1. Efficiency roll-off in light-emitting electrochemical cells
- Author
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Zhang, Xiaoying, Ràfols-Ribé, Joan, Mindemark, Jonas, Tang, Shi, Lindh, Mattias, Gracia-Espino, Eduardo, Larsen, Christian, Edman, Ludvig, Zhang, Xiaoying, Ràfols-Ribé, Joan, Mindemark, Jonas, Tang, Shi, Lindh, Mattias, Gracia-Espino, Eduardo, Larsen, Christian, and Edman, Ludvig
- Abstract
Understanding “efficiency roll-off” (i.e., the drop in emission efficiency with increasing current) is critical if efficient and bright emissive technologies are to be rationally designed. Emerging light-emitting electrochemical cells (LECs) can be cost- and energy-efficiently fabricated by ambient-air printing by virtue of the in situ formation of a p-n junction doping structure. However, this in situ doping transformation renders a meaningful efficiency analysis challenging. Herein, a method for separation and quantification of major LEC loss factors, notably the outcoupling efficiency and exciton quenching, is presented. Specifically, the position of the emissive p-n junction in common singlet-exciton emitting LECs is measured to shift markedly with increasing current, and the influence of this shift on the outcoupling efficiency is quantified. It is further verified that the LEC-characteristic high electrochemical-doping concentration renders singlet-polaron quenching (SPQ) significant already at low drive current density, but also that SPQ increases super-linearly with increasing current, because of increasing polaron density in the p-n junction region. This results in that SPQ dominates singlet-singlet quenching for relevant current densities, and significantly contributes to the efficiency roll-off. This method for deciphering the LEC efficiency roll-off can contribute to a rational realization of all-printed LEC devices that are efficient at highluminance.
- Published
- 2024
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