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Van der Waals ferromagnets are thrilling materials from both a fundamental and technological point of view. VI3 is an interesting example, with a complex magnetism that differentiates it from the first reported Cr based layered ferromagnets. Here, we show in an indirect way through angle resolved photoemission spectroscopy experiments, the importance of spin-orbit coupling setting the electronic properties of this material. Our light polarized photoemission measurements point to a ground state with a half-filled e ± ′ doublet, where a gap opening is triggered by spin-orbit coupling enhanced by electronic correlations.

Medical laboratory technicians (MLTs) play an essential role in health care, and the profession has to deal increasingly with staff shortages. Consequently, retention of employees has become a crucial issue. So far, little attention has been paid to generational differences in factors regarding job satisfaction of MLTs, and comparatively few studies have included the youngest cohort of Generation Z. The aim of this study was to analyse aspects of MLTs’ job satisfaction from a generational perspective and to identify potential for improvement according to the different generations studied.

The BaAl4 prototype crystal structure is the most populous of all structure types, and is the building block for a diverse set of sub-structures including the famous ThCr2Si2 family that hosts high-temperature superconductivity and numerous magnetic and strongly correlated electron systems. The MA4 family of materials (M = Sr, Ba, Eu; A = Al, Ga, In) themselves present an intriguing set of ground states including charge and spin orders, but have largely been considered as uninteresting metals. We predict the exemplary compound BaAl4 to harbor a three-dimensional Dirac spectrum with non-trivial topology and possible nodal lines crossing the Brillouin zone, wherein one pair of semi-Dirac points with linear dispersion along the kz direction and quadratic dispersion along the kx/ky direction resides on the rotational axis with C4v point group symmetry. An extremely large, unsaturating positive magnetoresistance in BaAl4 despite an uncompensated band structure is revealed, and quantum oscillations and angle-resolved photoemission spectroscopy measurements confirm the predicted multiband semimetal structure with pockets of Dirac holes and a Van Hove singularity (VHS) remarkably consistent with the theoretical prediction. We thus present BaAl4 as a topological semimetal, casting its prototype status into a role as a building block for a vast array of topological materials.

Spin orbit assisted Mott insulators such as sodium iridate (Na2IrO3) have been an important subject of study in recent years. In these materials, the interplay of electronic correlations, spin-orbit coupling, crystal field effects, and a honeycomb arrangement of ions bring exciting ground states, predicted in the frame of the Kitaev model. The insulating character of Na2IrO3 has hampered its integration to an electronic device, desirable for applications, such as the manipulation of quasiparticles interesting for topological quantum computing. Here we show through electronic transport measurements supported by angle-resolved photoemission spectroscopy (ARPES) experiments, that electronic transport in Na2IrO3 is ruled by variable range hopping and it is strongly dependent on the magnetic ordering transition known for bulk Na2IrO3, as well as on external electric fields. Electronic transport measurements allow us to deduce a value for the localization length and the density of states in our Na2IrO3 thin crystal devices, and offer an alternative approach to study insulating 2D-materials.

Recent direct experimental observation of multiple highly dispersive C60 valence bands has allowed for a detailed analysis of the unusual photoemission traits of these features through photon energy- and polarization-dependent measurements. Previously obscured dispersions and strong photoemission traits are now revealed by specific light polarizations. The observed intensity effects prove the locking in place of the C60 molecules at low temperatures and the existence of an orientational order imposed by the substrate chosen. Most importantly, photon energy- and polarization-dependent effects are shown to be intimately linked with the orbital character of the C60 band manifolds which allow for a more precise determination of the orbital character within the third highest occupied molecular orbital (HOMO-2). Our observations and analysis provide important considerations for the connection between molecular and crystalline C60 electronic structure, past and future band structure studies, and for increasingly popular C60 electronic device applications, especially those making use of heterostructures.

While long-theorized, the direct observation of multiple highly dispersive C60 valence bands has eluded researchers for more than two decades due to a variety of intrinsic and extrinsic factors. Here we report a realization of multiple highly dispersive (330-520 meV) valence bands in pure thin film C60 on a novel substrate - the three-dimensional topological insulator Bi2Se3 - through the use of angle-resolved photoemission spectroscopy (ARPES) and first-principles calculations. The effects of this novel substrate reducing C60 rotational disorder are discussed. Our results provide important considerations for past and future band structure studies as well as the increasingly popular C60 electronic device applications, especially those making use of heterostructures.

Molecular crystals are a flexible platform to induce novel electronic phases. Due to the weak forces between molecules, intermolecular distances can be varied over larger ranges than interatomic distances in atomic crystals. On the other hand, the hopping terms are generally small, which results in narrow bands, strong correlations, and heavy electrons. Here, by growing K_{x}C_{60} fullerides on hexagonal layered Bi_{2}Se_{3}, we show that upon doping the series undergoes a Mott transition from a molecular insulator to a correlated metal and an in-gap state evolves into highly dispersive Dirac-like fermions at half filling, where superconductivity occurs. This picture challenges the commonly accepted description of the low-energy quasiparticles as appearing from a gradual electron doping of the conduction states and suggests an intriguing parallel with the more famous family of the cuprate superconductors. More in general, it indicates that molecular crystals offer a viable route to engineer electron-electron interactions.

Abstract The BaAl4 prototype crystal structure is the most populous of all structure types, and is the building block for a diverse set of sub-structures including the famous ThCr2Si2 family that hosts high-temperature superconductivity and numerous magnetic and strongly correlated electron systems. The MA4 family of materials (M = Sr, Ba, Eu; A = Al, Ga, In) themselves present an intriguing set of ground states including charge and spin orders, but have largely been considered as uninteresting metals. We predict the exemplary compound BaAl4 to harbor a three-dimensional Dirac spectrum with non-trivial topology and possible nodal lines crossing the Brillouin zone, wherein one pair of semi-Dirac points with linear dispersion along the k z direction and quadratic dispersion along the k x /k y direction resides on the rotational axis with C 4v point group symmetry. An extremely large, unsaturating positive magnetoresistance in BaAl4 despite an uncompensated band structure is revealed, and quantum oscillations and angle-resolved photoemission spectroscopy measurements confirm the predicted multiband semimetal structure with pockets of Dirac holes and a Van Hove singularity (VHS) remarkably consistent with the theoretical prediction. We thus present BaAl4 as a topological semimetal, casting its prototype status into a role as a building block for a vast array of topological materials.

The purpose of the present article was to determine odour emission rate from primary settling tanks after hermetisation. The paper presents the results of the research on odour emission from four settling tanks, covered with self-supporting aluminium domes with a diameter of 52 meters, located on urban wastewater treatment plants, with the planned flow capacity equal to 200 000 m3/day. Altogether, the olfactometry analysis of 189 samples of polluted air pulled from the domes with the use of an air blower which has efficiency of 12 000 m3/h was conducted. The results of odour concentration measurements were in a range of approximately 10 800 to 763 600 ouE/m3. Average odour emission rate was equal to 102 ouE/(s · m2). The obtained value is much higher than the literature data, available for non-hermetised settlers only. This rate enables better estimation of the odour stream that has to be deodorised after sealing the settling tanks.

This work aimed to obtain hybrid composites based on photoactive metal oxide and carbon having adsorption properties. The materials, composed of titanium dioxide or zinc oxide and spherical carbon, were obtained from resorcinol-formaldehyde resin, treated in a solvothermal reactor heated with microwaves and then subjected to carbonization, were received. The functional groups of pure carbon spheres (unsaturated stretching C=C, stretching C−OH and C−H bending vibrations), CS/ZnO and CS/TiO2 samples were determined by FT-IR analysis. The characteristic bands for ZnO and TiO2 were observed below 1000 cm−1. The thermal oxidative properties are similar for TiO2- and ZnO-modified carbon spheres. We have observed that the increased carbon sphere content in nanocomposites results in starting the decomposition process at a lower temperature, therefore, nanocomposites have a broader combustion temperature range. The effect of the oxides’ addition to carbon spheres on their adsorption properties was evaluated in detail by examining CO2 adsorption from the gas phase. The selectivity of CO2 over N2 at a temperature of 25 °C and pressure of 1 bar (a novelty in testing CS-based sorbents) calculated for 3.00 CS/TiO2 and 4.00 CS/ZnO was 15.09 and 16.95, respectively. These nanocomposites exhibit excellent cyclic stability checked over 10 consecutive adsorption–desorption cycles.

Exposure of phosphatidylserine (PS) in the outer leaflet of the plasma membrane is induced by infection with several members of the Alphaherpesvirinae subfamily. There is evidence that PS is used by the equine herpesvirus type 1 (EHV-1) during entry, but the exact role of PS and other phospholipids in the entry process remains unknown. Here, we investigated the interaction of differently charged phospholipids with virus particles and determined their influence on infection. Our data show that liposomes containing negatively charged PS or positively charged DOTAP (N-[1-(2,3-Dioleoyloxy)propyl]-N,N,N-trimethylammonium) inhibited EHV-1 infection, while neutral phosphatidylcholine (PC) had no effect. Inhibition of infection with PS was transient, decreased with time, and was dose dependent. Our findings indicate that both cationic and anionic phospholipids can interact with the virus and reduce infectivity, while, presumably, acting through different mechanisms. Charged phospholipids were found to have antiviral effects and may be used to inhibit EHV-1 infection.

This article attempts exposure enterprise concept of intelligent and specify its characteristics. It identified three key features of the intelligent enterprise: learning, association and understanding. Detailed studies were characteristic of understanding. For this purpose, based on the results of empirical research conducted among students of the Faculty of Management and Economics Gdańsk University of Technology. Improving this feature enables enterprises to intelligently maintain a competitive edge.

The traditional approach to educating language minority students separates English language development from content instruction because it is assumed that English proficiency is a prerequisite for subject matter learning. Takes an alternative view that the integration of inquiry science and language acquisition enhances learning in both domains. (Contains 66 references.) (Author/YDS)

Background: Intrahospital patient transports (IHTs) in intensive care involve an appreciable risk of adverse events (AEs). Research on determinants of AE occurrence during IHT has hitherto focused on patient, transport, and intensive care unit (ICU) characteristics. By contrast, the role of Bsoft[ factors, although arguably relevant for IHTs and a topic of interest in general health care settings, has not yet been explored. Purpose: The study aims at examining the effect of safety climate and team processes on the occurrence of AE during IHT and whether team processes mediate the effect of safety climate. Methodology/Approach: Data stem from a noninterventional, observational multicenter study in 33 ICUs (from 12 European countries), with 858 transports overall recorded during 28 days. AEs include medication errors, dislodgments, equipment failures, and delays. Safety climate scales were taken from the BPatient Safety Climate in Healthcare Organizations[ (short version), team processes scales from the BLeiden Operating Theatre and Intensive Care Safety[ questionnaire. Patient condition was assessed with NEMS (Nine Equivalents of Nursing Manpower Use Score). All other variables could be directly observed. Hypothesis testing and assessment of effects rely on bivariate correlations and binomial logistic multilevel models (with ICU as random effect). Findings: Both safety climate and team processes are comparatively important determinants of AE occurrence, also when controlling for transport-, staff-, and ICU-related variables. Team processes partially mediate the effect of safety climate. Patient condition and transport duration are consistently related with AE occurrence, too. Practice Implications: Unlike most patient, transport, and ICU characteristics, safety climate and team processes are basically amenable to managerial interventions. Coupled with their considerable effect on AE occurrence, this makes pertinent endeavors a potentially promising approach for improving patient safety during IHT. Although literature suggests that safety climate is slow and hard to change (also compared to team processes), efforts to improve safety climate should not be forgone. [ABSTRACT FROM AUTHOR]

PURPOSE: The aim of this prospective study was to evaluate the clinical performance of anterior and posterior fixed partial dentures (FPDs) with frameworks made using DC-Zirkon after a mean observation time of 3 years. MATERIALS AND METHODS: Forty-six patients with 1 to 3 missing anterior or posterior teeth were included in this study. All abutment teeth were prepared for full crowns with a chamfer preparation of 0.6 to 0.8 mm. The zirconia frameworks were produced with the Precident DCS system and veneered with veneering porcelain (Vita D). A self-curing resin cement was used for the anterior FPDs and a conventional zinc oxide phosphate cement was used for the posterior FPDs. RESULTS: Fifteen anterior FPDs and 50 posterior FPDs were recalled at least once a year after cementation. The mean observation period was 38 (+/- 18.0) months for the anterior FPDs and 37 (+/- 15.5) months for the posterior FPDs. Within the observation time, no remakes were necessary, but in 4 cases a small chipping of the veneering material occurred in the posterior region. Two FPDs were recemented after decementation, and 3 teeth needed endodontic treatment. No negative influences at the gingival margin were observed. CONCLUSIONS: Within the mean observation time of 3 years, zirconia-based FPDs demonstrated a sufficient success rate under clinical conditions. However, special attention should be paid to designing the zirconia framework to ensure a sufficient veneering layer thickness with a range between 1 to 2 mm. [ABSTRACT FROM AUTHOR]

This study explores how refugees relocate, acquire, and convert cultural, social, and economic capital when entering the Austrian labor market. Drawing on Bourdieu's theory of practice, we conducted 35 semi-structured interviews with Afghan and Syrian refugee job seekers to investigate how the value of the capital forms changes when they move to a culturally distant field, and what strategies they use to develop their career capital portfolio. Findings reveal that (a) all capital forms are strongly devaluated; (b) refugees striving to use their cultural capital encounter unfamiliar labor market rules, occupational identity threats, and status loss; (c) acquisition and conversion of new capital require both the intricate interplay of capital forms and refugees' proactivity. The article concludes with a discussion of theoretical contributions and practical implications for refugee labor market integration. [ABSTRACT FROM AUTHOR]

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Background: Safety climate (SC) and more recently patient engagement (PE) have been identified as potential determinants of patient safety, but conceptual and empirical studies combining both are lacking. Purposes: On the basis of extant theories and concepts in safety research, this study investigates the effect of PE in conjunction with SC on perceived error occurrence (pEO) in hospitals, controlling for various staff-, patient-, and hospital-related variables as well as the amount of stress and (lack of) organizational support experienced by staff. Besides the main effects of PE and SC on error occurrence, their interaction is examined, too. Methodology/Approach: In 66 hospital units, 4,345 patients assessed the degree of PE, and 811 staff assessed SC and pEO. PE was measured with a new instrument, capturing its core elements according to a recent literature review: Information Provision (both active and passive) and Activation and Collaboration. SC and pEO were measured with validated German-language questionnaires. Besides standard regression and correlational analyses, partial least squares analysis was employed to model the main and interaction effects of PE and SC on pEO, also controlling for stress and (lack of) support perceived by staff, various staff and patient attributes, and potential single-source bias. Findings: Both PE and SC are associated with lower pEO, to a similar extent. The joint effect of these predictors suggests a substitution rather than mutually reinforcing interaction. Accounting for control variables and/or potential single-source bias slightly attenuates some effects without altering the results. Practice Implications: Ignoring PE potentially amounts to forgoing a potential source of additional safety. On the other hand, despite the abovementioned substitution effect and conjectures of SC being inert, PE should not be considered as a replacement for SC. [ABSTRACT FROM AUTHOR]

Analyzing the development of the consequences of voluntary job changes in Germany between 1985 and 2013, the study focuses on income gains and job satisfaction increases. Drawing on arguments of the job-search literature on the one hand and the proliferation of choices on the other we investigate whether the returns of job changes have increased or decreased. Results show that income gains have decreased over time while the job satisfaction surplus has remained stable. We further conclude that in determining the outcomes of job changes over time, structural factors seem to be more important than individual ones. [ABSTRACT FROM AUTHOR]

Electricity production costs and overall net efficiency of the system are determining factors regarding the quality and cost effectiveness of a solar tower power plant. These factors are strongly dependent on the quality of heliostats, the receiver and the thermal storage concept. This work describes the optimization of load states of a storage system through applying internal process control strategies for the air circuit of the Solar Tower Jülich which works with open volumetric air receiver technology. A concept for optimal operation of the thermal storage system was formulated and developed. Storage concepts include both technical adjustments of the existing storage system as well as the control process of the thermal storage. For simulating the optimized operating strategy of the power plant systems all main power plant components were modeled in MATLAB ® /Simulink ® and interconnected to form a complete system. The focus of the simulation lies in optimizing the operating strategy of a discretized thermal energy storage model. [ABSTRACT FROM AUTHOR]

In this work transient simulation results of a hybrid solar tower power plant with openvolumetric receiver technology are presented for several locations in China. The openvolumetric receiver uses ambient air as heat transfer fluid and the hybridization can be realized with additional firing. The solar receiver and/or the additional firing heat up the air which is then passed through a boiler of a conventional Rankine cycle. The simulated plantis based on the configuration of the solar thermal test and demonstration power plant located in Jülich (STJ). The investigatedplant operates in hybrid - parallelmode which allows a constant power generation. The meteorological data for the different sites in China was taken from the software Meteonorm in a time resolution of one hour. The solar tower power simulation tool was developed in the simulation environment MATLAB/Simulink. [ABSTRACT FROM AUTHOR]

Abstract: In this work the transient simulations of four hybrid solar tower power plant concepts with open-volumetric receiver technology for a location in Barstow-Daggett, USA, are presented. The open-volumetric receiver uses ambient air as heat transfer fluid and the hybridization is realized with a gas turbine. The Rankine cycle is heated by solar-heated air and/or by the gas turbine's flue gases. The plant can be operated in solar-only, hybrid parallel or combined cycle-only mode as well as in any intermediate load levels where the solar portion can vary between 0 to 100%. The simulated plant is based on the configuration of a solar-hybrid power tower project, which is in planning for a site in Northern Algeria. The meteorological data for Barstow-Daggett was taken from the software meteonorm. The solar power tower simulation tool has been developed in the simulation environment MATLAB/Simulink and is validated. [Copyright &y& Elsevier]

Abstract: By examining trends in intra-organizational and inter-organizational job transition probabilities among professional and managerial employees in Germany, we test the applicability of mainstream career theory to a specific context and challenge its implied change assumption. Drawing on data from the German Socio-Economic Panel (GSOEP), we apply linear probability models to show the influence of time, economic cycle and age on the probability of job transitions between 1984 and 2010. Results indicate a slight negative trend in the frequency of job transitions during the analyzed time span, owing to a pronounced decrease in intra-organizational transitions, which is only partly offset by a comparatively weaker positive trend towards increased inter-organizational transitions. The latter is strongly influenced by fluctuations in the economic cycle. Finally, the probability of job transitions keeps declining steadily through the course of one's working life. In contrast to inter-organizational transitions, however, this age effect for intra-organizational transitions has decreased over time. [Copyright &y& Elsevier]