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A sample of warm low level semi-regular variables chosen from the General Catalogue of Variable Stars is studied for their chemical compositions by analysing high resolution optical spectra. The abundance ratios from Na/Fe to Eu/Fe displayed by these and previously analysed semi-regular variables are quite similar to ratios displayed by normal red giants across the Galactic thin and thick disks and halo populations in the solar neighbourhood suggesting from this perspective that the variables may be among the more photometrically active red giants.

We present the results of a sensitive search for high-velocity gas in interstellar absorption lines associated with the Cygnus Loop supernova remnant (SNR). We examine high-resolution, high signal-to-noise ratio optical spectra of six stars in the Cygnus Loop region with distances greater than ~700 pc. All stars show low-velocity Na I and Ca II absorption. However, only one star, HD 198301, exhibits high-velocity Ca II absorption components, at velocities of +62, +82, and +96 km/s. The distance to this star of ~870 pc helps to constrain the distance to the receding edge of the Cygnus Loop's expanding shock front. One of our targets, HD 335334, was previously thought to exhibit high positive and high negative velocity interstellar Na I and Ca II absorption. This was one factor leading Fesen et al. to derive a distance to the Cygnus Loop of 725 pc. However, we find that HD 335334 is in fact a double-line spectroscopic binary and shows no evidence of high-velocity interstellar absorption. As such, the distance to HD 335334 cannot be used to constrain the distance to the Cygnus Loop. Our detection of Ca II absorption approaching 100 km/s toward HD 198301 is the first conclusive detection of high-velocity absorption from a low ionization species associated with the Cygnus Loop SNR. A large jump in the Na I column density toward BD+31 4218, a star located beyond the northwestern boundary of the Cygnus Loop, helps to constrain the distance to a large molecular cloud complex with which the Cygnus Loop is evidently interacting., Comment: 14 pages, 14 figures, submitted to MNRAS

In this investigation, we present an analysis of the metallicity distribution that pertains to neutral gas in the local Galactic interstellar medium (ISM). We derive relative ISM metallicities for a sample of 84 sight lines probing diffuse atomic and molecular gas within 4 kpc of the Sun. Our analysis is based, in large part, on column density measurements reported in the literature for 22 different elements that are commonly studied in interstellar clouds. We supplement the literature data with new column density determinations for certain key elements and for several individual sight lines important to our analysis. Our methodology involves comparing the relative gas-phase abundances of many different elements for a given sight line to simultaneously determine the strength of dust depletion in that direction and the overall metallicity offset. We find that many sight lines probe multiple distinct gas regions with different depletion properties, which complicates the metallicity analysis. Nevertheless, our results provide clear evidence that the dispersion in the metallicities of neutral interstellar clouds in the solar neighborhood is small ($\sim$0.10 dex) and only slightly larger than the typical measurement uncertainties. We find no evidence for the existence of very low metallicity gas (as has recently been reported by De Cia et al.) along any of the 84 sight lines in our sample. Our results are consistent with a local Galactic ISM that is well mixed and chemically homogeneous., Comment: 34 pages, 14 figures, accepted for publication in ApJ

Lithium abundances for red giants in the GALAH DR3 survey are studied. The rare examples of Li-enriched stars with abundances A(Li) $\geq 1.5$ are confirmed to be He-core burning stars belonging to or evolved from the red clump with similar masses and metallicity: $M\simeq 1.1\pm0.2{\rm M_\odot}$ and [Fe/H] $\simeq-0.3\pm0.3$. Li enrichment over the Li abundance present in a star's predecessor at the tip of the red giant branch likely occurs in all these red clump stars. Examination of the elemental abundances (C to Eu) in the GALAH catalogue shows no anomalous abundances in red clump giants and, in particular, no dependence on the Li abundance, which ranges over at least five dex. Lithium synthesis is attributed to the He-core flash occurring in stars at the tip of the red giant branch. Models from the Modules for Experiments in Stellar Astrophysics (MESA) match the observed evolution of these stars along the red giant branch and to the red clump but only at the low effective temperature end of the observed spread of red clump giants. Run of Li abundance on the red giant branch is fairly well reproduced by MESA models. A speculation is presented that the series of He-core flashes not only leads to $^7$Li synthesis from a star's internal reservoir of $^3$He but also may lead to internal restructuring leading to the observed effective temperature spread of red clump stars at about a constant luminosity. Giants exhibiting marked Li enrichments are not found at other evolutionary phases and, in particular, not directly associated with the luminosity bump on the red giant branch for which the Li abundance increase does not exceed 0.3 dex., Comment: 20 Pages, 16 figures, 2 tables. Accepted for publication in MNRAS. Data available at https://zenodo.org/record/5086894

We study four lines of sight that probe the transition from diffuse molecular gas to molecular cloud material in Taurus. Measurements of atomic and molecular absorption are used to infer the distribution of species and the physical conditions toward stars behind the Taurus Molecular Cloud (TMC). New high-resolution spectra at visible and near infrared wavelengths of interstellar Ca II, Ca I, K I, CH, CH^+, C2, CN, and CO toward HD28975 and HD29647 are combined with data at visible wavelengths and published CO results from ultraviolet measurements for HD27778 and HD30122. Gas densities and temperatures are inferred from C2, CN, and CO excitation and CN chemistry. Our results for HD29647 are noteworthy because the CO column density is 10^{18} cm^{-2} while C2 and CO excitation reveals a temperature of 10 K and density about 1000 cm^{-3}, more like conditions found in dark molecular clouds. Similar results arise from our chemical analysis for CN through reactions involving observations of CH, C2, and NH. Enhanced potassium depletion and a reduced CH/H2 column density ratio also suggest the presence of a dark cloud. The directions toward HD27778 and HD30122 probe molecule-rich diffuse clouds, which can be considered CO-dark gas, while the sight line toward HD28975 represents an intermediate case. Maps of dust temperature help refine the description of the material along the four sight lines and provide an estimate of the distance between HD29647 and a clump in the TMC. An Appendix provides results for the direction toward HD26571; this star also probes diffuse molecular gas., Comment: 11 figures, 14 tables, 75 pages; higher quality maps appear in the published version

In this study, we explore the evolution of lithium in giant stars based on data assembled from the literature on asteroseismology and Li abundances for giants. Our final sample of 187 giants consists of 44 red giant branch (RGB), 140 core He-burning (CHeB) and three giants with an unclassified evolutionary phase. For all 187 stars, the seismic parameters $\nu\rm_{max}$ (frequency of maximum oscillation power) and $\Delta \nu$ (large frequency spacing) are available, while $\Delta \Pi\rm_{1}$ (the asymptotic gravity-mode period spacing) is available for a subset of 64. For some of the CHeB giants, mass estimates from the asteroseismic scaling relations are found to be underestimated when compared with mass estimates from isochrones based on seismic data. Whilst most of the Li-rich giants in the sample have masses less than 1.5 $M_\odot$, they are also present up to and beyond the maximum mass expected to have suffered a core He-flash, i.e. $M$ $\leq$ 2.25 $M_\odot$: this suggests contributions from other processes towards Li enrichment. To understand the evolution of giants in the $\Delta \Pi\rm_{1}$ $-$ $\Delta \nu$ plane, we use the {\it Modules for Experiments in Stellar Astrophysics} models which show the presence of mini He-flashes following the initial strong core He-flash. From the distribution of A(Li) as a function of $\Delta \nu$, which is similar to the distribution of A(Li) as a function of luminosity, we find no indication of Li enrichment near the luminosity bump. Also, A(Li) trends to $\sim$ -1.5 dex near the RGB tip. The data also suggest a decrease in A(Li) with an increase in $\Delta \Pi\rm_{1}$ for CHeB giants., Comment: Updated Fig 4 and added comments about giants with unclassified evolutionary phase in our list. Also updated supplementary data in Zenodo (see https://zenodo.org/record/4519625 )

We have detected CH$^{+}$ and CH molecular absorption lines from the young compact planetary nebula IC 4997 from high resolution optical spectra. A high-resolution infra-red (H and K bands) spectrum provides detection of H$_2$ emission lines amongst many other lines. The H$_2$ lines provide an excitation temperature of 2100 K which may result from UV fluorescence in the envelope or from shocks formed at the interface between an expanding outflow of ionized gas and the neutral envelope ejected when the star was on the AGB. It is suggested that the CH$^+$ may result from the endothermic reaction C + H$_2$ $\rightarrow$ CH$^+$ + H. Intriguingly, CH$^{+}$ and also CH show a higher expansion velocity than H$_{\rm 2}$ emission suggesting they may be part of the post-shocked gas., Comment: 12 pages, 2 tables, 6 figures, accepted for publication in Publications of the Astronomical Society of the Pacific (PASP)

Compositions of lithium-enriched and normal giants among the GALAH survey are compared. Except for Li, the only detectable abundance difference between lithium-enriched and normal giants among the investigated elements from carbon to europium occurs for carbon. Among Li-rich giants with A(Li) = 1.8 to 3.1, the C deficiency is very similar to that reported for the normal giants (with A(Li) $<$ 1.8) where the slight C deficiency arises from the first dredge-up. Carbon is slightly under abundant relative to normal giants among the super Li-rich giants where the Li abundance exceeds A(Li) = 3.2. The C abundance as well as the $^{12}$C/$^{13}$C ratios from the literature suggest that addition of Li to create a Li-rich giant may occur independently of the abundance changes wrought by the first dredge-up. Creation of a super Li-rich giant, however, appears to occur with additional CN-cycle conversion of C to N. The probability of becoming a Li-rich giant is approximately independent of a star's mass, although the majority of the Li-rich giants are found to be low mass ($M \leq$ 2 M$_\odot$). The frequency of occurrence of Li-enriched giants among normal giants is about one percent and slightly dependent on metallicity ([Fe/H]). Li-enriched and normal giants are found to have similar projected rotational velocity which suggest that Li-enrichment in giants is not linked to scenarios such as mergers and tidal interaction between binary stars., Comment: 20 pages, 14 figures, accepted for publication in the Monthly Notices of the Royal Astronomical Society on March 09, 2020

The hydrogen-deficient star DY Cen has been reported as an R CrB-type variable, an extreme helium star (with some hydrogen), and as a single-lined spectroscopic binary. It has been associated with a dramatic change in visual brightness and colour corresponding to a change in effective temperature ($T_{\mathrm eff}$) of some 20,000 K in the last century. To characterize the binary orbit and $T_{\mathrm eff}$ changes more precisely, new high-resolution spectroscopy has been obtained with SALT. The previous orbital period is not confirmed; previous measurements may have been confused by the presence of pulsations. Including data from earlier epochs (1987, 2002, and 2010), self-consistent spectral analyses from all four epochs demonstrate an increase in $T_{\mathrm eff}$ from 18,800 to 24,400 K between 1987 and 2015. Line profiles demonstrate that the surface rotation has increased by a factor two over the same interval. This is commensurate with the change in $T_{\mathrm eff}$ and an overall contraction. Rotation will exceed critical if contraction continues. The 1987 spectrum shows evidence of a very high abundance of the s-process element strontium. The very rapid evolution, non-negligible surface hydrogen and high surface strontium point to a history involving a very late thermal pulse. Observations over the next thirty years should look for a decreasing pulsation period, reactivation of R CrB-type activity as the star seeks to shed angular momentum and increasing illumination by emission lines from nebular material ejected in the past., Comment: MNRAS accepted 2020 February. 11 pages, 6 figures, + 4 page appendix incl. 4 figures

The main objective of this paper is to explore abundances of fluorine in hot Extreme Helium Stars (EHes). Overabundance of fluorine is a characteristic feature for cool EHes and R Coronae Borealis (RCB) stars and further enforces their close connection. For hot EHes this relationship with the cooler EHes, based on their fluorine abundance is unexplored. We present in this paper the first abundance estimates of fluorine determined from singly ionised fluorine lines (F\,{\sc ii}) for 10 hot EHe stars from optical spectra. Fluorine abundances were determined using the F\,{\sc ii} lines in two windows centered at 3505 \AA \ and 3850 \AA . Six of the 10 stars show significant enhancement of fluorine similar to the cool EHes. Two carbon-poor hot EHes show no signature of fluorine and have a significant low upper limit for the F abundance. These fluorine abundances are compared with the other elemental abundances observed in these stars which provide an idea about the formation and evolution of these stars. The trends of fluorine with C, O, and Ne show that significant helium burning after a CO-He white dwarf merger can account for a majority of the observed abundances. Predictions from simulations of white dwarf mergers are discussed in light of the observed abundances., Comment: 41 pages, 18 figures, 5 tables, Accepted for publication in ApJ

High-resolution optical spectra were obtained in 2017-2019 with The Southern African Large Telescope of fifteen stars in the direction of the Vela supernova remnant. Interstellar Ca ii H and K and Na i D lines are discussed in this paper. In particular, the line profiles are compared with profiles at a comparable spectral resolution obtained in 1993-1996 by Cha & Sembach. Ten of the lines of sight show changes to one or more of the components in that line of sight. Changes include small changes (1-2 km/s) in radial velocity and/or increases/decreases in equivalent width over the two decades between the periods of observation. Changes are more obvious in the Ca K line than in the Na D lines. These changes are attributed to gas disturbed by interactions between the supernova ejecta and the surrounding interstellar medium. A representative timescale may be 20-50 years. Small-scale variations in line profiles across the face of the remnant suggest, as previously remarked, that a linear scale for interactions is a small fraction of the 40 pc size of the present remnant., Comment: 24 pages, 18 figures, Accepted for publication in Monthly Notices of the Royal Astronomical Society Main Journal

Carbon and oxygen isotopic ratios are reported for a sample of 51 SRb- and Lb-type variable asymptotic giant branch stars. Vibration-rotation first- and second-overtone CO lines in 1.5-2.5 mum spectra were measured to derive isotopic ratios for 12C/13C, 16O/17O, and 16O/18O. Comparisons with previous measurements for individual stars and with various samples of evolved stars, as available in the extant literature, are discussed. Using the oxygen isotopic ratios, the masses of the SRb stars can be derived. Combining the masses with Gaia luminosities, the SRb stars are shown to be antecedents of the Mira variables. The limiting parameters where plane-parallel, hydrostatic equilibrium model atmospheres can be used for abundance analysis of M giants are explored.

The chemical evolution of fluorine is investigated in a sample of Milky Way red giantstars that span a significant range in metallicity from [Fe/H] $\sim$ -1.3 to 0.0 dex. Fluorine abundances are derived from vibration-rotation lines of HF in high-resolution infraredspectra near $\lambda$ 2.335 $\mu$m. The red giants are members of the thin and thick disk / halo,with two stars being likely members of the outer disk Monoceros overdensity. At lowermetallicities, with [Fe/H]<-0.4 to -0.5, the abundance of F varies as a primary element with respect to the Fe abundance, with a constant subsolar value of [F/Fe] $\sim$ -0.3 to -0.4 dex. At larger metallicities, however, [F/Fe] increases rapidly with [Fe/H] anddisplays a near-secondary behavior with respect to Fe. Comparisons with various models of chemical evolution suggest that in the low-metallicity regime (dominated hereby thick disk stars), a primary evolution of $^{19}$F with Fe, with a subsolar [F/Fe] valuethat roughly matches the observed plateau can be reproduced by a model incorporatingneutrino nucleosynthesis in the aftermath of the core collapse in supernovae of type II (SN II). A primary behavior for [F/Fe] at low metallicity is also observed for a model including rapid rotating low-metallicity massive stars but this overproduces [F/Fe] atlow metallicity. The thick disk red giants in our sample span a large range of galactocentric distance (Rg $\sim$ 6--13.7 kpc), yet display a $\sim$constant value of [F/Fe], indicating a very flat gradient (with a slope of 0.02 $\pm$ 0.03 dex/kpc) of this elemental ratio over asignificant portion of the Galaxy having|Z|>300 pc away from the Galaxy mid-plane., Comment: 36 pages

We present chemical abundances for the elements carbon, sodium, and fluorine in 15 red giants of the globular cluster M 4, as well as six red giants of the globular cluster $\omega$ Centauri. The chemical abundances were calculated in LTE via spectral synthesis. The spectra analyzed are high-resolution spectra obtained in the near-infrared region around $\lambda$2.3$\mu$m with the Phoenix spectrograph on the 8.1m Gemini South Telescope, the IGRINS spectrograph on the McDonald Observatory 2.7m Telescope, and the CRIRES spectrograph on the ESO 8.2m Very Large Telescope. The results indicate a significant reduction in the fluorine abundances when compared to previous values from the literature for M 4 and $\omega$ Centauri, due to a downward revision in the excitation potentials of the HF(1-0) R9 line used in the analysis. The fluorine abundances obtained for the M 4 red giants are found to be anti-correlated with those of Na, following the typical pattern of abundance variations seen in globular clusters between distinct stellar populations. In M 4, as the Na abundance increases by $\sim$+0.4 dex, the F abundance decreases by $\sim$-0.2 dex. A comparison with abundance predictions from two sets of stellar evolution models finds that the models predict somewhat less F depletion ($\sim$-0.1 dex) for the same increase of +0.4 dex in Na.

We have analysed high-dispersion echelle spectra ($R = 60000$) of red giant members of five open clusters to derive abundances for many elements from Na to Eu. The [Fe/H] values are $-0.06\pm0.03$ for Stock 2, $-0.11\pm0.03$ for NGC 2168, $-0.01\pm0.03$ for NGC 6475, $0.00\pm0.03$ for NGC 6991 and $-0.07\pm0.03$ for NGC 7662. Sodium is enriched in the giants relative to the abundance expected of main sequence stars of the same metallicity. This enrichment of [Na/Fe] by about $+0.25$ attributed to the first dredge-up is discussed in the light of theoretical predictions and recently published abundance determinations. Abundance ratios [El/Fe] for other elements are with very few exceptions equal to those of field giants and dwarfs, i.e., [El/Fe] $\simeq 0.00$ for [Fe/H] $\sim 0.0$. An exception is the overabundance of La, Ce, Nd and Sm in NGC 6991 but this is consistent with our previous demonstration that the abundances of these $s$-process products vary by about $\pm0.2$ among clusters of the same [Fe/H], a variation found also among field giants and dwarfs., Comment: (21 pages, 8 figures, 10 tables, accepted for publication in MNRAS)

An abundance analysis for 20 elements from Na to Eu is reported for 34 K giants from the Hyades supercluster and for 22 K giants from the Sirius supercluster. Observed giants were identified as highly probable members of their respective superclusters by Famaey et al. (2005, A&A, 430, 165). Three giants each from the Hyades and Praesepe open clusters were similarly observed and analysed. Each supercluster shows a range in metallicity: $-0.20 \leq$ [Fe/H] $\leq +0.25$ for the Hyades supercluster and $-0.22 \leq $ [Fe/H] $\leq +0.15$ for the Sirius supercluster with the metal-rich tail of the metallicity distribution of the Hyades supercluster extending beyond that of the Sirius supercluster and spanning the metallicity of the Hyades and Praesepe cluster giants. Relative elemental abundances [El/Fe] across the supercluster giants are representative of the Galactic thin disc as determined from giants in open clusters analysed in a similar way to our approach. Judged by metallicity and age, very few and likely none of the giants in these superclusters originated in an open cluster: the pairings include the Hyades supercluster with the Hyades - Praesepe open clusters and the Sirius supercluster with the U Ma open cluster. Literature on main sequence stars attributed to the two superclusters and the possible relation to the associated open cluster is reviewed. It is suggested that the Hyades supercluster's main sequence population contains few stars from the two associated open clusters. As suggested by some previous investigations, the Sirius supercluster, when tightly defined kinematically, appears to be well populated by stars shed by the U Ma open cluster.

We present an extensive analysis of the gas-phase abundances and depletion behaviors of neutron-capture elements in the interstellar medium (ISM). Column densities (or upper limits to the column densities) of Ga II, Ge II, As II, Kr I, Cd II, Sn II, and Pb II are determined for a sample of 69 sight lines with high- and/or medium-resolution archival spectra obtained with the Space Telescope Imaging Spectrograph onboard the Hubble Space Telescope. An additional 59 sight lines with column density measurements reported in the literature are included in our analysis. Parameters that characterize the depletion trends of the elements are derived according to the methodology developed by Jenkins (2009; arXiv:0905.3173). (In an appendix, we present similar depletion results for the light element B.) The depletion patterns exhibited by Ga and Ge comport with expectations based on the depletion results obtained for many other elements. Arsenic exhibits much less depletion than expected, and its abundance in low-depletion sight lines may even be supersolar. We confirm a previous finding by Jenkins (2009; arXiv:0905.3173) that the depletion of Kr increases as the overall depletion level increases from one sight line to another. Cadmium shows no such evidence of increasing depletion. We find a significant amount of scatter in the gas-phase abundances of Sn and Pb. For Sn, at least, the scatter may be evidence of real intrinsic abundance variations due to s-process enrichment combined with inefficient mixing in the ISM., Comment: 73 pages, 23 figures, accepted for publication in the ApJ Supplement

Optical high-resolution spectra of V652 Her and HD 144941, the two extreme helium stars with exceptionally low C/He ratios, have been subjected to a non-LTE abundance analysis using the tools TLUSTY and SYNSPEC. Defining atmospheric parameters were obtained from a grid of non-LTE atmospheres and a variety of spectroscopic indicators including He I and He II line profiles, ionization equilibrium of ion pairs such as C II/C III and N II/N III. The various indicators provide a consistent set of atmospheric parameters: $T_{\rm eff}$=25000$\pm$300K, $\log g$ = 3.10$\pm$0.12(cgs), and $\xi=13\pm2 {\rm km\,s^{-1}}$ are provided for V652 Her, and $T_{\rm eff}$=22000$\pm$600K, $\log g$ = 3.45$\pm$0.15 (cgs), and $\xi=10 {\rm km\,s^{-1}}$ are provided for HD 144941. In contrast to the non-LTE analyses, the LTE analyses - LTE atmospheres and a LTE line analysis - with the available indicators do not provide a consistent set of atmospheric parameters. The principal non-LTE effect on the elemental abundances is on the neon abundance. It is generally considered that these extreme helium stars with their very low C/He ratio result from the merger of two helium white dwarfs. Indeed, the derived composition of V652 Her is in excellent agreement with predictions by Zhang & Jeffery (2012) who model the slow merger of helium white dwarfs; a slow merger results in the merged star having the composition of the accreted white dwarf. In the case of HD 144941 which appears to have evolved from metal-poor stars a slow merger is incompatible with the observed composition but variations of the merger rate may account for the observed composition. More detailed theoretical studies of the merger of a pair of helium white dwarfs are to be encouraged., Comment: 23 pages including 5 Tables and 14 Figures, Accepted for publication in ApJ

There are two accepted mechanisms to explain the origin of runaway OB-type stars: the Binary Supernova Scenario (BSS), and the Cluster Ejection Scenario (CES). In the former, a supernova explosion within a close binary ejects the secondary star, while in the latter close multi-body interactions in a dense cluster cause one or more of the stars to be ejected from the region at high velocity. Both mechanisms have the potential to affect the surface composition of the runaway star. TLUSTY non-LTE model atmosphere calculations have been used to determine atmospheric parameters and carbon, nitrogen, magnesium and silicon abundances for a sample of B-type runaways. These same analytical tools were used by Hunter et al. (2009) for their analysis of 50 B-type open cluster Galactic stars (i.e. non-runaways). Effective temperatures were deduced using the silicon-ionization balance technique, surface gravities from Balmer line profiles and microturbulent velocities derived using the Si spectrum. The runaways show no obvious abundance anomalies when compared with stars in the open clusters. The runaways do show a spread in composition which almost certainly reflects the Galactic abundance gradient and a range in the birthplaces of the runaways in the Galactic disk. Since the observed Galactic abundance gradients of C, N, Mg and Si are of a similar magnitude, the abundance ratios (e.g., N/Mg) are, as obtained, essentially uniform across the sample.

Several abundance analyses of Galactic open clusters (OCs) have shown a tendency for Ba but not for other heavy elements (La$-$Sm) to increase sharply with decreasing age such that Ba was claimed to reach [Ba/Fe] $\simeq +0.6$ in the youngest clusters (ages $<$ 100 Myr) rising from [Ba/Fe]$=0.00$ dex in solar-age clusters. Within the formulation of the $s$-process, the difficulty to replicate higher Ba abundance and normal La$-$Sm abundances in young clusters is known as {\it the barium puzzle}. Here, we investigate the barium puzzle using extremely high-resolution and high signal-to-noise spectra of 24 solar twins and measured the heavy elements Ba, La, Ce, Nd and Sm with a precision of 0.03 dex. We demonstrate that the enhanced Ba {\scs II} relative to La$-$Sm seen among solar twins, stellar associations and OCs at young ages ($<$100 Myr) is unrelated to aspects of stellar nucleosynthesis but has resulted from overestimation of Ba by standard methods of LTE abundance analysis in which the microturbulence derived from the Fe lines formed deep in the photosphere is insufficient to represent the true line broadening imposed on Ba {\scs II} lines by the upper photospheric layers from where the Ba {\scs II} lines emerge. As the young stars have relatively active photospheres, Ba overabundances most likely result from the adoption of too low a value of microturbulence in the spectum synthesis of the strong Ba {\scs II} lines but the change of microturbulence in the upper photosphere has only a minor affect on La$-$Sm abundances measured from the weak lines., Comment: 14 pages,14 figures and 5 tables; accepted for publication in ApJ

In a survey conducted between 2011-12 of interstellar Na I D line profiles in the direction of the Vela supernova remnant, a few lines of sight showed dramatic changes in low velocity absorption components with respect to profiles from 1993-1994 reported by Cha & Sembach. Three stars - HD 63578, HD 68217 and HD 76161 showed large decrease in strength over the 1993-2012 interval. HD 68217 and HD 76161 are associated with the Vela SNR whereas HD 63578 is associated with $\gamma^2$ Velorum wind bubble. Here, we present high spectral resolution observations of Ca II K lines obtained with the Southern African Large Telescope (SALT) towards these three stars along with simultaneous observations of Na I D lines. These new spectra confirm that the Na D interstellar absorption weakened drastically between 1993-1994 and 2011-2012 but show for the first time that the Ca II K line is unchanged between 1993-1994 and 2015. This remarkable contrast between the behaviour of Na D and Ca II K line absorption lines is a puzzle concerning gas presumably affected by the outflow from the SNR and the wind from $\gamma^2$ Velorum., Comment: 9 pages, 6 figures, 3 tables, accepted for publication in MNRAS

We have collected high-dispersion echelle spectra of red giant members in the twelve open clusters (OCs) and derived stellar parameters and chemical abundances for 26 species by either line equivalent widths or synthetic spectrum analyses. We confirm the lack of an age-metallicity relation for OCs but argue that such a lack of trend for OCs arise from the limited coverage in metallicity compared to that of field stars which span a wide range in metallicity and age. We confirm that the radial metallicity gradient of OCs is steeper (flatter) for Rgc < 12 kpc (> 12 kpc). We demonstrate that the sample of clusters constituting a steep radial metallicity gradient of slope $-$0.052$\pm$0.011 dex kpc$^{-1}$ at Rgc < 12 kpc are younger than 1.5 Gyr and located close to the Galactic midplane (|z| < 0.5 kpc) with kinematics typical of the thin disc. Whereas the clusters describing a shallow slope of $-$0.015$\pm$0.007 dex kpc$^{-1}$ at Rgc > 12 kpc are relatively old, thick disc members with a striking spread in age and height above the midplane (0.5 < |z| < 2.5 kpc). Our investigation reveals that the OCs and field stars yield consistent radial metallicity gradients if the comparison is limited to samples drawn from the similar vertical heights. We argue via the computation of Galactic orbits that all the outer disc clusters were actually born inward of 12 kpc but the orbital eccentricity has taken them to present locations very far from their birthplaces., Comment: 18 pages, 8 figures, 16 tables (available online), Accepted for publication in MNRAS

Determinations of the chemical composition of red giants in a large sample of open clusters show that the abundances of the heavy elements La, Ce, Nd and Sm but not so obviously Y and Eu vary from one cluster to another across a sample all having about the solar metallicity. For La, Ce, Nd and Sm the amplitudes of the variations at solar metallicity scale approximately with the main s-process contribution to solar system material. Consideration of published abundances of field stars suggest that such a spread in heavy element abundances is present for the thin and thick disk stars of different metallicity. This new result provides an opportunity to chemically tag stars by their heavy elements and to reconstruct dissolved open clusters from the field star population., Comment: 8 pages, 6 figures, 2 tables, Accepted for publication in ApJ

We have derived elemental abundances of a remarkable star, HD 179821, with unusual composition (e.g. [Na/Fe]=1.0$\pm$0.2 dex) and extra-ordinary spectral characteristics. Its metallicity at [Fe/H]=0.4 dex places it among the most metal-rich stars yet analyzed. The abundance analysis of this luminous star is based on high resolution and high quality (S/N$\approx$120--420) optical echelle spectra from McDonald Observatory and Special Astronomy Observatory. The data includes five years of observations over twenty-one epochs. Standard 1D {\sc LTE} analysis provides a fresh determination of the atmospheric parameters over all epochs: \Teff = 7350$\pm$200 \kelvin, \logg = +0.6$\pm$0.3, and a microturbulent velocity $\xi =$ 6.6$\pm$1.6 km s$^{\rm -1}$ and [Fe/H] = 0.4$\pm$0.2, and a carbon abundance [C/Fe]= $-$0.19$\pm$0.30. We find oxygen abundance [O/Fe]= $-$0.25$\pm$0.28 and an enhancement of 0.9 dex in N. A supersonic macroturbulent velocity of 22.0 $\pm$ 2.0 km s$^{\rm -1}$ is determined from both strong and weak Fe\,{\sc i} and Fe\,{\sc ii} lines. Elemental abundances are obtained for 22 elements. HD 179821 is not enriched in s-process products. Eu is overabundant relative to the anticipated [X/Fe] $\approx$ 0.0. Some peculiarities of its optical spectrum (e.g. variability in the spectral line shapes) is noticed. This includes the line profile variations for H$\alpha$ line. Based on its estimated luminosity, effective temperature and surface gravity, HD 179821 is a massive star evolving to become a red supergiant and finally a Type II supernova., Comment: 19 pages, 8 figures, accepted for publication in MNRAS

An abundance analysis is reported of 58 K giants identified by Famaey et al. (2005) as highly probable members of the Hercules stream selected from stars north of the celestial equator in the Hipparcos catalogue. The giants have compositions spanning the interval [Fe/H] from $-$0.17 to $+$0.42 with a mean value of $+$0.15 and relative elemental abundances [El/Fe] representative of the Galactic thin disc. Selection effects may have biassed the selection from the Hipparcos catalogue against the selection of metal-poor stars. Our reconsideration of the recent extensive survey of FG dwarfs which included metal-poor stars (Bensby et al. 2014) provides a [Fe/H] distribution for the Hercules stream which is similar to that from the 58 giants. It appears that the stream is dominated by metal-rich stars from the thin disc. Suggestions in the literature that the stream includes metal-poor stars from the thick disc are discussed.

Aims: We report the discovery of a young lithium rich giant, HD 16771, in the core-helium burning phase that does not seem to fit existing proposals of Li synthesis near the luminosity function bump or during He-core flash. We aim to understand the nature of Li enrichment in the atmosphere of HD 16771 by exploring various Li enhancement scenarios. Methods: We have collected high-resolution echelle spectra of HD 16771 and derived stellar parameters and chemical abundances for 27 elements by either line equivalent widths or synthetic spectrum analyses. Results: HD 16771 is a Li-rich (log(n(Li))=+2.67+/-0.10 dex) intermediate mass giant star (M=2.4+/-0.1 Msun) with age=0.76+/-0.13 Gyr and located at the red giant clump. Kinematics and chemical compositions are consistent with HD 16771 being a member of the Galactic thin disk population. The non-detection of 6Li(< 3%), a low carbon isotopic ratio (12C/13C=12+/-2), and the slow rotation (vsini=2.8 km/s) all suggest that lithium might have been synthesized in this star. On the contrary, HD 16771 with a mass of 2.4 Msun has no chance of encountering luminosity function bump and He-core flash where the possibility of fast deep-mixing for Li enrichment in K giants has been suggested previously. Conclusions: Based of the evolutionary status of this star, we discuss the possibility that 7Li synthesis in HD 16771 is triggered by the engulfment of close-in planet(s) during the RGB phase., Comment: 6 pages, 3 figures, 2 tables, Accepted for publication in Astronomy & Astrophysics

High-resolution spectral profiles of Na I D lines from the interstellar medium towards 64 stars in the direction of the Vela supernova remnant are presented. This survey conducted mostly between 2011-12 complements an earlier survey of the same stars by Cha & Sembach done in the 1993-96 period. The interval of 15 to 18 years provides a base line to search for changes in the interstellar profiles. Dramatic disappearance of strong absorption components at low radial velocity is seen towards three stars - HD 63578, HD 68217, HD 76161 - over 15-18 years; HD 68217 and HD 76161 are associated with the Vela SNR but HD 63578 is likely associated with the wind bubble of g2 Velorum. The vanishing of these cold neutral clouds in the short time of 15 to 18 years needs some explanation. Other changes are seen in high-velocity Na D components., Comment: 26 pages, 20 figures, 7 tables, accepted in MNRAS

We have observed high-dispersion echelle spectra of main-sequence stars in five nearby young associations -- Argus, Carina-Near, Hercules-Lyra, Orion and Subgroup B4 -- and derived abundances for elements ranging from Na to Eu. These are the first chemical abundance measurements for two of the five associations, while the remaining three associations are analysed more extensively in our study. Our results support the presence of chemical homogeneity among association members with a typical star-to-star abundance scatter of about 0.06 dex or less over many elements. The five associations show log$\epsilon$(Li) consistent with their age and share a solar chemical composition for all elements with the exception of Ba. We find that all the heavy elements (Y, Zr, La, Ce, Nd, Sm and Eu) exhibit solar ratios, i.e., [X/Fe] $\simeq$ 0, while Ba is overabundant by about 0.2-0.3 dex. The origin of the overabundance of Ba is a puzzle. Within the formulation of the s-process, it is difficult to create a higher Ba abundance without a similar increase in the s-process contributions to other heavy elements (La-Sm). Given that Ba is represented by strong lines of Ba II and La-Sm are represented by rather weak ionized lines, the suggestion, as previously made by other studies, is that the Ba abundance may be systematically overestimated by standard methods of abundance analysis perhaps because the upper reaches of the stellar atmospheres are poorly represented by standard model atmospheres. A novel attempt to analyse the Ba I line at 5535 \AA\ gives a solar Ba abundance for stars with effective temperatures hotter than about 5800 K but increasingly subsolar Ba abundances for cooler stars with apparent Ba deficiencies of 0.5 dex at 5100 K. This trend with temperature may signal a serious non-LTE effect on the Ba I line., Comment: (18 pages, 8 figures, 11 tables. This paper has been accepted for publication in Monthly Notices of the Royal Astronomical Society Main Journal.)

The structure and properties of the diffuse interstellar medium (ISM) on small scales, sub-au to 1 pc, are poorly understood. We compare interstellar absorption-lines, observed towards a selection of O- and B-type stars at two or more epochs, to search for variations over time caused by the transverse motion of each star combined with changes in the structure in the foreground ISM. Two sets of data were used: 83 VLT- UVES spectra with approximately 6 yr between epochs and 21 McDonald observatory 2.7m telescope echelle spectra with 6 - 20 yr between epochs, over a range of scales from 0 - 360 au. The interstellar absorption-lines observed at the two epochs were subtracted and searched for any residuals due to changes in the foreground ISM. Of the 104 sightlines investigated with typically five or more components in Na I D, possible temporal variation was identified in five UVES spectra (six components), in Ca II, Ca I and/or Na I absorption-lines. The variations detected range from 7\% to a factor of 3.6 in column density. No variation was found in any other interstellar species. Most sightlines show no variation, with 3{\sigma} upper limits to changes of the order 0.1 - 0.3 dex in Ca II and Na I. These variations observed imply that fine-scale structure is present in the ISM, but at the resolution available in this study, is not very common at visible wavelengths. A determination of the electron densities and lower limits to the total number density of a sample of the sightlines implies that there is no striking difference between these parameters in sightlines with, and sightlines without, varying components., Comment: 19 pages, 11 figures, accepted for publication in MNRAS

We have observed high-dispersion echelle spectra of red giant members in the five open clusters NGC 1342, NGC 1662, NGC 1912, NGC 2354 and NGC 2447 and determined their radial velocities and chemical compositions. These are the first chemical abundance measurements for all but NGC 2447. We combined our clusters from this and previous papers with a sample drawn from the literature for which we remeasured the chemical abundances to establish a common abundance scale. With this homogeneous sample of open clusters, we study the relative elemental abundances of stars in open clusters in comparison with field stars as a function of age and metallicity. We find a range of mild enrichment of heavy (Ba-Eu) elements in young open cluster giants over field stars of the same metallicity. Our analysis succinct that the youngest stellar generations in cluster might be under-represented by the solar neighbourhood field stars., Comment: (21 pages, 18 figures, 16 tables. Accepted for publication in MNRAS)

We report the first detection of C$^{15}$N in diffuse molecular gas from a detailed examination of CN absorption lines in archival VLT/UVES spectra of stars probing local diffuse clouds. Absorption from the C$^{15}$N isotopologue is confidently detected (at $\gtrsim4\sigma$) in three out of the four directions studied and appears as a very weak feature between the main $^{12}$CN and $^{13}$CN absorption components. Column densities for each CN isotopologue are determined through profile fitting, after accounting for weak additional line-of-sight components of $^{12}$CN, which are seen in the absorption profiles of CH and CH$^+$ as well. The weighted mean value of C$^{14}$N/C$^{15}$N for the three sight lines with detections of C$^{15}$N is $274\pm18$. Since the diffuse molecular clouds toward our target stars have relatively high gas kinetic temperatures and relatively low visual extinctions, their C$^{14}$N/C$^{15}$N ratios should not be affected by chemical fractionation. The mean C$^{14}$N/C$^{15}$N ratio that we obtain should therefore be representative of the ambient $^{14}$N/$^{15}$N ratio in the local interstellar medium. Indeed, our mean value agrees well with that derived from millimeter-wave observations of CN, HCN, and HNC in local molecular clouds., Comment: 13 pages, 3 figures, accepted for publication in ApJ Letters

Mid-infrared photometry of R Coronae Borealis stars obtained from various satellites from IRAS to WISE has been utilized in studying the variations of the circumstellar dust's contributions to the spectral energy distribution of these stars. The variation of the fractional coverage (R) of dust clouds and their blackbody temperatures (T$_d$) have been used in trying to understand the dust cloud evolution over the three decades spanned by the satellite observations. In particular, it is shown that a prediction R $ \propto T_d^4$ developed in this paper is satisfied, especially by those stars for which a single collection of cloud dominates the IR fluxes. Correlations of R with photospheric abundance and luminosity of the stars are explored., Comment: 15 pages, 15 figures, accepted in MNRAS

Based on our prior accurate determination of fundamental parameters for 36 Galactic A-, F- and G-type supergiants and bright giants (luminosity classes I and II), we undertook a non-LTE analysis of the carbon abundance in their atmospheres. It is shown that the non-LTE corrections to the C abundances derived from C I lines are negative and increase with the effective temperature Teff; the corrections are especially significant for the infrared C I lines with wavelengths 9060-9660 \AA. The carbon underabundance as a general property of the stars in question is confirmed; a majority of the stars studied has the carbon deficiency [C/Fe] between -0.1 and -0.5 dex, with a minimum at -0.7 dex. When comparing the derived C deficiency with the N excess found by us for the same stars earlier, we obtain a pronounced N vs. C anti-correlation, which could be expected from predictions of the theory.We found that the ratio [N/C] spans mostly the range from 0.3 to 1.7 dex. Both these enhanced [N/C] values and the C and N anomalies themselves are an obvious evidence of the presence on a star's surface of mixed material from stellar interiors; so, a majority of programme stars passed through the deep mixing during the main sequence (MS) and/or the first dredge-up (FD) phase. Comparison with theoretical predictions including rotationally-induced mixing shows that the stars are either post-MS objects with the initial rotational velocities V0 = 200-300 km/s or post-FD objects with V0 = 0-300 km/s. The observed N vs. C anti-correlation reflects a dependence of the C and N anomalies on the V0 value: on average the higher V0 the greater the anomalies. It is shown that an absence of detectable lithium in the atmospheres of the stars, which is accompanied with the observed N excess and C deficiency, is quite explainable., Comment: 15 pages, 13 figures, 3 tables

DY Cen has shown a steady fading of its visual light by about 1 magnitude in the last 40 years suggesting a secular increase in its effective temperature. We have conducted non-LTE and LTE abundance analyses to determine the star's effective temperature, surface gravity, and chemical composition using high-resolution spectra obtained over two decades. The derived stellar parameters for three epochs suggest that DY Cen has evolved at a constant luminosity and has become hotter by about 5000 K in 23 years. We show that the derived abundances remain unchanged for the three epochs. The derived abundances of the key elements, including F and Ne, are as observed for the extreme helium stars resulting from a merger of an He white dwarf with a C-O white dwarf. Thus, DY Cen by chemical composition appears to be also a product of a merger of two white dwarfs. This appearance seems to be at odds with the recent suggestion that DY Cen is a single-lined spectroscopic binary., Comment: Accepted to ApJ with 8 Figures and 5 Tables

High-resolution optical spectra of the R Coronae Borealis (RCB) star V532 Oph at light maximum are discussed. The absolute visual magnitude M_V of the star is found to be -4.9 \pm 0.5. The elemental abundances suggest the star belongs to the majority class of RCB stars but is among the most O-poor of this class with mild enhancements of heavy elements Y, Zr, Ba and La. The C_2 Swan bands are weak in V532 Oph relative to R CrB. Other aspects of the high-resolution spectrum confirm that V532 Oph is representative of majority RCBs, i.e., the radial velocity is variable, circumstellar material is present and the photosphere feeds a high-velocity stellar wind., Comment: 12 pages, 10 figures

We derived atmospheric parameters and spectroscopic abundances for C and O for a large sample of stars located in the Hertzsprung gap in the Hertzsprung-Russell Diagram in order to detect chemical peculiarities and get a comprehensive overview of the population of stars in this evolutionary state. We have observed and analyzed high resolution spectra (R = 60 000) of 188 stars in the mass range 2 - 5 Msun with the 2.7 m Harlan J. Smith Telescope at the McDonald Observatory including 28 stars previously identified as Am/Ap stars. We find that the C and O abundances of the majority of stars in the Hertzsprung gap are in accordance with abundances derived for local lower mass dwarfs but detect expected peculiarities for the Am/Ap stars. The C and O abundances of stars with Teff < 6500 K are slightly lower than for the hotter objects but the C/O ratio is constant in the analyzed temperature domain. No indication of an alteration of the C and O abundances of the stars by mixing during the evolution across the Hertzsprung gap could be found before the homogenization of their atmospheres by the first dredge-up., Comment: 13 pages, 12 figures, accepted for publication in the Astrophysical Journal

We examine the mid-infrared fluxes and spectral energy distributions for metal-poor stars with iron abundances [Fe/H] $\lesssim-5$, as well as two CEMP-no stars, to eliminate the possibility that their low metallicities are related to the depletion of elements onto dust grains in the formation of a debris disk. Six out of seven stars examined here show no mid-IR excess. These non-detections rule out many types of circumstellar disks, e.g. a warm debris disk ($T\!\le\!290$ K), or debris disks with inner radii $\le1$ AU, such as those associated with the chemically peculiar post-AGB spectroscopic binaries and RV Tau variables. However, we cannot rule out cooler debris disks, nor those with lower flux ratios to their host stars due to, e.g. a smaller disk mass, a larger inner disk radius, an absence of small grains, or even a multicomponent structure, as often found with the chemically peculiar Lambda Bootis stars. The only exception is HE0107-5240, for which a small mid-IR excess near 10 microns is detected at the 2-$\sigma$ level; if the excess is real and associated with this star, it may indicate the presence of (recent) dust-gas winnowing or a binary system., Comment: Accepted for publication in ApJ

We aim to reveal the nature of the Sloan Digital Sky Survey (SDSS) stars: SDSSJ100921.40+375233.9, SDSSJ015717.04+135535.9, and SDSSJ171422.43+283657.2, showing apparently high NUV excesses for their g-z colors, as expected for extremely low-metallicity stars. High resolution (R=60 000) spectra of the stars with a wide wavelength coverage were obtained to determine their chemical compositions with the Tull echelle spectrograph on the 2.7 m telescope at the McDonald Observatory. We derived the spectroscopic parameters Teff =5820+-125 K, log g =3.9+-0.2, and vt =1.1+-0.5 km/s for SDSSJ100921.40+375233.9, Teff=6250+-125 K, log g =3.7+-0.2, and vt =4.0+-0.5 km/s for SDSSJ015717.04+135535.9, and Teff=6320+-125 K, log g =4.1+-0.3, and vt =1.5+-0.5 km/s for SDSS J171422.43+283657.2, and elemental abundances were computed for 21 elements for J100921 and J171422 and for 19 elements for J015717 for the first time. We find metallicities of [Fe/H]= -1.30, -0.94, and -0.80 for SDSSJ100921.40+375233.9, J015717.04+135535.9, and J171422.43+283657.2, respectively. On the basis of calculated abundance ratios for J171422.43+283657.2 and J015717.04+135535.9, we also report that these two program stars have the expected composition of main-sequence halo turnoff stars, but with low-alpha abundances, i.e., the [alpha/Fe] ratio is ~0.0 for J171422.43+283657.2 and ~0.1 for J015717.04+135535.9. The latter one shows typical halo or thick-disk alpha-element abundances, but has a substantial rotational line broadening and vsini=40 +- 0.5 km/s., Comment: 29 pages, 4 figures, 8 tables

We have analyzed high-resolution echelle spectra of red giant members for seven open clusters in the Galactic anticentre direction to explore their chemical positions. Cluster membership has been confirmed by radial velocity. The spread in temperatures and gravities being very small among the red giants, nearly the same stellar lines were employed for all stars thereby reducing the abundance errors: the errors of the average abundance for a cluster were generally in the 0.02 to 0.05 dex range. Our present sample covers Galactocentric distances of 8.3 to 11.3 kpc and an age range of 0.2 to 4.3 Gyr. A careful comparison of our results for the cluster NGC 2682 (M 67) to other high-resolution abundance studies in the literature shows general good agreement for almost all elements in common., Comment: 15 pages, 4 figures and 13 tables. Table 13 is available in the online version of the paper

We determined the chemical composition of a large sample of weak G band stars -- a rare class of G and K giants of intermediate mass with unusual abundances of C, N, and Li. We have observed 24 weak G band stars with the 2.7 m Harlan J. Smith Telescope at the McDonald Observatory and derived spectroscopic abundances for C, N, O, and Li, as well as for selected elements from Na - Eu. The results show that the atmospheres of weak G band stars are highly contaminated with CN-cycle products. The C underabundance is about a factor of 20 larger than for normal giants and the $^{12}$C/$^{13}$C ratio approaches the CN-cycle equilibrium value. In addition to the striking CN-cycle signature the strong N overabundance may indicate the presence of partially ON-cycled material in the atmospheres of the weak G band stars. The exact mechanism responsible for the transport of the elements to the surface has yet to be identified but could be induced by rapid rotation of the main sequence progenitors of the stars. The unusually high Li abundances in some of the stars are an indicator for Li production by the Cameron-Fowler mechanism. A quantitative prediction of a weak G band star's Li abundance is complicated by the strong temperature sensitivity of the mechanism and its participants. In addition to the unusual abundances of CN-cycle elements and Li we find an overabundance of Na that is in accordance with the NeNa chain running in parallel with the CN-cycle. Apart from these peculiarities the element abundances in a weak G band star's atmosphere are consistent with those of normal giants., Comment: 18 pages, 18 figures, accepted for publication in ApJ

We present a non-local thermodynamic equilibrium abundance analysis of the resonance doublet Li I at 6707.8 A for 55 Galactic F and G supergiants and bright giants. The derived lithium abundances log \epsilon(Li) may be considered in three groups, namely: (i) 10 Li-rich giants with log \epsilon(Li) = 2.0-3.2 (all 10 are F-type or A9 stars); (ii) 13 G- to K0-type stars with Li abundances in the narrow range log \epsilon(Li) = 1.1-1.8; (iii) all other stars provide just upper limits to the Li abundance. The derived Li abundances are compared with theoretical predictions of 2-15 Msun stars. Our results are generally in good agreement with theory. In particular, the absence of detectable lithium for the majority of programme stars is explainable. The comparison suggests that the stars may be separated by mass M into two groups, namely M < 6 Msun and M > 6 Msun. All Li-rich giants and supergiants with log \epsilon(Li) > 2.0 have masses M < 6 Msun; 11 of 13 stars with log \epsilon(Li) = 1.1-1.8, specifically the stars with M < 6 Msun, show good agreement with the post-first dredge-up surface abundance log \epsilon(Li) = 1.4 predicted for the non-rotating 2-6 Msun stellar models. An absence of Li-rich stars in the range M > 6 Msun agrees with the theoretical prediction that F and G supergiants and giants with M > 6 Msun cannot show detectable lithium. We note that present theory appears unable to account for the derived Li abundances for some stars, namely for (i) a few relatively low-mass Li-rich giants (M < 6 Msun), whose high Li abundances accompanied by rather high rotational velocities or substantial nitrogen excess contradict theoretical predictions; (ii) the relatively high-mass supergiants HR 461 and HR 8313 (M > 6 Msun) with the detected abundances log \epsilon = 1.3-1.5. It is possible that the lithium in such stars was synthesized recently., Comment: 18 pages, 8 figures

The high resolution optical spectra of H-deficient stars, R Coronae Borealis stars and H-deficient carbon stars are analyzed by synthesizing the C2 Swan bands (0,1), (0,0), and (1,0) using our detailed line-list and Uppsala model atmosphere, to determine the C-abundances and the 12C/13C ratios which are potential clues to the formation process of these stars. The C-abundances derived from C2 bands are about the same for the adopted models constructed with different carbon abundances over the range 8.5 (C/He = 0.1%) to 10.5 (C/He = 10%). The carbon abundances derived from C I lines are a factor of four lower than that adopted for the model atmosphere over the same C/He interval, as reported by Asplund et al.: 'the carbon problem'. In principle, the carbon abundances obtained from C2 Swan bands and that adopted for the model atmosphere can be equated for a particular choice of C/He that varies from star to star (unlike C I lines). Then, the carbon problem for C2 bands is eliminated. However, such C/He ratios are in general less than those of the extreme helium stars, the seemingly natural relatives to the RCB and HdC stars. The derived carbon abundances and the 12C/13C ratios are discussed in light of the double degenerate (DD) and the final flash (FF) scenarios. The carbon abundance and the 12C/13C ratios for the FF product, Sakurai's Object is derived. The carbon abundance in the Sakurai's object is 10 times higher than in the RCB star VZ Sgr. On an average, the carbon abundance in the Sakurai's Object is about 10 to 100 times higher than in RCB stars. The 12C/13C ratio in Sakurai's Object is 3.4, the equilibrium value, as expected for FF products., Comment: Accepted for publication on Proceedings of Science

The remarkable hot R Coronae Borealis star DY Cen is revealed to be the first and only binary system to be found among the R Coronae Borealis (RCB) stars and their likely relatives, including the Extreme Helium stars and the hydrogen-deficient carbon stars. Radial velocity determinations from 1982-2010 have shown DY Cen is a single-lined spectroscopic binary in an eccentric orbit with a period of 39.67 days. It is also one of the hottest and most H-rich member of the class of RCB stars. The system may have evolved from a common-envelope to its current form., Comment: Published in The Astrophysical Journal Letters; one missing reference has been added in order to fit the published version ApJ, 760, L3

We search high-resolution and high-quality VLT/UVES optical spectra of the hot R Coronae Borealis (RCB) star DY Cen for electronic transitions of the C60 molecule and diffuse interstellar bands (DIBs). We report the non-detection of the strongest C60 electronic transitions (e.g., those at ~3760, 3980, and 4024 A). Absence of C60 absorption bands may support recent laboratory results, which show that the ~7.0, 8.5, 17.4, and 18.8 um emission features seen in DY Cen - and other similar objects with PAH-like dominated IR spectra - are attributable to proto-fullerenes or fullerene precursors rather than to C60. DIBs towards DY Cen are normal for its reddening; the only exception is the DIB at 6284 A (possibly also the 7223A DIB) that is found to be unusually strong. We also report the detection of a new broad (FWHM~2 A) and unidentified feature centered at ~4000 A. We suggest that this new band may be related to the circumstellar proto-fullerenes seen at infrared wavelengths., Comment: Accepted for publication in The Astrophysical Journal Letters (15 pages, 3 figures, and 2 tables)

We present abundances for 20 elements for stars in two stellar streams identified by Arifyanto & Fuchs (2006, A&A, 449, 533): 18 stars from the Arcturus stream and 26 from a new stream, which we call AF06 stream, both from the Galactic thick disk. Results show both streams are metal-poor and very old (10$-$14 Gyrs) with kinematics and abundances overlapping with the properties of local field thick disk stars. Both streams exhibit a range in metallicity but with relative elemental abundances that are identical to those of thick disk stars of the same metallicity. These results show that neither stream can result from dissolution of an open cluster. It is highly unlikely that either stream represents tidal debris from an accreted satellite galaxy. Both streams most probably owe their origin to dynamical perturbations within the Galaxy., Comment: 10 figures, Accepted for publication in MNRAS

In this study, we aim to reveal the nature of the Sloan Digital Sky Survey (SDSS) star: SDSS J100921.40+375233.9, suspected to have an extremely low metallicity. We observed this star at high spectral resolution and performed an abundance analysis. We derived the spectroscopic parameters Teff =5820+-125 K, log g = 3.9+-0.2, and xi = 1.1+-0.5 km/s. The star is consistent with belonging to the thick disk., Comment: To appear in Astronomical Society of India Conference Series (ASICS), P. Prugniel and H. P. Singh (Editors)

Observed spectra of R Coronae Borealis (RCB) and hydrogen-deficient carbon (HdC) stars are analyzed by synthesizing the C2 Swan bands (1,0), (0,0), and (0,1) using our detailed line list and the Uppsala model atmospheres. The (0,1) and (0,0) C2 bands are used to derive the 12C abundance, and the (1,0) 12C13C band to determine the 12C/13C ratios. The carbon abundance derived from the C2 Swan bands is about the same for the adopted models constructed with different carbon abundances over the range: 8.5 (C/He = 0.1%), to 10.5 (C/He = 10%). Carbon abundances derived from C I lines are about a factor of 4 lower than the carbon abundance of the adopted model atmosphere over the same C/He interval, as reported by Asplund et al. (2000), who dubbed the mismatch between adopted and derived C abundance the 'carbon problem'. In principle, the carbon abundances obtained from C2 Swan bands and that assumed for the model atmosphere can be equated for a particular choice of C/He that varies from star to star. Then, the carbon problem for C2 bands is eliminated. However, such C/He ratios are in general less than those of the EHe stars, the seemingly natural relatives to the RCB and HdC stars. A more likely solution to the C2 carbon problem may lie in a modification of the model atmosphere's temperature structure. The derived carbon abundances and the 12C/13C ratios are discussed in light of the double degenerate (DD) and the final flash (FF) scenarios., Comment: Accepted for Publication in ApJ

The star R Corona Borealis (R CrB) shows forbidden lines of [O II], [N II], and [S II] during the deep minimum when the star is fainter by about 8 to 9 magnitudes from normal brightness, suggesting the presence of nebular material around it. We present low and high spectral resolution observations of these lines during the ongoing deep minimum of R CrB, which started in July 2007. These emission lines show double peaks with a separation of about 170 km/s. The line ratios of [S II] and [O II] suggest an electron density of about 100 cm$^{-3}$. We discuss the physical conditions and possible origins of this low density gas. These forbidden lines have also been seen in other R Coronae Borealis stars during their deep light minima and this is a general characteristic of these stars, which might have some relevance to their origins., Comment: Proceedings IAU Symposium No.283, 2011 ` Planetary Nebulae: an Eye to the Future'

We have analyzed high-dispersion echelle spectra ($R \ga 50,000$) of red giant members for four open clusters to derive abundances for many elements. The spread in temperatures and gravities being very small among the red giants nearly the same stellar lines were employed thereby reducing the random errors. The errors of average abundance for the cluster were generally in 0.02 to 0.07 dex range. Our present sample covers galactocentric distances of 8.3 to 10.5 kpc. The [Fe/H] values are $-0.02\pm$0.05 for NGC 752, $-0.07\pm$0.06 for NGC 2360, $-0.11\pm$0.05 for NGC 1817 and $-0.19\pm$0.06 for NGC 2506. Abundances relative to Fe for elements from Na to Eu are equal within measurement uncertainties to published abundances for thin disk giants in the field. This supports the view that field stars come from disrupted open clusters., Comment: 13 pages, 4 figures and 12 tables