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Hydrogen internal combustion engines (H2-ICEs) have advantages such as clean combustion and zero carbon emissions, and have become one of the important technical routes for decarbonization in the internal combustion engine industry. In this paper, several key factors affecting the performance and emissions of hydrogen internal combustion engines, such as ignition timing, excess air coefficient, and hydrogen injection timing, were systematically studied on a spark ignition multi-point injection (MPI) hydrogen internal combustion engine bench. The experimental results indicate that the ignition timing controls the combustion phase of hydrogen. Moderate early ignition can improve the brake thermal efficiency (BTE) while having little impact on the NOX emissions. Excess air coefficient(λ) can significantly affect the performance and emissions of H2-ICE. Along with the increase of the λ, the NOX emissions first increases and then continues to decline. When the λ reaching 2.1 or above, near zero emissions of NOX can be achieved. The advance of hydrogen injection timing will slightly increase the peak of cylinder pressure and instantaneous heat release rate. However, overall, the impact of hydrogen injection timing on BTE and NOX emissions is not significant on MPI H2-ICE.

The emission characteristics of regulated emissions and unregulated emissions were studied under the full loads and the cold/hot transient cycle (WHTC) on a six-cylinder, multi-point injection, and spark ignition methanol engine. The results show that the emissions of THC and CO for the methanol engine is at a high level without three-way catalyst (TWC) and the emission of NOX could be controlled at a lower level than 400 mg/kW·h with exhaust gas recirculation (EGR). The emissions of THC, CO and NOX are low with TWC, whose weighted results under WHTC could be kept at a lower level than the limits in China VI Standard. It is a technical difficulty to control the emissions of methanol (CH3OH) and formaldehyde (HCHO) for methanol engines, especially under the cold WHTC, there has a high risk for the emission of CH3OH exceeding the limit of standard.

In this study, the volatile organic compounds (VOCs) emissions from engine fueled diesel with and without detergent synergist were measured by gas chromatography mass spectrometry(GC-MS). The test results show that compared with reference diesel fuel (without diesel detergent synergist), the use of different diesel detergent synergists has different effects on the VOCs emissions while without after-treatment device. Whether with or without after-treatment device, alkanes always account for the highest proportion of VOCs emissions while engine fuels with different diesel detergent synergists. After-treatment device diesel oxidation catalyst coupled with diesel particulate filter (DOC+DPF) has high catalytic efficiency for VOCs emissions from engine fueled with different fuels, and most of the catalytic efficiency could reach more than 95%. With the catalytic treatment of after-treatment device,the concentrations of carcinogens (detected in this study) in VOCs emissions from engine fueled with and without detergent synergist are far lower than that specified in reference standard GBZ 2.1-2007 “Occupational Exposure Limits for Hazardous Factors in the Workplace and Chemical Hazardous Factors”, respectively. The test results indicate that the use of diesel detergent synergist will not have an adverse impact on human health and it can be safely used.

The Woduhe area of Heilongjiang Province is located in the eastern side of the Greater Xing'an Range. This area has experienced the evolution of the Palaeo‐Asian Ocean, the Palaeo‐Pacific, and the Mongolia–Okhotsk Ocean, and it can be used to discuss the transformation process of these palaeo‐oceanic plates to continental plates. However, controversies exist over its time period and the process of transformation. The 1:250000 Woduhe Geological Map shows that Early Cretaceous granitic batholith developed near the Dajinshan area. However, the LA‐ICP‐MS zircon U–Pb dating presented in this paper shows that the trondhjemites from the southern part of the Dajinshan area were formed at 156.9 ± 2.2 Ma, syenogranites were formed at 131.7 ± 1.6 Ma, and diorite porphyrite dikes were formed at 126.0 ± 3.1 Ma. Therefore, Early Cretaceous batholiths should be reclassified as different, separate units. The Late Jurassic intrusive rocks belong to TTGG assemblages (tonalite–trondhjemite–granodiorite‐granite). Trace element spider diagrams show that the rocks are enriched in K, Pb, Zr, and Hf; depleted in Nb, Ta, and Eu; with higher Sr; and lower Y content. The rare earth element pattern is right‐sloping (La/Yb > 12). The Early Cretaceous intrusive rocks belong to G assemblages (granodiorite). Combined with the tectonic settings, we determined that the Late Jurassic and the Early Cretaceous granites were formed in a magmatic arc setting related to subduction. Late Jurassic intrusive magma mainly originated from the partial melting of the thickened lower crust under the Xing'an arc, and was likely contaminated by mantle material. Early Cretaceous intrusive magma originated from the partial melting of the Xing'an sub‐arc crust. Based on the distribution of the Late Jurassic TTG (N and NE) and G (S and SW) assemblages, intrusive records of the southward and southwestward subduction of the Mongolia–Okhotsk Ocean can be observed. In addition, the grade of maturity of the Xing'an arc is increasing during Late Jurassic to Early Cretaceous. [ABSTRACT FROM AUTHOR]

Large-scale Mesozoic granitoids are exposed in the Greater Khingan Mountains. Their relationship with the Mongolia–Okhotsk and the Paleo-Pacific Ocean is still under discussion and a matter of debate. In this study, field observations were made and a total of 18 granitoids exposed in the vicinity of the Heihe–Baishilazi area in the northern part of the Greater Khingan Mountains were sampled for petrological, geochronological, and geochemical research. In addition, to complement this study, 90 granitic samples from the Xinghua, Dajinshan, Yili, Chabaqi, and Sankuanggou areas in the Greater Khingan Mountains were compiled in order to reveal rock assemblages, magma sources, and then inquire into the tectonic background. Zircon LA–ICP–MS U–Pb dating indicates that two samples from the Heihe area were formed in the Early Jurassic period (194.2 ± 1.4 Ma and 183.1 ± 1.3 Ma), and the εHf(t) values and TDM2 of the zircons were mainly +5.8 to +10.7 and 528 Ma to 834 Ma, respectively, with a large variation range. The intrusive rocks from the Greater Khingan Mountains (108 in total) belonging to the T1T2G1G2 assemblage contained tonalites (T1), trondhjemites (T2), granodiorites (G1), and granites (G2). These granitoids are presented as subalkaline series in a plot of total alkali versus SiO2 (TAS diagram), medium-K calc-alkaline and high-K calc-alkaline series on SiO2 versus K2O diagram, with metaluminous to peraluminous characteristics on an A/CNK versus A/NK diagram. These are shown as a MA (magnesium andesite) series and LMA (lower (or non) magnesium andesite) series on a SiO2 versus MgO diagram, which can be further divided into the higher-pressure TTG subtype of the MA (corresponding to high-SiO2 adakite (HSA)) series and the lower-pressure TTG subtype of LMA (corresponding to typical calc-alkaline suprasubduction zone rocks). In addition, granitoids were enriched in light rare earth elements (LREEs) and large ion lithophile elements (LILEs) and depleted in heavy rare earth elements (HREEs) and high-field-strength elements (HFSEs), corroborating a suprasubduction zone environment. Regional correlations as well as geochemical characteristics indicate that the rocks from the Greater Khingan Mountains formed in a subduction zone environment during the Early Jurassic; primary magma had presumably originated from the melting of young and hot oceanic crust under eclogite to amphibolite facies conditions. According to the spatial variation in rock assemblages (T1T2G1 to G1G2 and G2), we speculate that the northeastern Heihe, Baishilazi, and Xinghua areas as well as the westward Dajinshan area were adjacent to the ocean and formed an outer subduction zone, whereas the southwestward Sankuanggou, Yili, and Chabaqi areas were adjacent to the continent, forming an inner subduction zone. The distribution sites of the inner and outer subduction zones indicate southward and southwestward ocean subduction. Therefore, we propose a direct connection with southward subduction of the Mongolia–Okhotsk Ocean. [ABSTRACT FROM AUTHOR]