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Excessive discharge of toxic dyes is detrimental to ecological system and human health. Therefore, an effective photocatalyst must be designed and developed to degrade dyes from wastewater. Herein, a novel one-dimensional (1D) flower-like recoverable ZnFe2O4/C/MnO2/BiOI magnetic composite photocatalyst was synthesized via electrospinning technique combined with hydrothermal method. The photocatalytic activities of composite photocatalyst were evaluated by degrading methyl orange (MO) and Rhodamine B (RhB) under simulated light irradiation. The efficiency of ZnFe2O4/C/MnO2/BiOI photocatalyst in visible light for 150 min reached 91% (MO) and 120 min reached 94% (RhB). Moreover, the degradation rate of MO still remained 78% after five cycles. The design of 1D magnetic flower-like composite provided a new strategy for preparing photocatalysts possessing excellent photocatalytic efficiency and cyclic stability. [ABSTRACT FROM AUTHOR]

Thin properties and efficient absorption performance are two significant factors in the practical application of electromagnetic wave absorbers, but still face considerable conflicts. Three-dimensional (3D) Carbon Nanotube (CNTs) interpenetrating network structure has been proved to be an effective strategy to obtain high performance electromagnetic waves (EMW) absorption materials. We report a 3D sea cucumber-like nanomaterial that uses pyrolysis to self-grow CNTs on the surface of bimetallic metal-organic frameworks (MOFs). FeCo bimetallic MOF were successfully prepared and CNTs were grown after the pyrolysis of bimetallic MOF. The excellent EMW absorption performance of FeCo/CNTs composites was attributed to its multiple absorption mechanism. Electromagnetic analysis showed that the 3D structure increases the multiple reflections of the EMW and the CNT produces sufficient polarization effects. The interconnection of CNTs provides more opportunities for electron leap and electron hopping. When the matched thickness is 1.38 mm, the performance of EMW absorption properties showed a minimum reflection loss of − 59.24 dB at 17.10 GHz. Moreover, the ultrathin FeCo/CNTs composites could reach an effective absorption of 10.96 GHz (60.9% of 2–18 GHz) showing an ultra-wide absorption. This work provided options for the modification of MOFs derivatives as excellent candidates for EMW absorbers. • FeCo multi MOF were successfully prepared and self-grown CNTs after pyrolysis. • The 3D structure can extend the transmission path of electromagnetic waves and increase the attenuation effect. • The excellentEMWabsorption performance is mainly attributed to magnetoelectric synergistic effect between FeCo and CNTs. [ABSTRACT FROM AUTHOR]

New types of electromagnetic (EM) wave absorption materials with a light weight, strong absorption ability and wide absorption frequency have been widely explored. Nevertheless, it is still an intractable challenge to design the structure of the materials and rationalize multiple components. In this work, one-dimensional (1D) CoFe 2 /C@MoS 2 composites were prepared via electrospinning technology, high-temperature carbonization and hydrothermal method. SEM and TEM images reveal that the as-prepared CoFe 2 /C fibers with a 1D structure are well coated with MoS 2 . The excellent absorption performance of the composites is mainly attributed to the 1D structure and the ideal impedance matching. CoFe 2 /C@MoS 2 composites show strong absorption ability with an optimal reflection loss (RL) of -66.8 dB (13.28 GHz) at a matching thickness of 2.12 mm. Meanwhile, the composite possesses an effective absorption frequency range between 10.70 and 16.02 GHz with a bandwidth of 5.32 GHz. These results indicate that CoFe 2 /C@MoS 2 composites will become promising lightweight and highly efficient MA materials.