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6. Synthesis of o‐carboranyl‐acyl‐substituted diazo compounds from B(4)‐acylmethyl carboranes and 2‐azido‐1,3‐dimethylimidazolinium hexafluorophosphate.

8. Synthesis of o‐carboranyl‐acyl‐substituteddiazo compounds from B(4)‐acylmethyl carboranes and 2‐azido‐1,3‐dimethylimidazoliniumhexafluorophosphate

9. Direct and Regioselective Palladium(II)-Catalyzed B(4)–H Monoacyloxylation and B(4,5)–H Diacetoxylation of o-Carborane Acids with Phenyliodonium Dicarboxylates

16. Expansion of Azulenes as Nonbenzenoid Aromatic Compounds for C–H Activation: Rhodium- and Iridium-Catalyzed Oxidative Cyclization of Azulene Carboxylic Acids with Alkynes for the Synthesis of Azulenolactones and Benzoazulenes

17. Rhodium(III)‐Catalyzed Sequential C−H Activation and Cyclization from N‐Methoxyarylamides and 3‐Diazooxindoles for the Synthesis of Isochromenoindolones.

19. Rhodium(III)‐Catalyzed N−H Insertion Reaction of Phosphoryl Amides with α‐Aryl Diazoesters for the Synthesis of α‐Phosphoryl Amino Esters.

20. Rhodium(III)‐Catalyzed N−H Insertion Reaction of Phosphoryl Amides with α‐ArylDiazoesters for the Synthesis of α‐PhosphorylAmino Esters

21. Rhodium(III)-Catalyzed B(4)-Azo Coupling of o-Carboranes with Aryl Diazonium Tetrafluoroborates

22. Regiodivergent metal-catalyzed B(4)- and C(1)-selenylation of o -carboranes.

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