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1. Ligand-modified catalysts for the McMurry pinacol reaction

Author

Lipski, Timothy A., Hilfiker, Mark A., and Nelson, Scott G.

Subjects
Chemical reactions -- Research, Ligands -- Research, Catalysts -- Research, Biological sciences, Chemistry
Abstract

The use of organic-soluble Ti(III) complexes as highly efficient catalysts for pinacol homocoupling reaction and the development of ligand-modified catalysts for controlling diastereoselectivity in the reduced coupling of aryl aldehydes was reported. Ligand-modified Ti(III) complexes were found to be effective in catalyzing reductive homocoupling of various carbonyl compounds.

Published
1997

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