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The Honghai volcanogenic massive sulfide (VMS) deposit occurs in the Kalatage inlier of the Dananhu-Haerlik arc, Eastern Tianshan, in the southern Altaids. The deformed deposit, hosted in a suite of early Paleozoic basic to intermediate volcanic, volcaniclastic, and sedimentary rocks, consists of lenticular massive to semimassive, and sulfide-silicate stockwork orebodies. The orebodies are characterized by zoning of metallogenic elements and sulfide minerals outward from a central stockwork zone as follows: (Fe +/- Cu), (Fe + Cu + Zn + Au + Ag; Cu > Zn), (Fe + Zn + Cu + Au + Ag; Zn > Cu), and (Fe +/- [Cu/Zn]). A typical VMS hydrothermal alteration zone that formed around the foot of the massive orebodies is several times larger than the lenticular massive orebody. The hydrothermally altered rocks contain sericite, chlorite, and epidote zones from the core outward. Re-Os and argon dating of pyrite and sericite shows that the Honghai VMS deposit formed in the Early Silurian (436 +/- 2 Ma) and was deformed in the Early Devonian (410 +/- 4 Ma). This is the first documented early Paleozoic VMS deposit in the Eastern Tianshan. Our multidisciplinary data indicate that the Honghai Cu-Zn deposit formed in an immature/nascent island arc, where early tholeiitic lavas evolved into transitional basic-andesitic volcanic rocks and calc-alkaline intrusions with relatively high epsilon(Nd)(t) values (+6.2-+8.4) and low (Sr-87/Sr-86)(i) ratios (0.70412-0.70541). The Sr-Nd-Pb-S isotopic and geochemical data suggest that the ore-forming melts started in mantle-derived volcanic rocks and deep subvolcanic intrusions, and some alteration was influenced by seawater. The deposit formed in a high-level subvolcanic intrusion driven by sub-seafloor CO2-rich, NaCl-CaCl2-H2O hydrothermal fluids (temperatures: 99-377 degrees C, salinities: 6%-18% NaCl equivalent) circulating in active extensional faults in a submarine caldera. Extension of the immature (nascent) intra-oceanic arc was one of the important factors that controlled the development and preservation of the VMS deposit. Future work will benefit from this improved understanding of the VMS deposits formed in immature (nascent) intra-oceanic arcs, especially in early Paleozoic island arcs in the Eastern Tianshan in the southern Altaids.

A clear insight of the Indo-Burma amalgamation is required for an understanding of the complex processes of the Indo-Asian collision. Where and when the northeastern part of the Indian subcontinent amalgamated with the Burma plate has not yet been well defined. In order to better understand the tectonic affiliations and evolution of the Indo-Burma Ranges (IBR), we report new detrital zircon U-Pb and Hf isotope data of nine sandstone/siltstone samples (late Miocene–Pliocene) from the Chittagong-Tripura Fold Belt, Bangladesh, which is in the Neogene belt of the IBR. Our results show that the zircon ages of all nine samples have three peaks at

International audience

The general structure of the Chinese Altai has been traditionally regarded as being formed by five tectono-stratigraphic ‘terranes’ bounded by large-scale faults. However, numerous detrital zircon studies of the Paleozoic volcano-sedimentary sequences shown that the variably metamorphosed Cambro-Ordovician sequence, known as the Habahe Group, is present at least in four ‘terranes’. It structurally represents deepest rocks unconformably covered by Devonian and Carboniferous sedimentary and volcanic rocks. Calc-alkaline, mostly Devonian, granitoids that intruded all the terranes revealed their syn-subduction related setting. Geochemistry and isotope features of the syn-subduction granitoids have shown that they originated mainly from the melting of youthful sediments derived from an eroded Ordovician arc further north. In contrast, Permian alkaline granitoids, mostly located in the southern part of the Chinese Altai, reflect a post-subduction intraplate setting. The metamorphic evolution of the metasedimentary sequences shows an early MP-MT Barrovian event, followed by two Buchan events: LP-HT mid-Devonian (ca. 400–380 Ma) and UHT-HT Permian (ca. 300–270 Ma) cycles. The Barrovian metamorphism is linked to the formation of a regional sub-horizontal possibly Early Devonian fabric and the burial of the Cambro-Ordovician sequence. The Middle Devonian Buchan type event is related to intrusions of the syn-subduction granitoids during an extensional setting and followed by Late Devonian-Early Carboniferous NE-SW trending upright folding and crustal scale doming during a general NW-SE shortening, responsible for the exhumation of the hot lower crust. The last Permian deformation formed NW-SE trending upright folds and vertical zones of deformation related to the extrusion of migmatites, anatectic granitoids and granulite rocks, and to the intrusions of gabbros and granites along the southern border of the Chinese Altai. Finally, the Permo-Triassic cooling and thrust systems affected the whole mountain range from ca. 265 to 230 Ma. In conclusion, the Chinese Altai represents different crustal levels of the lower, middle and upper orogenic crust of a single Cambro-Ordovician accretionary wedge, heterogeneously affected by the Devonian polyphase metamorphism and deformation followed by the Permian tectono-thermal reworking event related to the collision with the Junggar arc. It is the interference of Devonian and Permian upright folding events that formed vertical boundaries surrounding the variously exhumed and eroded crustal segments. Consequently, these crustal segments should not be regarded as individual suspect terranes.

International audience

Structural analysis and U–Pb geochronological study on zircons from the southern Chinese Altai (the Kalasu area, SE of the Altai city) show that the Cambro-Ordovician accretionary wedge (ca. 520–492 Ma) underwent four major geological events: 1) emplacement of Early Devonian magmas (ca. 410–400) associated with formation of a volcano-sedimentary cover, 2) major Middle Devonian (ca. 390–374 Ma) tectono-metamorphic event, 3) Late Devonian-Early Carboniferous folding without apparent metamorphism, and 4) a regional folding with localized Early Permian high- to ultrahigh-temperature reworking (ca. 300–280 Ma). The Early Devonian magmatism is characterized by emplacement of mafic rocks and granitoids in the centre of the NE-SW profile, coevally with granitoid magmatism and rhyolite volcanism in the southwest and northeast, respectively. The whole volcano-sedimentary and magmatic edifice was transposed by sub-horizontal metamorphic fabric associated with variable metamorphic degrees in different areas ranging from greenschist facies in the northeast (mu + bi±g) to amphibolite facies in the southwest (st + g ± sill) and granulite facies in the centre (g + sill+kfs). This metamorphic architecture, distribution of magmatism and character of metamorphic zircon populations allow to correlate these areas with upper, middle and lower orogenic crust that developed during important vertical shortening and horizontal flow in Middle Devonian. Subsequently, the whole edifice was affected by regional NE-SW trending upright (possibly Late Devonian-Early Carboniferous) folding. Finally, Early Permian shortening produced NW-SE trending regional upright folds in the southwest and northeast and a crustal-scale vertical, tabular deformation zone in the centre. The Permian deformation is accompanied by granulite facies (kfs + cd + sill+g) metamorphism and anatexis reworking the Devonian lower orogenic crust, with extensive resetting and growth of new zircons and with intrusions of Permian granites and gabbros. This study suggests that the Early Permian event was related to massive perturbation of thermal structure of the mantle lithosphere due to the collision of the Junggar arc with the Chinese Altai terrane.

International audience; A new concept of continental construction based on four main terms: ( 1) crustal growth, (2) crustal formation, (3) continental growth and (4) continental formation is presented here. Each of these terms reflects a certain process responsible for the formation of what we call now "continental crust". This concept is applied to the Central Asian Orogenic Belt (CAOB), which is a global major accretionary orogen formed after the closure of the Paleo-Asian Ocean, and to its actualistic analogues - orogenic belts and accretionary complexes of the Western Pacific. The main focuses of the paper are the state of activities in the study of the CAOB, the theoretical basics of the new concept of continental construction, its challenges, prospects and social impacts, main methods of investigation. The main issues of the paper are what has been done in this field of geoscience, which questions remained unaddressed and which problems should be solved. The most important challenges are: (a) dominantly Phanerozoic formation of the CAOB continental crust versus its dominantly Archean growth; (h) to what extent the CAOB continental crust was juvenile or recycled; (c) whether magmatic arcs or Gondwana-derived terranes were accreted to the Siberian, Kazakhstan, Tarim and North China cratons; (d) what was the balance between continental formation and tectonic erosion based on modern examples from the Western Pacific; (e) what social benefits (mineral deposits) and geohazards (seismicity and volcanism) can be inferred from the study of orogenic belts formed in place of former oceans.

International audience; Using an automated coupled colorimetric assay for the Escherichia coli cyclopropane fatty acid synthase (CFAS), we have screened an academic chemical library of 3040 compounds, to identify new inhibitors of this enzyme. We identified 8 compounds as potent inhibitors of this enzyme, with IC(50) ranging from 1 to 10 microM, in the presence of 750 microM S-adenosyl-l-methionine and 1 mg/mL phospholipids. We conducted kinetic analyses of the inhibition of the CFAS using dioctylamine and three inhibitors identified in this report: sinefungin, 1, a synthetic S-adenosyl-l-homocysteine analog, 2, and an indoloquinolizine derivative, 3. The inhibition patterns observed were interpreted assuming that the E. coli CFAS operated via an ordered Bi Bi mechanism with binding of S-adenosyl-l-methionine first. Dioctylamine was the most potent inhibitor with a competitive inhibition constant of 130 nM with respect to the phospholipids. Compound 2 bound to the two substrate-binding sites of the enzyme suggesting that it acted as a bisubstrate analog (apparent inhibition constant, K(I)=6 microM). Compound 2 was also found to completely inhibit cyclopropanation of the phospholipids in growing E. coli cells, at 150 microM. This molecule is thus the first inhibitor of a cyclopropane synthase that is active in vivo, contrary to sinefungin and other analogs that are only active on the isolated enzyme.

We obtained 453.21.8 Ma and 449.41.8 Ma (2) laser step-heating 40 Ar/ 39 Ar plateau ages for phengite from quartzite mylonites from the blueschist- facies Ondor Sum subduction-accretion complex in Inner Mongolia (northern China). These ages are within error of the inverse isochron ages calculated using the plateau steps and the weighted mean ages of total fusion of single grains. The compositional change from glaucophane in the cores to crossite in the rims of blue amphiboles, as revealed by electron microprobe analysis, points to decompression, probably caused by progressive exhumation of the subducted material. The Late Ordovician ages were not affected by excess argon incorporation because in all likelihood the oceanic sediments were wet on arrival at the trench and free of older detrital mica. The ca. 450 Ma ages are, hence, interpreted as the time of crystallization during mylonitization under high fluid activity at fairly low temperatures. This means that accretion of the quartzite mylonite unit occured about 200 Ma before final closure of the Paleo-Asian Ocean, amalgamation of the Siberian, Tarim and North China cratons, and formation of the end-Permian Solonker suture zone. We argue that the Early Paleozoic evolution of the Ondor Sum complex occurred along the northeastern Cimmerian margin of Gondwana, which was composed of micro-continents fringed by subduction-accretion complexes and island arcs. The later evolution took place during the building of the Eurasian continent following middle Devonian and younger rifting along the East Gondwanan margin and northward drift of the detached North China craton. An extensive review shows that this type of two-stage scenario probably also applies to the geodynamic evolution of other micro- continents like, South China, Tarim, a number of Kazakh terranes, Alashan, Qaidam and Kunlun, as well as South Kitakami and correlatives in Japan, and probably Indochina. Like the North China craton, these were bordered by Early Paleozoic subduction-accretion complexes, island arcs or contained calc-alkaline volcanic mar- gins, like for example, the central Tienshan, North Qinling, North Qaidam-Altun, North Qilian and Kunlun belts in China, as well as the Oeyama and Miyamori ophiolites and Matsugadaira-Motai blueschist belt of Japan and the dismembered Sergeevka ophiolite of the southern part of the Russian Far East. This implies that a vast orogenic system, comprising an archipelago of micro-continents, seems to have existed along the Cimmerian margin of East Gondwana in Early Paleozoic time in which the ultrahigh-pressure metamorphism that characterizes the early evolution of many of the Asian micro-continents occurred. introduction and aim

We obtained 453.2 ± 1.8 Ma and 449.4 ± 1.8 Ma (2σ) laser step-heating Ar/Ar plateau ages for phengite from mylonitic meta-chert from the blueschist-facies Ondor Sum subduction-accretion complex in Inner Mongolia. These ages are within error of the inverse isochron ages calculated using the plateau steps and the weighted mean ages of total fusion of single grains. The compositional change from glaucophane in the cores to crossite in the rims of blue amphiboles, as revealed by electron microprobe analysis, points to decompression, probably caused by progressive exhumation of the subducted material. The Late Ordovician ages were not affected by excess or inherited argon because in all likelihood the oceanic sediments were wet on arrival at the trench and free of older detrital mica. The ca. 450 Ma ages are, hence, interpreted as the time of crystallization during mylonitization under high fluid activity at fairly low temperatures. This means that accretion of the meta-chert unit occurred about 200 Ma before final closure of the Palaeo-Asian Ocean, amalgamation of the Siberian, Tarim and North China cratons, and formation of the end-Permian Solonker suture zone that can be followed from Kyrgyzstan in the west to northernmost North Korea in the east. We argue that the early Palaeozoic evolution of the Ondor Sum complex occurred along the Cimmerian margin of East Gondwana, which was composed of micro-continents fringed by subduction-accretion complexes and island arcs. Only the later evolution took place during the building of the Eurasian continent following middle Devonian and younger rifting along the Gondwanan margin and northward drift of the detached North China craton. Such a two-stage scenario probably also applies to the geodynamic evolution of other micro-continents in Asia. This implies that a vast orogenic system, comprising an archipelago of micro-continents, seems to have existed along the Cimmerian margin of East Gondwana in early Palaeozoic time in which the ultrahigh-pressure metamorphism that characterizes the early evolution of many of the Asian micro-continents occurred. < Am. J. Sci., in press >

International audience; The Feidong-Zhangbaling Massif is located between the Dabieshan and Sulu areas along the Tan-Lu fault in eastern China. Five tectonic-metamorphic events are distinguished there. The earliest deformation (D1) corresponds to a southward compression that occurred during subduction of the South China Block below the North China Block. Top-to-the-south shearing is coeval with Late Permian-Early Triassic blueschist facies metamorphism, and possibly with the development of south-verging recumbent folds in the Neoproterozoic-Paleozoic sedimentary cover of the South China foreland. The main ductile deformation (D2) is an extensional one, characterized by top-to-the-north shearing, coeval with the early stage of exhumation of the high-pressure rocks. A top-to-the-NW ductile shearing, and microfolds overturned to the northwest, belong to a second deformational phase of exhumation (D3) which is distinct from the main event (D2). Previous 40Ar–39Ar mica dates ranging between 245 and 212 Ma suggest Late Permian-Early Triassic ages for the D1 to D3 events. The D4 event produced NE–SW trending folds in the sedimentary cover interpreted as gravity collapse structures. A Late Cretaceous brittle extensional event (D5) controls the opening and infill of continental half-grabens. In the study area, the Tan-Lu fault is a Cretaceous brittle normal fault. The lack of ductile deformation presented along the Tan-Lu fault suggests that it did not play a significant role in the exhumation of high-pressure metamorphic rocks.