Search

Context. Abundances of s- and r-process elements in Sun-like stars constrain nucleosynthesis in extreme astrophysical events, such as compact binary mergers and explosions of highly magnetised rapidly rotating massive stars. Aims. We measure solar abundances of yttrium (Y) and europium (Eu) using 3D non-local thermal equilibrium (NLTE) models. We use the model to determine the abundance of Y, and also explore the model's ability to reproduce the solar centre-to-limb variation of its lines. In addition, we determine the Eu abundance using solar disc-centre and integrated flux spectra. Methods. We developed an NLTE model of Eu and updated our model of Y with collisional data from detailed quantum-mechanical calculations. We used the IAG spatially resolved high-resolution solar spectra to derive the solar abundances of Y across the solar disc and of Eu for integrated flux and at disc centre using a set of carefully selected lines and a 3D radiation-hydrodynamics model of the solar atmosphere. Results. We find 3D NLTE solar abundances of A(Y)$_{\textrm{3D NLTE}}$=$2.30 \pm 0.03_{\textrm{stat}} \pm 0.07_{\textrm{syst}}$ dex based on observations at all angles and A(Eu)$_{\textrm{3D NLTE}}$=$0.57 \pm 0.01_{\textrm{stat}} \pm 0.06_{\textrm{syst}}$ dex based on the integrated flux and disc-centre intensity. 3D NLTE modelling offers the most consistent abundances across the solar disc, and resolves the problem of severe systematic bias in Y and Eu abundances inherent to 1D LTE, 1D NLTE, and 3D LTE modelling., Comment: 8 pages, 4 figures, accepted by A&A

We present i and z photometry for 25 T dwarfs and one L dwarf. Combined with published photometry, the data show that the i - z, z - Y and z - J colors of T dwarfs are very red, and continue to increase through to the late-type T dwarfs, with a hint of a saturation for the latest types with T_eff ~ 600 K. We present new 0.7-1.0 um and 2.8-4.2 um spectra for the very late-type T dwarf UGPS J072227.51-054031.2, as well as improved astrometry for this dwarf. Examination of the spectral energy distribution using the new and published data, with Saumon & Marley models, shows that the dwarf has T_eff = 505 +/- 10 K, a mass of 3-11 M_Jupiter and an age between 60 Myr and 1 Gyr. This young age is consistent with the thin disk kinematics of the dwarf. The mass range overlaps with that usually considered to be planetary, despite this being an unbound object discovered in the field near the Sun. This apparently young rapid rotator is also undergoing vigorous atmospheric mixing, as determined by the IRAC and WISE-2 4.5 um photometry and the Saumon & Marley models. The optical spectrum for this 500 K object shows clearly detected lines of the neutral alkalis Cs and Rb, which are emitted from deep atmospheric layers with temperatures of 900-1200 K., Comment: 46 pages, 5 Tables, 15 Figures; accepted for publication in ApJ, January 13 2012

We report abundances of elements from 26Fe to 34Se in the cosmic radiation measured during fifty days of exposure of the Trans-Iron Galactic Element Recorder (TIGER) balloon-borne instrument. These observations add support to the concept that the bulk of cosmic-ray acceleration takes place in OB associations, and they further support cosmic-ray acceleration models in which elements present in interstellar grains are accelerated preferentially compared with those found in interstellar gas., Comment: 18 pages including 9 figures

We develop a new 1D photochemical kinetics code to address stratospheric chemistry and stratospheric heating in hot Jupiters. Here we address optically active S-containing species and CO2 at 1200 < T < 2000 K. HS (mercapto) and S2 are highly reactive species that are generated photochemically and thermochemically from H2S with peak abundances between 1-10 mbar. S2 absorbs UV between 240 and 340 nm and is optically thick for metallicities [SH] > 0 at T > 1200 K. HS is probably more important than S2, as it is generally more abundant than S2 under hot Jupiter conditions and it absorbs at somewhat redder wavelengths. We use molecular theory to compute an HS absorption spectrum from sparse available data and find that HS should absorb strongly between 300 and 460 nm, with absorption at the longer wavelengths being temperature sensitive. When the two absorbers are combined, radiative heating (per kg of gas) peaks at 100 microbars, with a total stratospheric heating of about 8 x 10^4 W/m^2 for a jovian planet orbiting a solar-twin at 0.032 AU. Total heating is insensitive to metallicity. The CO2 mixing ratio is a well-behaved quadratic function of metallicity, ranging from 1.6 x 10^-8 to 1.6 x 10^-4 for -0.3 < [M/H] < 1.7. CO2 is insensitive to insolation, vertical mixing, temperature (1200 < T <2000 K), and gravity. The photochemical calculations confirm that CO2 should prove a useful probe of planetary metallicity., Comment: Astrophysical Journal Lett. in press; important revision includes effect of updated thermodynamic data and a new opacity source

A review of the abundances and condensation temperatures of the elements and their nuclides in the solar nebula and in chondritic meteorites. Abundances of the elements in some neighboring stars are also discussed., Comment: 42 pages, 11 tables, 8 figures, chapter, In Landolt- B\"ornstein, New Series, Vol. VI/4B, Chap. 4.4, J.E. Tr\"umper (ed.), Berlin, Heidelberg, New York: Springer-Verlag, p. 560-630

The atmospheres of substellar objects contain clouds of oxides, iron, silicates, and other refractory condensates. Water clouds are expected in the coolest objects. The opacity of these `dust' clouds strongly affects both the atmospheric temperature-pressure profile and the emergent flux. Thus any attempt to model the spectra of these atmospheres must incorporate a cloud model. However the diversity of cloud models in atmospheric simulations is large and it is not always clear how the underlying physics of the various models compare. Likewise the observational consequences of different modeling approaches can be masked by other model differences, making objective comparisons challenging. In order to clarify the current state of the modeling approaches, this paper compares five different cloud models in two sets of tests. Test case 1 tests the dust cloud models for a prescribed L, L--T, and T-dwarf atmospheric (temperature T, pressure p, convective velocity vconv)-structures. Test case 2 compares complete model atmosphere results for given (effective temperature Teff, surface gravity log g). All models agree on the global cloud structure but differ in opacity-relevant details like grain size, amount of dust, dust and gas-phase composition. Comparisons of synthetic photometric fluxes translate into an modelling uncertainty in apparent magnitudes for our L-dwarf (T-dwarf) test case of 0.25 < \Delta m < 0.875 (0.1 < \Delta m M 1.375) taking into account the 2MASS, the UKIRT WFCAM, the Spitzer IRAC, and VLT VISIR filters with UKIRT WFCAM being the most challenging for the models. (abr.), Comment: 22 pages, 17 figures, MNRAS 2008, accepted, (minor grammar/typo corrections)

A test case comparison is presented for different dust cloud model approaches applied in brown dwarfs and giant gas planets. We aim to achieve more transparency in evaluating the uncertainty inherent to theoretical modelling. We show in how far model results for characteristic dust quantities vary due to different assumptions. We also demonstrate differences in the spectral energy distributions resulting from our individual cloud modelling in 1D substellar atmosphere simulations, Comment: 5 pages, Proceeding to "Exoplantes: Detection, Formation, Dynamics", eds. Ferraz-Mello et a

We present new infrared spectra of the T8 brown dwarf 2MASS J04151954-0935066: 2.9-4.1 micron spectra obtained with the Infrared Camera and Spectrograph on the Subaru Telescope, and 5.2-14.5 micron spectra obtained with the Infrared Spectrograph on the Spitzer Space Telescope. We use these data and models to determine an accurate bolometric luminosity of log L_bol/L_sun=-5.67 and to constrain the effective temperature, gravity, mass and age to 725-775K, log g=5.00-5.37, M=33-58 M_Jupiter and age=3-10Gyr. We perform the same analysis using published 0.6-15 micron spectra for the T7.5 dwarf 2MASS J12171110-0311131, for which we find a metal-rich composition ([Fe/H]~0.3) and log L_bol/L_sun=-5.31, T_eff=850-950K, log g=4.80-5.42, M=25-66M_Jupiter and age=1-10Gyr. These luminosities and effective temperatures straddle those determined with the same method and models for Gl 570D by Saumon et al. (2006) and make 2MASS J04151954-0935066 the coolest and least luminous T dwarf with well-determined properties. We find that synthetic spectra generated by the models reproduce the observed red through mid-infrared spectra of 2MASS J04151954-0935066 and 2MASS J12171110-0311131 very well, except for known discrepancies which are most likely due to the incomplete CH4 opacities. Both objects show evidence of departures from strict chemical equilibrium and we discuss this result in the context of other late T dwarfs where disequilibrium phenomena have been observed., Comment: Accepted for publication in the Ap. J. 35 pages, including 12 figures (10 in color)

We study the nature of the [TiII] and [NiII] emission from the so-called strontium filament found in the ejecta of eta Carinae. To this purpose we employ multilevel models of the TiII and NiII systems which are used to investigate the physical condition of the filament and the excitation mechanisms of the observed lines. For the TiII ion, for which no atomic data was previously available, we carry out ab initio calculations of radiative transition rates and electron impact excitation rate coefficients. It is found that the observed spectrum is consistent with the lines being excited in a mostly neutral region with an electron density of the order of $10^7$ cm$^{-3}$ and a temperature around 6000 K. In analyzing three observations with different slit orientations recorded between March~2000 and November~2001 we find line ratios that change among various observations, in a way consistent with changes of up to an order of magnitude in the strength of the continuum radiation field. These changes result from different samplings of the extended filament, due to the different slit orientations used for each observation, and yield clues on the spatial extent and optical depth of the filament. The observed emission indicates a large Ti/Ni abundance ratio relative to solar abundances. It is suggested that the observed high Ti/Ni ratio in gas is caused by dust-gas fractionation processes and does not reflect the absolute Ti/Ni ratio in the ejecta of \etacar. We study the condensation chemistry of Ti, Ni and Fe within the filament and suggest that the observed gas phase overabundance of Ti, Comment: 14 paginas, 12 figures

We present the first analysis of an optical to mid-infrared spectrum of the T7.5 dwarf Gliese 570D with model atmospheres, synthetic spectra, and brown dwarf evolution sequences. We obtain precise values for the basic parameters of Gl 570D: Teff=800 - 820K, log g (cm/s^2)=5.09 - 5.23, and log L/Lsun= -5.525 to -5.551. The Spitzer IRS spectrum shows prominent features of ammonia (NH3) that can only be fitted by reducing the abundance of NH3 by about one order of magnitude from the value obtained with chemical equilibrium models. We model departures from chemical equilibrium in the atmosphere of Gl 570D by considering the kinetics of nitrogen and carbon chemistry in the presence of vertical mixing. The resulting model spectrum reproduces the data very well., Comment: Accepted for publication in the ApJ. 10 pages, including 3 figures

We investigate the atmosphere and interior of the new transiting planet HD 149026b, which appears to be very rich in heavy elements. We first compute model atmospheres at metallicities ranging from solar to ten times solar, and show how for cases with high metallicity or inefficient redistribution of energy from the day side, the planet may develop a hot stratosphere due to absorption of stellar flux by TiO and VO. The spectra predicted by these models are very different than cooler atmosphere models without stratospheres. The spectral effects are potentially detectable with the Spitzer Space Telescope. In addition the models with hot stratospheres lead to a large limb brightening, rather than darkening. We compare the atmosphere of HD 149026b to other well-known transiting planets, including the recently discovered HD 189733b, which we show have planet-to-star flux ratios twice that of HD 209458 and TrES-1. The methane abundance in the atmosphere of HD 189733b is a sensitive indicator of atmospheric temperature and metallicity and can be constrained with Spitzer IRAC observations. We then turn to interior studies of HD 149026b and use a grid of self-consistent model atmospheres and high-pressure equations of state for all components to compute thermal evolution models of the planet. We estimate that the mass of heavy elements within the planet is in the range of 60 to 93 M_earth. Finally, we discuss trends in the radii of transiting planets with metallicity in light of this new member of the class., Comment: Accepted to the Astrophysical Journal. 18 pages, including 10 figures. New section on the atmosphere of planet HD 189733b. Enhanced discussion of atmospheric Ti chemistry and core mass for HD 149026b

We present new self-consistent atmosphere models for transiting planets TrES-1 and HD209458b. The planets were recently observed with the Spitzer Space Telescope in bands centered on 4.5 and 8.0 $\mu$m, for TrES-1, and 24 $\mu$m, for HD209458b. We find that standard solar metallicity models fit the observations for HD209458b. For TrES-1, which has an T_eff ~300 K cooler, we find that models with a metallicity 3-5 times enhanced over solar abundances can match the 1$\sigma$ error bar at 4.5 $\mu$m and 2$\sigma$ at 8.0$\mu$m. Models with solar abundances that included energy deposition into the stratosphere give fluxes that fall within the 2$\sigma$ error bars in both bands. The best-fit models for both planets assume that reradiation of absorbed stellar flux occurs over the entire planet. For all models of both planets we predict planet/star flux ratios in other Spitzer bandpasses., Comment: Accepted to the Astrophysical Journal Letters, May 17, 2005

We present an analysis of brown dwarf model spectra in the mid-infrared spectral region (5 - 20 microns), in anticipation of data obtained with the Space Infrared Telescope Facility. The mid-infrared spectra of brown dwarfs are in several ways simpler than those in the near-infrared and yet provide powerful diagnostics of brown dwarf atmospheric physics and chemistry, especially when combined with ground-based data. We discuss the possibility of detection of new molecular species and of the silicate cloud, predict strong observational diagnostics for non-equilibrium chemistry between CO and CH4, and N2 and NH3, and speculate on the possibility of discovering brown dwarf stratospheres., Comment: 14 pages, including 3 figures and 1 table. Submitted to ApJ Letters

A sophisticated approach to condensate opacity is required to properly model the atmospheres of L and T dwarfs. Here we review different models for the treatment of condensates in brown dwarf atmospheres. We conclude that models which include both particle sedimentation and upwards transport of condensate (both gas and particles) provide the best fit for the L dwarf colors. While a globally uniform cloud model fits the L dwarf data, it turns to the blue in J-K too slowly to fit the T dwarfs. Models which include local clearings in the global cloud deck, similar to Jupiter's prominent five-micron hot spots, better reproduce the available photometric data and also account for the observed resurgence of FeH absorption in early type T dwarfs., Comment: 12 pages, 2 figures, in newpasp.sty format, To appear in "IAU Symposium 211: Brown Dwarfs", E.L. Martin Ed., Publications of the Astronomical Society of the Pacific, Conference Series

Carbon monoxide and ammonia have been detected in the spectrum of Gl 229B at abundances that differ substantially from those obtained from chemical equilibrium. Vertical mixing in the atmosphere is a mechanism that can drive slowly reacting species out of chemical equilibrium. We explore the effects of vertical mixing as a function of mixing efficiency and effective temperature on the chemical abundances in the atmospheres of brown dwarfs and on their spectra. The models compare favorably with the observational evidence and indicate that vertical mixing plays an important role in brown dwarf atmospheres., Comment: 9 pages, 4 figures, to appear in the proceedings of the IAU symposium 211 on "Brown dwarfs"

The optical and infrared colors of L and T dwarfs are sensitive to cloud sedimentation and chemical equilibrium processes in their atmospheres. The i'-z' vs. J-K color-color diagram provides a window into diverse atmospheric processes mainly because different chemical processes govern each color, and cloud opacity largely affects J-K but not i'-z'. Using theoretical atmosphere models that include for the first time a self-consistent treatment of cloud formation, we present an interpretation of the i'-z' vs. J-K color trends of known L and T dwarfs. We find that the i'-z' color is extremely sensitive to chemical equilibrium assumptions: chemical equilibrium models accounting for cloud sedimentation predict redder i'-z' colors--by up to 2 magnitudes--than models that neglect sedimentation. We explore the previously known J-K color trends where objects first become redder, then bluer with decreasing effective temperature. Only models that include sedimentation of condensates are able to reproduce these trends. We find that the exact track of a cooling brown in J-K (and i'-z') is very sensitive to the details of clouds, in particular to the efficiency of sedimentation of condensates in its atmosphere. We also find that clouds still affect the strength of the J, H, and K band fluxes of even the coolest T dwarfs. In addition, we predict the locus in the i'-z' vs. J-K color-color diagram of brown dwarfs cooler than yet discovered., Comment: 20 pages, 4 figures, AASTex, accepted by Astrophysical Journal; replacement version substantially expands discussion of clouds and chemical processes and adds figure showing model temperature profiles

We have obtained a good quality R$\sim$400 0.8-2.5 $\mu$m spectrum and accurate photometry of Gl 570D, one of the coolest and least luminous brown dwarfs currently known. The spectrum shows that Gl 570D has deeper absorptions in the strong water and methane bands at 1.12-1.17 $\mu$m, 1.33-1.45 $\mu$m, 1.62-1.88 $\mu$m, and 2.20-2.45 $\mu$m and is both bluer at J-K and redder at $K-L^{\prime}$ than previously observed T dwarfs. Data analysis using model spectra coupled with knowledge of the well-understood primary implies that for the same surface gravity, Gl 570D is about 160 K cooler than Gl 229B. For an age range of 2-5 Gyr Gl 570D has an effective temperature in the range 784-824 K, a log gravity in the range 5.00-5.27 cm s$^{-2}$, and a luminosity in the range 2.88-2.98 $\times$ 10$^{-6}$ L$_\odot$., Comment: 22 pages (Latex) and 4 figures (postscript); accepted for publication by ApJ (main journal)

We present new, high resolution, infrared spectra of the T dwarf Gliese 229B in the J, H, and K bandpasses. We analyze each of these as well as previously published spectra to determine its metallicity and the abundances of NH3 and CO in terms of the surface gravity of Gl 229B, which remains poorly constrained. The metallicity increases with increasing gravity and is below the solar value unless Gl 229B is a high-gravity brown dwarf with log g(cgs) ~ 5.5. The NH3 abundance is determined from both the H and the K band spectra which probe two different levels in the atmosphere. We find that the abundance from the K band data is well below that expected from chemical equilibrium, which we interpret as strong evidence for dynamical transport of NH3 in the atmosphere. This is consistent with the previous detection of CO and provides additional constraints on the dynamics of the atmosphere of this T dwarf., Comment: 22 pages and 19 figures. Accepted for publication in the Astrophysical Journal

We study the chemical abundances of the Strontium Filament found in the ejecta of (eta) Carinae. In particular, we derive the abundances of iron-peak elements front spectra of their singly ionized ions present in the optical/IR spectra. In this paper we analyze the spectrum of Mn II using a new non-LTE model for this system. In constructing this models we carried out theoretical calculations of radiative transition rates and electron impact excitation rate coefficients. We find that relative to Ni the gas phase abundance ratio of Mn is roughly solar, similar to the Cr abundance but in contrast to the large enhancements in the abundances of Sc and Ti. NVe interpret this result as an indication of non-equilibrium condensation in the ejecta of (eta) Carinae.

We report results from 50 days of data accumulated in two Antarctic flights of the Trans-Iron Galactic Element Recorder (TIGER). With a detector system composed of scintillators, Cherenkov detectors, and scintillating optical fibers, TIGER has a geometrical acceptance of 1.7 sq m sr and a charge resolution of 0.23 cu at Iron. TIGER has obtained abundance measurements of some of the rare galactic cosmic rays heavier than iron, including Zn, Ga, Ge, Se, and Sr, as well as the more abundant lighter elements (down to Si). The heavy elements have long been recognized as important probes of the nature of the galactic cosmic-ray source and accelerator. After accounting for fragmentation of cosmic-ray nuclei as they propagate through the Galaxy and the atmosphere above the detector system, the TIGER source abundances are consistent with a source that is a mixture of about 20% ejecta from massive stars and 80% interstellar medium with solar system composition. This result supports a model of cosmic-ray origin in OB associations previously inferred from ACE-CRIS data of more abundant lighter elements. These TIGER data also support a cosmic-ray acceleration model in which elements present in interstellar grains are accelerated preferentially compared with those found in interstellar gas.

We continue a systematic study of chemical abundances of the Strontium Filament found in the ejecta of eta Carinae. To this end we interpret the emission spectrum of Sc II and Cr II using multilevel non-LTE models of these systems. Since the atomic data for these ions was previously unavailable, we carry out ab initio calculations of radiative transition rates and electron impact excitation rate coefficients. The observed spectrum is emitted from a mostly neutral region with electron density of the order of 10(exp 7) cm (exp -3) and a temperature between 6000 and 7000 K. These conditions are consistent with our previous diagnostics from [Ni II], [Ti II], amd [Sr II]. The observed spectrum indicates an abundance of Sc relative Ni that more than 40 times the solar values, while the Cr/Ni abundance ratio is roughly solar. Various scenarios of depletion and dust destruction are suggested to explain such abnormal abundances.

We study the nature of the [Ti II] and [Ni II] emission from the so-called strontium filament found in the ejecta of eta Carinae. To this purpose we employ multilevel models of the Ti II and Ni II systems which are used to investigate the physical condition of the filament and the excitation mechanisms of the observed lines. For the Ti II ion, for which no atomic data was previously available, we carry out ab initio calculations of radiative transition rates and electron impact excitation rate coefficients. It is found that the observed spectrum is consistent with the lines being excited in a mostly neutral region with an electron density of the order of 10(exp 7) per cubic centimeter and a temperature around 6000 K. In analyzing three observations with different slit orientations recorded between March 2000 and November 2001 we find line ratios that change among various observations, in a way consistent with changes of up to an order of magnitude in the strength of the continuum radiation field. These changes result from different samplings of the extended filament, due to the different slit orientations used for each observation, and yield clues on the spatial extent and optical depth of the filament. The observed emission indicates a large Ti/Ni abundance ratio relative to solar abundances. It is suggested that the observed high Ti/Ni ratio in gas is caused by dust-gas fractionation processes and does not reflect the absolute Ti/Ni ratio in the ejecta of eta Carinae. We study the condensation chemistry of Ti, Ni and Fe within the filament and suggest that the observed gas phase overabundance of Ti is likely the result of selective photo-evaporation of Ti-bearing grains. Some mechanisms for such a scenario are proposed.

We study the nature of the [Ti II] and [Ni II] emission from the so-called strontium filament found in the ejecta of eta Carinae. To this purpose we employ multilevel models of the Ti II and Ni II systems which are used to investigate the physical condition of the filament and the excitation mechanisms of the observed lines. For the Ti II ion, for which no atomic data was previously available, we carry out ab initio calculations of radiative transition rates and electron impact excitation rate coefficients. It is found that the observed spectrum is consistent with the lines being excited in a mostly neutral region with electron density of the order of 10(exp 7) cm(exp -3) and a temperature around 6000 K. In analyzing three observations with different slit orientations recorded between March 2000 and November 2001 we find line ratios that change among various observations, in a way consistent with changes of up to an order of magnitude in the strength of the continuum radiation field. These changes result from different samplings of the extended filament, due to the different slit orientations used for each observation, and yield clues on the spatial extent and optical depth of the filament. The observed emission indicates a large Ti/Ni abundance ratio relative to solar abundances. It is suggested that the observed high Ti/Ni ratio in gas is caused dust-gas fractionation processes and does not reflect the absolute Ti/Ni ratio in the ejecta of eta Carinae. The condensation chemistry shows that if dust condensed in a sequence of layers according to decreasing temperature and increasing distance from the central star, the most refractory dust could be selectively affected by photoevaporation. Thus, Ti would be released back to the gas and the Ti/Ni ratio in the gas would increase to the observed super-solar ratio.

To date, approximately 120 planet-sized objects have been discovered around other stars, mostly through the radial-velocity technique. This technique can provide information about a planet s minimum mass and its orbital period and distance; however, few other planetary data can be obtained at this point in time unless we are fortunate enough to find an extrasolar giant planet that transits its parent star (i.e., the orbit is edge-on as seen from Earth). In that situation, many physical properties of the planet and its parent star can be determined, including some compositional information. Our prospects of directly obtaining spectra from extrasolar planets may improve in the near future, through missions like NASA's Terrestrial Planet Finder. Most of the extrasolar giant planets (EGPs) discovered so far have masses equal to or greater than Jupiter's mass, and roughly 16% have orbital radii less than 0.1 AU - extremely close to the parent star by our own Solar-System standards (note that Mercury is located at a mean distance of 0.39 AU and Jupiter at 5.2 AU from the Sun). Although all EGPs are expected to have hydrogen-dominated atmospheres similar to Jupiter, the orbital distance can strongly affect the planet's temperature, physical, chemical, and spectral properties, and the abundance of minor, detectable atmospheric constituents. Thermochemical equilibrium models can provide good zero-order predictions for the atmospheric composition of EGPs. However, both the composition and spectral properties will depend in large part on disequilibrium processes like photochemistry, chemical kinetics, atmospheric transport, and haze formation. We have developed a photochemical kinetics, radiative transfer, and 1-D vertical transport model to study the atmospheric composition of EGPs. The chemical reaction list contains H-, C-, O-, and N-bearing species and is designed to be valid for atmospheric temperatures ranging from 100-3000 K and pressures up to 50 bar. Here we examine the effect of stellar distance (e.g., incident ultraviolet flux, atmospheric temperature) on the chemical properties of EGPs. The model is applied to two generic Class II and III intermediate temperature EGPs located at 3.3 and 0.27 AU from a solar-like parent star, and the results are compared with a model for Jupiter at 5.2 AU.

We discovered that the abundances of now extinct radioactivities (relative to stable reference isotopes) in meteorites vary as a function of their mean lifetimes squared. This relationship applies to chondrites, achondrites, and irons but to calcium-aluminum inclusions (CAIs). Certain meteorites contain excesses in isotopic abundances from the decay of radioactive isotopes with half-lives much less than the age of the solar system. These short-lived radioactivities are now extinct, but they were alive when meteorites assembled in the early solar system. The origin of these radioactivities and the processes which control their abundances in the solar nebula are still not well understood. Some clues may come from our finding that the meteoritic abundances of now extinct radioactivities (relative to stable reference isotopes) vary as a function of their mean lifetimes squared. This relationship applies to chondrites, achondrites, and irons, but not to CAIs. This points to at least two different processes establishing the abundances of short-lived isotopes found in the meteoritic record.

The abundances of alkali elements in the Earth's core are predicted by assuming that accretion of the Earth started from material similar in composition to enstatite chondrites and that enstatite achondrites (aubrites) provide a natural laboratory to study core-mantle differentiation under extremely reducing conditions. If core formation on the aubrite parent body is comparable with core formation on the early Earth, it is found that 2600 (+/- 1000) ppm Na, 550 (+/- 260) ppm K, 3.4 (+/- 2.1) ppm Rb, and 0.31 (+/- 0.24) ppm Cs can reside in the Earth's core. The alkali-element abundances are consistent with those predicted by independent estimates based on nebula condensation calculations and heat flow data.

The depletion of Na, K, Rb, and Cs in the Earth's upper mantle and crust relative to their abundances in chondrites is a long standing problem in geochemistry. Here we consider two commonly invoked mechanisms, namely core formation, and vaporization, for producing the observed depletions. Our models predict that a significant percentage of the Earth's bulk alkali element inventory is in the core (30 percent for Na, 52 percent for K, 74 percent for Rb, and 92 percent for Cs). These predictions agree with independent estimates from nebular volatility trends and (for K) from terrestrial heat flow data. Our models also predict that vaporization and thermal escape during planetary accretion are unlikely to produce the observed alkali element depletion pattern. However, loss during the putative giant impact which formed the Moon cannot be ruled out. Experimental, observational, and theoretical tests of our predictions are also described. Alkali element partitioning into the Earth's core was modeled by assuming that alkali element partitioning during core formation on the aubrite parent body (APB) is analogous to that on the early Earth. The analogy is reasonable for three reasons. First, the enstatite meteorites are the only known meteorites with the same oxygen isotope systematics as the Earth-Moon system. Second, the large core size of the Earth and the V depletion in the mantle requires accretion from planetesimals as reduced as the enstatite chondrites. Third, experimental studies of K partitioning between silicate and metal plus sulfide show that more K goes into the metal plus sulfide at higher pressures than at one atmosphere pressure. Thus partitioning in the relatively low pressure natural laboratory of the APB is a good guide to alkali elemental partitioning during the growth of the Earth.

A detailed chemical study is conducted of the Pena Blanca Spring aubrite in order to clarify both the origin of the aubrite parent body (APB) and its relation to the enstatite chondrites. The distribution of REE among aubritic minerals cannot be the result of fractional distillation, which would occur if high degrees of partial melting had occurred on the APB. The REE distributions instead indicate a complete equilibrium of oldhamite and other phases, so that a brief nonequilibrium melting episode must have led to the segregation of metal and sulfides.

This abstract reports results of an experimental study of the chemical weathering of pyrite (FeS2) under Venus-like conditions. This work, which extends the earlier study by Fegley and Treiman, is part of a long range research program to experimentally measure the rates of thermochemical gas-solid reactions important in the atmospheric-lithospheric sulfur cycle on Venus. The objectives of this research are (1) to measure the kinetics of thermochemical gas-solid reactions responsible for both the production (e.g., anhydrite formation) and destruction (e.g., pyrrhotite oxidation) of sulfur-bearing minerals on the surface of Venus and (2) to incorporate these and other constraints into holistic models of the chemical interactions between the atmosphere and surface of Venus. Experiments were done with single crystal cubes of natural pyrite (Navajun, Logrono, Spain) that were cut and polished into slices of known weight and surface area. The slices were isothermally heated at atmospheric pressure in 99.99 percent CO2 (Coleman Instrument Grade) at either 412 C (685 K) or 465 C (738 K) for time periods up to 10 days. These two isotherms correspond to temperatures at about 6 km and 0 km altitude, respectively, on Venus. The reaction rate was determined by measuring the weight loss of the reacted slices after removal from the furnace. The reaction products were characterized by X-ray diffraction, scanning electron microscopy, and energy dispersive spectroscopy on the SEM.