1. Ultrahigh Carbon Nanotube Volume Fraction Effects on Micromechanical Quasi-Static & Dynamic Properties of Poly(Urethane-Urea) Filled Nanocomposites
- Author
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Massachusetts Institute of Technology. Department of Aeronautics and Astronautics, Lidston, Dale Leigh, Wardle, Brian L, Gair, Jr., Jeffrey L., Cole, Daniel P., Lambeth, Robert H., Hsieh, Alex J., Bruck, Hugh A., Hall, Asha J., Bundy, Mark L., Massachusetts Institute of Technology. Department of Aeronautics and Astronautics, Lidston, Dale Leigh, Wardle, Brian L, Gair, Jr., Jeffrey L., Cole, Daniel P., Lambeth, Robert H., Hsieh, Alex J., Bruck, Hugh A., Hall, Asha J., and Bundy, Mark L.
- Abstract
Poly(urethane-urea) (PUU) has been infused into ultrahigh volume fraction carbon nanotube (CNT) forests using a heat-curable polymer formula. Polymer nanocomposites with carbon nanotube volume-fractions of 1%, 5%, 10%, 20%, and 30% were fabricated by overcoming densification and infusion obstacles. These polymer nanocomposites were nanoindented quasi-statically and dynamically to discern process-structure-(mechanical) property relations of polymerizing PUU in such densely-packed CNT forests. A 100× increase in indentation modulus has been observed, which is attributed not only to CNT reinforcement of the matrix, but also to molecular interactions in the matrix itself. Quasi-static elastic moduli ranging from 10 MPa–4.5 GPa have been recorded. Storage modulus for all materials is found to track well at loadings of 200 Hz, with little effect observed from increasing CNT volume fraction. Keywords: carbon nanotubes; polymer nanocomposites; polyurethane urea; self-assembly, United States. Army Research Office (Contract W911NF-13-D-0001)
- Published
- 2018