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Ionized interstellar gas is an important component of the interstellar medium and its lifecycle. The recent evidence for a widely distributed highly ionized warm interstellar gas with a density intermediate between the warm ionized medium (WIM) and compact HII regions suggests that there is a major gap in our understanding of the interstellar gas. Here we investigate the properties of the dense warm ionized medium (D-WIM) in the Milky Way using spectrally resolved SOFIA GREAT [NII] 205 micron line emission and Green Bank Telescope hydrogen radio recombination lines (RRL) data, supplemented by Herschel PACS [NII] 122 micron data, and spectrally resolved 12CO. We observed eight lines of sight in the 20deg 50% of the observed [CII] intensity along these LOS. The kinetic temperatures we derive are too low to explain the presence of N+ resulting from electron collisional ionization and/or proton charge transfer of atomic nitrogen. Rather, these regions most likely are ionized by extreme ultraviolet radiation., Comment: 16 pages, 10 figures

Determining the properties of the warm ionized medium (WIM) at the leading edge of spiral arms is important for understanding its dynamics and cloud formation. The inner edge of the Scutum arm tangency is a unique location in which to disentangle the WIM from other components. We use high spectral resolution [C II] 158 micron and [N II] 205 micron fine structure line observations taken with the upGREAT and GREAT instruments on SOFIA, along with auxiliary HI and 13CO observations. The observations were in and out of the Galactic plane along 18 lines of sight between longitude 30deg and 32deg. We detect strong [N II] emission throughout the Scutum tangency. At VLSR = 110 to 125 km/s, where there is little, if any, 13CO, we could disentangle the [N II] and [C II] emission that arises from the WIM at the inner edge. We find an average electron density, about 0.9 cm{-3} in the plane, and about 0.4 cm{-3} above the plane. For VLSR < 110 km/s there is [N II] emission tracing highly ionized gas throughout the arm's molecular layer. This ionized gas has a high density, n(e) ~ 30 cm{-3}, and a few percent filling factor. Thus, [N II] and [C II] at the Scutum arm tangency reveal a highly ionized gas with about 10 to 20 times those of the interarm WIM, which is best explained by a model in which the interarm WIM is compressed as it falls into the potential well of the arm. The widespread distribution of [N II] in the molecular layers shows that high density ionized gas is distributed throughout the Scutum arm. The n(e) derived from [N II] for these molecular cloud regions are about 30 cm{-3}, and probably arise in the ionized boundary layers of clouds. This [N II] emission from the ionized boundary layers is probably the result of the shock compression of the WIM as it impacts the arm's neutral gas, but some could arise from extended HII regions., Comment: 12 pages, 9 figures

The Galactic Central Molecular Zone (CMZ) is a region containing massive and dense molecular clouds, with dynamics driven by a variety of energy sources including a massive black hole. It is thus the nearest template for understanding physical processes in extragalactic nuclei. The CMZ's neutral interstellar gas has been mapped spectrally in many neutral atomic and molecular gas tracers, but the ionized and CO-dark H2 regions are less well traced spectroscopically. We mapped the fine structure line of C+ at 158 microns, [C II], to identify and characterize features of the ionized gas in the CMZ, including UV irradiated neutral gas, photon dominated regions (PDRs), CO-dark H2 gas, and highly ionized gas. We observed the [C II] 158-micron fine structure line with high spectral resolution using Herschel HIFI with two perpendicular On-the-Fly strip scans, along l = -0.8 to +0.8 and b = -0.8 to +0.8, both centered on (l,b) = (0,0). We analyzed the spatial-velocity distribution of the [C II] data and compared them to those of [C I] and CO, and to dust continuum maps, in order to determine the properties and distribution of the UV irradiated gas and its dynamics within the CMZ. The longitude- and latitude-velocity maps of [C II] trace portions of the orbiting open gas streams of dense molecular clouds, the cloud G0.253+0.016, also known as the Brick, the Arched Filaments, and the ionized gas near Sgr A and Sgr B2. We use the [C II] and auxiliary data to determine the physical and dynamical properties of these CMZ features. The [C II] emission arises primarily from dense PDRs and highly ionized gas, and is an important tracer of the kinematics and physical conditions of this gas., Comment: 17 pages, 12 figures, A&A in press

The interstellar medium (ISM) consists of highly ionized and neutral atomic, as well as molecular, components. Knowledge of their distribution is important for tracing the structure and lifecycle of the ISM. Here we determine the properties of the highly ionized and neutral weakly ionized gas in the Galaxy traced by the fine-structure lines of ionized nitrogen, [N II], and ionized carbon, [C II]. To analyze the ionized ISM we utilize [C II] 158 micron and [N II] 205 micron lines taken with the high spectral resolution Heterodyne Instrument in the Far-Infrared (HIFI) on the Herschel Space Observatory along ten lines of sight towards the inner Galaxy. [N II] emission can be used to estimate the contribution of the highly ionized gas to the [C II] emission and separate the highly ionized and weakly ionized neutral gas. We find that [N II] has strong emission in distinct spectral features along all lines of sight associated with strong [C II] emission. The [N II] arises from moderate density extended HII regions or ionized boundary layers of clouds. Comparison of the [N II] and [C II] spectra in 31 separate kinematic features shows that many of the [C II] spectra are affected by absorption from low excitation gas associated with molecular clouds, sometimes strongly so. The apparent fraction of the [C II] associated with the [N II] gas is unrealistically large in many cases, most likely due to the reduction of [C II] by absorption. In a few cases the foreground absorption can be modeled to determine the true source intensity. In these sources we find that the foreground absorbing gas layer has C$^+$ column densities of order 10$^{18}$ cm$^{-2}$. [C II] emission arising from strong sources of [N II] emission is frequently absorbed by low excitation foreground gas complicating the interpretation of the properties of the ionized and neutral gas components that give rise to [C II] emission., Comment: 11 pages, 6 figures

The spiral arm tangencies are ideal lines of sight in which to determine the distribution of interstellar gas components in the spiral arms and study the influence of spiral density waves on the interarm gas in the Milky Way. We present a large scale (~15deg) position-velocity map of the Galactic plane in [CII] from l = 326.6 to 341.4deg observed with Herschel HIFI. We use [CII] l-v maps along with those for Hi and 12CO to derive the average spectral line intensity profiles over the longitudinal range of each tangency. Using the VLSR of the emission features, we locate the [CII], HI, and 12CO emissions along a cross cut of the spiral arm. In the spectral line profiles at the tangencies [CII] has two emission peaks, one associated with the compressed WIM and the other the molecular gas PDRs. When represented as a cut across the inner to outer edge of the spiral arm, the [CII]-WIM peak appears closest to the inner edge while 12CO and [CII] associated with molecular gas are at the outermost edge. HI has broader emission with an intermediate peak located nearer to that of 12CO. The velocity resolved spectral line data of the spiral arm tangencies unravel the internal structure in the arms locating the emission lanes within them. We interpret the excess [CII] near the tangent velocities as shock compression of the WIM induced by the spiral density waves and as the innermost edge of spiral arms. For the Norma and Perseus arms, we estimate widths of ~250 pc in [CII]-WIM and ~400 pc in 12CO and overall spiral arm widths of ~500 pc in [CII] and 12CO emissions. The electron densities in the WIM are ~ 0.5 cm^-3, about an order of magnitude higher than the average for the disk. The enhanced electron density in the WIM is a result of compression of the WIM by the spiral density wave potential., Comment: 12 pages; 11 figures

To determine the properties of the ionized gas at the edge of the CMZ near Sgr E we observed a small portion of the edge of the CMZ near Sgr E with spectrally resolved [C II] 158 micron and [N II] 205 micron fine structure lines at six positions with the GREAT instrument on SOFIA and in [C II] using Herschel HIFI on-the-fly strip maps. We use the [N II] spectra along with a radiative transfer model to calculate the electron density of the gas and the [C II] maps to illuminate the morphology of the ionized gas and model the column density of CO-dark H2. We detect two [C II] and [N II] velocity components, one along the line of sight to a CO molecular cloud at -207 km/s associated with Sgr E and the other at -174 km/s outside the edge of another CO cloud. From the [N II] emission we find that the average electron density is in the range of about 5 to 25 cm{-3} for these features. This electron density is much higher than that of the warm ionized medium in the disk. The column density of the CO-dark H$_2$ layer in the -207 km/s cloud is about 1-2X10{21} cm{-2} in agreement with theoretical models. The CMZ extends further out in Galactic radius by 7 to 14 pc in ionized gas than it does in molecular gas traced by CO. The edge of the CMZ likely contains dense hot ionized gas surrounding the neutral molecular material. The high fractional abundance of N+ and high electron density require an intense EUV field with a photon flux of order 1e6 to 1e7 photons cm{-2} s{-1}, and/or efficient proton charge exchange with nitrogen, at temperatures of order 1e4 K, and/or a large flux of X-rays. Sgr E is a region of massive star formation which are a potential sources of the EUV radiation that can ionize the gas. In addition X-ray sources and the diffuse X-ray emission in the CMZ are candidates for ionizing nitrogen., Comment: 12 pages, 9 figures

We determine the source of the diffuse [CII] emission by studying its spatial (radial and vertical) distributions. We used the HIFI [CII] Galactic survey (GOT C+), along with HI, 12CO, and 13CO data toward 354 lines of sight, and several HIFI [CII] and [CI] position-velocity maps. We quantified the emission in each spectral line profile by evaluating the intensities in 3 km/s wide velocity bins, 'spaxels'. Using the detection of [CII] with CO or [CI], we separated the dense and diffuse gas components. We derived 2-D Galactic disk maps using the spaxel velocities for kinematic distances. We separated the warm and cold H2 gases by comparing CO emissions with and without associated [CII]. We find evidence of widespread diffuse [CII] emission with a z-scale distribution larger than that for the total [CII] or CO. and it consists of (i) diffuse molecular (CO-faint) H2 clouds and (ii) diffuse HI clouds and/or WIM. In the inner Galaxy we find a lack of [CII] detections in a majority (~62%) of HI spaxels and show that the diffuse component primarily comes from the WIM (~21%) and that the HI gas is not a major contributor to the diffuse component (~6%). The warm-H2 radial profile shows an excess in the range 4 to 7 kpc, consistent with enhanced star formation there. We derive, for the first time, the 2-D [CII] spatial distribution in the plane and the z-distributions of the individual [CII] gas component. We estimate the fractional [CII] emission tracing (i) H2 gas in dense and diffuse molecular clouds as ~48% and ~ 14%, respectively, (ii) in the HI gas ~18%, and (iii) in the WIM ~21%. Including non-detections from HI increases the [CII] in HI to ~ 27%. The z-scale distributions FWHM are [CII] sources with CO, ~130 pc, (CO-faint) diffuse H2 gas, ~200 pc, and the diffuse HI and WIM, ~330 pc. CO observations, when combined with [CII], probe the warm-H2 gas, tracing star formation., Comment: 20 pages, 15 figures, 4 tables

The distribution of various interstellar gas components and the pressure in the interstellar medium (ISM) is a result of the interplay of different dynamical mechanisms and energy sources on the gas in the Milky Way. The scale heights of the different gas tracers, such as HI and CO, are a measure of these processes. The scale height of [CII] emission in the Galactic plane is important for understanding those ISM components not traced by CO or HI. We determine the average distribution of [CII] perpendicular to the plane in the inner Galactic disk and compare it to the distributions of other key gas tracers, such as CO and HI. We calculated the vertical, z, distribution of [CII] in the inner Galactic disk by adopting a model for the emission that combines the latitudinal, b, spectrally unresolved BICE survey, with the spectrally resolved $Herschel$ Galactic plane survey of [CII] at b = 0 deg. Our model assumed a Gaussian emissivity distribution vertical to the plane, and related the distribution in z to that of the latitude b using the spectrally resolved [CII] Herschel survey as the boundary solution for the emissivity at b=0 deg. We find that the distribution of [CII] perpendicular to the plane has a full-width half-maximum of 172 pc, larger than that of CO, which averages ~110 pc in the inner Galaxy, but smaller than that of HI, ~230 pc, and is offset by -28 pc. We explain the difference in distributions of [CII], CO, and HI as due to [CII] tracing a mix of ISM components. Models of hydrostatic equilibrium of clouds in the disk predict different scale heights, for the same interstellar pressure. The diffuse molecular clouds with [CII] but no CO emission likely have a scale height intermediate between the low density atomic hydrogen HI clouds and the dense CO molecular clouds., Comment: 7 pages, 5 figures, accepted for publication in A&A

ABRIDGED: Context: HI and CO large scale surveys of the Milky Way trace the diffuse atomic clouds and the dense shielded regions of molecular hydrogen clouds. However, until recently, we have not had spectrally resolved C+ surveys to characterize the photon dominated interstellar medium, including, the H2 gas without C, the CO-dark H2, in a large sample of clouds. Aims: To use a sparse Galactic plane survey of the 1.9 THz [C II] spectral line from the Herschel Open Time Key Programme, Galactic Observations of Terahertz C+ (GOT C+), to characterize the H2 gas without CO in a statistically significant sample of clouds. Methods: We identify individual clouds in the inner Galaxy by fitting [CII] and CO isotopologue spectra along each line of sight. We combine these with HI spectra, along with excitation models and cloud models of C+, to determine the column densities and fractional mass of CO-dark H2 clouds. Results: We identify 1804 narrow velocity [CII] interstellar cloud components in different categories. About 840 are diffuse molecular clouds with no CO, 510 are transition clouds containing [CII] and 12CO, but no 13CO, and the remainder are dense molecular clouds containing 13CO emission. The CO-dark H2 clouds are concentrated between Galactic radii 3.5 to 7.5 kpc and the column density of the CO-dark H2 layer varies significantly from cloud-to-cloud with an average 9X10^(20) cm-2. These clouds contain a significant fraction of CO-dark H2 mass, varying from ~75% for diffuse molecular clouds to ~20% for dense molecular clouds. Conclusions: We find a significant fraction of the warm molecular ISM gas is invisible in HI and CO, but is detected in [CII]. The fraction of CO-dark H2 is greatest in the diffuse clouds and decreases with increasing total column density, and is lowest in the massive clouds., Comment: 21 pages, 19 figures, accepted for publication in A&A (2014)

To study the role of protosellar jets and outflows in the time evolution of the parent cores and the protostars, the astronomical community needs a large enough data base of infrared images of protostars at the highest spatial resolution possible, to reveal the details of their morphology. Spitzer provides unprecedented sensitivity in the infrared to study both the jet and outflow features, however its spatial resolution is limited by its 0.85m mirror. Here we use a high resolution deconvolution algorithm, "HiRes", to improve the visualization of spatial morphology by enhancing resolution (to sub-arcsecond levels in the IRAC bands) and removing the contaminating sidelobes from bright sources in a sample of 89 protostellar objects. These reprocessed images are useful to detect: (i) wide angle outflow seen in scattered light; (ii) morphological details of H2 emission in jets and bow shocks; and (iii) compact features in MIPS 24 micron images as protostar/ disk and atomic/ionic line emissions associated with the jets. The HiRes fits image data of such a large homogeneous sample presented here will be useful to the community in studying these protostellar objects. To illustrate the utility of this HiRes sample, we show how the opening angle of the wide angle outflows in 31 sources, all observed in the HiRes processed Spitzer images, correlates with age. Our data suggest a power law fit to opening angle versus age with an exponent of ~0.32 and 0.02, respectively for ages less than 8000 yr and greater than 8000 yr., Comment: To appear in ApJ: January 20, 2014, V781-1. 30 pages; 7 figures; Note the on line only FIGURE SET 3 containing a total of 53 figures will appear in ApJ electronic edition

HIFI GOT C+ Galactic plane [CII] spectral survey has detected strong emission at the spiral arm tangencies. We use the unique viewing geometry of the Scutum-Crux (S-C) tangency near i = 30degs to detect the warm ionized medium (WIM) component traced by [CII] and to study the effects of spiral density waves on Interstellar Medium (ISM) gas. We compare [CII] velocity features with ancillary HI, 12CO and 13CO data near tangent velocities at each longitude to separate the cold neutral medium and the warm neutral + ionized components in the S-C tangency, then we identify [CII] emission at the highest velocities without any contribution from 12CO clouds, as WIM. We present the GOT C+ results for the S-C tangency. We interpret the diffuse and extended excess [CII] emission at and above the tangent velocities as arising in the electron-dominated warm ionized gas in the WIM. We derive an electron density in the range of 0.2 - 0.9 cm^-3 at each longitude, a factor of several higher than the average value from Halpha and pulsar dispersion. We interpret the excess [CII] in S-C tangency as shock compression of the WIM induced by the spiral density waves., Comment: 5 pages, 3 figures and 1 Table

In some protostellar objects both wide angle outflows and collimated jets are seen, while in others only one is observed. Spitzer provides unprecedented sensitivity in the infrared to study both the jet and outflow features. Here, we use HiRes deconvolution to improve the visualization of spatial morphology by enhancing resolution (to sub-arcsecond levels in the IRAC bands) and removing the contaminating sidelobes from bright sources. We apply this approach to study the jet and outflow features in Cep E a young, energetic Class 0 protostar. In the reprocessed images we detect: (i) wide angle outflow seen in scattered light; (ii) morphological details on at least 29 jet driven bow shocks and jet heads or knots; (iii) three compact features in 24 micron continuum image as atomic/ionic line emission coincident with the jet heads; and, (iv) a flattened 35 arcsec size protostellar envelope seen against the interstellar background PAH emission as an absorption band across the protostar at 8 micron. By separating the protostellar photospheric scattered emission in the wide angle cavity from the jet emission we show that we can study directly the scattered light spectrum. We present the H2 emission line spectra, as observed in all IRAC bands, for 29 knots in the jets and bowshocks and use them in the IRAC color -- color space as a diagnostic of the thermal gas in the shocks driven by the jets. The data presented here will enable detailed modeling of the individual shocks retracing the history of the episodic jet activity and the associated accretion on to the protostar. The Spitzer data analysis presented here shows the richness of its archive as a resource to study the jet/outflow features in H2 and scattered light in a large homogeneous sample., Comment: 23 pages, 10 figures

We have examined methanol emission from Orion KL with of the {\em Herschel}/HIFI instrument, and detected two methanol bands centered at 524 GHz and 1061 GHz. The 524 GHz methanol band (observed in HIFI band 1a) is dominated by the isolated $\Delta$J$=$0, K$=-4\rightarrow$-3, v$_t$$=$0 Q branch, and includes 25 E-type and 2 A-type transitions. The 1061 GHz methanol band (observed in HIFI band 4b) is dominated by the $\Delta$J$=$0, K$=7\rightarrow$6, v$_t$$=$0 Q branch transitions which are mostly blended. We have used the isolated E-type v$_t$$=$0 methanol transitions to explore the physical conditions in the molecular gas. With HIFI's high velocity resolution, the methanol emission contributed by different spatial components along the line of sight toward Orion KL (hot core, low velocity flow, and compact ridge) can be distinguished and studied separately. The isolated transitions detected in these bands cover a broad energy range (upper state energy ranging from 80 K to 900 K), which provides a unique probe of the thermal structure in each spatial component. The observations further show that the compact ridge is externally heated. These observations demonstrate the power of methanol lines as probes of the physical conditions in warm regions in close proximity to young stars., Comment: 8 pages, 9 figures, accepted for publication in Astronomy & Astrophysics

We report observations of the reactive molecular ions OH$^+$, H$_2$O$^+$, and H$_3$O$^+$ towards Orion KL with Herschel/HIFI. All three $N=1-0$ fine-structure transitions of OH$^+$ at 909, 971, and 1033GHz and both fine-structure components of the doublet {\it ortho}-H$_2$O$^+$ $1_{11}-0_{00}$ transition at 1115 and 1139GHz were detected; an upper limit was obtained for H$_3$O$^+$. OH$^+$ and H$_2$O$^+$ are observed purely in absorption, showing a narrow component at the source velocity of 9 kms$^{-1}$, and a broad blueshifted absorption similar to that reported recently for HF and {\it para}-H$_{2}^{18}$O, and attributed to the low velocity outflow of Orion KL. We estimate column densities of OH$^+$ and H$_2$O$^+$ for the 9 km s$^{-1}$ component of $9 \pm 3 \times 10^{12}$cm$^{-2}$ and $7 \pm 2 \times 10^{12}$cm$^{-2}$, and those in the outflow of $1.9 \pm 0.7 \times 10^{13}$cm$^{-2}$ and $1.0 \pm 0.3 \times 10^{13}$cm$^{-2}$. Upper limits of $2.4\times 10^{12}$cm$^{-2}$ and $8.7\times 10^{12}$cm$^{-2}$ were derived for the column densities of {\it ortho} and {\it para}-H$_3$O$^+$ from transitions near 985 and 1657GHz. The column densities of the three ions are up to an order of magnitude lower than those obtained from recent observations of W31C and W49N. The comparatively low column densities may be explained by a higher gas density despite the assumption of a very high ionization rate., Comment: 5 pages, 1 figure. Accepted to and to be published in the Herschel HIFI special issue of A\&A Letters

In contrast with numerous studies on the physical and chemical structure of low- and high-mass protostars, much less is known about their intermediate-mass counterparts, a class of objects that could help to elucidate the mechanisms of star formation on both ends of the mass range. We present the first results from a rich HIFI spectral dataset on an intermediate-mass protostar, OMC2-FIR4, obtained in the CHESS (Chemical HErschel SurveyS of star forming regions) key programme. The more than 100 methanol lines detected between 554 and 961 GHz cover a range in upper level energy of 40 to 540 K. Our physical interpretation focusses on the hot core, but likely the cold envelope and shocked regions also play a role in reality, because an analysis of the line profiles suggests the presence of multiple emission components. An upper limit of 10^-6 is placed on the methanol abundance in the hot core, using a population diagram, large-scale source model and other considerations. This value is consistent with abundances previously seen in low-mass hot cores. Furthermore, the highest energy lines at the highest frequencies display asymmetric profiles, which may arise from infall around the hot core., Comment: 2 figures, accepted for publication in the A&A Herschel-HIFI special issue

We report the detection of more than 48 velocity-resolved ground rotational state transitions of H2(16)O, H2(18)O, and H2(17)O - most for the first time - in both emission and absorption toward Orion KL using Herschel/HIFI. We show that a simple fit, constrained to match the known emission and absorption components along the line of sight, is in excellent agreement with the spectral profiles of all the water lines. Using the measured H2(18)O line fluxes, which are less affected by line opacity than their H2(16)O counterparts, and an escape probability method, the column densities of H2(18)O associated with each emission component are derived. We infer total water abundances of 7.4E-5, 1.0E-5, and 1.6E-5 for the plateau, hot core, and extended warm gas, respectively. In the case of the plateau, this value is consistent with previous measures of the Orion-KL water abundance as well as those of other molecular outflows. In the case of the hot core and extended warm gas, these values are somewhat higher than water abundances derived for other quiescent clouds, suggesting that these regions are likely experiencing enhanced water-ice sublimation from (and reduced freeze-out onto) grain surfaces due to the warmer dust in these sources., Comment: 5 pages, 2 figures

To investigate the accretion and feedback processes in massive star formation, we analyze the shapes of emission lines from hot molecular cores, whose asymmetries trace infall and expansion motions. The high-mass star forming region SgrB2(M) was observed with Herschel/HIFI (HEXOS key project) in various lines of HCN and its isotopologues, complemented by APEX data. The observations are compared to spherically symmetric, centrally heated models with density power-law gradient and different velocity fields (infall or infall+expansion), using the radiative transfer code RATRAN. The HCN line profiles are asymmetric, with the emission peak shifting from blue to red with increasing J and decreasing line opacity (HCN to H$^{13}$CN). This is most evident in the HCN 12--11 line at 1062 GHz. These line shapes are reproduced by a model whose velocity field changes from infall in the outer part to expansion in the inner part. The qualitative reproduction of the HCN lines suggests that infall dominates in the colder, outer regions, but expansion dominates in the warmer, inner regions. We are thus witnessing the onset of feedback in massive star formation, starting to reverse the infall and finally disrupting the whole molecular cloud. To obtain our result, the THz lines uniquely covered by HIFI were critically important., Comment: A&A, HIFI special issue, accepted

Observations of HDO are an important complement for studies of water, because they give strong constraints on the formation processes -- grain surfaces versus energetic process in the gas phase, e.g. in shocks. The HIFI observations of multiple transitions of HDO in Sgr~B2(M) presented here allow the determination of the HDO abundance throughout the envelope, which has not been possible before with ground-based observations only. The abundance structure has been modeled with the spherical Monte Carlo radiative transfer code RATRAN, which also takes radiative pumping by continuum emission from dust into account. The modeling reveals that the abundance of HDO rises steeply with temperature from a low abundance ($2.5\times 10^{-11}$) in the outer envelope at temperatures below 100~K through a medium abundance ($1.5\times 10^{-9}$) in the inner envelope/outer core, at temperatures between 100 and 200~K, and finally a high abundance ($3.5\times 10^{-9}$) at temperatures above 200~K in the hot core., Comment: A&A HIFI special issue, accepted

In the past decade, much progress has been made in characterising the processes leading to the enhanced deuterium fractionation observed in the ISM and in particular in the cold, dense parts of star forming regions such as protostellar envelopes. Very high molecular D/H ratios have been found for saturated molecules and ions. However, little is known about the deuterium fractionation in radicals, even though simple radicals often represent an intermediate stage in the formation of more complex, saturated molecules. The imidogen radical NH is such an intermediate species for the ammonia synthesis in the gas phase. Herschel/HIFI represents a unique opportunity to study the deuteration and formation mechanisms of such species, which are not observable from the ground. We searched here for the deuterated radical ND in order to determine the deuterium fractionation of imidogen and constrain the deuteration mechanism of this species. We observed the solar-mass Class 0 protostar IRAS16293-2422 with the heterodyne instrument HIFI as part of the Herschel key programme CHESS (Chemical HErschel Surveys of Star forming regions). The deuterated form of the imidogen radical ND was detected and securely identified with 2 hyperfine component groups of its fundamental transition in absorption against the continuum background emitted from the nascent protostar. The 3 groups of hyperfine components of its hydrogenated counterpart NH were also detected in absorption. We derive a very high deuterium fractionation with an [ND]/[NH] ratio of between 30 and 100%. The deuterium fractionation of imidogen is of the same order of magnitude as that in other molecules, which suggests that an efficient deuterium fractionation mechanism is at play. We discuss two possible formation pathways for ND, by means of either the reaction of N+ with HD, or deuteron/proton exchange with NH., Comment: Accepted; To appear in A&A Herschel/HIFI Special Issue

We present the first high spectral resolution observations of Orion KL in the frequency ranges 1573.4 - 1702.8 GHz (band 6b) and 1788.4 - 1906.8 GHz (band 7b) obtained using the HIFI instrument on board the Herschel Space Observatory. We characterize the main emission lines found in the spectrum, which primarily arise from a range of components associated with Orion KL including the hot core, but also see widespread emission from components associated with molecular outflows traced by H2O, SO2, and OH. We find that the density of observed emission lines is significantly diminished in these bands compared to lower frequency Herschel/HIFI bands., Comment: Accepted for publication in the Herschel HIFI special issue of Astronomy and Astrophysics Letters, 5 pages, 3 figures

Despite the low elemental deuterium abundance in the Galaxy, enhanced molecular D/H ratios have been found in the environments of low-mass star forming regions, and in particular the Class 0 protostar IRAS 16293-2422. The CHESS (Chemical HErschel Surveys of Star forming regions) Key Program aims at studying the molecular complexity of the interstellar medium. The high sensitivity and spectral resolution of the HIFI instrument provide a unique opportunity to observe the fundamental 1,1,1 - 0,0,0 transition of the ortho-D2O molecule, inaccessible from the ground, and to determine the ortho-to-para D2O ratio. We have detected the fundamental transition of the ortho-D2O molecule at 607.35 GHz towards IRAS 16293-2422. The line is seen in absorption with a line opacity of 0.62 +/- 0.11 (1 sigma). From the previous ground-based observations of the fundamental 1,1,0 - 1,0,1 transition of para-D2O seen in absorption at 316.80 GHz we estimate a line opacity of 0.26 +/- 0.05 (1 sigma). We show that the observed absorption is caused by the cold gas in the envelope of the protostar. Using these new observations, we estimate for the first time the ortho to para D2O ratio to be lower than 2.6 at a 3 sigma level of uncertainty, to be compared with the thermal equilibrium value of 2:1., Comment: 5 pages, 5 figures, accepted the A&A HIFI Special Issue as a letter

We present observations of twelve rotational transitions of H2O-16, H2O-18, and H2O-17 toward the massive star-forming region NGC 6334 I, carried out with Herschel/HIFI as part of the guaranteed time key program Chemical HErschel Surveys of Star forming regions (CHESS). We analyze these observations to obtain insights into physical processes in this region. We identify three main gas components (hot core, cold foreground, and outflow) in NGC 6334 I and derive the physical conditions in these components. The hot core, identified by the emission in highly excited lines, shows a high excitation temperature of 200 K, whereas water in the foreground component is predominantly in the ortho- and para- ground states. The abundance of water varies between 4 10^-5 (outflow) and 10^-8 (cold foreground gas). This variation is most likely due to the freeze-out of water molecules onto dust grains. The H2O-18/H2O-17 abundance ratio is 3.2, which is consistent with the O-18/O-17 ratio determined from CO isotopologues. The ortho/para ratio in water appears to be relatively low 1.6(1) in the cold, quiescent gas, but close to the equilibrium value of three in the warmer outflow material (2.5(0.8))., Comment: 7 pages, 3 figures, accepted by A&A

We present the first results on the diffuse transition clouds observed in [CII] line emission at 158 microns (1.9 THz) towards Galactic longitudes near 340deg (5 LOSs) and 20deg (11 LOSs) as part of the GOT C+ survey. Out of the total 146 [CII] velocity components detected by profile fitting we identify 53 as diffuse molecular clouds with associated $^{12}$CO emission but without $^{13}$CO emission and characterized by A$_V$ < 5 mag. We estimate the fraction of the [CII] emission in the diffuse HI layer in each cloud and then determine the [CII] emitted from the molecular layers in the cloud. We show that the excess [CII] intensities detected in a few clouds is indicative of a thick H$_2$ layer around the CO core. The wide range of clouds in our sample with thin to thick H$_2$ layers suggests that these are at various evolutionary states characterized by the formation of H$_2$ and CO layers from HI and C$^+$, respectively. In about 30% of the clouds the H$_2$ column densities (''dark gas'') traced by the [CII] is 50% or more than that traced by $^{12}$CO emission. On the average about 25% of the total H$_2$ in these clouds is in an H$_2$ layer which is not traced by CO. We use the HI, [CII], and $^{12}$CO intensities in each cloud along with simple chemical models to obtain constraints on the FUV fields and cosmic ray ionization rates., Comment: To be published in HIFI A&A special edition

We present the first results of the Herschel open time key program, Galactic Observations of Terahertz C$^+$ (GOT C+) survey of the [CII] fine-structure line at 1.9 THz (158 microns) using the HIFI instrument on Herschel. We detected 146 interstellar clouds along sixteen lines-of-sight towards the inner Galaxy. We also acquired HI and CO isotopologue data along each line-of-sight for analysis of the physical conditions in these clouds. Here we analyze 29 diffuse clouds (A$_{V}$ < 1.3 mag.) in this sample characterized by having [CII] and HI emission, but no detectable CO. We find that [CII] emission is generally stronger than expected for diffuse atomic clouds, and in a number of sources is much stronger than anticipated based on their HI column density. We show that excess [CII] emission in these clouds is best explained by the presence of a significant diffuse warm H$_2$, dark gas, component. This first [CII] 158 micron detection of warm dark gas demonstrates the value of this tracer for mapping this gas throughout the Milky Way and in galaxies., Comment: To be published in A&A HIFI Special Edition

We present initial results from the Herschel GT key program: Herschel observations of EXtra-Ordinary Sources (HEXOS) and outline the promise and potential of spectral surveys with Herschel/HIFI. The HIFI instrument offers unprecedented sensitivity, as well as continuous spectral coverage across the gaps imposed by the atmosphere, opening up a largely unexplored wavelength regime to high-resolution spectroscopy. We show the spectrum of Orion KL between 480 and 560 GHz and from 1.06 to 1.115 THz. From these data, we confirm that HIFI separately measures the dust continuum and spectrally resolves emission lines in Orion KL. Based on this capability we demonstrate that the line contribution to the broad-band continuum in this molecule-rich source is ~20-40% below 1 THz and declines to a few percent at higher frequencies. We also tentatively identify multiple transitions of HD18O in the spectra. The first detection of this rare isotopologue in the interstellar medium suggests that HDO emission is optically thick in the Orion hot core with HDO/H2O ~ 0.02. We discuss the implications of this detection for the water D/H ratio in hot cores., Comment: 6 pages, 5 figures, accepted and to be published in Herschel HIFI special issue of A&A Letters

We report a detection of the fundamental rotational transition of hydrogen fluoride in absorption towards Orion KL using Herschel/HIFI. After the removal of contaminating features associated with common molecules ("weeds"), the HF spectrum shows a P-Cygni profile, with weak redshifted emission and strong blue-shifted absorption, associated with the low-velocity molecular outflow. We derive an estimate of 2.9 x 10^13 cm^-2 for the HF column density responsible for the broad absorption component. Using our best estimate of the H2 column density within the low-velocity molecular outflow, we obtain a lower limit of ~1.6 x 10^-10 for the HF abundance relative to hydrogen nuclei, corresponding to 0.6% of the solar abundance of fluorine. This value is close to that inferred from previous ISO observations of HF J=2--1 absorption towards Sgr B2, but is in sharp contrast to the lower limit of 6 x 10^-9 derived by Neufeld et al. (2010) for cold, foreground clouds on the line of sight towards G10.6-0.4., Comment: 5 pages, 3 figures, paper to be published in the Herschel special issue of A&A letters

We have observed CH absorption lines ($J=3/2, N=1 \leftarrow J=1/2, N=1$) against the continuum source Sgr~B2(M) using the \textit{Herschel}/HIFI instrument. With the high spectral resolution and wide velocity coverage provided by HIFI, 31 CH absorption features with different radial velocities and line widths are detected and identified. The narrower line width and lower column density clouds show `spiral arm' cloud characteristics, while the absorption component with the broadest line width and highest column density corresponds to the gas from the Sgr~B2 envelope. The observations show that each `spiral arm' harbors multiple velocity components, indicating that the clouds are not uniform and that they have internal structure. This line-of-sight through almost the entire Galaxy offers unique possibilities to study the basic chemistry of simple molecules in diffuse clouds, as a variety of different cloud classes are sampled simultaneously. We find that the linear relationship between CH and H$_2$ column densities found at lower $A_V$ by UV observations does not continue into the range of higher visual extinction. There, the curve flattens, which probably means that CH is depleted in the denser cores of these clouds., Comment: Accepted for publication in A&A, HIFI Special Issue

In contrast to extensively studied dense star-forming cores, little is known about diffuse gas surrounding star-forming regions. We study molecular gas in the high-mass star-forming region NGC6334I, which contains diffuse, quiescent components that are inconspicuous in widely used molecular tracers such as CO. We present Herschel/HIFI observations of CH toward NGC6334I observed as part of the CHESS key program. HIFI resolves the hyperfine components of its J=3/2-1/2 transition, observed in both emission and absorption. The CH emission appears close to the systemic velocity of NGC6334I, while its measured linewidth of 3 km/s is smaller than previously observed in dense gas tracers such as NH3 and SiO. The CH abundance in the hot core is 7 10^-11, two to three orders of magnitude lower than in diffuse clouds. While other studies find distinct outflows in, e.g., CO and H2O toward NGC6334I, we do not detect outflow signatures in CH. To explain the absorption signatures, at least two absorbing components are needed at -3.0 and +6.5 km/s with N(CH)=7 10^13 and 3 10^13 cm^-2. Two additional absorbing clouds are found at +8.0 and 0.0 km/s, both with N(CH)=2 10^13 cm^-2. Turbulent linewidths for the four absorption components vary between 1.5 and 5.0 km/s in FWHM. We constrain physical properties of our CH clouds by matching our CH absorbers with other absorption signatures. In the hot core, molecules such as H2O and CO trace gas that is heated and dynamically influenced by outflow activity, whereas CH traces more quiescent material. The four CH absorbers have column densities and turbulent properties consistent with diffuse clouds: two are located near NGC6334, and two are unrelated foreground clouds. Local density and dynamical effects influence the chemical composition of physical components of NGC6334, causing some components to be seen in CH but not in other tracers, and vice versa., Comment: Accepted by A&A Letters; 5 pages, 1 figure; v2: minor textual and typographical changes

We report the first detection of chloronium, H$_2$Cl$^+$, in the interstellar medium, using the HIFI instrument aboard the \emph{Herschel} Space Observatory. The $2_{12}-1_{01}$ lines of ortho-H$_2^{35}$Cl$^+$ and ortho-H$_2^{37}$Cl$^+$ are detected in absorption towards NGC~6334I, and the $1_{11}-0_{00}$ transition of para-H$_2^{35}$Cl$^+$ is detected in absorption towards NGC~6334I and Sgr~B2(S). The H$_2$Cl$^+$ column densities are compared to those of the chemically-related species HCl. The derived HCl/H$_2$Cl$^+$ column density ratios, $\sim$1--10, are within the range predicted by models of diffuse and dense Photon Dominated Regions (PDRs). However, the observed H$_2$Cl$^+$ column densities, in excess of $10^{13}$~cm$^{-2}$, are significantly higher than the model predictions. Our observations demonstrate the outstanding spectroscopic capabilities of HIFI for detecting new interstellar molecules and providing key constraints for astrochemical models., Comment: Accepted for publication in A&A, HIFI Special Issue; 4 pages, 2 figures, 1 table

H2O+ has been observed in its ortho- and para- states toward the massive star forming core Sgr B2(M), located close to the Galactic center. The observations show absorption in all spiral arm clouds between the Sun and Sgr B2. The average o/p ratio of H2O+ in most velocity intervals is 4.8, which corresponds to a nuclear spin temperature of 21 K. The relationship of this spin temperature to the formation temperature and current physical temperature of the gas hosting H2O+ is discussed, but no firm conclusion is reached. In the velocity interval 0 to 60 km/s, an ortho/para ratio of below unity is found, but if this is due to an artifact of contamination by other species or real is not clear., Comment: A&A, HIFI special issue, accepted

The outflow driven by the low-mass class 0 protostar L1157 is the prototype of the so-called chemically active outflows. The bright bowshock B1 in the southern outflow lobe is a privileged testbed of magneto-hydrodynamical (MHD) shock models, for which dynamical and chemical processes are strongly interdependent. We present the first results of the unbiased spectral survey of the L1157-B1 bowshock, obtained in the framework of the key program "Chemical Herschel Surveys of Star Forming Regions" (CHESS). The main aim is to trace the warm and chemically enriched gas and to infer the excitation conditions in the shock region. The CO 5-4 and H2O lines have been detected at high-spectral resolution in the unbiased spectral survey of the HIFI-Band 1b spectral window (555-636 GHz), presented by Codella et al. in this volume. Complementary ground-based observations in the submm window help establish the origin of the emission detected in the main-beam of HIFI, and the physical conditions in the shock.}{Both lines exhibit broad wings, which extend to velocities much higher than reported up to now. We find that the molecular emission arises from two regions with distinct physical conditions: an extended, warm (100K), dense (3e5 cm-3) component at low-velocity, which dominates the water line flux in Band~1; a secondary component in a small region of B1 (a few arcsec) associated with high-velocity, hot (> 400 K) gas of moderate density ((1.0-3.0)e4 cm-3), which appears to dominate the flux of the water line at 179mu observed with PACS. The water abundance is enhanced by two orders of magnitude between the low- and the high-velocity component, from 8e-7 up to 8e-5. The properties of the high-velocity component agree well with the predictions of steady-state C-shock models., Comment: Accepted for Publication in Astronomy and Astrophysics (Herschel Special Issue)

We identify a prominent absorption feature at 1115 GHz, detected in first HIFI spectra towards high-mass star-forming regions, and interpret its astrophysical origin. The characteristic hyperfine pattern of the H2O+ ground-state rotational transition, and the lack of other known low-energy transitions in this frequency range, identifies the feature as H2O+ absorption against the dust continuum background and allows us to derive the velocity profile of the absorbing gas. By comparing this velocity profile with velocity profiles of other tracers in the DR21 star-forming region, we constrain the frequency of the transition and the conditions for its formation. In DR21, the velocity distribution of H2O+ matches that of the [CII] line at 158\mu\m and of OH cm-wave absorption, both stemming from the hot and dense clump surfaces facing the HII-region and dynamically affected by the blister outflow. Diffuse foreground gas dominates the absorption towards Sgr B2. The integrated intensity of the absorption line allows us to derive lower limits to the H2O+ column density of 7.2e12 cm^-2 in NGC 6334, 2.3e13 cm^-2 in DR21, and 1.1e15 cm^-2 in Sgr B2., Comment: Accepted for publication in A&A

We present new details of the structure and morphology of the jets and outflows in HH46/47 as seen in Spitzer infrared images from IRAC and MIPS, reprocessed using the ``HiRes'' deconvolution technique. HiRes improves the visualization of spatial morphology by enhancing resolution (to sub-arcsec levels in IRAC bands) and removing the contaminating side lobes from bright sources. In addition to sharper views of previously reported bow shocks, we have detected: (i) the sharply-delineated cavity walls of the wide-angle biconical outflow, seen in scattered light on both sides of the protostar, (ii) several very narrow jet features at distances 400 AU to 0.1 pc from the star, and, (iii) compact emissions at MIPS 24 micron coincident with the jet heads, tracing the hottest atomic/ionic gas in the bow shocks., Comment: 11 pages, 4 Figures, Accepted for publication in ApJ(Letters)

We have surveyed submillimeter continuum emission from relatively quiescent regions in the Orion molecular cloud to determine how the core mass function in a high mass star forming region compares to the stellar initial mass function. Such studies are important for understanding the evolution of cores to stars, and for comparison to formation processes in high and low mass star forming regions. We used the SHARC II camera on the Caltech Submillimeter Observatory telescope to obtain 350 \micron data having angular resolution of about 9 arcsec, which corresponds to 0.02 pc at the distance of Orion. Our analysis combining dust continuum and spectral line data defines a sample of 51 Orion molecular cores with masses ranging from 0.1 \Ms to 46 \Ms and a mean mass of 9.8 \Ms, which is one order of magnitude higher than the value found in typical low mass star forming regions, such as Taurus. The majority of these cores cannot be supported by thermal pressure or turbulence, and are probably supercritical.They are thus likely precursors of protostars. The core mass function for the Orion quiescent cores can be fitted by a power law with an index equal to -0.85$\pm$0.21. This is significantly flatter than the Salpeter initial mass function and is also flatter than the core mass function found in low and intermediate star forming regions. Thus, it is likely that environmental processes play a role in shaping the stellar IMF later in the evolution of dense cores and the formation of stars in such regions., Comment: 30 pages, 10 figures, accepted by ApJ

The dynamics and chemistry of protostellar disks are likely to be intricately linked, with dynamical processes altering the chemical composition, and chemistry, in turn, controlling the ionization structure and hence the ability of the magneto-rotational instability to drive the disk turbulence. Here we present the results from the first chemical models of the outer regions (R > 100 AU) of protoplanetary disks to consider the effects of turbulence driven diffusive mixing in the vertical direction. We show that vertical diffusion can greatly affect the column densities of many species, increasing them by factors of up to two orders of magnitude. Previous disk models have shown that disks can be divided into three chemically distinct layers, with the bulk of the observed molecular emission coming from a region between an atomic/ionic layer on the surface of the disk and the midplane regoin where the bulk of molecules are frozen onto grains. Diffusion retains this three layer structure, but increases the depth of the molecular layer by bringing atoms and atomic ions form by photodissociation in the surface layers into the shielded molecular layer where molecules can reform. For other species, notably NH3 and N2H+, the column densities are relatively unaffected by diffusion. These species peak in abundance near the midplane where most other molecules are heavily depleted, rather than in the molecular layer above. Diffusion only affects the abundances of those molecules with peak abundances in the molecular layer. We find that diffusion does not affect the ionization fraction of the disk. We compare the calculated column densities to observations of DM Tau, LkCa 15 and TW Hya and find good agreement for many molecules with a diffusion coefficient of 1e18 cm^2 s^-1., Comment: Accepted in ApJ

It has been suggested that under average interstellar field strengths the cyclotron interaction between ions and magnetic fields is strong enough to narrow the linewidth and suppress the line wings in the ion spectra. We present evidence for the cyclotron interaction effect at arcsec scale on the velocity dispersions in the spectra of ion/neutral molecular species in DR21(OH) observed with the OVRO-MMA. Using a spatial resolution $\sim$ 3 times higher than previous CSO observations by Houde et al. (2002), we show that H$^{13}$CO$^+$ and H$^{13}$CN are coexistent at the scale of our observations (6\arcsec). In the eastern parts of the DR21(OH) core where the dynamics is simple, the ion linewidths are indeed narrower than the neutral linewidths with an average ion-to-neutral linewidth ratio of 0.82$\pm$0.04. We use our results, along with the existing Zeeman and dust/CO polarization data on small scales, to derive the 3-D magnetic field structure. We obtain a field strength of $0.44\pm$0.12 mG with inclination of 36\deg to the line of sight, directed toward the observer, and a position angle of $-$75\deg in the plane of the sky. With the full magnetic field strength derived here, we are able to conclude that the MM1 core of DR21(OH) is magnetically supercritical; although turbulence provides the dominant support., Comment: 11 pages, 4 figures, accepted for publication in ApJL (Oct 20, 2003)

We have investigated the physical and chemical status of the pre-protostellar core B68. A previous extinction study suggested that the density profile of B68 is remarkably consistent with a Bonnor-Ebert sphere with 2.1 $M_{\odot}$ at 16 K. We mapped B68 in C3H2, CCS, and NH3 with the Deep Space Network (DSN) 70m telescope at Goldstone. Our results show that the B68 chemical structure is consistent with that seen in other pre-protostellar cores (L1498, L1544) and is explained by time dependent chemical models that include depletion. We measured a kinetic temperature of 11K with NH3 (1,1) and (2,2) spectra. We also show that B68 is thermally dominated with little contribution from turbulence support (< 10%). We consider a modified Bonnor-Ebert sphere to include effects of turbulence and magnetic fields and use it to constrain the uncertainties in its distance determination. We conclude that the distance to B68 is $\sim$ 95pc with a corresponding mass of $\sim$ 1.0 $M_{\odot}$. If some magnetic field is present it can be further away (beyond $\sim$ 100pc) and still satisfy the density structure of a Bonnor-Ebert sphere. Our observations do not preclude any instability such as the onset of collapse, or slow contraction, occurring in the center of the core, which cannot be resolved with our beam size (45")., Comment: 19 pages, 5 figures, accepted for publication in AJ

The question "How did we get here and what will the future bring?" captures the human imagination and the attention of the National Academy of Science's Astronomy and Astrophysics Survey Commitee (AASC). Fulfillment of this "fundamental goal" requires astronomers to have sensitive, high angular and spectral resolution observations in the far-infrared/submillimeter (far-IR/sub-mm) spectral region. With half the luminosity of the universe and vital information about galaxy, star and planet formation, observations in this spectral region require capabilities similar to those currently available or planned at shorter wavelengths. In this paper we summarize the scientific motivation, some mission concepts and technology requirements for far-IR/sub-mm space interferometers that can be developed in the 2010-2020 timeframe., Comment: 11 pages, 6 figures, submitted as a "mission white paper" to NASA's SEU Roadmap Committee

The cumulene carbenes are important components of hydrocarbon chemistry in low mass star forming cores. Here we report the first astronomical detection of the long chain cumulene carbene H_2C_6 in the interstellar cloud TMC1, from observations of two of its rotational transitions: $J_{K,K'} = 7_{1,7} \rightarrow 6_{1,6}$ at 18.8 GHz and $8_{1,8} \rightarrow 7_{1,7}$ at 21.5 GHz, using NASA's Deep Space Network 70 m antenna at Goldstone, California. In addition we also observed the shorter cumulene carbene, H_2C_4 at the same position. The fractional abundance of H_2C_6 relative to H_2 is about $4.7 \times 10^{-11}$ and H_2C_4 is about $1.1 \times 10^{-9}$. The abundance of H_2C_6 is in fairly good agreement with gas phase chemical models for young molecular cloud cores, but the abundance of H_2C_4 is significantly larger than predicted., Comment: plain tex