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Toxic, hazardous petrochemical solvents are commonly used for industrial-scale ultra-high molecular weight polyethylene (UHMWPE) fiber production, but orange terpenes, a byproduct of orange fruit production, present a bio-derived, sustainable alternative. In this work, fine UHMWPE fibers were spun using orange terpenes as the spin solvent, hot-drawn at a draw ratio of 5:1, investigated for their morphology, microstructure, and thermal and mechanical properties. The resulting fibers exhibited a flat, micro-ribbon cross-section, which is highly desirable for achieving high fiber volume fractions in UHMWPE-fiber reinforced composites. After drawing, the fibers possessed 4x greater breaking tenacity than any previously published studies on UHMWPE fibers spun using orange terpenes with a tenacity of 8.6 cN/dtex and tensile modulus of 229.2 cN/dtex. Microstructural analysis via differential scanning calorimetry and X-ray diffraction revealed that the hot drawing process significantly increased molecular orientation, but crystallinity decreased due to crystallite melting during drawing. Therefore, the mechanical properties of these fibers may be significantly improved with optimization of the fiber drawing process. This work establishes the strong potential of orange terpenes as an environmentally-friendly alternative solvent for UHMWPE gel spinning and sets a foundation for future parametric optimization of the spinning and drawing of these fibers. Highlights * Micro-ribbon ultra-high molecular weight polyethylene fibers were prepared using bio-solvent orange terpenes. * Flat profile enables tight packing, aspect ratio maintained after drawing. * Drawn fibers were 4x stronger than any previous work with orange terpenes. * Near-melt drawing reduced crystallinity, improved molecular alignment. KEYWORDS bio-solvent, eco-friendly, fiber, gel spinning, green, high-performance, 1 | INTRODUCTION Polyethylene represents a broad family of polymers connected by the simple repeating unit [([C.sub.2][H.sub.4]).sub.n]. Members of this family are classified by their molecular weight and degree of [...]