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The atmospheric characterisation of GJ1214 b has so far remained uncertain due to the observed flatness of the transit spectra of this planet that is typically attributed to the presence of hazes or clouds in its atmosphere. Here we combine for the first time transit and eclipse observations obtained with JWST to benefit from both type of constraints and advance on the atmospheric characterisation of GJ1214 b. Our results reveal that photochemical hazes can be produced at high enough mass fluxes in the atmosphere of GJ1214 b to explain both type of observations. These hazes have a drastic impact on the atmospheric thermal structure, which has further ramifications on the emitted radiation of the planet, as well as, its Bond albedo. Clouds of KCL, NaCL and ZnS composition also form in this atmosphere but their opacity is too small to explain the observed flatness of the transit spectrum. We find that metallicities in the range 2000-3000x solar provide atmospheric structures that are closest to the observations for haze mass fluxes in the range of (1-3)x1E-11 g cm-2 s-1. Correspondingly the Bond albedo is within 10-20%. Moreover, sulfur photochemistry produces abundant OCS that has a detectable signature in the transit spectra and should be seaked for in future observations. Sulfur should also participate to the haze formation in this atmosphere, therefore optical properties of such compounds are needed.

We examine Saturn's non-auroral (dayglow) emissions at Lyman-$\alpha$ observed by the {Cassini/UVIS} instrument from 2004 until 2016, to constrain meridional and seasonal trends in the upper atmosphere. We separate viewing geometry effects from trends driven by atmospheric properties, by applying a multi-variate regression to the observed emissions. The Lyman-$\alpha$ dayglow brightnesses depend on the incident solar flux, solar incidence angle, emission angle, and observed latitude. The emissions across latitudes and seasons show a strong dependence with solar incidence angle, typical of resonantly scattered solar flux and consistent with no significant internal source. We observe a bulge in Ly-$\alpha$ brightness that shifts with the summer season from the southern to the northern hemisphere. We estimate atomic hydrogen optical depths above the methane homopause level for dayside disk observations (2004-2016) by comparing observed Lyman-$\alpha$ emissions to a radiative transfer model. We model emissions from resonantly scattered solar flux and a smaller but significant contribution by scattered photons from the interplanetary hydrogen (IPH) background. During northern summer, inferred hydrogen optical depths steeply decrease with latitude towards the winter hemisphere from a northern hemisphere bulge, as predicted by a 2D seasonal photochemical model. The southern hemisphere mirrors this trend during its summer. However, inferred optical depths show substantially more temporal variation between 2004 and 2016 than predicted by the photochemical model.

We present a study on the coupling of haze and clouds in the atmosphere of WASP-39b. We developed a cloud microphysics model simulating the formation of Na2S and MgSiO3 condensates over photochemical hazes in gas giant atmospheres. We apply this model to WASP-39b, recently observed with the JWST to study how these heterogeneous components may affect the transit spectrum. We simulate both morning and evening terminators independently and average their transit spectra. While MgSiO3 formation has negligible impact on the spectrum, Na2S condensates produce gray opacities in the water band, in agreement with HST and JWST observations. Moreover, the formation of Na2S on the morning side depletes the atmosphere of its sodium content, decreasing the strength of the Na line. Combining morning and evening profiles results in a good fit of the Na observations. These nominal results assume a small Na2S/haze contact angle (5.7{\deg}). Using a larger value (61{\deg}) reduces the cloud density and opacity, but the effect on the Na profile and spectral line remains identical. In addition, the presence of haze in the upper atmosphere reproduces the UV-visible slope observed in the HST and VLT data and contributes to the opacity between the water bands at wavelengths below 2 microns. The averaged spectra are rather insensitive to the variation of eddy diffusion and haze mass flux tested in this study, though the UV-visible slope, probing the haze layer above the clouds, is affected. Finally, our disequilibrium chemistry model, including photochemistry, reproduces the SO2 and CO2 absorption features observed., Comment: 19 pages, 16 figures

Ultraviolet observations of Ultra-hot Jupiters (UHJs), exoplanets with temperatures over 2000\,K, provide us with an opportunity to investigate if and how atmospheric escape shapes their upper atmosphere. Near-ultraviolet transit spectroscopy offers a unique tool to study this process owing to the presence of strong metal lines and a bright photospheric continuum as the light source against which the absorbing gas is observed. WASP-189b is one of the hottest planets discovered to date, with a day-side temperature of about 3400\,K orbiting a bright A-type star. We present the first near-ultraviolet observations of WASP-189b, acquired with the Colorado Ultraviolet Transit Experiment ($CUTE$). $CUTE$ is a 6U NASA-funded ultraviolet spectroscopy mission, dedicated to monitoring short-period transiting planets. WASP-189b was one of the $CUTE$ early science targets and was observed during three consecutive transits in March 2022. We present an analysis of the $CUTE$ observations and results demonstrating near-ultraviolet (2500--3300~\AA) broadband transit depth ($1.08^{+0.08}_{-0.08}\%$) of about twice the visual transit depth indicating that the planet has an extended, hot upper atmosphere with a temperature of about 15000\,K and a moderate mass loss rate of about \SI{4e8}{\kg\per\second}. We observe absorption by Mg{\sc ii} lines ($R_p/R_s$ of $0.212^{+0.038}_{-0.061}$) beyond the Roche lobe at $>$4$\sigma$ significance in the transmission spectrum at a resolution of 10~\AA, while at lower resolution (100~\AA), we observe a quasi-continuous absorption signal consistent with a "forest" of low-ionization metal absorption dominated by Fe{\sc ii}. The results suggest an upper atmospheric temperature ($\sim15000$\,K), higher than that predicted by current state-of-the-art hydrodynamic models., Comment: Accepted for publication in The Astrophysical Journal Letters

Photochemical hazes are expected to form in hot Jupiter atmospheres and may explain the strong scattering slopes and muted spectral features observed in the transmission spectra of many hot Jupiters. Absorption and scattering by photochemical hazes have the potential to drastically alter temperature structure and atmospheric circulation of these planets but have previously been neglected in general circulation models (GCMs). We present GCM simulations of hot Jupiter HD 189733b that include photochemical hazes as a radiatively active tracer fully coupled to atmospheric dynamics. The influence of haze radiative feedback strongly depends on the assumed haze optical properties. For soot hazes, two distinct thermal inversions form, separated by a local temperature minimum around 10$^{-5}$ bar caused by upwelling on the dayside mixing air with low haze abundance upwards. The equatorial jet broadens and slows down. The horizontal distribution of hazes remains relatively similar to simulations with radiatively passive tracers. For Titan-type hazes, the equatorial jet accelerates and extends to much lower pressures, resulting in a dramatically different 3D distribution of hazes compared to radiatively passive or soot hazes. Further experimental and observational studies to constrain the optical properties of photochemical hazes will therefore be crucial for understanding the role of hazes in exoplanet atmospheres. In the dayside emission spectrum, for both types of hazes the amplitude of near-infrared features is reduced, while the emitted flux at longer wavelengths ($>$4 $\mu$m) increases. Haze radiative feedback leads to increased phase curve amplitudes in many infrared wavelength regions, mostly due to stronger dayside emission., Comment: 31 pages, 18 figures, accepted for publication in ApJ

In the near-UV and optical transmission spectrum of the hot Jupiter WASP-121b, recent observations have detected strong absorption features of Mg, Fe, Ca, and H$\alpha$, extending outside of the planet's Roche lobe. Studying these atomic signatures can directly trace the escaping atmosphere and constrain the energy balance of the upper atmosphere. To understand these features, we introduce a detailed forward model by expanding the capability of a one-dimensional model of the upper atmosphere and hydrodynamic escape to include important processes of atomic metal species. The hydrodynamic model is coupled to a Ly$\alpha$ Monte Carlo radiative transfer calculation to simulate the excited hydrogen population and associated heating/ionization effects. Using this model, we interpret the detected atomic features in the transmission spectrum of WASP-121b and explore the impact of metals and excited hydrogen on its upper atmosphere. We demonstrate the use of multiple absorption lines to impose stronger constraints on the properties of the upper atmosphere than the analysis of a single transmission feature can provide. In addition, the model shows that line broadening due to atmospheric outflow driven by the Roche lobe overflow is necessary to explain the observed line widths and highlights the importance of the high mass-loss rate caused by the Roche lobe overflow that requires careful consideration of the structure of the lower and middle atmosphere. We also show that metal species and excited state hydrogen can play an important role in the thermal and ionization balance of ultra-hot Jupiter thermospheres., Comment: 35 pages, 31 figures, Accepted for publication in ApJ

We present a parameterization for the eddy diffusion profile of gas giant exoplanets based on physical phenomena and we explore how the parameterized eddy profile impacts the chemical composition, the thermal structure, the haze microphysics, and the transit spectra of 8 hot-Jupiters. Our eddy parameterization depends on the planetary intrinsic temperature (T$_{int}$ ), we thus evaluate how the increase of this parameter to values higher than those typically used ($\sim$100K) impacts the atmospheric structure and composition. Our investigation demonstrates that despite the strong impact of T$_{int}$ on the chemical composition of the deep atmosphere, the upper atmosphere is not affected for T$_{eq}$ $>$ 1300 K owing to high altitude quench levels at these conditions. Below this threshold, however, the larger atmospheric temperatures produced by increasing T$_{int}$ affect the quenched chemical composition. Our parameterization depends on two parameters, the eddy magnitude at the radiative-convective boundary (K$_0$) and the corresponding magnitude at the homopause (K$_{top}$). We demonstrate that, when using common K$_0$ and K$_{top}$ values among most of the different planet cases studied, we derive transit spectra consistent with Hubble Space Telescope observations. Moreover, our simulations show that increasing the eddy profile enhances the photochemical production of haze particles and reduces their average radius, thus providing a steeper UV-Visible slope. Finally, we demonstrate for WASP-39b that the James Webb Space Telescope observations provide improved constraints for the hazes and clouds and we show that both components seem necessary to interpret the combined transit spectrum from HST and JWST observations., Comment: 19 pages, 12 figures

The magnetosphere of an exoplanet has yet to be unambiguously detected. Investigations of star-planet interaction and neutral atomic hydrogen absorption during transit to detect magnetic fields in hot Jupiters have been inconclusive, and interpretations of the transit absorption non-unique. In contrast, ionized species escaping a magnetized exoplanet, particularly from the polar caps, should populate the magnetosphere, allowing detection of different regions from the plasmasphere to the extended magnetotail, and characterization of the magnetic field producing them. Here, we report ultraviolet observations of HAT-P-11b, a low-mass (0.08 MJ) exoplanet showing strong, phase-extended transit absorption of neutral hydrogen (maximum and tail transit depths of 32 \pm 4%, 27 \pm 4%) and singly ionized carbon (15 \pm 4%, 12.5 \pm 4%). We show that the atmosphere should have less than six times the solar metallicity (at 200 bars), and the exoplanet must also have an extended magnetotail (1.8-3.1 AU). The HAT-P-11b equatorial magnetic field strength should be about 1-5 Gauss. Our panchromatic approach using ionized species to simultaneously derive metallicity and magnetic field strength can now constrain interior and dynamo models of exoplanets, with implications for formation and evolution scenarios., Comment: 68 pages, 12 figures. Published in Nature Astronomy on December 16 2021. Main draft and Supplementary information are included in a single file. Full-text access to a view-only version of the paper via : https://rdcu.be/cDlYv

We present a study of photochemical hazes of exoplanet atmospheres based on a self-consistent model including haze microphysics, disequilibrium chemistry, and radiative feedbacks. We derive the haze properties required to match HST observations of ten hot-Jupiters. HAT-P-12b, HD-189733b, HD-209458b and WASP-6b require haze mass fluxes between 5x10$^{-15}$ and 9x10$^{-12} g.cm^{-2}.s^{-1}$ to match the observations. WASP-12b and WASP-19b with equilibrium temperatures above 2000 K are incompatible with the presence of haze and are better fitted by heavy metals. HAT-P-1b and WASP-31b do not show clear evidence for the presence of hazes with upper mass fluxes of 10$^{-15}$ and 10$^{-16}g.cm^{-2}.s^{-1}$, respectively, while WASP-17b and WASP-39b present an upper mass flux limit of 10$^{-16} g.cm^{-2}.s^{-1}$. We discuss the implications of the self-consistent model and we derive upper limits for the haze abundances based on photochemistry results. Our results suggest HCN as the main haze precursor up to 1300 K effective temperatures and CO above. Our derived haze mass fluxes based on the fit to the observations are consistent with the photochemistry with formation yields up to $\sim$6.4\%. Disequilibrium chemistry has negligible impact on the spectra considering the low resolution observations used but impacts the chemical composition and temperature profiles. We find that hazes produce hotter upper atmosphere temperatures with a detectable impact on the spectra. Clouds may have implications for interpreting the transit spectra of HD-209458b, WASP-31b and WASP-39b. Nevertheless, the presence of silicate and iron clouds is expected in all studied atmospheres except WASP-12b and WASP-19b., Comment: 29 pages, 25 figures

Aerosols have been found to be nearly ubiquitous in substellar atmospheres. The precise temperature at which these aerosols begin to form in exoplanets has yet to be observationally constrained. Theoretical models and observations of muted spectral features suggest that silicate clouds play an important role in exoplanets between at least 950 and 2,100 K. However, some giant planets are thought to be hot enough to avoid condensation altogether. Here, we present the near-UV transmission spectrum of an ultra-hot Jupiter, WASP-178b ($\sim$2,450~K), that exhibits significant NUV absorption. This short-wavelength absorption is among the largest spectral features ever observed in an exoplanet in terms of atmospheric scale heights. Bayesian retrievals indicate the presence of gaseous refractory species containing silicon and magnesium, which are the precursors to condensate clouds at lower temperatures. SiO in particular has not been detected in exoplanets before, but the presence of SiO in WASP-178b is consistent with theoretical expectation as the dominant Si-bearing species at high temperatures. These observations allow us to re-interpret previous observations of HAT-P-41b and WASP-121b that did not consider SiO to suggest that silicate cloud formation begins on exoplanets with equilibrium temperatures between 1,950 and 2,450~K., Comment: 24 pages, 11 figures, 3 tables, published in Nature

We explore atmospheric escape from close-in exoplanets with the highest mass loss rates. First, we locate the transition from stellar X-ray and UV-driven escape to rapid Roche lobe overflow, which occurs once the 10-100 nbar pressure level in the atmosphere reaches the Roche lobe. Planets enter this regime when the ratio of the substellar radius to the polar radius along the visible surface pressure level, that aligns with a surface of constant Roche potential, is X/Z~$\gtrsim$~1.2 for Jovian planets (Mp~$\gtrsim$~100 M$_{\Earth}$) and X/Z~$\gtrsim$~1.02 for sub-Jovian planets ($M_p \approx$~10--100 M$_{\Earth}$). Around a sun-like star, this regime applies to orbital periods of less than two days for planets with radii of about 3--14 R$_{\Earth}$. Our results agree with the properties of known transiting planets and can explain parts of the sub-Jovian desert in the population of known exoplanets. Second, we present detailed numerical simulations of atmospheric escape from a planet like Uranus or Neptune orbiting close to a sun-like star that support the results above and point to interesting qualitative differences between hot Jupiters and sub-Jovian planets. We find that hot Neptunes with solar metallicity hydrogen and helium envelopes have relatively more extended upper atmospheres than typical hot Jupiters, with a lower ionization fraction and higher abundances of escaping molecules. This is consistent with existing ultraviolet transit observations of warm Neptunes and it might provide a way to use future observations and models to distinguish solar metallicity atmospheres from higher metallicity atmospheres., Comment: Accepted to Astrophysical Journal

In response to ESA Voyage 2050 announcement of opportunity, we propose an ambitious L-class mission to explore one of the most exciting bodies in the Solar System, Saturn largest moon Titan. Titan, a "world with two oceans", is an organic-rich body with interior-surface-atmosphere interactions that are comparable in complexity to the Earth. Titan is also one of the few places in the Solar System with habitability potential. Titan remarkable nature was only partly revealed by the Cassini-Huygens mission and still holds mysteries requiring a complete exploration using a variety of vehicles and instruments. The proposed mission concept POSEIDON (Titan POlar Scout/orbitEr and In situ lake lander DrONe explorer) would perform joint orbital and in situ investigations of Titan. It is designed to build on and exceed the scope and scientific/technological accomplishments of Cassini-Huygens, exploring Titan in ways that were not previously possible, in particular through full close-up and in situ coverage over long periods of time. In the proposed mission architecture, POSEIDON consists of two major elements: a spacecraft with a large set of instruments that would orbit Titan, preferably in a low-eccentricity polar orbit, and a suite of in situ investigation components, i.e. a lake lander, a "heavy" drone (possibly amphibious) and/or a fleet of mini-drones, dedicated to the exploration of the polar regions. The ideal arrival time at Titan would be slightly before the next northern Spring equinox (2039), as equinoxes are the most active periods to monitor still largely unknown atmospheric and surface seasonal changes. The exploration of Titan northern latitudes with an orbiter and in situ element(s) would be highly complementary with the upcoming NASA New Frontiers Dragonfly mission that will provide in situ exploration of Titan equatorial regions in the mid-2030s., Comment: arXiv admin note: substantial text overlap with arXiv:1908.01374

We construct Saturn equatorial neutral temperature and density profiles of H, H$_2$, He, and CH$_4$, between 10$^{-12}$ and 1 bar using measurements from Cassini's Ion Neutral Mass Spectrometer (INMS) taken during the spacecraft's final plunge into Saturn's atmosphere on 15 September 2017, combined with previous deeper atmospheric measurements from the Cassini Composite InfraRed Spectrometer (CIRS) and from the UltraViolet Imaging Spectrograph (UVIS). These neutral profiles are fed into an energy deposition model employing soft X-ray and Extreme UltraViolet (EUV) solar fluxes at a range of spectral resolutions ($\Delta\lambda=4\times10^{-3}$ nm to 1 nm) assembled from TIMED/SEE, from SOHO/SUMER, and from the Whole Heliosphere Interval (WHI) quiet Sun campaign. Our energy deposition model calculates ion production rate profiles through photo-ionisation and electron-impact ionisation processes, as well as rates of photo-dissociation of CH$_4$. The ion reaction rate profiles we determine are important to obtain accurate ion density profiles, meanwhile methane photo-dissociation is key to initiate complex organic chemical processes. We assess the importance of spectral resolution in the energy deposition model by using a high-resolution H$_2$ photo-absorption cross section, which has the effect of producing additional ionisation peaks near 800 km altitude. We find that these peaks are still formed when using low-resolution ($\Delta\lambda=1$ nm) or mid-resolution ($\Delta\lambda=0.1$ nm) solar spectra, as long as high-resolution cross sections are included in the model., Comment: 21 pages, 13 figures, 5 tables, accepted for publication in Icarus

Following the detection of CO and HCN in Pluto's atmosphere, we report on new ALMA observations of Pluto with two main goals: (i) obtaining spatially-resolved measurements (~0.06'' on the ~0.15'' disk subtended by Pluto and its atmosphere) of CO(3-2) and HCN(4-3) (ii) targetting new chemical compounds, primarily hydrogen isocyanide (HNC). The CO line shows an absorption core at beam positions within Pluto's disk, a direct signature of Pluto's cold mesosphere. Analysis provides tentative evidence for a non-uniform temperature field in the lower atmosphere (near 30 km), with summer pole latitudes being 7$\pm$3.5 K warmer than low latitudes. This unexpected result may point to shorter radiative timescales in the atmosphere than previously thought. The HCN emission is considerably more extended than CO, peaking at radial distances beyond Pluto limb, and providing a new method to determine Pluto's HCN vertical profile in 2017. The mean (column-averaged) location of HCN is at 690+/-75 km altitude, with an upper atmosphere (> 800 km) mixing ratio of ~ 1.8 x 10$^{-4}$. Little or no HCN (<5 x 10$^{-9}$ at 65 km) is present in the lower atmosphere, implying undersaturation of HCN there. The HCN emission appears enhanced above the low-latitude limb, but interpretation, in terms of an enhanced HCN abundance or a warmer upper atmosphere there, is uncertain. The first detection of HNC is reported, with a (7.0$\pm$2.1) x 10$^{12}$ cm$^{-2}$ column density, referred to Pluto surface, and a HNC / HCN ratio of 0.095+/-0.026, very similar to their values in Titan's atmosphere. We also obtain upper limits on CH3CN (< 2.6 x 10$^{13}$ cm$^{-2}$) and CH$_3$CCH (< 8.5 x 10$^{14}$ cm$^{-2}$); the latter value is inconsistent with the reported detection of CH$_3$CCH from New Horizons. These upper limits also point to incomplete resublimation of ice-coated aerosols in the lower atmosphere., Comment: Icarus, accepted. 37 pages, including 15 figures. Abstract slightly rewritten to fit with character limit

We present analysis of XMM-Newton Optical Monitor observations in the near-ultraviolet of HD 189733, covering twenty primary transits of its hot Jupiter planet. The transit is clearly detected with both the UVW2 and UVM2 filters, and our fits to the data reveal transit depths in agreement with that observed optically. The measured depths correspond to radii of $1.059^{+0.046}_{-0.050}$ and $0.94^{+0.15}_{-0.17}$ times the optically-measured radius (1.187 R$_{\rm J}$ at 4950 \r{A}) in the UVW2 and UVM2 bandpasses, respectively. We also find no statistically significant variation in the transit depth across the 8 year baseline of the observations. We rule out extended broadband absorption towards or beyond the Roche lobe at the wavelengths investigated, although observations with higher spectral resolution are required to determine if absorption out to those distances from the planet is present in individual near-UV lines., Comment: 7 pages, 7 figures, 3 tables; accepted for publication in MNRAS

(Abridged) Short-period gas giant exoplanets are susceptible to intense atmospheric escape due to their large scale heights and strong high-energy irradiation. This process is thought to occur ubiquitously, but to date we have only detected direct evidence of atmospheric escape in hot Jupiters and warm Neptunes. The paucity of cases for intermediate, Saturn-sized exoplanets at varying levels of irradiation precludes a detailed understanding of the underlying physics in atmospheric escape of hot gas giants. Our objectives here are to assess the high-energy environment of the warm ($T_\mathrm{eq} = 970$ K) Saturn WASP-29 b and search for signatures of atmospheric escape. We used far-ultraviolet (FUV) observations from the Hubble Space Telescope to analyze the flux time series of H I, C II, Si III, Si IV, and N V during the transit of WASP-29 b. At 3$\sigma$ confidence, we rule out any in-transit absorption of H Ilarger than 92% in the Lyman-$\alpha$ blue wing and 19% in the red wing. We found an in-transit flux decrease of $39\%^{+12\%}_{-11\%}$ in the ground-state C II emission line at 133.45 nm. But due to this signal being significantly present in only one visit, it is difficult to attribute a planetary or stellar origin for the ground-state C II signal. We place 3$\sigma$ absorption upper limits of 40%, 49% and 24% for Si III, Si IV, and for excited-state C II at 133.57 nm, respectively. Low activity levels and the faint X-ray luminosity suggest that WASP-29 is an old, inactive star. An energy-limited approximation combined with the reconstructed EUV spectrum of the host suggests that the planet is losing its atmosphere at a rate of $4 \times 10^9$ g s$^{-1}$. The non-detection at Lyman-$\alpha$ could be partly explained by a low fraction of escaping neutral hydrogen, or by the state of fast radiative blow-out we infer from the reconstructed stellar Lyman-$\alpha$ line., Comment: 10 pages, 8 figures, accepted for publication in Astronomy & Astrophysics. v2 with a few text changes for consistency

Neptune-size exoplanets seem particularly sensitive to atmospheric evaporation, making it essential to characterize the stellar high-energy radiation that drives this mechanism. This is particularly important with M dwarfs, which emit a large and variable fraction of their luminosity in the UV and can display strong flaring behavior. The warm Neptune GJ3470b, hosted by an M2 dwarf, was found to harbor a giant hydrogen exosphere thanks to 3 transits observed with the HST/STIS. Here we report on 3 additional transit observations from the PanCET program, obtained with the HST/COS. These data confirm the absorption signature from GJ3470b's exosphere in the stellar Ly-alpha line and demonstrate its stability over time. No planetary signatures are detected in other lines, setting a 3sigma limit on GJ3470b's FUV radius at 1.3x its Roche lobe radius. We detect 3 flares from GJ3470. They show different spectral energy distributions but peak consistently in the Si III line, which traces intermediate-temperature layers in the transition region. These layers appear to play a particular role in GJ3470's activity as emission lines that form at lower or higher temperatures than Si III evolved differently over the long term. Based on the measured emission lines, we derive synthetic XUV spectra for the 6 observed quiescent phases, covering one year, as well as for the 3 flaring episodes. Our results suggest that most of GJ3470's quiescent high-energy emission comes from the EUV domain, with flares amplifying the FUV emission more strongly. The hydrogen photoionization lifetimes and mass loss derived for GJ3470b show little variation over the epochs, in agreement with the stability of the exosphere. Simulations informed by our XUV spectra are required to understand the atmospheric structure and evolution of GJ3470b and the role played by evaporation in the formation of the hot-Neptune desert., Comment: 21 pages, 18 figures, accepted in A&A

We investigate the impact of photochemical hazes and disequilibrium gases on the thermal structure of hot-Jupiters, using a detailed 1-D radiative-convective model. We find that the inclusion of photochemical hazes results in major heating of the upper and cooling of the lower atmosphere. Sulphur containing species, such as SH, S$_2$ and S$_3$ provide significant opacity in the middle atmosphere and lead to local heating near 1 mbar, while OH, CH, NH, and CN radicals produced by the photochemistry affect the thermal structure near 1 $\mu$bar. Furthermore we show that the modifications on the thermal structure from photochemical gases and hazes can have important ramifications for the interpretation of transit observations. Specifically, our study for the hazy HD 189733 b shows that the hotter upper atmosphere resulting from the inclusion of photochemical haze opacity imposes an expansion of the atmosphere, thus a steeper transit signature in the UV-Visible part of the spectrum. In addition, the temperature changes in the photosphere also affect the secondary eclipse spectrum. For HD 209458 b we find that a small haze opacity could be present in this atmosphere, at pressures below 1 mbar, which could be a result of both photochemical hazes and condensates. Our results motivate the inclusion of radiative feedback from photochemical hazes in general circulation models for a proper evaluation of atmospheric dynamics.

Photochemical hazes have been suggested as candidate for the high-altitude aerosols observed in the transmission spectra of many hot Jupiters. We present 3D simulations of the hot Jupiter HD 189733b to study how photochemical hazes are transported by atmospheric circulation. The model includes spherical, constant-size hazes particles that gravitationally settle and are transported by the winds as passive tracers, with particle radii ranging from 1 nm to 300 $\mu$m. We identify two general types of haze distribution based on particle size: In the small-particle regime (<30 nm), gravitational settling is unimportant, and hazes accumulate in two large mid-latitude vortices centered on the night side that extend across the morning terminator. Therefore, small hazes are more concentrated at the morning terminator than at the evening terminator. In the large-particle regime (>30 nm), hazes settle out quickly on the nightside, resulting in more hazes at the evening terminator. For small particles, terminator differences in haze mass mixing ratio and temperature considered individually can result in significant differences in the transit spectra of the terminators. When combining both effects for HD189733b, however, they largely cancel out each other, resulting in very small terminator differences in the spectra. Transit spectra based on the GCM-derived haze distribution fail to reproduce the steep spectral slope at short wavelengths in the current transit observations of HD 189733b. Differing optical properties of hazes, hotter temperatures at low pressures because of heating by hazes, enhanced sub-grid-scale mixing, or star spots might explain the mismatch between the model and observations., Comment: This version incorporates the corrected versions of equations (7) and (8), as described in the correction published in July 2024, available at \url{https://academic.oup.com/mnras/article/531/3/3444/7691150}

We present a comprehensive analysis of the 0.3--5\,$\mu$m transit spectrum for the inflated hot Jupiter HAT-P-41b. The planet was observed in transit with Hubble STIS and WFC3 as part of the Hubble Panchromatic Comparative Exoplanet Treasury (PanCET) program, and we combine those data with warm \textit{Spitzer} transit observations. We extract transit depths from each of the data sets, presenting the STIS transit spectrum (0.29--0.93\,$\mu$m) for the first time. We retrieve the transit spectrum both with a free-chemistry retrieval suite (AURA) and a complementary chemical equilibrium retrieval suite (PLATON) to constrain the atmospheric properties at the day-night terminator. Both methods provide an excellent fit to the observed spectrum. Both AURA and PLATON retrieve a metal-rich atmosphere for almost all model assumptions (most likely O/H ratio of $\log_{10}{Z/Z_{\odot}} = 1.46^{+0.53}_{-0.68}$ and $\log_{10}{Z/Z_{\odot}} = 2.33^{+0.23}_{-0.25}$, respectively); this is driven by a 4.9-$\sigma$ detection of H$_2$O as well as evidence of gas absorption in the optical ($>$2.7-$\sigma$ detection) due to Na, AlO and/or VO/TiO, though no individual species is strongly detected. Both retrievals determine the transit spectrum to be consistent with a clear atmosphere, with no evidence of haze or high-altitude clouds. Interior modeling constraints on the maximum atmospheric metallicity ($\log_{10}{Z/Z_{\odot}} < 1.7$) favor the AURA results. The inferred elemental oxygen abundance suggests that HAT-P-41b has one of the most metal-rich atmospheres of any hot Jupiters known to date. Overall, the inferred high metallicity and high inflation make HAT-P-41b an interesting test case for planet formation theories., Comment: Resubmitted to AAS Journals after revisions

Titan's ionosphere contains a plethora of hydrocarbons and nitrile cations and anions as measured by the Ion Neutral Mass Spectrometer and Cassini Plasma Spectrometer (CAPS) onboard the Cassini spacecraft. Data from the CAPS Ion Beam Spectrometer (IBS) sensor have been examined for five close encounters of Titan during 2009. The high relative velocity of Cassini with respect to the cold ions in Titan's ionosphere allows CAPS IBS to function as a mass spectrometer. Positive ion masses between 170 and 310 u/q are examined with ion mass groups identified between 170 and 275 u/q containing between 14 and 21 heavy (carbon/nitrogen/oxygen) atoms. These groups are the heaviest positive ion groups reported so far from the available in situ ion data at Titan. The ion group peaks are found to be consistent with masses associated with Polycyclic Aromatic Compounds (PAC), including Polycyclic Aromatic Hydrocarbon (PAH) and nitrogen-bearing polycyclic aromatic molecular ions. The ion group peak identifications are compared with previously proposed neutral PAHs and are found to be at similar masses, supporting a PAH interpretation. The spacing between the ion group peaks is also investigated, finding a spacing of 12 or 13 u/q indicating the addition of C or CH. Lastly, the occurrence of several ion groups is seen to vary across the five flybys studied, possibly relating to the varying solar radiation conditions observed across the flybys. These findings further the understanding between the low mass ions and the high mass negative ions, as well as with aerosol formation in Titan's atmosphere.

We present a 0.3-5 micron transmission spectrum of the hot Jupiter HAT-P-32Ab observed with the Space Telescope Imaging Spectrograph (STIS) and Wide Field Camera 3 (WFC3) instruments mounted on the Hubble Space Telescope, combined with Spitzer Infrared Array Camera (IRAC) photometry. The spectrum is composed of 51 spectrophotometric bins with widths ranging between 150 and 400 \AA, measured to a median precision of 215 ppm. Comparisons of the observed transmission spectrum to a grid of 1D radiative-convective equilibrium models indicate the presence of clouds/hazes, consistent with previous transit observations and secondary eclipse measurements. To provide more robust constraints on the planet's atmospheric properties, we perform the first full optical to infrared retrieval analysis for this planet. The retrieved spectrum is consistent with a limb temperature of 1248$\pm$92 K, a thick cloud deck, enhanced Rayleigh scattering, and $\sim$10x solar H2O abundance. We find log($Z/Z_{\odot}$) = 2.41$_{-0.07}^{+0.06}$, in agreement with the mass-metallicity relation derived for the Solar System., Comment: 30 pages, 13 figures, accepted for publication in AJ

We present new observations of the transmission spectrum of the hot Jupiter WASP-6b both from the ground with the Very Large Telescope (VLT) FOcal Reducer and Spectrograph (FORS2) from 0.45-0.83 $\mu$m, and space with the Transiting Exoplanet Survey Satellite (TESS) from 0.6-1.0 $\mu$m and the Hubble Space Telescope (HST) Wide Field Camera 3 from 1.12-1.65 $\mu$m. Archival data from the HST Space Telescope Imaging Spectrograph (STIS) and Spitzer is also reanalysed on a common Gaussian process framework, of which the STIS data show a good overall agreement with the overlapping FORS2 data. We also explore the effects of stellar heterogeneity on our observations and its resulting implications towards determining the atmospheric characteristics of WASP-6b. Independent of our assumptions for the level of stellar heterogeneity we detect Na I, K I and H$_2$O absorption features and constrain the elemental oxygen abundance to a value of [O/H] $\simeq -0.9\pm0.3$ relative to solar. In contrast, we find that the stellar heterogeneity correction can have significant effects on the retrieved distributions of the [Na/H] and [K/H] abundances, primarily through its degeneracy with the sloping optical opacity of scattering haze species within the atmosphere. Our results also show that despite this presence of haze, WASP-6b remains a favourable object for future atmospheric characterisation with upcoming missions such as the James Webb Space Telescope., Comment: Accepted to MNRAS

We perform atmospheric retrievals on the full optical to infrared ($0.3-5 \, \mu \mathrm{m}$) transmission spectrum of the inflated hot Jupiter WASP-52b by combining HST/STIS, WFC3 IR, and Spitzer/IRAC observations. As WASP-52 is an active star which shows both out-of-transit photometric variability and starspot crossings during transits, we account for the contribution of non-occulted active regions in the retrieval. We recover a $0.1-10\times$ solar atmospheric composition, in agreement with core accretion predictions for giant planets, and a weak contribution of aerosols. We also obtain a $<3000$ K temperature for the starspots, a measure which is likely affected by the models used to fit instrumental effects in the transits, and a 5% starspot fractional coverage, compatible with expectations for the host star's spectral type. Such constraints on the planetary atmosphere and on the activity of its host star will inform future JWST GTO observations of this target., Comment: 16 pages, 11 figures, 1 table. Updated figure 5

As part of the PanCET program, we have conducted a spectroscopic study of WASP-79b, an inflated hot Jupiter orbiting an F-type star in Eridanus with a period of 3.66 days. Building on the original WASP and TRAPPIST photometry of Smalley et al (2012), we examine HST/WFC3 (1.125 - 1.650 $\mu$m), Magellan/LDSS-3C (0.6 - 1 $\mu$m) data, and Spitzer data (3.6 and 4.5 $\mu$m). Using data from all three instruments, we constrain the water abundance to be --2.20 $\leq$ log(H$_2$O) $\leq$ --1.55. We present these results along with the results of an atmospheric retrieval analysis, which favor inclusion of FeH and H$^-$ in the atmospheric model. We also provide an updated ephemeris based on the Smalley, HST/WFC3, LDSS-3C, Spitzer, and TESS transit times. With the detectable water feature and its occupation of the clear/cloudy transition region of the temperature/gravity phase space, WASP-79b is a target of interest for the approved JWST Director's Discretionary Early Release Science (DD ERS) program, with ERS observations planned to be the first to execute in Cycle 1. Transiting exoplanets have been approved for 78.1 hours of data collection, and with the delay in the JWST launch, WASP-79b is now a target for the Panchromatic Transmission program. This program will observe WASP-79b for 42 hours in 4 different instrument modes, providing substantially more data by which to investigate this hot Jupiter.

We present HST near-ultraviolet (NUV) transits of the hot Jupiter WASP-121b, acquired as part of the PanCET program. Time series spectra during two transit events were used to measure the transmission spectra between 2280 and 3070 Angstroms at a resolution of 30,000. Using HST data from 61 STIS visits, we show that data from HST's Pointing Control System can be used to decorrelate the instrument systematic errors (Jitter Decorrelation), which we used to fit the WASP-121b light curves. The NUV spectrum show very strong absorption features, with the NUV white light curve found to be larger than the average optical and near-infrared value at 6-$\sigma$ confidence. We identify and spectrally resolve absorption from the Mg ii doublet in the planetary exosphere at a 5.9-$\sigma$ confidence level. The Mg ii doublet is observed to reach altitudes of $R_{pl}/R_{star}=0.284\pm0.037$ for the 2796 Angstrom line and $0.242\pm0.0431$ in the 2804 Angstrom line, which exceeds the Roche lobe size as viewed in transit geometry ($R_{\rm eqRL}/R_{star}$ = 0.158). We also detect and resolve strong features of the Fe ii UV1 and UV2 multiplets, and observe the lines reaching altitudes of $R_{pl}/R_{star}\approx0.3$. At these high altitudes, the atmospheric Mg ii and Fe ii gas is not gravitationally bound to the planet, and these ionized species may be hydrodynamically escaping or could be magnetically confined. Refractory Mg and Fe atoms at high altitudes also indicates that these species are not trapped into condensate clouds at depth, which places constraints on the deep interior temperature., Comment: 22 pages, 16 figures, 2 Tables. Accepted for publication in AJ. Spectra available at https://pages.jh.edu/~dsing3/

(Abridged) The quiet M2.5 star GJ 436 hosts a warm Neptune that displays an extended atmosphere that dwarfs its own host star. Predictions of atmospheric escape in such planets state that H atoms escape from the upper atmosphere in a collisional regime and that the flow can drag heavier atoms to the upper atmosphere. It is unclear, however, what astrophysical mechanisms drive the process. Our objective is to leverage the extensive coverage of HST/COS observations of the far-ultraviolet (FUV) spectrum of GJ 436 to search for signals of metallic ions in the upper atmosphere of GJ 436 b. We analyzed flux time-series of species present in the FUV spectrum of GJ 436, as well as the Lyman-$\alpha$ line. GJ 436 displays FUV flaring events with a rate of $\sim$10 d$^{-1}$. There is evidence for a possibly long-lived active region or longitude that modulates the FUV metallic lines of the star with amplitudes up to 20%. Despite the strong geocoronal contamination in the COS spectra, we detected in-transit excess absorption signals of $\sim$50% and $\sim$30% in the blue and red wings, respectively, of the Lyman-$\alpha$ line. We rule out a wide range of excess absorption levels in the metallic lines of the star during the transit. The large atmospheric loss of GJ 436 b observed in Lyman-$\alpha$ transmission spectra is stable over the timescale of a few years, and the red wing signal supports the presence of a variable hydrogen absorption source besides the stable exosphere. The previously claimed in-transit absorption in the Si III line is likely an artifact resulting from the stellar magnetic cycle. The non-detection of metallic ions in absorption could indicate that the escape is not hydrodynamic or that the atmospheric mixing is not efficient in dragging metals high enough for sublimation to produce a detectable escape rate of ions to the exosphere., Comment: 15 pages, 14 figures, accepted for publication on A&A

We study the properties of photochemical hazes in super-Earths/mini-Neptunes atmospheres with particular focus on GJ1214b. We evaluate photochemical haze properties at different metallicities between solar and 10000$\times$solar. Within the four orders of magnitude change in metallicity, we find that the haze precursor mass fluxes change only by a factor of $\sim$3. This small diversity occurs with a non-monotonic manner among the different metallicity cases, reflecting the interaction of the main atmospheric gases with the radiation field. Comparison with relative haze yields at different metallicities from laboratory experiments reveals a qualitative similarity with our theoretical calculations and highlights the contributions of different gas precursors. Our haze simulations demonstrate that higher metallicity results into smaller average particle sizes. Metallicities at and above 100$\times$solar with haze formation yields of $\sim$10$\%$ provide enough haze opacity to satisfy transit observation at visible wavelengths and obscure sufficiently the H$_2$O molecular absorption features between 1.1 $\mu$m and 1.7 $\mu$m. However, only the highest metallicity case considered (10000$\times$solar) brings the simulated spectra into closer agreement with transit depths at 3.6 $\mu$m and 4.5 $\mu$m indicating a high contribution of CO/CO$_2$ in GJ1214b's atmosphere. We also evaluate the impact of aggregate growth in our simulations, in contrast to spherical growth, and find that the two growth modes provide similar transit signatures (for D$_f$=2), but with different particle size distributions. Finally, we conclude that the simulated haze particles should have major implications for the atmospheric thermal structure and for the properties of condensation clouds.

GJ 3470b is a warm Neptune transiting an M-dwarf star at the edge of the evaporation desert. It offers the possibility of investigating how low-mass, close-in exoplanets evolve under the irradiation from their host stars. We observed three transits of GJ 3470b in the Lyman-alpha line with the Hubble Space Telescope (HST) as part of the Panchromatic Comparative Exoplanet Treasury (PanCET) program. Absorption signatures are detected with similar properties in all three independent epochs, with absorption depths of 35+-7% in the blue wing of the line, and 23+-5% in the red wing. The repeatability of these signatures, their phasing with the planet transit, and the radial velocity of the absorbing gas allow us to conclude that there is an extended upper atmosphere of neutral hydrogen around GJ 3470 b. We determine from our observations the stellar radiation pressure and XUV irradiation from GJ 3470 and use them to perform numerical simulations of the upper atmosphere of GJ 3470b with the EVaporating Exoplanets (EVE) code. The unusual redshifted signature can be explained by the damping wings of dense layers of neutral hydrogen that extend beyond the Roche lobe and are elongated in the direction of the planet motion. This structure could correspond to a shocked layer of planetary material formed by the collision of the expanding thermosphere with the wind of the star. The blueshifted signature is well explained by neutral hydrogen atoms escaping at rates of about 1e10 g s-1 that are blown away from the star by its strong radiation pressure and are quickly photoionized, resulting in a smaller exosphere than that of the warm Neptune GJ 436b. The stronger escape from GJ 3470b, however, may have led to the loss of about 4-35% of its current mass over its 2 Gyr lifetime., Comment: 14 pages, 12 figures, published in A&A

We present an atmospheric transmission spectrum for the ultra-hot Jupiter WASP-121b, measured using the Space Telescope Imaging Spectrograph (STIS) onboard the Hubble Space Telescope (HST). Across the 0.47-1 micron wavelength range, the data imply an atmospheric opacity comparable to - and in some spectroscopic channels exceeding - that previously measured at near-infrared wavelengths (1.15-1.65 micron). Wavelength-dependent variations in the opacity rule out a gray cloud deck at a confidence level of 3.8-sigma and may instead be explained by VO spectral bands. We find a cloud-free model assuming chemical equilibrium for a temperature of 1500K and metal enrichment of 10-30x solar matches these data well. Using a free-chemistry retrieval analysis, we estimate a VO abundance of -6.6(-0.3,+0.2) dex. We find no evidence for TiO and place a 3-sigma upper limit of -7.9 dex on its abundance, suggesting TiO may have condensed from the gas phase at the day-night limb. The opacity rises steeply at the shortest wavelengths, increasing by approximately five pressure scale heights from 0.47 to 0.3 micron in wavelength. If this feature is caused by Rayleigh scattering due to uniformly-distributed aerosols, it would imply an unphysically high temperature of 6810+/-1530K. One alternative explanation for the short-wavelength rise is absorption due to SH (mercapto radical), which has been predicted as an important product of non-equilibrium chemistry in hot Jupiter atmospheres. Irrespective of the identity of the NUV absorber, it likely captures a significant amount of incident stellar radiation at low pressures, thus playing a significant role in the overall energy budget, thermal structure, and circulation of the atmosphere., Comment: Accepted for publication in The Astronomical Journal

The upper atmospheres of the planets and their satellites are more directly exposed to sunlight and solar wind particles than the surface or the deeper atmospheric layers. At the altitudes where the associated energy is deposited, the atmospheres may become ionized and are referred to as ionospheres. The details of the photon and particle interactions with the upper atmosphere depend strongly on whether the object has anintrinsic magnetic field that may channel the precipitating particles into the atmosphere or drive the atmospheric gas out to space. Important implications of these interactions include atmospheric loss over diverse timescales, photochemistry and the formation of aerosols, which affect the evolution, composition and remote sensing of the planets (satellites). The upper atmosphere connects the planet (satellite) bulk composition to the near-planet (-satellite) environment. Understanding the relevant physics and chemistry provides insight to the past and future conditions of these objects, which is critical for understanding their evolution. This chapter introduces the basic concepts of upper atmospheres and ionospheres in our solar system, and discusses aspects of their neutral and ion composition, wind dynamics and energy budget. This knowledge is key to putting in context the observations of upper atmospheres and haze on exoplanets, and to devise a theory that explains exoplanet demographics., Comment: Invited Review

We present a thermal emission spectrum of the bloated hot Jupiter HAT-P-32Ab from a single eclipse observation made in spatial scan mode with the Wide Field Camera 3 (WFC3) aboard the Hubble Space Telescope (HST). The spectrum covers the wavelength regime from 1.123 to 1.644 microns which is binned into 14 eclipse depths measured to an averaged precision of 104 parts-per million. The spectrum is unaffected by a dilution from the close M-dwarf companion HAT-P-32B, which was fully resolved. We complemented our spectrum with literature results and performed a comparative forward and retrieval analysis with the 1D radiative-convective ATMO model. Assuming solar abundance of the planet atmosphere, we find that the measured spectrum can best be explained by the spectrum of a blackbody isothermal atmosphere with Tp = 1995 +/- 17K, but can equally-well be described by a spectrum with modest thermal inversion. The retrieved spectrum suggests emission from VO at the WFC3 wavelengths and no evidence of the 1.4 micron water feature. The emission models with temperature profiles decreasing with height are rejected at a high confidence. An isothermal or inverted spectrum can imply a clear atmosphere with an absorber, a dusty cloud deck or a combination of both. We find that the planet can have continuum of values for the albedo and recirculation, ranging from high albedo and poor recirculation to low albedo and efficient recirculation. Optical spectroscopy of the planet's day-side or thermal emission phase curves can potentially resolve the current albedo with recirculation degeneracy., Comment: 14 pages, 10 figures, 3 tables, accepted for publication in MNRAS

We use a model of aerosol microphysics to investigate the impact of high-altitude photochemical aerosols on the transmission spectra and atmospheric properties of close-in exoplanets, such as HD209458b and HD189733b. The results depend strongly on the temperature profiles in the middle and upper atmosphere that are poorly understood. Nevertheless, our model of HD189733b, based on the most recently inferred temperature profiles, produces an aerosol distribution that matches the observed transmission spectrum. We argue that the hotter temperature of HD209458b inhibits the production of high-altitude aerosols and leads to the appearance of a more clear atmosphere than on HD189733b. The aerosol distribution also depends on the particle composition, the photochemical production, and the atmospheric mixing. Due to degeneracies among these inputs, current data cannot constrain the aerosol properties in detail. Instead, our work highlights the role of different factors in controlling the aerosol distribution that will prove useful in understanding different observations, including those from future missions. For the atmospheric mixing efficiency suggested by general circulation models (GCMs) we find that aerosol particles are small ($\sim$nm) and probably spherical. We further conclude that composition based on complex hydrocarbons (soots) is the most likely candidate to survive the high temperatures in hot Jupiter atmospheres. Such particles would have a significant impact on the energy balance of HD189733b's atmosphere and should be incorporated in future studies of atmospheric structure. We also evaluate the contribution of external sources in the photochemical aerosol formation and find that their spectral signature is not consistent with observations., Comment: Accepted for publication in ApJ

Infrared radiation emitted from a planet contains information about the chemical composition and vertical temperature profile of its atmosphere. If upper layers are cooler than lower layers, molecular gases will produce absorption features in the planetary thermal spectrum. Conversely, if there is a stratosphere - where temperature increases with altitude - these molecular features will be observed in emission. It has been suggested that stratospheres could form in highly irradiated exoplanets, but the extent to which this occurs is unresolved both theoretically and observationally. A previous claim for the presence of a stratosphere remains open to question, owing to the challenges posed by the highly variable host star and the low spectral resolution of the measurements. Here we report a near-infrared thermal spectrum for the ultrahot gas giant WASP-121b, which has an equilibrium temperature of approximately 2,500 kelvin. Water is resolved in emission, providing a detection of an exoplanet stratosphere at 5-sigma confidence. These observations imply that a substantial fraction of incident stellar radiation is retained at high altitudes in the atmosphere, possibly by absorbing chemical species such as gaseous vanadium oxide and titanium oxide., Comment: This is the authors' version of the manuscript. 23 pages, 9 figures, 4 tables

Investigating the overall brightness of planets (and moons) provides insight into their envelopes and energy budgets [1, 2, 3, 4]. Titan phase curves (a representation of overall brightness vs. Sun-object-observer phase angle) have been published over a limited range of phase angles and spectral passbands [5, 6]. Such information has been key to the study of the stratification, microphysics and aggregate nature of Titan's atmospheric haze [7, 8], and has complemented the spatially-resolved observations first showing that the haze scatters efficiently in the forward direction [7, 9]. Here we present Cassini Imaging Science Subsystem whole-disk brightness measurements of Titan from ultraviolet to near-infrared wavelengths. The observations reveal that Titan's twilight (loosely defined as the view when the phase angle 150deg) outshines its daylight at various wavelengths. From the match between measurements and models, we show that at even larger phase angles the back-illuminated moon will appear much brighter than when fully illuminated. This behavior is unique to Titan in our solar system, and is caused by its extended atmosphere and the efficient forward scattering of sunlight by its atmospheric haze. We infer a solar energy deposition rate (for a solar constant of 14.9 Wm-2) of (2.84+/-0.11)x10^14 W, consistent to within 1-2 standard deviations with Titan's time-varying thermal emission spanning 2007- 2013 [10, 11]. We propose that a forward scattering signature may also occur at large phase angles in the brightness of exoplanets with extended hazy atmospheres, and that this signature has valuable diagnostic potential for atmospheric characterization., Comment: Pre-print of a manuscript published in Nature Astronomy 1, 0114 (2017) DOI: 10.1038/s41550-017-0114, http://www.nature.com/nastronomy

The Alice instrument on NASA's New Horizons spacecraft observed an ultraviolet solar occultation by Pluto's atmosphere on 2015 July 14. The transmission vs. altitude was sensitive to the presence of N2, CH4, C2H2, C2H4, C2H6, and haze. We derived line-of-sight abundances and local number densities for the 5 molecular species, and line-of-sight optical depth and extinction coefficients for the haze. We found the following major conclusions: 1) We confirmed temperatures in Pluto's upper atmosphere that were colder than expected before the New Horizons flyby, with upper atmospheric temperatures near 65-68 K. The inferred enhanced Jeans escape rates were (3e22-7e22) N2/s and (4e25-8e25) CH4/s at the exobase (at a radius of ~2900 km, or an altitude of ~1710 km). 2) We measured CH4 abundances from 80 to 1200 km above the surface. A joint analysis of the Alice CH4 and Alice and REX N2 measurements implied a very stable lower atmosphere with a small eddy diffusion coefficient, most likely between 550 and 4000 cm2/s. Such a small eddy diffusion coefficient placed the homopause within 12 km of the surface, giving Pluto a small planetary boundary layer. The inferred CH4 surface mixing ratio was ~0.28-0.35%. 3) The abundance profiles of the C2Hx hydrocarbons (C2H2, C2H4, C2H6) were not simply exponential with altitude. We detected local maxima in line-of-sight abundance near 410 km altitude for C2H4, near 320 km for C2H2, and an inflection point or the suggestion of a local maximum at 260 km for C2H6. We also detected local minima near 200 km altitude for C2H4, near 170 km for C2H2, and an inflection point or minimum near 170-200 km for C2H6. These compared favorably with models for hydrocarbon production near 300-400 km and haze condensation near 200 km, especially for C2H2 and C2H4 (Wong et al. 2017). 4) We found haze that had an extinction coefficient approximately proportional to N2 density.

UV observations with Cassini ISS Narrow Angle Camera of Titan's detached haze is an excellent tool to probe its aerosols content without being affected by the gas or the multiple scattering. Unfortunately, its low extent in altitude requires a high resolution calibration and limits the number of images available in the Cassini dataset. However, we show that it is possible to extract on each profile the local maximum of intensity of this layer and confirm its stability at $500 \pm 8$ km during the 2005-2007 period for all latitudes lower than 45$^\circ$N. Using the fractal aggregate scattering model of Tomasko et al. (2008) and a single scattering radiative transfer model, it is possible to derive the optical properties required to explain the observations made at different phase angles. Our results indicates that the aerosols have at least ten monomers of 60 nm radius, while the typical tangential column number density is about $2\cdot 10^{10}$ agg.m$^{-2}$. Moreover, we demonstrate that these properties are constant within the error bars in the southern hemisphere of Titan over the observed time period. In the northern hemisphere, the size of the aerosols tend to decrease relatively to the southern hemisphere and are associated with a higher tangential opacity. However, the lower number of observations available in this region due to the orbital constraints is a limiting factor in the accuracy of these results. Assuming a fixed homogeneous content we notice that the tangential opacity can fluctuate up to a factor 3 among the observations at the equator. These variations could be linked with short scale temporal and/or longitudinal events changing the local density of the layer.

Haze in Pluto's atmosphere was detected in images by both the Long Range Reconnaissance Imager (LORRI) and the Multispectral Visible Imaging Camera (MVIC) on New Horizons. LORRI observed haze up to altitudes of at least 200 km above Pluto's surface at solar phase angles from ~20{\deg} to ~169{\deg}. The haze is structured with about ~20 layers, and the extinction due to haze is greater in the northern hemisphere than at equatorial or southern latitudes. However, more haze layers are discerned at equatorial latitudes. A search for temporal variations found no evidence for motions of haze layers (temporal changes in layer altitudes) on time scales of 2 to 5 hours, but did find evidence of changes in haze scale height above 100 km altitude. An ultraviolet extinction attributable to the atmospheric haze was also detected by the ALICE ultraviolet spectrograph on New Horizons. The haze particles are strongly forward-scattering in the visible, and a microphysical model of haze is presented which reproduces the visible phase function just above the surface with 0.5 {\mu}m spherical particles, but also invokes fractal aggregate particles to fit the visible phase function at 45 km altitude and account for UV extinction. A model of haze layer generation by orographic excitation of gravity waves is presented. This model accounts for the observed layer thickness and distribution with altitude. Haze particles settle out of the atmosphere and onto Pluto's surface, at a rate sufficient to alter surface optical properties on seasonal time scales. Pluto's regional scale albedo contrasts may be preserved in the face of the haze deposition by atmospheric collapse., Comment: 48 pages, 26 figures Corrected author name: Alex H. Parker

We present results from the first observations of the Hubble Space Telescope (HST) Panchromatic Comparative Exoplanet Treasury (PanCET) program for WASP-101b, a highly inflated hot Jupiter and one of the community targets proposed for the James Webb Space Telescope (JWST) Early Release Science (ERS) program. From a single HST Wide Field Camera 3 (WFC3) observation, we find that the near-infrared transmission spectrum of WASP-101b contains no significant H$_2$O absorption features and we rule out a clear atmosphere at 13{\sigma}. Therefore, WASP-101b is not an optimum target for a JWST ERS program aimed at observing strong molecular transmission features. We compare WASP-101b to the well studied and nearly identical hot Jupiter WASP-31b. These twin planets show similar temperature-pressure profiles and atmospheric features in the near-infrared. We suggest exoplanets in the same parameter space as WASP-101b and WASP-31b will also exhibit cloudy transmission spectral features. For future HST exoplanet studies, our analysis also suggests that a lower count limit needs to be exceeded per pixel on the detector in order to avoid unwanted instrumental systematics., Comment: 7 pages, 4 figures, 1 table, Accepted to ApJL

Observations of the Pluto-Charon system, acquired with the ALMA interferometer on June 12-13, 2015, have yielded a detection of the CO(3-2) and HCN(4-3) rotational transitions from Pluto, providing a strong confirmation of the presence of CO, and the first observation of HCN, in Pluto's atmosphere. The CO and HCN lines probe Pluto's atmosphere up to ~450 km and ~900 km altitude, respectively. The CO detection yields (i) a much improved determination of the CO mole fraction, as 515+/-40 ppm for a 12 ubar surface pressure (ii) clear evidence for a well-marked temperature decrease (i.e., mesosphere) above the 30-50 km stratopause and a best-determined temperature of 70+/-2 K at 300 km, in agreement with recent inferences from New Horizons / Alice solar occultation data. The HCN line shape implies a high abundance of this species in the upper atmosphere, with a mole fraction >1.5x10-5 above 450 km and a value of 4x10-5 near 800 km. The large HCN abundance and the cold upper atmosphere imply supersaturation of HCN to a degree (7-8 orders of magnitude) hitherto unseen in planetary atmospheres, probably due to the slow kinetics of condensation at the low pressure and temperature conditions of Pluto's upper atmosphere. HCN is also present in the bottom ~100 km of the atmosphere, with a 10-8 - 10-7 mole fraction; this implies either HCN saturation or undersaturation there, depending on the precise stratopause temperature. The HCN column is (1.6+/-0.4)x10^14 cm-2, suggesting a surface-referred net production rate of ~2x10^7 cm-2s-1. Although HCN rotational line cooling affects Pluto's atmosphere heat budget, the amounts determined in this study are insufficient to explain the well-marked mesosphere and upper atmosphere's ~70 K temperature. We finally report an upper limit on the HC3N column density (< 2x10^13 cm-2) and on the HC15N / HC14N ratio (< 1/125)., Comment: Revised version. Icarus, in press, Oct. 11, 2016. 57 pages, including 13 figures and 4 tables

Observations made during the New Horizons flyby provide a detailed snapshot of the current state of Pluto's atmosphere. While the lower atmosphere (at altitudes <200 km) is consistent with ground-based stellar occultations, the upper atmosphere is much colder and more compact than indicated by pre-encounter models. Molecular nitrogen (N$_2$) dominates the atmosphere (at altitudes <1800 km or so), while methane (CH$_4$), acetylene (C$_2$H$_2$), ethylene (C$_2$H$_4$), and ethane (C$_2$H$_6$) are abundant minor species, and likely feed the production of an extensive haze which encompasses Pluto. The cold upper atmosphere shuts off the anticipated enhanced-Jeans, hydrodynamic-like escape of Pluto's atmosphere to space. It is unclear whether the current state of Pluto's atmosphere is representative of its average state--over seasonal or geologic time scales., Comment: in Science 351, aad8866 (2016)

We describe a detailed study on the properties of alkali atoms in extrasolar giant planets, and specifically focus on their role in generating the atmospheric free electron densities, as well as their impact on the transit depth observations. We focus our study on the case of HD 209458 b, and we show that photoionization produces a large electron density in the middle atmosphere that is about two orders of magnitude larger than the density anticipated from thermal ionization. Our purely photochemical calculations though result in a much larger transit depth for K than observed for this planet. This result does not change even if the roles of molecular chemistry and excited state chemistry are considered for the alkali atoms. In contrast, the model results for the case of exoplanet XO-2 b are in good agreement with the available observations. Given these results we discuss other possible scenarios, such as changes in the elemental abundances, changes in the temperature profiles, and the possible presence of clouds, which could potentially explain the observed HD 209458 b alkali properties. We find that most of these scenarios can not explain the observations, with the exception of a heterogeneous source (i.e. clouds or aerosols) under specific conditions, but we also note the discrepancies among the available observations.

Strong ionization on close-in extrasolar giant planets suggests that their atmospheres may be affected by ion drag and resistive heating arising from wind-driven electrodynamics. Recent models of ion drag on these planets, however, are based on thermal ionization only and do not include the upper atmosphere above the 1 mbar level. These models are also based on simplified equations of resistive MHD that are not always valid in extrasolar planet atmospheres. We show that photoionization dominates over thermal ionization over much of the dayside atmosphere above the 100 mbar level, creating an upper ionosphere dominated by ionization of H and He and a lower ionosphere dominated by ionization of metals such as Na, K, and Mg. The resulting dayside electron densities on close-in exoplanets are higher than those encountered in any planetary ionosphere of the solar system, and the conductivities are comparable to the chromosphere of the Sun. Based on these results and assumed magnetic fields, we constrain the conductivity regimes on close-in EGPs and use a generalized Ohm's law to study the basic effects of electrodynamics in their atmospheres. We find that ion drag is important above the 10 mbar level where it can also significantly alter the energy balance through resistive heating. Due to frequent collisions of the electrons and ions with the neutral atmosphere, however, ion drag is largely negligible in the lower atmosphere below the 10 mbar level for a reasonable range of planetary magnetic moments [abridged]., Comment: 16 pages, 22 figures, accepted by ApJ