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We present numerous aspects of the evolution of the LP 890-9 (SPECULOOS-2/TOI-4306) planetary system, focusing on the likelihood that planet c can support life. We find that the host star reaches the main sequence in 1 Gyr and that planet c lies close to the inner boundary of the habitable zone. We find the magma ocean stage can last up to 50 Myr, remove 8 Earth-oceans of water, and leave up to 2000 bars of oxygen in the atmosphere. However, if the planet forms with a hydrogen envelope as small as 0.1 Earth-masses, no water will be lost during the star's pre-main sequence phase from thermal escape processes. We find that the planets are unlikely to be in a 3:1 mean motion resonance and that both planets tidally circularize within 0.5 Gyr when tidal dissipation is held constant. However, if tidal dissipation is a function of mantle temperature and rheology, then we find that planet c's orbit may require more than 7 Gyr to circularize, during which time tidal heating may reach hundreds of terawatts. We thus conclude that the habitability of planet c depends most strongly on the initial volatile content and internal properties, but no data yet preclude the viability of an active biosphere on the planet., Comment: 16 pages, 9 figures, accepted to PSJ

The Hadean, once thought to be uninhabitable and tumultuous, has more recently been recontextualized as a clement time in which oceans, land, and life likely appeared on Earth. This non-exhaustive chapter follows multiple threads from planet formation to the origin of life. We place significant emphasis on the solar system context for the Earth, the timing and nature of crustal formation and the evolution of the surface and atmosphere. Several scenarios for prebiotic chemistry are also discussed including atmospheric photochemistry, wet-dry and freeze-thaw cycles, and hydrothermal vent systems. We attempt to draw connections between the large-scale, planetary processes and various origin of life pathways to illustrate possible overlaps and correlations. In detail, we conclude with and discuss the "impact of impacts" to show how asteroid and comet impacts during the Hadean may have affected many of these processes and scenarios, from generating land to altering the chemical composition and oxidation state of the early Earth's atmosphere and surface., Comment: 18 pages, 5 figures, accepted for publication in "The Archean Earth" (ed.: M. Homan, P. Mason, R. Ernst, T. Lyons, C. Heubeck, D. Papineau, E. Stueeken, R. Mazumder, A. Webb, W. Altermann), Elsevier

Atmospheric pollutants such as CFCs and NO$_{2}$ have been proposed as potential remotely detectable atmospheric technosignature gases. Here we investigate the potential for artificial greenhouse gases including CF$_{4}$, C$_{2}$F$_{6}$, C$_{3}$F$_{8}$, SF$_{6}$, and NF$_{3}$ to generate detectable atmospheric signatures. In contrast to passive incidental byproducts of industrial processes, artificial greenhouse gases would represent an intentional effort to change the climate of a planet with long-lived, low toxicity gases and would possess low false positive potential. An extraterrestrial civilization may be motivated to undertake such an effort to arrest a predicted snowball state on their home world or to terraform an otherwise uninhabitable terrestrial planet within their system. Because artificial greenhouse gases strongly absorb in the thermal mid-infrared window of temperate atmospheres, a terraformed planet will logically possess strong absorption features from these gases at mid-IR wavelengths ($\sim$8-12 $\mu$m), possibly accompanied by diagnostic features in the near-IR. As a proof of concept, we calculate the needed observation time to detect 1 [10](100) ppm of C$_{2}$F$_{6}$/C$_{3}$F$_{8}$/SF$_{6}$ on TRAPPIST-1f with JWST MIRI/LRS and NIRSpec. We find that a combination of 1[10](100) ppm each of C$_{2}$F$_{6}$, C$_{3}$F$_{8}$, and SF$_{6}$ can be detected with an S/N $\geq$ 5 in as few as 25[10](5) transits with MIRI/LRS. We further explore mid-infrared direct-imaging scenarios with the LIFE mission concept and find these gases are more detectable than standard biosignatures at these concentrations. Consequently, artificial greenhouse gases can be readily detected (or excluded) during normal planetary characterization observations with no additional overhead., Comment: 18 pages, 8 figures, 6 tables; ApJ, 969, 20

This chapter reviews proposed exoplanet biosignatures, including their biological origins, observable features, atmospheric sinks, and potentially confounding abiotic sources. Emphasis is placed on material published since past comprehensive reviews while providing a foundational understanding of each named biosignature. Topics include possible gaseous biosignatures (e.g., O$_2$, O$_3$, CH$_4$, N$_2$O, DMS, CH$_3$Cl, C$_5$H$_8$, NH$_3$, PH$_3$), surface biosignatures (e.g., vegetation red edge, other pigment features, polarization signatures), and temporal biosignatures (e.g., atmospheric seasonality). Potential frameworks for assessing remote biosignatures are described. Text and table summaries provide references to relevant original research articles., Comment: Chapter 13 accepted for publication in the Reviews in Mineralogy and Geochemistry (RiMG) Volume 90 on "Exoplanets: Compositions, Mineralogy, and Evolution" edited by Natalie Hinkel, Keith Putirka, and Siyi Xu; 44 pages, 14 figures, and 4 tables

Radiative transfer (RT) models are critical in the interpretation of exoplanetary spectra, in simulating exoplanet climates and when designing the specifications of future flagship observatories. However, most models differ in methodologies and input data, which can lead to significantly different spectra. In this paper, we present the experimental protocol of the MALBEC (Modeling Atmospheric Lines By the Exoplanet Community) project. MALBEC is an exoplanet model intercomparison project (exoMIP) that belongs to the CUISINES (Climates Using Interactive Suites of Intercomparisons Nested for Exoplanet Studies) framework which aims to provide the exoplanet community with a large and diverse set of comparison and validation of models. The proposed protocol tests include a large set of initial participating RT models, a broad range of atmospheres (from Hot Jupiters to temperate terrestrials) and several observation geometries, which would allow us to quantify and compare the differences between different RT models used by the exoplanetary community. Two types of tests are proposed: transit spectroscopy and direct imaging modeling, with results from the proposed tests to be published in dedicated follow-up papers. To encourage the community to join this comparison effort and as an example, we present simulation results for one specific transit case (GJ-1214 b), in which we find notable differences in how the various codes handle the discretization of the atmospheres (e.g., sub-layering), the treatment of molecular opacities (e.g., correlated-k, line-by-line) and the default spectroscopic repositories generally used by each model (e.g., HITRAN, HITEMP, ExoMol).

The first potential exoplanet biosignature detections are likely to be ambiguous due to the potential for false positives: abiotic planetary processes that produce observables similar to those anticipated from a global biosphere. Here we propose a class of methylated gases as corroborative `capstone' biosignatures. Capstone biosignatures are metabolic products that may be less immediately detectable, but have substantially lower false positive potential, and can thus serve as confirmation for a primary biosignature such as O$_2$. CH$_3$Cl has previously been established as a biosignature candidate, and other halomethane gases such as CH$_3$Br and CH$_3$I have similar potential. These gases absorb in the mid infrared at wavelengths that are likely to be captured while observing primary biosignatures such as O$_3$ or CH$_4$. We quantitatively explore CH$_3$Br as a new capstone biosignature through photochemical and spectral modeling of Earth-like planets orbiting FGKM stellar hosts. We also re-examine the biosignature potential of CH$_3$Cl over the same set of parameters using our updated model. We show that CH$_3$Cl and CH$_3$Br can build up to relatively high levels in M dwarf environments and analyze synthetic spectra of TRAPPIST-1e. Our results suggest that there is a co-additive spectral effect from multiple CH$_3$X gases in an atmosphere, leading to increased signal-to-noise and greater ability to detect a methylated gas feature. These capstone biosignatures are plausibly detectable in exoplanetary atmospheres, have low false positive potential, and would provide strong evidence for life in conjunction with other well established biosignature candidates., Comment: 18 pages, 11 figures, appendix. Published in ApJ

Accurately measuring and modeling the Lyman-$\alpha$ (Ly$\alpha$; $\lambda$1215.67 \AA) emission line from low mass stars is vital for our ability to build predictive high energy stellar spectra, yet interstellar medium (ISM) absorption of this line typically prevents model-measurement comparisons. Ly$\alpha$ also controls the photodissociation of important molecules, like water and methane, in exoplanet atmospheres such that any photochemical models assessing potential biosignatures or atmospheric abundances require accurate Ly$\alpha$ host star flux estimates. Recent observations of three early M and K stars (K3, M0, M1) with exceptionally high radial velocities (>100 km s$^{-1}$) reveal the intrinsic profiles of these types of stars as most of their Ly$\alpha$ flux is shifted away from the geocoronal line core and contamination from the ISM. These observations indicate that previous stellar spectra computed with the PHOENIX atmosphere code have underpredicted the core of Ly$\alpha$ in these types of stars. With these observations, we have been able to better understand the microphysics in the upper atmosphere and improve the predictive capabilities of the PHOENIX atmosphere code. Since these wavelengths drive the photolysis of key molecular species, we also present results analyzing the impact of the resulting changes to the synthetic stellar spectra on observable chemistry in terrestrial planet atmospheres., Comment: 17 pages, 12 figures

In the near future, extremely-large ground-based telescopes may conduct some of the first searches for life beyond the solar system. High-spectral resolution observations of reflected light from nearby exoplanetary atmospheres could be used to search for the biosignature oxygen. However, while Earth's abundant O$_2$is photosynthetic, early ocean loss may also produce high atmospheric O$_2$ via water vapor photolysis and subsequent hydrogen escape. To explore how to use spectra to discriminate between these two oxygen sources, we generate high-resolution line-by-line synthetic spectra of both a habitable Earth-like, and post-ocean-loss Proxima Centauri b. We examine the strength and profile of four bands of O$_2$ from 0.63 to 1.27 $\mu$m, and quantify their relative detectability. We find that 10 bar O$_2$ post-ocean-loss atmospheres have strong suppression of oxygen bands, and especially the 1.27$\mu$m band. This suppression is due to additional strong, broad O$_2$-O$_2$ collisionally-induced absorption (CIA) generated in these more massive O$_2$atmospheres, which is not present for the smaller amounts of oxygen generated by photosynthesis. Consequently, any detection of the 1.27$\mu$m band in reflected light indicates lower Earth-like O$_2$ levels, which suggests a likely photosynthetic origin. However, the 0.69 $\mu$m O$_2$ band is relatively unaffected by O$_2$-O$_2$ CIA, and the presence of an ocean-loss high-O$_2$ atmosphere could be inferred via detection of a strong 0.69 $\mu$m O$_2$ band, and a weaker or undetected 1.27 $\mu$m band. These results provide a strategy for observing and interpreting O$_2$ in exoplanet atmospheres, that could be considered by future ground-based telescopes., Comment: 14 pages, 11 figures