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Composite foundations have been widely used and promoted in practical engineering applications. However, research on the joint-bearing mechanism of piles and soil within composite foundations is still not comprehensive enough. This paper proposes a method for calculating the additional internal forces of piles and soil within composite foundations. Based on a three-dimensional finite element analysis, this study investigates the variation patterns of the stress, displacement, and additional internal forces of piles and soil in the depth direction under the action of upper loads when using friction piles and end-bearing piles. This research aims to reveal the bearing performance of piles and soil. The results showed that, under the same conditions and due to the presence of end-bearing effects, the internal forces experienced by the entire pile body of the end-bearing piles were more uniform, exhibiting significant advantages in resisting deformation and being able to withstand larger loads. Additionally, the diffusion mechanism of the vertical forces, stresses, and displacements of piles and soil is discussed. Due to the negative frictional resistance of soil and the influence of pile end-bearing effects, the distribution of internal forces and the displacements of piles and soil exhibited different characteristics. This study provides a scientific reference for the theoretical analysis and design of composite foundations. [ABSTRACT FROM AUTHOR]

In order to develop novel pyrene-derived thermally activated delayed fluorescence (TADF) materials and deeply study their structure–property relationship, two emitters of PyPzCN-TPA2 and PyQlCN-TPA2 were designed and synthesized by alternating dicyano pyrenopyrazine (PyPzCN) and dicyano pyrenoquinoxaline (PyQlCN) as the rigid electron-deficient skeleton, as well as triphenylamine (TPA) as an electron-rich unit anchored at the K-region of pyrene, respectively. The effects of the rigid electron-deficient skeleton and electron-rich unit on photophysical and electroluminescence (EL) properties were primarily studied. The extending rigid electron-deficient skeleton made PyQlCN-TPA2 exhibit red-shifted emission at 658 nm in toluene and 840 nm in its neat film. The appending electron-rich unit at the K-region made both emitters exhibit large steric hindrance with a torsion angle of more than 70°, which resulted in a small ΔEST value of about 0.032 eV and a high kRISC of about 1.6–4.7 × 105 s−1. As a result, the solution-processed PyPzCN-TPA2 and PyQlCN-TPA2-doped OLEDs simultaneously exhibited high EQEs of 9.30% at 588 nm and 8.94% at 630 nm, respectively. The EQE roll-off was efficiently suppressed with an increase of emission wavelength. This is the first time that high-efficiency red-emitting pyrene-derived TADF materials were obtained by extending the rigid electron-deficient skeleton and appending the electron-rich unit at the K-region for solution-processed OLEDs. [ABSTRACT FROM AUTHOR]

Reducing the computational workload by simplifying the analysis of karst foundations into a plane strain problem can yield significant advantages. Yet, such an approach fails in reproducing the engineering situation in a rigorous manner. In this regard, this paper proposes an upper-bound method that can effectively analyze the bearing capacity of three-dimensional karst foundations. This method is utilized to investigate the impact of various pile diameters, the ratio of roof thickness to pile diameter, and the ratio of cave width to pile diameter on the stability of karst foundations. The validity of this method is established through an illustrative example. The outcomes illustrate that when subjected to both tensile and compressive horizontal stresses if the maximum horizontal stress surpasses the tensile strength of the rock mass, the roof rock mass may suffer damage. Increasing the ratio of roof thickness to pile diameter can bring down the horizontal stress value. The stability factor is largely influenced by the ratio of roof thickness to pile diameter. The most prominent growth trend of the stability factor is observed when the ratio is less than 3. If the ratio of the roof thickness to pile diameter exceeds 3, the prediction of the bearing capacity estimation for the karst foundation in three-dimensional circumstances is more conservative than that in two-dimensional circumstances. [ABSTRACT FROM AUTHOR]