ejecta modify our understanding of the effects of impact processing on the isotopic evolution of planetary crusts., Fe isotopic composition of the distal ejecta of a terrestrial impact crater records both evaporation and condensation, refining the nature of the isotopic fractionation taking place during hypervelocity impacts in the Solar System.

Dust in the Upper Stratosphere Tracking Experiment and Retrieval (DUSTER) aims to collect and characterize uncontaminated particles (In addition to DUSTER, only a few other attempts have been made for the collection of particles through balloons at altitude >30km [4,5]. The innovations brought by DUSTER include: (i) does not require sample manipulation after collection; (ii) guarantees low impact velocities between particles and the collector’s substrate; and (iii) a key factor, adopts a strict control protocol for the minimization of contamination [3,6]. On the collector (a holder with 13 TEM grids), directly exposed to the airflow, the particles remain stuck without the use of adhesive materials (dry collection). High-resolution images of the collector and the blank (similar to the collector but not exposed to the airflow) are acquired before and after the flight, to exclude from the count pre-existing particles [6,7].Five DUSTER launch campaigns successfully collected stratospheric particles. The most recent ones took place at the ESRANGE, Kiruna (Sweden), in 2019 and 2021. DUSTER sampled the stratosphere at an altitude of ~33km for ~5 hours over Lapland, and its collector and blank are currently under analysis. Up to now, the identified particles range from 0.1 to 150µm (latest data to be published). Morphologically, they can be classified as mineral fragments and aggregates, spherules, fungal spores [10], and a type-I cosmic spherule. EDX analyses have shown the occurrence of minerals like plagioclase, silica, fassaite, but also carbonates, CaO – all mineralogic phases present in CI and CM carbonaceous chondrites, unequilibrated ordinary chondrites, and comets [8]. The occurrence of CaO and carbon nanoparticles has been suggested to be a result of condensation after disaggregation of carbonates of extraterrestrial origin [11]. The ambitious goal of DUSTER is to become a reference collection for uncontaminated extraterrestrial particles available for scientific research – a unique and barely explored reservoir complementary to (micro)meteorites and IDPs available at the Earth’s surface. In general, the properties of solid and condensed dust in the upper stratosphere remain poorly known. Complete morphological and chemical characterization of particles collected at altitudes >30 km remains incidental with few exceptions, DUSTER will provide a record of the amount of solid aerosols, their size, shapes and chemical properties in the upper stratosphere, including particles less than 3 microns in size.Acknowledgement – ASI-INAF “Rosetta GIADA”,I/024/12/0 and 2019-33-HH.0; PRIN2015/MIUR; European Union's Horizon 2020 research and Innovation programme,No.730970.References – [1]Flynn, 1997. Nature,387, 248. [2]Brownlee 1985. Annu.Rev.Earth Planet.Sci., 13(1),147-173. [3]Della Corte & Rotundi, 2021. Elsevier,269-293. [4]Testa et al., 1990. Earth Planet.Sci.Lett., 98,287-302. [5]Wainwright et al., 2003. FEMS Microbiol.Lett., 218,161-165. [6]Della Corte et al., 2012. SpaceSci.Rev, 169,159-180. [7]Palumbo et al., 2008. Mem.Soc.Astron.Ital., 79,853. [8]Rietmeijer et al., 2016. Icarus, 266,217-234. [10]Della Corte et al., 2014. Astrobiology, 14(8),694-705. [11]Della Corte et al., 2013. TellusB: Chem.Phys.Meteorol.,65(1),1-12.

Planetary differentiation in small bodies is believed to be ruled by several partial end-states that were dominated by low degrees of partial melting and melt segregation, before arriving at the formation of rocky planets. Having a better understanding of non-equilibrium melting processes in undifferentiated chondritic materials is critical to characterize planetary differentiation processes and the formation of rocky planets and differentiated asteroids. In this context, partial melting experiments of natural chondrites can provide unique insights into the petrological evolution associated with early planetary differentiation of planetesimals. For this study, we performed partial melting experiments using fragments from the ordinary chondrite DAV01001. Experiments were performed in a piston-cylinder at 1 GPa pressure, at temperatures from 1100 to 1300 °C and for 24 hours run duration. Reducing conditions were imposed by the use of graphite capsules. The experimental products were analysed using electron microprobe and synchrotron radiation computed microtomography (SR-µCT).DAV01001 is an equilibrated L6 ordinary chondrite that has still visible relic chondrules and contains olivine (Fo75), low-Ca pyroxene (En77Fs21Wo2), high-Ca pyroxene (En47Fs8Wo45), albitic plagioclase (An13Ab81Or6), metal, troilite, chromite, and apatite. Upon heating, metal and troilite disappear at 1100 °C forming two immiscible phases, one made of pure metal with variable amounts of Ni, the other made of a metal-sulphide liquid of variable composition. Chromite starts melting at 1100 °C and disappears at 1300 °C. Silicatic melt forms already at 1100 °C as a result of the melting of plagioclase. With increasing temperature, the pyroxene and olivine begin to melt and shift the composition of the liquid towards trachy-andesitic (1200 °C) and basaltic trachy-andesitic to andesitic (1300 °C) compositions. Melting of olivine and pyroxene is accompanied by the crystallisation of both phases. The newly-formed olivine has a composition varying from Fo80 to Fo59, becoming progressively enriched in Fe and Ca and depleted in Ni at increasing temperature. The newly-formed pyroxene has a variable Ca content, and is enriched in Al and Cr and depleted in Fe and Mn. The new-grown olivine and pyroxene crystals have a strong affinity with chondritic/primitive achondrites compositions, in contrast to the melts that have a good affinity to a bulk HED composition. Overall, the combination of melting and crystallisation fixes the amount of silicatic liquid to a rather constant value of 10% vol.SR-µCT was used to create 3D reconstructions of the experimental samples, in order to evaluate the efficiency of metal segregation at increasing degrees of partial melting. At increasing temperature, no change in the object density (number of 3D particles divided by the sample volume) is observed but only a progressive increase of the roundness and sphericity of the particles. This suggests that, even in presence of an interconnected liquid silicate phase (~10% vol), the coalescence of the metal phases does not occur spontaneously and other forces such as rotational spin or deformation are needed to segregate metal under these conditions.

We examined 16 white opaque inclusions exposed on two polished slices of a Muong Nong-type Australasian tektite from Muong Phin, Laos. The inclusions usually consist of a core, surrounded by a froth layer, and a quartz neoblast layer. The cores are composed primarily of a mixture of silica glass, coesite, and quartz in varying proportions. A thin (up to ~4 μm) layer of SiO2-poor glass enriched in FeO, MgO, CaO, Al2O3, and TiO2 is observed as a bright halo in backscattered electron images around the quartz neoblasts and in places contains μm-sized crystals, which may be Fe,Mg-rich spinel. The distribution and textural relationships between the coesite-bearing inclusions and the tektite matrix point to an in situ formation of the coesite due to an impact, rather than to infall, from a nearby impact, into tektite melt produced by the aerial burst of a bolide. The quartz neoblasts probably formed by crystallization of silica melt squeezed out of the inclusion core during the development of the froth layer. The bright halo may be the result of silica diffusing from the adjacent tektite melt into the growing quartz neoblasts. We propose that the survival of coesite was possible due to the froth layer that acted as a heat sink during bubble expansion and then as a thermal insulator.

With an age of less than ~5000 yr and a diameter of 45 m, Kamil crater in Egypt is one of the youngest and smallest terrestrial impact craters known to date. Abundant evidence of shock-deformed sandstone has been reported from Kamil crater, including shatter cones, vesicular impact glass, high-pressure polymorphs of silica and carbon, planar deformation features (PDFs) and planar fractures (PFs) in quartz, dissociated zircon, melt veins, and intergranular melt, giving rise to a range of estimated shock pressures from ~20 to ~60 GPa. Here, we investigated shocked zircon from Kamil crater through characterization of microstructures in a centimeter-sized clast of shocked nonporous sandstone ejecta, previously described as containing quartz grains with PDFs and PFs, coesite, stishovite, diamond, and lechatelierite. Orientation analysis by electron backscatter diffraction (EBSD) showed that the quartz arenite consists of damaged detrital quartz grains surrounded by a matrix of either comminuted quartz or intergranular melt. Individual quartz grains are pervasively fractured (abundant PFs and PDFs); apparent isotropic crushing resulted in uniformly and highly dispersed orientation clusters on pole figures. Zircon grains are not abundant; however, four of 19 grains analyzed by EBSD contained {112} deformation twin lamellae, with individual lamellae ranging in length from 1 to 2 µm. Lengths of twin lamellae in Kamil zircon grains are anomalously short compared to those reported in shocked zircon from other impact structures, where individual lamellae are tens of micrometers long. Previous empirical studies have suggested that {112} twin lamellae in zircon form at ~20 GPa in non-porous target rocks, a finding supported by their coexistence, in some impactites, with high-pressure phases such as reidite. The only available experimental constraint, by diamond anvil cell, found {112} twins in zircon powder quenched at 20 GPa. The presence of coesite, stishovite, lechatelierite, and shocked quartz with PDFs in the studied sample is consistent with empirically derived pressure estimates of ~20 GPa for {112} twin formation in zircon in the ejecta sample from Kamil crater. Kamil thus represents the smallest and youngest impact structure where shock-twinned zircon has been reported. Given the apparent efficiency of {112} twin formation (21% of grains), shock-twinned zircon is here shown to provide a robust and readily identifiable record of shock deformation in a relatively common mineral at one of the smallest known terrestrial impact craters.

Table S1: Electron backscatter diffraction (EBSD) analysis conditions

The early stages of atmospheric entry are investigated in four large (250–950 μm) unmelted micrometeorites (three fine‐grained and one composite), derived from the Transantarctic Mountain micrometeorite collection. These particles have abundant, interconnected, secondary pore spaces which form branching channels and show evidence of enhanced heating along their channel walls. Additionally, a micrometeorite with a double‐walled igneous rim is described, suggesting that some particles undergo volume expansion during entry. This study provides new textural data which links together entry heating processes known to operate inside micrometeoroids, thereby generating a more comprehensive model of their petrographic evolution. Initially, flash heated micrometeorites develop a melt layer on their exterior; this igneous rim migrates inwards. Meanwhile, the particle core is heated by the decomposition of low‐temperature phases and by volatile gas release. Where the igneous rim acts as a seal, gas pressures rise, resulting in the formation of interconnected voids and higher particle porosities. Eventually, the igneous rim is breached and gas exchange with the atmosphere occurs. This mechanism replaces inefficient conductive rim‐to‐core thermal gradients with more efficient particle‐wide heating, driven by convective gas flow. Interconnected voids also increase the likelihood of particle fragmentation during entry and, may therefore explain the rarity of large fine‐grained micrometeorites among collections.

The practical limitations inherent to human and robotic planetary exploration necessitate the development of specific protocols and methods. This non-standard approach requires testing and validation phases in order to optimise instrumental setups and improve data interpretation; this can occur prior to, during, or even after a mission. Flight instruments, and/or their spare models, may be evaluated using relevant terrestrial materials and/or locations. These materials are called analogues: “analogue sites” for large-scale locations, and “analogue samples” for smaller-scale materials. Depending on the scientific domain, the word “analogue” may carry different meanings but is invariably used to denote objects having compositions and/or physical properties similar to specific extraterrestrial objects. However, due to the variability in composition and properties of natural materials, there are always – inevitably – some differences between the analogue and the object(s) to which it refers. In analogue studies, it is, thus, important to focus on the specific properties that need to be imitated and to consider analogue properties rather than analogue sites or samples alone. Here, we introduce the concept of “functional analogues”. We first make an overview of the different types of analogues and sort them according to their utility. We then describe how different types of functional analogues can be used throughout the timeline of space missions, from the evaluation of different methods in the definition of a mission to understanding the results acquired by probes exploring extraterrestrial bodies. Finally, logical pathways are outlined that facilitate the selection of the best-suited functional analogue(s) according to their intended use and taking into account practical limitations., SCOPUS: ar.j, info:eu-repo/semantics/published

Optical tweezers are powerful tools based on focused laser beams. They are able to trap, manipulate, and investigate a wide range of microscopic and nanoscopic particles in different media, such as liquids, air, and vacuum. Key applications of this contactless technique have been developed in many fields. Despite this progress, optical trapping applications to planetary exploration are still to be developed. Here we describe how optical tweezers can be used to trap and characterize extraterrestrial particulate matter. In particular, we exploit light scattering theory in the T-matrix formalism to calculate radiation pressure and optical trapping properties of a variety of complex particles of astrophysical interest. Our results open perspectives in the investigation of extraterrestrial particles on our planet, in controlled laboratory experiments, aiming for space tweezers applications: optical tweezers used to trap and characterize dust particles in space or on planetary bodies surface.

Coesite in impact rocks is traditionally considered a retrograde product formed during pressure release by the crystallisation of an amorphous phase (either silica melt or diaplectic glass). Recently, the detailed microscopic and crystallographic study of impact ejecta from Kamil crater and the Australasian tektite strewn field pointed in turn to a different coesite formation pathway, through subsolidus quartz-to-coesite transformation. We report here further evidence documenting the formation of coesite directly from quartz. In Kamil ejecta we found sub-micrometric single-coesite-crystals that represent the first crystallization seeds of coesite. Coesite in Australasian samples show instead well-developed subeuhedral crystals, growing at the expenses of hosting quartz and postdating PDF deformation. Coesite (010) plane is most often parallel to quartz {10–11} plane family, supporting the formation of coesite through a topotactic transformation. Such reaction is facilitated by the presence of pre-existing and shock-induced discontinuities in the target. Shock wave reverberations can provide pressure and time conditions for coesite nucleation and growth. Because discontinuities occur in both porous and non-porous rocks and the coesite formation mechanism appears similar for small and large impacts, we infer that the proposed subsolidus transformation model is valid for all types of quartz-bearing target rocks.

We analysed the heterogenous fine-grained (sub-μm) matrix of a small (58 × 93 μm), unmelted and minimally heated (

Sample return missions are among the most exciting space missions, providing both scientifically unique information and an unparalleled mechanism for the inspiring the public. Returned samples allow us to make critical ground truth measurements that can calibrate remote sensing measurements from spacecraft. Some scientific studies can only be done in laboratories rather than remotely or with landed spacecraft. Currently Europe does not have a facility suitable for the curation of returned extra-terrestrial samples. This not only hinders European Space Agency (ESA) missions, but also renders European institutions and Principal Investigators unable to fully participate as equal participants in missions implemented by other countries. The EURO CARES project was the first European attempt to review and evaluate the current state-of-the-art in curatorial practice for sample return missions, and determine the different and necessary steps in order to create a fully functional European Extra-terrestrial Sample Curation Facility to match the ESA requirements.

Cosmic dust particles are usually collected in space or in the Earth’s stratosphere and deposited on a substrate to be analysed at large terrestrial facilities. We use Raman tweezers technique for the contacless manypulation of cosmic dust particles, to identify their compositions and to characterize their response to optical forces without any substrate effects, documenting the high potential of this novel technique for space exploration.

Muong Nong-type (MN) tektites are a layered type of tektite associated to the Australasian strewn field, the youngest (790 kyr) and largest on Earth. In some MN tektites, coesite is observed in association with relict quartz and silica glass within inclusions surrounded by a froth layer. The formation of coesite-bearing frothy inclusions is here investigated through a 3D textural multiscale analysis of the vesicles contained in a MN tektite sample, combined with compositional and spectroscopic data. The vesicle size distribution testifies to a post-shock decompression that induced melting and extensive vesiculation in the tektite melt. Compared to free vesicles, nucleated homogeneously in the tektite melt, froth vesicles nucleated heterogeneously on relict quartz surfaces at the margins of coesite-bearing inclusions. The rapid detachment of the froth vesicles and prompt reactivation of the nucleation site favoured the packing of vesicles and the formation of the froth structure. Vesicle relaxation time scales suggest that the vesiculation process lasted few seconds. The formation of the froth layer was instrumental for the preservation of coesite, promoting quenching of the inclusion core through the subtraction of heat during froth expansion, thereby physically insulating the inclusion until the final quench of the tektite melt.

1. Introduction A recent study on a Muong Nong-type tektite [1] revealed the occurrence of quartz with a “spongy texture”. The orientation and distribution of the voids in quartz were supposed to be crystallographically controlled. Similar structures were not reported before in the literature except for a glass impactite from the 45-m-Kamil crater, Egypt (sample L09) [2]. No Raman or TEM studies were carried out on this lapillus and due to the occurrence of voids, this SiO2-rich material was interpreted as glass. The renewed interest induced us to check again these structures in Kamil impactites. They were found along borders and fractures in numerous quartz relicts occurring in impact melt lapilli. In this work, we present the preliminary results of the characterization of these structures. 2. Impactite L09 The present study focuses on the SiO2 glass-rich impactite L09 (max length ~5 cm). This sample was described in [2] as white glass, i.e., a glass derived from the melting of the target rock without interaction with the projectile (Ni below detection limit). The glass is locally stained by reddish-brownish material. Among Kamil white glasses, L09 is the only sample showing large quartz relicts (up to a few millimeters). 3. Methods The sample was optically characterized through polarized microscope and Raman spectroscopy. Successively, it was investigated by scanning electron microscopy (SEM) and spot chemical analyses from the vesicular glass and quartz relicts were acquired through electron microprobe (EMP). 4. Results Under crossed polarized light the quartz relicts have a very low birefringence and show sporadic birefractive domains. In the birefractive domains, planar deformation features (PDFs) have been observed. Raman spectra of quartz relicts vary between a pure SiO2 glass spectrum with the typical large asymmetric band at ~490 cm-1 and a glass-free shocked-quartz spectrum (main peak at 460 cm-1). Shocked-quartz is easily recognized by Raman spectroscopy: the peaks are shifted towards lower frequencies due to the increase in the angle spanning two tetrahedra [3,4]. Up to two sets of PDFs were recognized at the SEM. PDFs are irregular, closely spaced, enlarged, and tend to coalesce. The PDF areas are in spatial continuity with PDF-free amorphous regions. The PDF-free amorphous regions can contain sporadic vesicles. No flux textures have been recognized in quartz relicts. Occasionally, quartz relicts are crossed by vesicular glass veins chemically enriched in Al2O3 and FeO and open fractures. The margins of the quartz relicts and fractures are mostly surrounded by a layer (usually 30-µm-thick; exceptionally up to 100-µm-thick) of unshocked quartz (Raman main peak at 465 cm-1). Quartz appears in form of skeletal hexagonal aggregates. The numerous voids left out from the skeletal growth are partially filled by iron oxides. The number of the voids increases and their size decreases towards the quartz relicts describing a kind of rim. Small concentric fractures are frequent in the quartz relicts, marking the rim of the skeletal quartz layers. No cristobalite or high-pressure SiO2 polymorphs (i.e., coesite and stishovite) have been detected by Raman. 5. Preliminary discussion The occurrence of skeletal quartz is indicative of a rapid crystallization of the quartz from a fluid phase. Due to the size of the impact event and size of the lapillus, a hydrothermal post-shock alteration could be ruled out. Thus, it is plausible that the quartz crystallized from a SiO2-rich melt. Due to its viscosity, this melt should have been formed at the same location where the skeletal quartz occurs. The melt formed at the expense of the highly-shocked-quartz/diaplectic-glass grains with a minor involvement of the Si-Fe-Al surrounding melt/glass. The melting should have occurred immediately after the pressure release, in the early decompression stage. The subsequent drop of the temperature induced the fast (skeletal) crystallization of the quartz. That probably started in the stability field of β-quartz (4.5 GPa Acknowledgements This work is supported by the Deutsche Forschungsgemeinschaft (DFG; FA 1599/1-1 to AF). Prof. Langenhorst is thanked for the access to the SEM/FIB and TEM facilities at the University of Jena founded via the Gottfried Wilhelm Leibniz prize (LA830/14-1). Dr. Kiefer (University of Jena) is acknowledged for technical assistance during the EMP measurements. The studied sample was collected during the 2010 geophysical expedition carried out within the framework of the 2009 Italian- Egyptian Year of Science and Technology and supported by the Italian Ministero degli Affari Esteri e Cooperazione Internazionale (MAECI)—Progetti di Grande Rilevanza. References [1] Glass, B.P., et al. (2020) Coesite in a Muong Nong-type tektite from Muong Phin, Laos: Description, formation, and survival. Meteoritics & Planetary Science. 55:253–273. [2] Fazio, A., et al. (2016) Target-projectile interaction during impact melting at Kamil Crater, Egypt. Geochimica et Cosmochimica Acta 180:33-50. [3] Fritz, J., et al. (2011) Shock experiments on quartz targets pre-cooled to 77 K. International Journal of Impact Engineering 38:440-445. [4] Mcmillan, P.F., G.H. Wolf, and P. Lambert (1992) A Raman-Spectroscopic study of shocked single crystalline quartz. Physics and Chemistry of Minerals 19:71-79.

We present new time series partial melting experiments performed on a natural enstatite chondrite (EL6), aimed at investigating the textural and geochemical changes induced by silicate-metal equilibration during early planetary differentiation. The starting material of our experiments consisted of small fragments (ca. 50 mg) obtained from the interior of the enstatite chondrite MCY 14005 (MacKay Glacier, Antarctica), collected during the XXX° Italian Expedition in Antarctica (PNRA). Experiments were performed in graphite capsules at a pressure of 1 GPa, at temperature ranging from 1100 to 1300 °C, with run durations from 1 to 24 h. The initial phase assemblage of the enstatite chondrite, mostly composed by granular enstatite and Fe-Ni metal (up to 400 µm in size) with minor amounts of sulphides and plagioclase, undergoes significant changes with increasing temperature and run duration. At 1100 °C, no silicate melt is produced and subsolidus reactions occur at the contact between the metal and silicate phases. At 1200 °C, small amounts of silicate melt are produced at the grain boundaries and enstatite grains in contact with the melt grow Fe-enriched rims. The metal portions are characterized by two immiscible liquid phases that exhibit rounded shapes when in contact with the silicate melt, whereas smaller (micrometric) liquid metal spheres occur isolated within the silicate melt throughout the experimental charges. These features are already observed in the 1 h experiment but become increasingly evident with increasing run duration, and at higher temperatures. In the experiments performed at 1300 °C, the amount of silicate melt increases and new silicate minerals form (olivine and low-Ca-pyroxene).Enstatite chondrites are characterized by an oxygen isotope composition similar to that of the bulk Earth and Moon, and are considered to have initially formed in the terrestrial planetary zone of the solar nebula. For this reason, they represent a suitable material to investigate the early planetary differentiation processes that occurred in the proto-Earth system. Preliminary results from our experiments indicate that, at the investigated oxygen fugacity (1-2 log units below the IW buffer), the Fe-Si exchange between the metal and silicate phases allows the formation of silicate melt and silicate phases such as olivine and low-Ca-pyroxene. At the same time, the change in shape of the metal grains (increasingly circular/spherical with increasing temperature) and the overall reduction of their number density with increasing experimental time point to rapid aggregation of the metal phase and, possibly, to fast silicate-metal differentiation in small planetesimals.

International audience; We describe the geological, geomorphological, and paleoclimatic setting of the Sahara of North Africa in particular, focused on the main meteorite dense collection areas (DCA; Morocco, Algeria, Tunisia, and Libya). We report on the outcome of several meteorite recovery field expeditions in Morocco and Tunisia since 2008, by car and by foot, that applied systematic search methods. The number of meteorites collected is 41 ordinary chondrites and one brachinite. The statistics of unpaired ordinary chondrites indicates that H chondrites are more abundant (21) than L chondrites (12), while LL chondrites are rare (2). Our meteorite density estimates for Tunisia and Morocco are in the order of magnitude of 1 met km(-2). An estimate of the total maximum number of meteorites that could be recovered from the Sahara is 780,000 meteorites. We selected 23 meteorites from Aridal, Bou Kra, Bir Zar, and Tieret DCAs for C-14 dating. The results show a wide range of terrestrial ages from 0.4 to more than 40 kyr with a majority of meteorites showing ages between 0.4 and 20 kyr. The weathering degree of these meteorites is ranges from minor (W1) to strong (W4). The highest weathering grades result from repeated oscillations between high and low humidity in the Sahara. However, there appears to be no correlation between weathering grade and terrestrial age of meteorites.

International audience; Impactor identification is one of the challenges of large-scale impact cratering studies due to the dilution of meteoritic material in impactites (typically

We analysed 44 fine-grained and scoriaceous micrometeorites. A bulk mid-IR spectrum (8–13 μm) for each grain was collected and the entire micrometeorite population classified into 5 spectral groups, based on the positions of their absorption bands. Corresponding carbonaceous Raman spectra, textural observations from SEM-BSE and bulk geochemical data via EMPA were collected to aid in the interpretation of mid-IR spectra. The 5 spectral groups identified correspond to progressive thermal decomposition. Unheated hydrated chondritic matrix, composed predominantly of phyllosilicates, exhibit smooth, asymmetric spectra with a peak at ∼10 μm. Thermal decomposition of sheet silicates evolves through dehydration, dehydroxylation, annealing and finally by the onset of partial melting. Both CI-like and CM-like micrometeorites are shown to pass through the same decomposition stages and produce similar mid-IR spectra. Using known temperature thresholds for each decomposition stage it is possible to assign a peak temperature range to a given micrometeorite. Since the temperature thresholds for decomposition reactions are defined by the phyllosilicate species and the cation composition and that these variables are markedly different between CM and CI classes, atmospheric entry should bias the dust flux to favour the survival of CI-like grains, whilst preferentially melting most CM-like dust. However, this hypothesis is inconsistent with empirical observations and instead requires that the source ratio of CI:CM dust is heavily skewed in favour of CM material. In addition, a small population of anomalous grains are identified whose carbonaceous and petrographic characteristics suggest in-space heating and dehydroxylation have occurred. These grains may therefore represent regolith micrometeorites derived from the surface of C-type asteroids. Since the spectroscopic signatures of dehydroxylates are distinctive, i.e. characterised by a reflectance peak at 9.0–9.5 μm, and since the surfaces of C-type asteroids are expected to be heated via impact gardening, we suggest that future spectroscopic investigations should attempt to identify dehydroxylate signatures in the reflectance spectra of young carbonaceous asteroid families.

This chapter provides an account of the present Egyptian impact cratering record as well as an overview of the Egyptian meteorite collection. The 45-m-diameter Kamil crater in the East Uweinat District in southwestern Egypt is so far the only confirmed impact crater in Egypt. Due to its exceptional state of preservation Kamil can be considered a type-structure for small-scale impacts on Earth. Enigmatic types of natural glasses including the Libyan Desert glass found in the Great Sand Sea and the Dakhleh glass found near Dakhla Oasis (note that Dakhla, Dakhleh and Dakhlah are transliterations) may be products of low-altitude airbursts of large and fragile cometary or asteroidal impactors. A number of circular, crater-shaped geological structures superficially resembling impact craters are discussed. To date the Egyptian meteorite collection totals 2 falls, including the ~10 kg Martian meteorite Nakhla that has served as a keystone for the understanding of magmatic differentiation processes on Mars, and 76 finds. With the exception of a minority of incidental findings, most Egyptian meteorite finds (~75%) were recovered over the last ~30 years from three dense meteorite collection areas, namely the El-Shaik Fedl, Great Sand Sea and Marsa Alam fields. The exceptional exposures of the Precambrian basement and Paleozoic to Cenozoic sedimentary covers in Egypt offer a good opportunity for the identification of new impact structures. Likewise, Egypt’s vast rocky desert surfaces are of great potential for the collection of meteorites through systematic searches. These prospects are fundamental ingredients for fostering the ongoing development of meteoritics and planetary science in Egypt as disciplines for future scientific endeavor in Africa.

EURO-CARES (European Curation of Astromaterials Returned from the Exploration of Space) was a three-year multinational project (2015-2017) funded by the European Commission's Horizon 2020 research programme. The objective of EURO-CARES was to create a roadmap for the implementation of a European Extra-terrestrial Sample Curation Facility (ESCF). This facility was intended to be suitable for the curation of samples from return missions from the Moon, asteroids, Mars, and other bodies of the Solar System. The EURO-CARES project covered five technical areas, led by scientists and engineers from institutions across Europe. 1. Planetary Protection: Planetary protection requirements and implementation approaches were assessed by experts and guided by international policy. Existing sterilization methods and techniques were reviewed. It was found that measures already employed for high containment biosafety facilities are suitable for a restricted sample return mission. However, the development of certain technologies, such as a 'double walled' isolator, remote manipulation, integration of scientific analytical instruments, etc. is also required. 2. Facilities and Infrastructure: Aspects from building design to storage of the samples were examined in the project. Requirements for the facility included that it contained a receiving laboratory, a cleaning and opening laboratory, a bio-assessment laboratory, a curation laboratory, and sample storage. Different design solutions were prepared in collaboration with architects. 3. Instruments and Methods: The methodology of characterisation of returned samples and the instrument base required at the ESCF were determined. The analyses provide an appropriate level of characterisation while ensuring minimal contamination and minimal alteration of the sample. When the samples are returned to Earth, several stages of studies would be conducted. 4. Analogue Samples: Analogue proxy samples were considered critical for testing sample handling, preparation techniques, storage conditions, planetary protection measures, as well as to validate new analytical methods. A list of useful analogue samples has been assembled. 5. Sample Transport: The Earth re-entry capsule from a sample return mission is targeted at a specific landing ellipse on Earth and must then be transported safely to the ESCF in an appropriate transport container. Lessons learned from past sample return missions show that preparations for recovery included: training of the recovery team for every possible scenario, possible temporary facilities nearby the landing site, environmental measurements and collection of samples at the landing site, added to this if necessary, would be planetary protection measures. In conclusion, long-term curation of extra-terrestrial samples requires that the samples are kept clean to minimize the risk of Earth contaminants, at the same time as contained, in case of a restricted sample return. This work describes a roadmap for a combined high containment and ultraclean European sample curation facility and the development of the necessary novel scientific and engineering methods and techniques., SCOPUS: cp.p, info:eu-repo/semantics/published

We report the discovery of a partially altered microchondrule within a fine-grained micrometeorite.This object is circular

Coesite, a high-pressure silica polymorph, is a diagnostic indicator of impact cratering in quartz-bearing target rocks. The formation mechanism of coesite during hypervelocity impacts has been debated since its discovery in impact rocks in the 1960s. Electron diffraction analysis coupled with scanning electron microscopy and Raman spectroscopy of shocked silica grains from the Australasian tektite/microtektite strewn field reveals fine-grained intergrowths of coesite plus quartz bearing planar deformation features (PDFs). Quartz and euhedral microcrystalline coesite are in direct contact, showing a recurrent pseudo iso-orientation, with the [1 1 ¯ 1] * vector of quartz near parallel to the [0 1 0]* vector of coesite. Moreover, discontinuous planar features in coesite domains are in textural continuity with PDFs in adjacent quartz relicts. These observations indicate that quartz transforms to coesite after PDF formation and through a solid-state martensitic-like process involving a relative structural shift of { 1 ¯ 0 1 1 } quartz planes, which would eventually turn into coesite (0 1 0) planes. This process further explains the structural relation observed between the characteristic (0 1 0) twinning and disorder of impact-formed coesite, and the 1 0 1 ¯ 1 PDF family in quartz. If this mechanism is the main way in which coesite forms in impacts, a re-evaluation of peak shock pressure estimates in quartz-bearing target rocks is required because coesite has been previously considered to form by rapid crystallization from silica melt or diaplectic glass during shock unloading at 30–60 GPa.

We report the discovery of a unique micrometeorite, containing an exotic Al-Cu-Fe alloy composed of two intermixed phases: khatyrkite (CuAl2) and stolperite (CuAl) and both containing minor Fe (2O3: 0.01–0.56 wt%, MnO: 0.03–0.32 wt% and CaO: 0.09–0.22 wt%) and a cumulate layered texture. These properties suggest the micrometeorite is derived from a carbonaceous chondrite (best matched to a CO chondrite) and entered the atmosphere a high speed (~16 kms−1), implying an origin from a highly eccentric orbit. This particle represents the second independent discovery of naturally occurring intermetallic Al-Cu-Fe alloys and is thus similar to the previously reported Khatyrka meteorite - a CV chondrite containing near-identical alloys and the only known natural quasicrystals. We did not observe quasicrystalline phases in this micrometeorite, likely due to the low amounts of Fe in the alloy, insufficient to stabilize quasicrystals. Our discovery confirms the existence of Al-Cu-Fe intermetallic alloys on chondritic parent bodies. These unusual phases require a currently unexplained formation process, we tentatively suggest this could represent the delivery of exotic interstellar material to the inner solar system via impact.

This study explores the petrology of five giant (>400 μm) hydrated fine-grained micrometeorites from the Transantarctic Mountain (TAM) micrometeorite collection. For the first time, the extent and mechanisms of aqueous alteration in unmelted cosmic dust are evaluated and quantified. We use a range of criteria, previously defined for use on hydrated chondrites, including phyllosilicate fraction, matrix geochemistry and micro textures. Collectively, these micrometeorites represent ∼2.22 mm2 of intensely altered hydrated chondritic matrix (with petrologic subtypes of

International audience; High Be-10 contents in tektites reported in literature are taken as evidence of a source material, melted at the impact site, enriched in atmospheric Be-10; i.e., a soil or sediment. In 0.8 Ma Australasian tektites, Be-10 content increases with distance from the putative impact location in Indochina, with geographic averages from 69 x 10(6) atoms/g (Indochina) to 136 x 10(6) atoms/g (Australia). Here we report, for the first time, Be-10 contents in microtektites collected from Antarctica and the South China Sea. We show that microtektites are similar to 30 x 10(6) atoms/g richer in Be-10 than tektites from the same geographic areas. Antarctic microtektites, with an average Be-10 content of 184 x 10(6) atoms/g after correction for in situ production, are the richest impact glass ever measured. The simplest explanation for such systematic size and geographic trends is that the source depth of the melt within the target surface decreases with ejection velocity. Indeed, higher initial kinetic energy implies higher launch distances and higher fragmentation of the ejecta. Antarctic microtektite source depth may tentatively be restricted to the upper tens of centimeters at the impact site. Alternative models invoking a marine or loessic sediment source, or a secondary enrichment in the microtektite (either by atmospheric scavenging, selective fractionation by volatilization, or post-depositional contamination) fail to reproduce the observed relationships.

International audience; The bulk of extraterrestrial matter currently accreted by the Earth is in the form of micrometeorites (MMs) and interplanetary dust particles (IDPs), thus they may have collectively made a substantial contribution to the volatile inventory of the Earth and the other terrestrial planets. We have performed a complete noble gas study, accompanied by a complete petrographic characterization, of MMs from the Transantarctic Mountain (TAM) collection in the size range similar to 300 to similar to 1000 mu m that fell over an extended time period during the last similar to 1 Ma. Our noble gas study includes krypton and xenon, which have been largely missing in previous work. Helium and neon are dominated by a solar component, with generally lower abundance in scoriaceous MMs than in unmelted ones, and also generally lower in abundance than in previously studied MMs, which may be explained by the larger particle size (surface/volume ratio) of the MMs we studied. Considering an enhanced MM flux in the early Solar System, such MMs may have supplied a significant fraction of Earth's neon. A number of MMs have kept what was probably their pre-terrestrial He/Ne ratio, from which we infer that the observed solar component is retained in a tiny surface region not affected by atmospheric entry. The abundances of (volume-correlated) heavier gases are similar to what was found in previous studies of smaller MMs. While Ar contains both solar and "planetary" contributions, the heavy noble gases (Kr, Xe) generally show "planetary" patterns but are often also compromised by terrestrial contamination as evidenced by an enhanced Kr/Xe ratio. Kr and Xe in a subset of scoriaceous MMs are dominated by isotopically fractionated air, possibly acquired during the passage through Earth's ionosphere. Those not obviously affected by air show isotopic ratios similar to primitive meteorites (the Q component), thus primordial heavy gases supplied to the Earth by MMs are likely as those found in macroscopic meteorites. There is no evidence for the presence of a "cometary" Xe component as identified in the coma of comet 67P/Churyumov-Gerasimenko, hence a cometary source for a significant fraction of MMs in the studied size range is unlikely. Cosmogenic helium, neon and argon were detected in several cases. Cosmic ray exposure ages were calculated based on cosmogenic Ne-21 in combination with the Poynting-Robertson effect, but depend on assumptions about atmospheric entry loss. Still, several cases are consistent with an origin from the asteroid belt (even assuming no loss) and one scoriaceous MM (#45b.17) would have to originate from beyond Jupiter. In at least two cases, including #45b.17, the isotopic composition of cosmogenic Ne appears to be inconsistent with predominant production in small particles free-floating in space, however; much of the irradiation of these MMs may have occurred when they were part of larger parent bodies.

Comets are typically considered to be pristine remnants of the early solar system. However, by definition they evolve significantly over their lifetimes through evaporation, sublimation, degassing and dust release. This occurs once they enter the inner solar system and are heated by the Sun. Some comets (e.g. 1P/Halley, 9P/Tempel and Hale-Bopp) as well as chondritic porous cosmic dust – released from comets – show evidence of minor aqueous alteration resulting in the formation of phyllosilicates, carbonates or other secondary phases (e.g. Cu-sulphides, amphibole and magnetite). These observations suggest that (at least some) comets experienced limited interaction with liquid water under conditions distinct from the alteration histories of hydrated chondritic asteroids (e.g. the CM and CR chondrites). This synthesis paper explores the viability of perihelion-induced heating as a mechanism for the generation of highly localised subsurface liquid water and thus mild aqueous alteration in periodic comets. We draw constraints from experimental laboratory studies, numerical modelling, spacecraft observations and microanalysis studies of cometary micrometeorites. Both temperature and pressure conditions necessary for the generation and short-term (hour-long) survival of liquid water are plausible within the immediate subsurface ( Most periodic comets which currently pass close to the Sun are dormant, having experienced surface heating, significant cometary activity and dust release in the past. These bodies may be responsible for the partially hydrated cometary micrometeorites we find at the Earth's surface and their aqueous alteration histories may have been produced by perihelion-induced subsurface heating. This is in contrast to radiogenic and impact heating that operated during the early solar system on asteroids. This study has implications for the alteration history of the active asteroid Phaethon, the target of JAXA's DESTINY+ mission.

Collecting cosmic dust is a tricky business! Despite Earth's surface being showered by thousands of tons of comic dust every year, such dust is quickly lost in a sea of terrestrial particles. Finding the tiny cosmic treasures requires collecting dust from the cleanest environments where the terrestrial particle background is low. The stratosphere can be sampled via high-flying aircraft, whereas sampling cosmic dust from polar regions and the deep sea requires techniques that concentrate the particles. Collection efforts are worth it. Cosmic dust derives from every dust-producing object in the Solar System, including ancient Solar System materials, possibly even interstellar materials, of a type not found in meteorites.

Bulk oxygen isotope data has the potential to match extraterrestrial samples to parent body sources based on distinctive δ18O and Δ17O ratios. We analysed 10 giant (>500µm) micrometeorites using combined µCT and O-isotope analysis to pair internal textures to inferred parent body groups. We identify three ordinary chondrite particles (L and LL groups), four from CR chondrites and the first micrometeorite from the enstatite chondrite (EH4) group. In addition, two micrometeorites are from hydrated carbonaceous chondrite parent bodies with 16O-poor isotopic compositions above the terrestrial fractionation line. They experienced intense aqueous alteration, contain pseudomorphic chondrules and are petrographically similar to the CM1/CR1 chondrites. These micrometeorites may be members of the newly established CY chondrites and/or derived from the enigmatic “Group 4” micrometeorite population, previously identified by Yada et al., 2005 [GCA, 69:5789-5804], Suavet et al., 2010 [EPSL, 293:313-320] (and others). One of our 16O-poor micrometeorite plots on the same isotopic trendline as the CO, CM and CY chondrites – “the CM mixing line” (with a slope of ~0.7 and a δ17O intercept of -4.23‰), implies a close relationship and potentially a genetic link to these hydrated chondrites. If position along the CM mixing line reflects the amount of 16O-poor (heavy) water-ice accreted onto the parent body at formation, then the CY chondrites and these 16O-poor micrometeorites must have accreted at least as much water-ice as CM chondrites but potentially more. In addition, thermal metamorphism could have played a role in further raising the bulk O-isotope compositions through the preferential loss of isotopically light water during phyllosilicate dehydration. The study of micrometeorites provides insights into asteroid belt diversity through the discovery of material not currently sampled by larger meteorites, perhaps as a result of atmospheric entry biases preventing the survival of large blocks of friable hydrated material.

Coesite, a high-pressure silica polymorph (pressure 3-10 GPa, temperature < 3000 K), is a diagnostic feature of shock metamorphism associated with impact cratering on quartz-bearing target rocks. It is preserved as a metastable phase in sedimentary target rocks that experienced peak pressures in excess of ~10 GPa, where it typically occurs as intergranular polycrystalline aggregates of microcrystals embedded in silica glass known as "symplectic regions." The presence of coesite in the symplectic regions of rocks experiencing shock conditions beyond the limits of the coesite stability field is a controversial issue. Through a combined scanning and transmission electron microscopy and Raman spectroscopy study of shocked quartzarenites from the 45-m-diameter Kamil Crater (southwest Egypt), we show that coesite in symplectic regions forms through direct subsolidus transformation from quartz, in contrast with the prevailing hypothesis for crystalline targets. The quartz-to-coesite transformation takes place during localized shock-wave reverberation at the beginning of the pore collapse process. Complete pore collapse generates the high temperature regimes responsible for the subsequent production of the embedding silica melts, in part at the expense of the previously formed coesite. This work documents the role of pore collapse in producing localized pressure-temperature-time gradients in shocked porous targets, as predicted by numerical models in the literature.

This paper investigates the mineralogy and noble gas composition of a unique micrometeorite from the Transantarctic Mountains, #45c.29. The magnetite rim and the particle interior with olivine, pyroxene and magnetite relict grains (30–250 µm in size) set in a vesicular mesostasis are typical features of coarse-grained, partially melted micrometeorites. Particle #45c.29 stands out from other micrometeorites of this type by the texture of the mesostasis made of abundant plagioclase and augite laths, the remarkably high Ni contents in magnetite and olivine relict grains, and by the similarly high abundance of cosmogenic noble gases ( 21 Ne cos up to 1.62 × 10 −7 cm 3 STP/g and 38 Ar up to 7.2 × 10 −8 cm 3 STP/g). The high Ni content of Fa 26 olivine relict grains (NiO ∼ 0.65 wt%), the high Ni (NiO ∼ 0.8 wt%) and Ti (TiO 2 ∼ 0.3 wt%) contents of magnetite relicts, and the oxygen isotope composition of a sample of the particle (δ 18 O ∼ 2.3‰, δ 17 O ∼ −1.5‰), suggest a parentage with rare equilibrated CK chondrites. Pyroxene and plagioclase are not expected to crystallize during atmospheric entry of micrometeoroids. Their occurrence in #45c.29 may be explained by the Ca-, Al- and Na- rich composition of its precursor – in agreement with the high abundance of plagioclase reported in the matrix of CK chondrites – if combined with a relatively low cooling rate and, therefore, unusual atmospheric entry parameters (velocity/angle) of the micrometeoroid. Given these specific entry parameters, the particle has recorded unique information on mineralogical and textural transformations of micrometeoroids during atmospheric entry, with solid-state oxidation of the olivine relict grains in the igneous rim, and partial melting of relict mineral phases and relict/melt reactions in the particle interior. The cosmogenic 21 Ne/ 22 Ne ratio of 0.94 ± 0.02 is incompatible with major production by cosmogenic ray irradiation of a small particle in space. We propose that micrometeorite #45c.29 mostly records an earlier irradiation stage, in a meteoroid or more likely near the surface (

Kamil is a 45 m diameter impact crater identified in 2008 in southern Egypt. It was generated by the hypervelocity impact of the Gebel Kamil iron meteorite on a sedimentary target, namely layered sandstones with subhorizontal bedding. We have carried out a petrographic study of samples from the crater wall and ejecta deposits collected during our first geophysical campaign (February 2010) in order to investigate shock effects recorded in these rocks. Ejecta samples reveal a wide range of shock features common in quartz-rich target rocks. They have been divided into two categories, as a function of their abundance at thin section scale: (1) pervasive shock features (the most abundant), including fracturing, planar deformation features, and impact melt lapilli and bombs, and (2) localized shock features (the least abundant) including high-pressure phases and localized impact melting in the form of intergranular melt, melt veins, and melt films in shatter cones. In particular, Kamil crater is the smallest impact crater where shatter cones, coesite, stishovite, diamond, and melt veins have been reported. Based on experimental calibrations reported in the literature, pervasive shock features suggest that the maximum shock pressure was between 30 and 60 GPa. Using the planar impact approximation, we calculate a vertical component of the impact velocity of at least 3.5 km s � 1 . The wide range of shock features and their freshness make Kamil a natural laboratory for studying impact cratering and shock deformation processes in small impact structures.

Elevating planetary and space sciences across Africa could help nations reach their development goals. Efforts will require collaboration, creativity, efficient planning, and political will.

Northwest Africa (NWA) 6583 is a silicate-bearing iron meteorite with Ni = 18 wt%. The oxygen isotope composition of the silicates (∆′17O = −0.439 ‰) indicates a genetic link with the IAB-complex. Other chemical, mineralogical, and textural features of NWA 6583 are consistent with classification as a new member of the IAB-complex. However, some unique features, e.g., the low Au content (1.13 μg g−1) and the extremely reducing conditions of formation (approximately −3.5 ∆IW), distinguish NWA 6583 from the known IAB-complex irons and extend the properties of this group of meteorites. The chemical and textural features of NWA 6583 can be ascribed to a genesis by impact melting on a parent body of chondritic composition. This model is also consistent with one of the most recent models for the genesis of the IAB-complex. Northwest Africa 6583 provides a further example of the wide lithological and mineralogical variety that impact melting could produce on the surface of a single asteroid, especially if characterized by an important compositional heterogeneity in space and time like a regolith.