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Teotihuacan is one of the most studied archaeological sites in Mesoamerica because of its exceptional size and urban planning; however, its last years of occupation and abandonment are still under debate. We report a high-resolution chronology for the Xalla complex integrating archaeomagnetic dates, radiocarbon (14C) ages, and detailed archaeological information about sample type and context in a Bayesian model. The model includes 42 14C ages and 7 archaeomagnetic dates grouped in 6 phases, including samples from collapsed roofs with 14C ages earlier than expected, suggesting a problem of inbuilt age. The archaeomagnetic dates on lime plasters were classified in unburned samples, related to the time of construction, and burned samples, related to the Big Fire associated to the abandonment of Teotihuacan. The modeled 14C ages resulted in shorter intervals, with the possibility of differentiating the construction phases, confirming that big beams had inbuilt age. Further, combining the two dating methods and classifying lime plaster samples in burned and unburned, it was possible to date different events within the same archaeological context. It is concluded that by combining these two dating methods and understanding the moment that each sample is dating, it is possible to obtain solid and precise chronologies.

Baldcypress, a long-lived species of riparian habitats, is sensitive to interannual climate variability. The annual radial growth is associated with the Standardized Precipitation Evaporation Index (SPEI) and Palmer Drought Severity Index (PDSI), both depending on a water balance. The baldcypress (Taxodium mucronatum Ten.) is a long-lived species and Mexico’s national tree. The objective of this study was to analyze the dendroclimatic response of baldcypress at sites located on the transitional zone between the semiarid and subtropical regions of Mexico, known as the Middle Zone of the state of San Luis Potosi, Mexico. The first site, Los Peroles (LPO), is a wetland where the oldest known baldcypress specimens in Mexico are found. The second site, Rio Verde (RVDE), is a riparian site located along a tributary of the Moctezuma River that drains into the Gulf of Mexico. Two ring-width chronologies were analyzed. The first one from LPO with a length of 633 years and the second one from RVDE with a length of 423 years. The species responded positively to the seasonal January–July precipitation (r = 0.52, p = 0.001) and negatively to the maximum monthly temperature of January, May, and June (r = − 0.42, −0.46, and −0.34; respectively). The average chronology was significantly associated with the mean January–August Standardized Precipitation Evaporation Index (SPEI) (r = 0.62, p = 0.000). An SPEI reconstruction was developed for the period 1575–1996 where the most prolonged and severe droughts were found at 70-year peaks in the El Nino Southern Oscillation frequency band. The annual radial growth of the species is a suitable indicator of the January–August water availability, and is important information that can be used to establish water management strategies for this semiarid environment and to preserve millennial baldcypress specimens.

espanolSe realizaron analisis de datacion por carbono catorce y microscopia electronica de barrido para determinar la edad y el estado de conservacion de un petate elaborado con fibras duras y una mortaja de algodon de un fardo mortuorio de Zimapan, Hidalgo. Ademas, las fibras fueron tratadas con quitosan y polipropilenglicol, tratamiento de conservacion innovador, cuyo funcionamiento se evaluo con microscopia electronica de barrido; asi mismo tambien fueron datadas las fibras despues del tratamiento. La datacion con radiocarbono indica que tanto el petate de fibras de palma como la mortaja de algodon son prehispanicos de 1022 a 1206 cal d.C; las fibras tratadas dieron edades considerablemente mas antiguas (72-418 cal d.C.). La diferencia de edades se debe posiblemente al efecto reservorio, ya que el quitosan se obtiene de los exoesqueletos de crustaceos marinos. Ademas, los analisis realizados indicaron que el tratamiento para las fibras fue efectivo consolidando, flexibilizando y fumigando las fibras al mismo tiempo. EnglishRadiocarbon dating and scanning electron microscopy analyses were used to determine the age and conservation state of a palm mat made with hard fibers and a cotton shroud found in a funerary bundle of Zimapan Hidalgo, Mexico. The fibers were also treated with an innovative treatment of chitosan and polypropylene glycol. The treatment was analyzed with a scanning electron microscopy and radiocarbon dating was applied to the treated fibers. The radiocarbon dating showed dates of 1022 a 1206 cal d.C therefore the textiles are prehispanic, and the treated fibers showed an early date (72-418 cal d.C.). This difference could be explained from the reservoir effect in the marine organisms because the chitosan is obtained from the chitin of crustacean’s exoskeletons. The analysis also showed that the treatment for the fibers was effective because the fibers gained consolidation, flexibilization and also microorganisms were killed and removed.

Northern Mexico is projected to become more arid in the future, however the magnitude, timing and spatial extent of precipitation change is presently poorly constrained. To address this, we have developed a multi-proxy (δ18O, δ13C, Mg/Ca) U-Th dated speleothem record of past rainfall variability spanning 4.6 to 58.5 ka from Tamaulipas, Mexico. Our results demonstrate a dominant thermodynamic control on hydroclimate via changes in Atlantic SSTs. Our record robustly demonstrates this response during major paleoclimate events including the Last Glacial Maximum, the Younger Dryas and Heinrich Stadials 1, 3, 4, and 5. While previous work has suggested the magnitude of the Caribbean Low-Level Jet as the predominant driver of regional rainfall, we utilize a state-of-the-art climate model to isolate cool Atlantic SSTs as the dominant mechanism of drying. We also demonstrate this response is consistent across large parts of Mesoamerica, suggesting drying in the future may be more spatially homogenous than currently predicted.

Platinum (Pt) concentrations in PM2.5 were evaluated by means of inductively coupled plasma mass spectrometry (ICP-MS) to evaluate the spatial and temporal behavior and to assess trends. Samples we...

We present a new record of atmospheric Δ14C from 1926–2002 AD constructed from annual measurements of dendrochronologically dated tree rings from Nuevo Leon in Northeast (NE) Mexico. The results are very similar to the Northern Hemisphere Zone 2 compilation, indicating that this location provides a suitable record of background atmospheric Δ14C. Closer examination of the atmospheric bomb peak years (1962–1965 AD), however reveals subtle differences from the Zone 2 compilation that may reflect transport of 14C-depleted air from the south during the summer season influenced not only by the northward migration of the Intertropical Convergence Zone but also by the North American Monsoon system and tropical storms and hurricanes over the Gulf of Mexico. These differences decrease after 1965 indicating that Northern Hemisphere atmospheric mixing had largely occurred by this point. Examination of the pre-bomb peak period reveals a steady decrease in F14C associated with fossil fuel derived CO2 emissions from 1922–1950 AD. The NE Mexico record is enriched in 14C relative to a record from the Pacific Northwest during this period, potentially reflecting a greater impact of fossil fuel emissions and/or release of aged CO2 from Pacific upwelling in this region. This record from NE Mexico represents the longest such record from North America and will contribute to improved characterization of the spatial and temporal variability of atmospheric Δ14C in the Northern Hemisphere.

In this study, atmospheric mercury concentration in airborne particulate matter with an aerodynamic diameter ≤ 2.5 µm (PM2.5) was analyzed by ICP-MS. Samples were collected in the Mexico City Metropolitan Area (MCMA), during 2013, in five locations, Northwest, Northeast (NE), Central, Southwest and Southeast, along three seasons: dry warm, rainy, and dry cold (DC). It can be observed that NE shows the highest mercury concentration (p

The recognition of past climatic fluctuations in sedimentary sequences in central Mexico is relevant for understanding the forcing mechanisms and responses of climatic system in the northern American tropic. Moreover, in this active volcanic setting the sedimentary record preserves the history of past volcanic activity. Climatic and environmental variability has been documented for the last tenths of thousands of years from the upper lacustrine sediments in Chalco basin. A series of cores drilled down to 122 m depth in this basin offer a long, continuous and high resolution record of past climatic changes of the last ca. 150 kyr in this region. Here we present the detailed lithostratigraphy and some physical properties (magnetic susceptibility and density) of the master sequence. Sedimentary components and their abundance were identified and quantified in smear slides and direct core observations. Age model is based on 13 14C and one 230Th/U dates. Based on their facies association seven lithostratigraphic units were defined, which reflect the main stages of lake Chalco evolution. These phases closely match the marine isotopic stages. The data reveal that at the end of MIS6 Chalco was a relatively deep and stratified freshwater lake. During MIS5 the depositional environment fluctuated between low lake stands to marshy and marginal playa settings with sporadic flooding events, and severe arid periods resulted in aerial exposure of lake sediments. Low lake stands persisted during MIS4 and MIS3, with minor fluctuations towards slightly deeper phases. The Last Glacial Maximum (LGM) and the deglacial period (21-13 kyr) are characterized by intense volcanism. The early and mid-Holocene high calcareous content and alkaline-subsaline lake suggest dry conditions. The fluctuations of lake levels inferred provide the basis for future paleoclimatic works.

The Mexico City Metropolitan Area (MCMA) was the object of a chemical elemental characterization (Ti, V, Cr, Mn, Co, Ni, Cu, Mo, Ag, Cd, Sb, Pb, La, Sm, Ce, and Eu) of PM2.5 collected during 2013 and analyzed by inductively coupled plasma mass spectrometry (ICP-MS). Sampling campaigns were carried out at five locations simultaneously—northwest, northeast, center, southwest, and southeast—during dry-warm season (April), rainy season (August), and dry-cold season (November). By means of enrichment factor (EF) and principal component analysis (PCA), it was possible to attribute the analyzed elements to geogenic and anthropogenic sources, as well as to identify a group of elements with mixed provenance sources. The highest concentrations for most metals were found in northwest and northeast, and during dry-warm (DW), confirming the trend observed in PM2.5 samples collected in 2011. Despite similarities between 2011 and 2013, an increase of 17% in PM2.5 mass concentration was observed, mainly attributable to geogenic sources, whereby the importance of wind intensity to the impact of emission sources is highlighted. The effect of wind intensity was revealed, by means of polar plots, as the controlling mechanism for this increase. This allowed us to conclude that high-speed episodes (5 m s−1) were responsible for raising geogenic metal concentrations rather than wind direction.

Palaeoclimate research in subtropical arid Mexico is mainly focused to infer dynamics and geographic distributions of different precipitation regimes, but droughts have received less attention. We present a new sedimentary core record indicating orbital-scale dynamics of droughts that occurred in central-northern Mexico during the late Quaternary. This record is reconstructed from abundances of authigenic carbonate and windblown clastic sediments in a 1026-cm-long sediment core from the Santiaguillo ephemeral lake. The Marine Isotope Stage (MIS) 2 lacked drought, and at least two different droughts were centred at c. 13.5 ka and at c. 7 ka during the MIS 1. The drought of c. 13.5 ka in the Santiaguillo ephemeral lake was contemporary to an interval of droughts in the Basin of Mexico (central Mexico) and stronger aeolian activity in the Baja California peninsula (northwestern Mexico). This synchronous arid condition, observed in the subtropical as well as tropical Mexico, occurred during an interval of higher spring insolation, relatively warmer but fluctuating global temperature, and stronger El Nino-Southern Oscillation. Unsuccessful radiocarbon dating for the lower part of the sediment core led to an assignment of uncertain chronology to droughts that occurred possibly between MIS 5 and MIS 3. Copyright © 2017 John Wiley & Sons, Ltd.

Tropical Mountain Cloud Forests (TMCF) occur within narrow elevational limits with very specific climatic conditions; this type of vegetation is among the most vulnerable terrestrial ecosystems to climate change. The present study aims to analyze the local and regional climatic response of tree-ring widths of Pinus pseudostrobus at "El Cielo" Biosphere Reserve (CBR) over a 66-year period (1950–2016). We also investigated the temporal stability of the climate-growth response in four 20 years sub-periods (1950–1969, 1970–1989, 1990–2009, and 1997–2016). The results of the climate-growth analyses over the full-time period indicate a positive correlation with precipitation from previous-year November to current-year May and a negative correlation with maximum temperature and evaporation from previous-year December to current-year April and current-year January to May, respectively. We found a positive correlation with April to June PDSI and no correlation with minimum temperature. Radial growth was correlated with the climate of northeastern Mexico (i.e. Coahuila, Nuevo Leon, and Tamaulipas) and with coupled-ocean atmosphere climate modes, such as the El Nino Southern Oscillation (ENSO), the Pacific Decadal Oscillation (PDO), and the Atlantic Multidecadal Oscillation (AMO). Correlation analyses for different periods indicate changes over time in the sensitivity of trees to climatic variability and broad-scale atmospheric circulation patterns such as PDO and AMO. Compared to the full-time period analyses the response of radial-growth to precipitation and PDSI increased in 30 and 48 % in the last 20 years, respectively.

We inferred millennial-scale climate variations and paleohydrological conditions in the northern sector of the American tropics for 30.3–5.5 cal ka BP using geochemical characteristics of sediments from Lake Chalco in central Mexico. The sediment sequence is chronologically constrainedwith three tephra and nine radiocarbon dates. Temporal variations in titanium, total inorganic carbon, total organic carbon/titanium ratio, carbon/nitrogen ratio, and silica/titanium ratio indicate changes in runoff, salinity, productivity, and sources. Higher concentrations of Ti indicate more runoff during latest Marine Isotope Stage (MIS) 3 (30.3–28.6 cal ka BP). Runoff was lower during the last glacial maximum (LGM; 23–19 cal ka BP) than during the Heinrich 2 event (26–24 cal ka BP). The interval of reduced runoff continued up to 17.5 cal ka BP but increased during the Bølling/Allerød. Trends of decreasing runoff and increasing salinity are observed throughout MIS 1. Lake Chalco received less runoff during the LGM compared to deglaciation, opposite the trend of other North American tropical records. Different amounts of rainfall at different sites are possibly due to shifts in the position of the Intertropical Convergence Zone, changes in the size of the Altlanticwarmpool, and varying sea-surface temperatures of the Atlantic and Pacific oceans

The study of airborne metals in urban areas is relevant due to their toxic effects on human health and organisms. In this study, we analyzed metals including rare earth elements (REE) in particles smaller than 2.5 μm (PM2.5), collected at five sites around the Mexico City Metropolitan Area (MCMA), during three periods in 2011: April (dry-warm season, DW), August (rainy season, R), and November (dry-cold season, DC). Principal component analysis allowed identifying factors related to geogenic sources and factors related to anthropogenic sources. The recognition of the high impact of geogenic sources in PM2.5 is in agreement with the REE distribution patterns, which show similar behavior as those shown by igneous rocks, confirming the influence of the regional geogenic material. Metals associated to geogenic sources showed higher concentration (p 0.05) and no similar seasonal pattern among them. These unexpected results exposed outstanding information regarding the identification of different geogenic sources as the main contributors of metals in the atmospheric environment in the MCMA and highlighted the importance of meteorology in the spatial and seasonal metal patterns.

Over the last glacial cycle, climate variations in the Neotropics were related to diverse forcing mechanisms whose understanding has been limited because of the scarcity of continuous long records. Here we use high-resolution charcoal particle accumulation, inorganic carbon precipitation and magnetic susceptibility data from Lake Chalco, located in high-altitude tropical central Mexico, to assess the fire regimes and drought periods between ∼85 and 10.8k cal a BP. Overall, drought intervals were characterized by high carbonate deposition and were contemporary with high spring insolation. Most of the high fire activity periods were coupled with droughts, whereas some of them seem to have responded to volcanic activity in the basin. Periods of more fire activity during the latest part of Marine Isotope Stage 3 were associated with a long interval of higher spring insolation. Increase in drought frequency during 47–27k cal a BP were possibly linked to a more active Laurentide Ice Sheet influencing the oceanic and atmospheric controls of the tropical climatic system. In fact, Chalco and Cariaco records show similar millennial-scale trends, suggesting a role of the Intertropical Convergence Zone in modulating moisture availability in the region.

The increase in platinum (Pt) in the airborne particulate matter with size ≤2.5 µm (PM2.5) in urban environments may be interpreted as result of the abrasion and deterioration of automobile catalyst. Nowadays, about four million vehicles in Mexico City use catalytic converters, which means that their impact should be considered. In order to evaluate the contribution of Pt to environmental pollution of the metropolitan area of Mexico City (MAMC), airborne PM2.5 was collected at five different sites in the urban area (NW, NE, C, SW, SE) in 2011 during April (dry-warm season), August (rainy season) and December (dry-cold season). Analytical determinations were carried out using a ICP-MS with a collision cell and kinetic energy discrimination. The analytical and instrument performance was evaluated with standard road dust reference material (BCR-723). Median Pt concentration in the analyzed particulate was is 38.4 pg m(-3) (minimal value 1 pg m(-3) maximal value 79 pg m(-3)). Obtained Pt concentrations are higher than those reported for other urban areas. Spatial variation shows that SW had Pt concentration significantly higher than NW and C only. Seasonal variation shows that Pt median was higher in rainy season than in both dry seasons. A comparison of these results with previously reported data of PM10 from 1991 and 2003 in the same studied area shows a worrying increase in the concentration of Pt in the air environment of MAMC.

Heavy-metals (Cu, Pb and Zn) in tree-ring sequences of Prosopis juliflora, a tree species native to arid environments, were analyzed by ICP-MS. The tree-ring sequences were obtained from three specimens growing in an urban area previously reported as contaminated by the activity of a Cu smelter facility. The metal found in highest concentration in the wood was Zn, with concentrations up to 120 mg/kg and an enrichment factor up to 26; followed by Cu (up to 9.6 mg/kg, enrichment factor up to 8.6) and Pb (up to 1.4 mg/kg, enrichment factor up to 3). By assessing the correlation between different metal concentration trends, it was possible to infer two main pollution sources: vehicle traffic and Cu smelter emissions. Vehicle traffic is indicated by a correlation between Pb and Zn over time within individual trees, whereas contamination from the Cu-smelting facility is indicated by a correlation of Cu over time between trees. In tree A there was a significant within-tree correlation between Pb and Zn concentration trends (r = 0.856, P < 0.001), whereas Cu showed no correlation with the other metals. For tree B, there were no within-tree correlations between these metals, but when comparing the concentration–time trends between trees A and B, there was a significant correlation for Cu (r = 0.768, P < 0.01). The tree-ring sequence from tree C showed significant within-tree correlation for Cu:Zn (r = 0.430, P < 0.01) and for Pb:Zn (r = 0.753, P < 0.001). The highest enrichment values were found in tree A, located along the path of the growing-season dominant wind direction from the smelter facility, and not in the tree growing closer to the smelter (tree C), suggesting that the smelter’s emissions are dispersed to longer distances through the tall chimneys, attenuating the impact to the area directly closest to the smelter facility. It is concluded that Prosopis juliflora appears as a good bioindicator based on its metal accumulation capacity and lack of metal mobility among tree rings, thus providing information on the chronology and sources of heavy-metal pollution in urban and industrial areas.

Dendrochronological studies are limited in tropical regions because not many tree species form annual growth rings. This work reports an evaluation of the dendrochronological potential of tropical ash (Fraxinus uhdei) and its use as a bioindicator of fossil CO2 concentration in urban areas by means of radiocarbon analysis on growth rings. We analyzed a cross-section of a tree that grew during the period 1932–2007 in San Luis Potosí, one of the most industrialized cities in Mexico. The Δ14C values obtained follow the same variation pattern as the calibration curve of the Northern Hemisphere (NH) zone 2 (Hua and Barbetti 2004), with the peak centered in 1964, but they are lower by up to 124′. The high correlation coefficient (r = 0.990, p < 0.001) between the variation patterns indicates that this species does form annual growth rings, and the lower values can be attributed to the 14C dilution caused by fossil CO2 emissions. The magnitude of the Suess effect varied between −6.9% and −0.5%, equivalent to fossil CO2 concentrations ranging between 21.9 and 1.5 ppmv. The Suess effect and fossil CO2 values have significant variations with no apparent monotone increasing trend, suggesting that the CO2 emissions during the studied period have diverse sources. It is concluded that F. uhdei has potential for dendrochronological studies in tropical areas because its growth rings are formed annually and, furthermore, it can be used as a bioindicator of atmospheric 14C variations and fossil CO2 concentration in urban areas.

We report a detailed rock-magnetic and archaeointensity analysis of four pottery fragments and a burned floor recovered from the Tzintzuntzan archaeological site in western Mexico. Results from rock-magnetic experiments (x-T curves and first-order reversal curves [FORC] diagrams) indicate the suitability of most of these materials as faithful geomagnetic field recorders. Potsherds were archaeomagnetically dated by comparing their mean intensity values against the paleosecular variation curve CALS3k, suggesting A.D. 600–941 as the most probable age range. This is younger than 14C-dated charcoal from the same burned floor (A.D. 1294–1426). More precise age estimates will require the use of the full geomagnetic vector (declination, inclination, and intensity). Multiple reheatings of the ceramic pieces, evidenced as secondary components in Zijderveld plots, could reflect multiple heating of these objects, perhaps from use as incense burners. Our study demonstrates the potential of archaeomagnetic analysis to both date burned ceramics recovered in situ and provide insight into their use-history.

We report the stratigraphic sequence of the 2005 eruption of Ilamatepec volcano together with sedimentological and chemical analyses of its products. Structural and textural characteristics of the deposits indicate that the eruption was driven by a small-volume rhyolitic intrusion at shallow levels, which resulted first in the collapse of the existing hydrothermally altered fan of previous deposits inside the crater lake, driving phreatic explosions with launching of blocks on ballistic trajectories; later the magma interacted with lake waters producing several hydromagmatic pyroclastic density currents (PDCs). These flows were energetic enough to knock down pine trees up to distances of 1.8 km from the crater in the E-NE sector of the volcano. Finally, ejection of ballistic blocks that landed on previously emplaced, wet pyroclastic density current deposits, caused the generation of a lahar that flowed down the steep eastern flank toward the El Jabillal gully. Subsequent lahars occurred as a result of intense rain caused by hurricane Stan. Radiocarbon ages on paleosols and charcoal fragments, separating previous volcanogenic sequences, indicate that similar eruptions have occurred more frequently in the past centuries, than previously thought. The new data confirms that Ilamatepec volcano is one of the most active volcanoes in El Salvador. Nevertheless, more detailed studies of the eruptive sequence of Ilamatepec volcano are mandatory to establish future eruptive patterns.

The degree of anthropogenic impact in the urban environments can be evaluated in terms of metal concentration of soils, often established in terms of integrated pollution index (IPI). Detailed geochemical investigations on urban soils require a great amount of chemical analyses, which are time consuming and expensive. The magnetic susceptibility signal detected in some urban topsoils is mainly attributed to the ferromagnetic components of anthropogenic origins, which include in their molecules a portion of heavy metals. Therefore, the application of susceptibility measurements of soils allows the assessment of polluted areas reducing the amount of chemical analyses. The magnetic survey reported here for first time on Mexico City's topsoils tries to establish the link between magnetic proprieties and the content of heavy metals (Fe, Pb, Cu, Zn, Ni, Cr and V). The best correlation between susceptibility values and the heavy metal content was found for highly contaminated samples yielding susceptibility values higher than 400 χ × 10− 8 SI. In contrast, low contamination levels (metals contents near to background values) don't have significant correlation with magnetic susceptibility. The results show that magnetic susceptibility has a significant correlation with IPI, Fe, Cu and Zn. It is concluded that magnetic susceptibility can be used as a first approach for heavy metal contamination in terms of IPI, allowing to recognize areas that would require a detailed chemical study.

This study reports the degree of heavy metal pollution (Cr, Cu, Ni, Pb, Zn and V) in 135 urban topsoil samples from the metropolitan area of Mexico City. Pollution indices (PI) were calculated to identify the metal accumulation with respect to the background values. The levels of heavy metals in the analyzed samples show a wide range of variation. Lead, Zn and Cu are the elements most enriched in the analyzed area, presenting pollution indexes of up to 23.8, 21.6 and 12.4, respectively. Geochemical maps were produced to assess the spatial distribution of pollution index. It is concluded that emissions from vehicles may be the major source of Pb urban contamination; furthermore, other small or large factories are possible sources for soil pollution (Cu, Zn). The concentration of Cr, Ni, and V in most of the analyzed samples do not appear to reach pollution levels. The assessment of the soil environmental quality in the metropolitan area Mexico City in terms of PI can be used as the basis for a regular monitoring program for implementing suitable pollution control measures.

Proxy records generated from chemical composition and radiocarbon dating of a sediment sequence collected from the El Potosi Basin provide information about variable hydroclimate of the subtropical northeastern Mexico since the last glacial maximum (LGM). Minimal amounts of runoff and more carbonate deposition during >19 ka represent the LGM. The deglaciation was wetter compared to the LGM and enhanced runoff during ∼ 19 – 12 ka transported more Ti-bearing clastics from a relatively humid watershed. Over the deglaciation, the basin received more runoff during the Bolling-Allerod compared to the Heinrich Stadial 1 and Younger Dryas. Reduction in the amount of runoff during ∼ 10 – 1 ka and deposition of unweathered Si-bearing clastics during ∼ 4 – 1 ka suggest that the Holocene was drier compared to the deglaciation. Hydroclimates of the northeastern Mexico and southern US were synchronous during the LGM as well as deglaciation. Change from the drier LGM to wetter Bolling-Allerod occurred as the Gulf of Mexico became warmer and the region received more summer precipitation. However, the dissimilarities observed in regional hydroclimates of the Holocene need further evaluation.

Stratigraphy, geochemistry and radiocarbon dating of a succession of sediment in the Santiaguillo Basin (central-northern Mexico) help reconstruct the millennial-scale dynamics of hydrological variability that occurred in the southern part of western subtropical North America since the late last glacial. Runoff was generally above average during the late last glacial from ~ 27 to 18 ka. Following this interval, runoff decreased and deposition of authigenic carbonate and aeolian transported sediment increased until ~ 4 ka. Heinrich 1 and 2, and Younger Dryas were intervals of reduced runoff and increased aeolian activity. The wetter climate of central-northern Mexico and arid conditions in north–northwestern Mexico during the late last glacial were probably related to formation of tropical cyclones in the eastern North Pacific during the autumn with restricted rainfall swaths and an absent/weaker North American Monsoon. Enhanced North American Monsoon and tropical cyclones with expanded rainfall swaths brought more summer and autumn precipitation to a broader region extending from the central-northern Mexico to the continental interiors of southwestern US during the early Holocene.

This study reports the compound specific stable carbon isotope compositions (δ13C) of lignin tetramethylammonium hydroxide (TMAH) chemolysates obtained with gas chromatography–combustion–isotope ratio mass spectrometry (GC–C–IRMS). The possible sources of the errors associated are considered. Off-line (TMAH) thermochemolysis was performed on wood samples and the δ13C values of the chemolysates were compared with the bulk δ13C of the native woods and their Klason lignins. For the four woods investigated, the δ13C values, corrected for derivative carbons added, were spread over a wide range of values, ranging from −40 to −25‰ and were, on average, depleted in 13C by ca. 9‰ relative to the native woods and by ca. 7‰ relative to the Klason lignins. This large variability can be partially attributed to overlapping chromatographic peaks and to the low intensity of some of the peaks. However, isotopic fractionation cannot be ruled out, especially in compounds resulting from CC bond cleavage in the propyl side chain. The uncertainties associated with the correction for carbons added by derivatisation were found to be high, especially for compounds having high contribution of derivative carbons.

Hydropyrolysis (hypy) as a fast means for preparing lignin concentrates for stable carbon isotope analysis was evaluated by performing hypy at different temperatures (200–500 °C) on Klason lignin concentrates, cellulose, and wood samples followed by bulk stable carbon isotope analysis of the solid residues. The δ 13 C values of cellulose, Klason lignin and their hypy residues revealed that hypy does not produce isotopic fractionation throughout the temperature range explored. The δ 13 C of hypy residues from cellulose-Klason lignin physical mixtures obtained at 500 °C were in the value range of the corresponding Klason lignin indicating that cellulose decomposed completely and that no major structural rearrangements, which could lead to carbon cross-linking between these two moieties are produced by hypy. The hypy residues obtained from wood samples at 500 °C were consistently depleted in 13 C by 0.8‰ and enriched by 1.6‰ relative to the original wood and Klason lignin, respectively. This finding results from polysaccharide derivatives remaining in the wood residue, with a percentage of polysaccharide derived carbon 1.9 and 3.7 times higher than expected at 300 and 350 °C, respectively. It is concluded that the results presented here provide an indicator of the extent of cross-linking between lignin and polysaccharides (hemicellulose) in the native wood forming lignin–carbohydrate complexes.

This contribution reports the first set of samples and the creation of an internal reference material at the recently opened Radiocarbon Laboratory at the National Autonomous University of Mexico (UNAM). Samples for the initial measurements were selected from archaeological and dating projects on Teotihuacán, one of the largest and best-studied Mesoamerican urban and ceremonial centers. The 14C dates were compared to results obtained by 2 other laboratories in order to assess the results obtained at UNAM and validate the adopted methodology. As part of the quality assurance protocol, an internal reference material was created that consists of charred wood from the Teotihuacán site with a 14C activity in the value range expected for samples from Mesoamerican archaeological sites. Results from 7 analyses have a mean of 1750 ± 16 BP (80.43 ± 0.16 pMC).

The use of hydropyrolysis (hypy) is described as a potentially rapid procedure for obtaining lignin-enriched residues from wood for either simply estimating lignin content or for performing stable isotope ratio measurements. Hypy was carried out on samples of oak wood and, as reference materials, Klason lignin and pure cellulose over the temperature range of 200–500 °C. The composition of the residues were assessed by solid-state 13C NMR. At 300 and 350 °C, the extents of conversion achieved for cellulose was 88 and 95% respectively, indicating that highly lignin-enriched residues should be obtained for wood samples. This was confirmed by solid-state 13C NMR which also indicated that any remaining cellulose had aromatised to a significant extent. In addition, hypy caused quite extensive demethylation of methoxyl functionalities and cleavage of the characteristic β-O-4 ether lignin linkage. Finally, correcting the 300 and 350 °C hypy residues for residual cellulose gave estimates of the lignin content for oak wood in close agreement with those obtained by the Klason method and by solid-state 13C NMR. At 350 °C, the residual cellulose accounts for ca. 30% of the lignin concentrate obtained from hypy.

This work shows the results of de investigations concerning Pt concentration in the environment of Mexico City, product of the impact of the use of catalytic converters in the urban area. This research was carried out by assessing Pt concentration in dust samples and PM2.5 collected in the metropolitan area of Mexico City. Dust samples were divided in “road dust” and “urban dust” according to vehicle traffic exposure. Pt concentration in road dust samples, exposed to high traffic density, range from 37.7 to 231 µg kg−1 (mean 112 µg kg−1), whereas Pt concentration found in urban dust, collected in areas with low traffic density, varied between 26.4 and 86.6 µg kg−1 (mean 57 µg kg−1). PM2.5 samples were collected in five sites of the urban area during three different seasons (dry-warm, rainy, dry-cold). Results do not show significant spatial or temporal variation. Pt concentration ranges from 1 to 79 pg m−3. The comparison of Pt concentration in dust and PM2.5 samples presented here, with data reported for other urban areas, as well as with data previously reported for PM10 collected in 1991 and 2003 for the metropolitan area of Mexico City, allows to conclude a significant increase of Pt in this urban environment.

Tree rings may be used as indicators of contamination events providing information on the chronology and the elemental composition of the contamination. In this framework, we report PGEs enrichment in growth rings of Taxodium mucronatum ten for trees growing in the central area of Mexico City as compared to trees growing in a non-urban environment. Concentrations of PGE were determined by ICP-MS analysis on microwave-digested tree rings. The element found in higher concentrations was Pd (1.13-87.98 μg kg(-1)), followed by Rh (0.28-36.81 μg kg(-1)) and Pt (0.106-7.21 μg kg(-1)). The concentration trends of PGEs in the tree-ring sequences from the urban area presented significant correlation values when comparing between trees (r between 0.618 and 0.98, P 0.025) and between elements within individual trees (r between 0.76 and 0.994, P 0.01). Furthermore, a clear increase was observed for rings after 1997, with enrichment of up to 60 times the mean concentration found for the sequence from the non-urban area and up to 40 times the mean concentration for the pre-1991 period in the urban trees. These results also demonstrate the feasibility of applying T. mucronatum ten to be used as a bioindicator of the increase in PGE in urban environments.

"El presente artículo describe los fundamentos de los sistemas para dataciones radiométricas de procesos geológicos y ambientales ocurridos en el Cuaternario tardío (

The radiocarbon variation for northwestern Mexico during the period 1950–2004 was studied by accelerator mass spectrometry (AMS) and liquid scintillation counting (LSC) analyses of tree rings. Two tree-ring sequences of Pseudotsuga menziesii, sampled in a site isolated from urban centers and active volcanoes (26.18°N, 106.3°W, 3000 m asl), were dendrochronologically dated and separated in annual rings prior to 14C analysis. Results obtained show a similar profile to the values reported for the Northern Hemisphere (NH), having significant correlation coefficients with the compilation curves for NH zone 2 (r = 0.987, p < 0.001) and NH zone 3 (r = 0.993, p < 0.001). The maximum peak is centered at 1964.5 with a δ14C value of 713.15 ± 9.3‰. The values obtained for the period 1958–1965 are lower than zone 2 values and higher than zone 3 values. For the period 1975–2004, the values obtained are higher than the NH compilation curve and other NH records. We attribute the first divergence to the North American monsoon that may have carried 14C-depleted air from the south during the summer months; the second divergence may be attributable to 14C-enriched biospheric CO2.