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Three‐dimensional graphene architecture (3DGA) as reinforcement with successive reinforcement effect has attracted intense attention in the field of polymer composites, while 3DGA also faces the disadvantages of weak interfacial adhesion with matrices. The surface decoration of 3DGA with molybdenum disulfide (3DGA@MoS2) further promoted the diffusion and penetration of epoxy molecular for 3DGA network with the aid of resin transfer molding (RTM) technic. The MoS2 transition nanolayer not only forms covalent bonding with 3DGA but mechanical interlocks with epoxy, which effectively improved the interface combination in composite. Compared with neat epoxy, the glass transition temperature (Tg) and tensile strength increased by 18°C and 58.6%, as well as the average friction coefficient and wear rate decreased by 84% and 89%, respectively, by low loading of only 2 wt% 3DGA@MoS2. Hence, the 3D graphene modified strategy by surface decoration provides a new insight for manufacturing high‐performance epoxy‐graphene composites with excellent tribological properties. Highlights: A highly ordered and interconnected 3DGA reinforcement was fabricated.MoS2 serves as interlayer, forming covalent bond and mechanical interlock.Incorporation of 3DGA@MoS2 enables rapid heat conduction and load transfer.Bi‐interpenetrating 3D structure/polymer network endows good wear resistance.Improved comprehensive properties ascribe to strong interface adhesion. [ABSTRACT FROM AUTHOR]

Addition of organic compounds containing O/N heteroatoms to aqueous electrolytes such as ZnSO4 (ZS) solutions is one of the effective strategies to inhibit Zn anode dendrites and side reactions. However, addressing the stability of Zn plating/stripping at high current densities and areal capacities by this method is still a challenge, especially in capacitors known for high power and long life. Herein, an organic heterocyclic compound of 1, 4, 7, 10‐tetraazacyclododecane (TC) containing four symmetrically distributed N atoms is employed as ZS additive, expanding the life of Zn anodes from ≈ 30 h to 1000 and 240 h at deep plating/stripping conditions of 10 and 20 mA cm−2/mAh cm−2, respectively; the cumulative capacity is as high as 5.0 Ah cm−2 with 99% Coulombic efficiency, far exceeding reported additives. TC with higher binding energies than H2O for Zn species tends to adsorb to Zn (002) in a lying manner and participate in the solvation shell of Zn2+, thus avoiding Zn dendrites and side‐reaction damage, especially at high current densities. The TC‐endowed Zn anode's stability under such extreme conditions is verified in Zn‐ion capacitors (i.e., > 94.6% capacity retention after 28 000 cycles), providing new insights into the development of high‐power Zn‐based energy storage devices. [ABSTRACT FROM AUTHOR]

Electrochemical carbon dioxide reduction reaction (CO2RR) can produce value-added hydrocarbons from renewable electricity, providing a sustainable and promising approach to meet dual-carbon targets and alleviate the energy crisis. However, it is still challenging to improve the selectivity and stability of the products, especially the C2+ products. Here we propose to modulate the electronic structure of copper oxide (CuO) through lattice strain construction by zinc (Zn) doping to improve the selectivity of the catalyst to ethylene. Combined performance and in situ characterization analyses show that the compressive strain generated within the CuO lattice and the electronic structure modulation by Zn doping enhances the adsorption of the key intermediate ⋆CO, thereby increasing the intrinsic activity of CO2RR and inhibiting the hydrogen precipitation reaction. Among the best catalysts had significantly improved ethylene selectivity of 60.5% and partial current density of 500 mA·cm−2, and the highest C2+ Faraday efficiency of 71.47%. This paper provides a simple idea to study the modulation of CO2RR properties by heteroatom doped and lattice strain. [ABSTRACT FROM AUTHOR]

Concrete vibration construction sustains high labor intensity, a poor working environment, difficulties in quality control, and other problems. Current research on concrete vibration focuses on monitoring vibration quality, evaluating vibration processes quantitatively, and assessing mechanical vibration of unreinforced mesh concrete (plain concrete). Standardizing concrete vibration under reinforcing steel mesh remains difficult. There is still a lag in the evaluation of the quality of rework and the consumption of human and material resources. To tackle these issues, a vibrating robotic arm system based on automation control technology, machine vision, and kinematic modeling is proposed. Research and simulation tests on intelligent concrete vibration under reinforcing steel mesh aim to enhance construction efficiency and quality. A five-degree-of-freedom robotic arm with a vision module identifies each rebar grid center in the image, extracts the pixel coordinates, and converts them to the mechanical coordinates by the integration of machine vision algorithms. A vibrator point screening algorithm is introduced to determine actual vibrator point locations based on specific insertion spacing, alongside a vibro-module for vertical movement. Real-time assessment of vibration quality is achieved using the YOLOv5 target detection model. Simulation tests confirm the feasibility of automated concrete vibration control under reinforcing steel mesh by a vibrating robot arm system. This research offers a new approach for unmanned vibration technology in concrete under reinforcing steel mesh, supporting future related technological advancements with practical value. [ABSTRACT FROM AUTHOR]

The triboelectric nanogenerator (TENG), as a novel energy harvesting technology, has garnered widespread attention. As a relatively young field in nanogenerator research, investigations into various aspects of the TENG are still ongoing. This review summarizes the development and dissemination of the fundamental principles of triboelectricity generation. It outlines the evolution of triboelectricity principles, ranging from the fabrication of the first TENG to the selection of triboelectric materials and the confirmation of the electron cloud overlapping model. Furthermore, recent advancements in TENG application scenarios are discussed from four perspectives, along with the research progress in performance optimization through three primary approaches, highlighting their respective strengths and limitations. Finally, the paper addresses the major challenges hindering the practical application and widespread adoption of TENGs, while also providing insights into future developments. With continued research on the TENG, it is expected that these challenges can be overcome, paving the way for its extensive utilization in various real-world scenarios. [ABSTRACT FROM AUTHOR]