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Graphdiyne (GDY), a new kind of two-dimensional carbon nanomaterial, has abundant chemical bonds, a highly π-conjugated structure, uniformly distributed pores, a large surface area, and good biocompatibility and has been applied in drug delivery, biosensing, antibacterial processes, and cancer therapy. Herein, this review is intended to provide an introduction of current advances in bioapplications of GDY, which covers the synthetic methods, structure and properties of GDY, and its application in antimicrobial processes, cancer therapy, biosensing, and bioimaging. Finally, we provide a perspective on future development in research relevant to GDY. We believe that this review can provide meaningful assistance for breakthroughs and innovations in the field of GDY. [ABSTRACT FROM AUTHOR]

Cu-SSZ-39 zeolite with an AEI structure exhibits excellent hydrothermal stability and can be a potential alternative to Cu-SSZ-13 zeolite SCR catalysts for NOx removal in diesel vehicles. However, the inferior low-temperature performance of Cu-SSZ-39 leads to substantial NOx emissions during the cold-start period, impeding its practical application. In this study, Ce-Mn oxide-modified Cu-SSZ-39 catalysts (CeMnOx/Cu-SSZ-39) and references (CeO2/Cu-SSZ-39 and MnOx/Cu-SSZ-39) were prepared by the ion-exchange of Cu ions followed by impregnation of the oxide precursors, with the aim of enhancing the NH3-SCR performance at low temperatures. The modified catalysts exhibited improved low-temperature activity and hydrothermal stability compared to the unmodified counterpart. In particular, CeMnOx/Cu-SSZ-39 showed the highest activity among the three catalysts and achieved NOx conversions above 90% within the temperature range of 180 °C to 600 °C, even after undergoing hydrothermal aging at 800 °C. Experimental results indicated that the synergistic effect between Ce and Mn in CeMnOx improves the redox properties and acidity of the catalyst due to the presence of Ce3+, Mn4+, and abundant adsorbed oxygen species, which facilitate low-temperature SCR reactions. Furthermore, the interaction of CeMnOx with Cu-SSZ-39 stabilizes the zeolite framework and hinders the agglomeration of Cu species during the hydrothermal aging process, contributing to its exceptional hydrothermal stability. The kinetics and NO oxidation experiments demonstrated that CeMnOx provides access to fast SCR reaction pathways by oxidizing NO to NO2, resulting in a significant increase in low-temperature activity. This study provides novel guidelines for the design and preparation of Cu-SSZ-39 zeolite with outstanding SCR performance over a wide temperature range. [ABSTRACT FROM AUTHOR]

Small porous Cu-SSZ-13 catalysts have recently been commercialized for the selective catalytic reduction of NOx with ammonia (NH3-SCR) on diesel vehicles. Unfortunately, the conventional Cu-SSZ-13 catalyst still confronts the challenge of diffusion limitations, which represent a major obstacle that reduces the catalyst's SCR performance. Herein, a hierarchically porous SSZ-13 zeolite was synthesized via a trans-crystallization method assisted by the use of carbon black as a hard template in a short synthetic period, and the corresponding Cu-SSZ-13 catalysts with mesopores exhibited improved low-temperature activity and hydrothermal stability when compared with their microporous counterpart. A series of characterizations revealed that the mesopores are conducive to an increase in Cu loading while helping to stabilize the CHA structure and maintain the Cu species in their ionic form. More importantly, intra-particle diffusion limitations are reduced via the introduction of the mesopores owing to the shortened diffusion path inside the SSZ-13 zeolite, thus not only enhancing the active sites' accessibility but also promoting the diffusion of the reactants and products. This work contributes to the design and synthesis of a high-performance Cu-SSZ-13 zeolite SCR catalyst for the removal of NOx emitted from diesel vehicles. [ABSTRACT FROM AUTHOR]

Nano sandwich-like storage structure or device is commonly designed as diaphragm to extend nano-battery working life, or fabricated as nanocomposite anode materials to maximumly improve electrochemical performance in nano-battery systems. This work aims to investigate size-dependent dynamic mechanical-diffusion responses of multi-layered laminated sandwich-like nanocomposites subjected to shock loadings of molar concentration in the context of nonlocal diffusion-elasticity model by a semi-analytical technique via Laplace transformation. The results reveal that the diffusion isolation will be maximally improved and lager harmful chemical stresses can be reduced to some extent for proper materials nonlocal parameters and constants ratios of selected. [ABSTRACT FROM AUTHOR]

A series of novel adamantane-based copoly(aryl ether ketone)s ( PAEK-CF3-Ad) with low dielectric constants were prepared by post-amidation of copoly(aryl ether ketone)s containing (3-trifluoromethyl)phenyl and carboxyl groups with 4-adamantylaniline. Compared with the preparation of adamantane-containing poly(aryl ether ketone)s by direct polymerization of adamantyl-substituted monomers, this side-chain grafting method avoids various problems, such as high polymerization temperature and the difficult polymerization of adamantyl-substituted monomers. The dielectric, thermal and mechanical properties of the synthesized PAEK-CF3-Ad were characterized using a precision impedance analyzer, differential scanning calorimetry and thermogravimetric analysis, and a universal tester, respectively. The results indicate that PAEK-CF3-Ad films exhibited low dielectric constants ranging from 2.33 to 2.65 at 1 MHz due to the introduction of the adamantyl groups. The synthesized PAEK-CF3-Ad copolymers exhibited good thermal and mechanical properties. © 2013 Society of Chemical Industry [ABSTRACT FROM AUTHOR]

An analytical method was established for the simultaneous determination of 204 pesticide residues in tea by ultra performance liquid chromatography coupled with quadrupole-time of flight mass spectrometry (UPLC-Q-TOF/MS). The samples were extracted with acetonitrile, and cleaned-up by solid phase extraction (SPE) with a Carb-PSA cartridge, eluted with acetonitrile-toluene (3:1, v/v), determined by UPLC-Q-TOF/MS and quantified by external standard method. A data base of the accurate mass numbers and a library which contains the 204 pesticides were established. The automatic retrieval of detection results was carried on according to the characteristics of the compound, such as accurate mass, retention time, isotopic ratio, and so on. Based on the above results, the qualitative identifications of the 204 pesticides were accomplished without the contrast of standard substances. The results indicated that this method can be used to determine the 204 pesticides in tea. At the three spiked levels of 10, 20, 50 µg/kg, mean recoveries for the 204 pesticides in tea were between 68. 1% and 117. 2%, with the relative standard deviations (RSDs) ranging from 3.1% to 18.9%. The limits of quantification for the 204 pesticides were lower than 10 µg/kg. The method has been applied to four positive samples, and the results generally accord with the detection results by the method of GB/T 23205-2008. This method has the characteristics of high efficiency, as well as high sensitivity and accuracy, which can meet the requirement of the determination of the 204 pesticides in tea.