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We present extensive new ab initio path integral Monte Carlo (PIMC) results for a variety of structural properties of warm dense hydrogen and beryllium. To deal with the fermion sign problem—an exponential computational bottleneck due to the antisymmetry of the electronic thermal density matrix—we employ the recently proposed [Y. Xiong and H. Xiong, J. Chem. Phys. 157, 094112 (2022); T. Dornheim et al., J. Chem. Phys. 159, 164113 (2023)] ξ-extrapolation method and find excellent agreement with the exact direct PIMC reference data where available. This opens up the intriguing possibility of studying a gamut of properties of light elements and potentially material mixtures over a substantial part of the warm dense matter regime, with direct relevance for astrophysics, material science, and inertial confinement fusion research. [ABSTRACT FROM AUTHOR]

Localized atomic orbitals are the preferred basis set choice for large-scale explicit correlated calculations, and high-quality hierarchical correlation-consistent basis sets are a prerequisite for correlated methods to deliver numerically reliable results. At present, numeric atom-centered orbital (NAO) basis sets with valence correlation consistency (VCC), designated as NAO-VCC-nZ, are only available for light elements from hydrogen (H) to argon (Ar) [Zhang et al., New J. Phys. 15, 123033 (2013)]. In this work, we extend this series by developing NAO-VCC-nZ basis sets for krypton (Kr), a prototypical element in the fourth row of the periodic table. We demonstrate that NAO-VCC-nZ basis sets facilitate the convergence of electronic total-energy calculations using the Random Phase Approximation (RPA), which can be used together with a two-point extrapolation scheme to approach the complete basis set limit. Notably, the Basis Set Superposition Error (BSSE) associated with the newly generated NAO basis sets is minimal, making them suitable for applications where BSSE correction is either cumbersome or impractical to do. After confirming the reliability of NAO basis sets for Kr, we proceed to calculate the Helmholtz free energy for Kr crystal at the theoretical level of RPA plus renormalized single excitation correction. From this, we derive the pressure–volume (P–V) diagram, which shows excellent agreement with the latest experimental data. Our work demonstrates the capability of correlation-consistent NAO basis sets for heavy elements, paving the way toward numerically reliable correlated calculations for bulk materials. [ABSTRACT FROM AUTHOR]

We employed a double-layer coupled diffractive optical element, based on metasurfaces and diffraction gratings, which exhibits wavefront modulation and chromatic dispersion compensation. Utilizing this double-layer coupled diffractive optical element in the optical information transmission process of a diffractive waveguide allows for the transmission of color image information using a single-layer waveguide structure. Our results demonstrate that, under the conditions of a field of view of 47° × 47°, an entrance pupil size of 2.9 × 2.9 mm2, and an exit pupil extension size of 8.9 mm, the uniformity of the brightness for each monochromatic field reached 85%, while the uniformity of color transmission efficiency exceeded 95%. [ABSTRACT FROM AUTHOR]

Post-politics consists of a comprehensive literature that includes new political formations and positions such as the new-right, the new-left, the third way, and at the same time tries to demonstrate that the possibilities of politicization suppressed by these new ones have not completely disappeared. In other words, the concept of post-politics, in this respect, includes discussions on depoliticization and counter-politicization, and with such a comprehensive content, it points to the search for politicization. Populism is read by this post-politics literature as depoliticization on the one hand and a new possibility of politicization on the other. The main purpose of this study is to reveal the discussion on populism as an element of depoliticization in the light of the intersections with the post-politics literature, and in line with this purpose, the relevant literature readings are handled in a way to reveal the place of populism in the post-politics literature. [ABSTRACT FROM AUTHOR]

Multiple populations (MPs) in globular clusters (GCs) are stars that are distinct for their abundances of light elements. The MPs can be directly separated by measuring abundances of C, N, O, Na, Al, and Mg with spectroscopy or indirectly from photometric sequences created by the impact of different chemistry on band passes of particular filters, such as the HST pseudo-colours in the ultraviolet. An attempt to link HST pseudo-colour maps (PCMs) and spectroscopy was made by Marino et al. (2019, MNRAS, 487, 3815), using abundances mostly from our FLAMES survey. However, we found that an incomplete census of stars in common was used in their population tagging. We corrected the situation by building our own PCMs and matching them with our abundances in 20 GCs, plus two GCs from other sources, doubling the sample with spectroscopic abundances available. We found that the pseudo-colour (magF275W − 2 × magF336W + magF438) does not have a monotonic trend with Na abundances, enhanced by proton-capture reactions in MPs. Moreover, on average about 16% of stars with spectroscopic Na abundances show a discrepant tagging of MPs with respect to the HST photometry. Stars with second generation (SG) chemistry are mistaken for first generation (FG) objects according to HST photometry and vice versa. In general, photometric indices tend to overestimate the fraction of FG stars, in particular in low mass GCs. We offer a simple explanation for these findings. Finally, we publish all our PCMs (with more than 31 800 stars in 22 GCs) with star ID and coordinates; this is done to ensure easy verification and reproduction, as should be the case in scientific papers. [ABSTRACT FROM AUTHOR]

Since 2016 there have been intense discussions within several established communities and networks regarding the consequences of the withdrawal of the LSVEC lithium carbonate reference material for carbon isotope‐delta measurement calibration. These include the Isotope Ratio Working Group (IRWG) of the Consultative Committee for the Amount of Substance (CCQM, French: Comité Consultatif pour la Quantité de Matière) of the International Committee of Weights and Measures (CIPM, French: Comité International des Poids et Mesures); participants within the 2016, 2021 and 2024 Technical Meetings on International Atomic Energy Agency (IAEA) stable isotope ratio reference products; and the International Union of Pure and Applied Chemistry's Commission on Isotopic Abundances and Atomic Weights (IUPAC CIAAW) amongst others. The reasons for these intensive discussions relate to the privileged position that LSVEC has occupied for traceability of carbon isotope‐delta measurements relative to Vienna Peedee belemnite (VPDB) and the potential implications of its withdrawal for all current and future measurements of carbon isotope‐delta values. This perspective summarises the background information regarding the LSVEC material in the context of the VPDB carbon isotope‐delta scale. The various proposals to address the LSVEC problem that have been discussed within those committees and networks are also presented. The information herein was used as a foundation for discussions at the 2024 IAEA Consultancy Meetings on the Development of IAEA Stable Isotope Reference Materials and Related Products and on the Definition and Realisation of the Isotopic Delta Scales for Light Elements (22–26 January 2024, Vienna, Austria). A summary of those 2024 meetings and associated outcomes can be found elsewhere. [ABSTRACT FROM AUTHOR]

We have examined the case of light atom (B, N) doped and co-doped graphitic films grown on copper for the anode-free Li Metal Battery (AFLMB) application. For nitrogen doping, the depositions were carried out by laser ablating pure graphite (Gr) in the presence of Nitrogen (N2) or Ammonia (NH3). In another interesting case, 5 wt. % Boron nitride (BN) was added into the graphite target itself to obtain BN-doped graphite films. It was found that the growth condition mediated film constitution and properties significantly influence the Coulombic efficiency and cycling stability of the cells when tested for AFLMB. The cycle life demonstrated by the cells of pure graphitic film (Gr) was only about 110 cycles, while the N-doped graphite films obtained using N2 gas (N2–Gr) exhibited stability up to about 300 cycles. Interestingly the N-doped films obtained using NH3 gas (NH3–Gr) exhibited a stability of 715 cycles and B, N co-doped graphite (BN–Gr) film resulted in an even longer cycle life of 795 cycles. Density functional theory calculations were also performed to deeply understand the interaction and binding energy of Lithium within the undoped and doped graphene sheets modeled through the addition of light elements. It was found that the binding of Li is stronger in the (B, N) co-doped graphene as compared to the N-doped graphene and undoped graphene but much weaker than the B-doped graphene. Therefore, an improved lateral Li diffusion in the (B, N) co-doped graphene is observed where the Li binding strength is optimum resulting in better cycling stability. [ABSTRACT FROM AUTHOR]

The interaction between a solute and vacancy is crucial for the diffusion and precipitation of alloy elements and ultimately affects the creep resistance and safety of refractory molybdenum (Mo) alloys. In this work, the first-principles calculations of the interaction between solutes (5 light impurity atoms and 23 transition metal elements) and vacancies show that Mo is sensitive to all the light impurity elements, which indicates that these solutes are easy to combine with an Mo alloy and have relatively strong interaction. In most cases, the interaction between the 23 transition metal solutes and vacancy is attractive, but the interaction between solutes V, Ti, and the first-nearest vacancy is repulsive, and the interaction between the early elements in the 3d, 4d, and 5d series and the second-nearest vacancy is also repulsive. Then, we discuss the main factors that affect the solute–vacancy interaction, that is, the effects of electron and strain-elimination. Finally, a solute–vacancy interaction database based on the above effects is established, which would contribute to the research on heat- and radiation-resistant Mo alloys. [ABSTRACT FROM AUTHOR]

We report first-principles investigations of the light-element effect on phonon states in neodymium-magnet compounds. It is found that B in Nd 2 Fe 14 B contributes to acoustic phonon hardening. As for the substitution of other light elements for B, frequencies of phonons that originate from light elements decrease with increasing the atomic number. However, imaginary phonons in Nd 2 Fe 14 F are attributed to the electronic states and the atomic configurations, not to the heavier mass of F. In addition, as the effect of the magnetic disordering on the phonon state, we show that the phonons of the paramagnetic Nd 2 Fe 14 B are softer than those of the ferromagnetic Nd 2 Fe 14 B. This suggests that the phonon effect decreases the Curie temperature through the stabilization of the paramagnetic state. [ABSTRACT FROM AUTHOR]

Thermochemical inhomogeneities in the Earth's outer core that enhance our understanding of the geodynamo have been elusive. Seismic constraints on such inhomogeneities would provide clues on the amount and distribution of light elements in the core apart from iron and nickel. Here, we present evidence for a low-velocity volume within the outer core via the global coda correlation wavefield. Several key correlogram features with a unique sensitivity to the liquid core show variations with wave paths remarkably slower in the equatorial than polar planes. We constrain a torus structure at low latitudes with ~2% lower velocity than the surrounding liquid outer core via waveform modeling. We propose a thermochemical origin for such a low-velocity torus, providing important constraints on the dynamical processes of the Earth's outer core. [ABSTRACT FROM AUTHOR]

Carbon and nitrogen are considered as candidate light elements present in planetary cores. However, there is limited understanding regarding the structure and physical properties of Fe‐C‐N alloys under extreme conditions. Here diamond anvil cell experiments were conducted, revealing the stability of hexagonal‐structured Fe7(N0.75C0.25)3 up to 120 GPa and 2100 K, without undergoing any structural transformation or dissociation. Notably, the thermal expansion coefficient and Grüneisen parameter of the alloy exhibit a collapse at 55–70 GPa. First‐principles calculations suggest that such anomaly is associated with the spin transition of iron within Fe7(N0.75C0.25)3. Our modeling indicates that the presence of ∼1.0 wt% carbon and nitrogen in liquid iron contributes to 9–12% of the density deficit of the Earth's outer core. The thermoelastic anomaly of the Fe‐C‐N alloy across the spin transition is likely to affect the density and seismic velocity profiles of (C,N)‐rich planetary cores, thereby influencing the dynamics of such cores. Plain Language Summary: A significant amount of light elements are believed to be present in the cores of Earth and other planets to explain the density difference between iron‐nickel alloys and geophysical observations. This study used experiments at high‐pressure and high‐temperature conditions and theoretical simulations to investigate a specific candidate phase of the core called Fe7(N0.75C0.25)3, which has a hexagonal structure, at high pressures similar to those in planetary cores. This phase did not undergo any major structural changes under the conditions investigated. However, its properties related to the thermoelastic behaviors showed significant changes between 55 and 70 GPa. Theoretical calculations indicate that this anomalous behavior is linked to the magnetic transition within h‐type Fe7(N0.75C0.25)3. These findings suggest that the characteristics of a planetary core would be altered in the transition region, leading to a more complex thermal evolution than previously believed. This study provides insights into the behavior of light elements in planetary cores and its implications for planetary dynamics. Key Points: The h‐type Fe7(N0.75C0.25)3 is stable to 120 GPa and 2100 K, but undergoes a pressure‐induced spin transitionSpin transition causes a significant reduction in γ0 and α0, and the thermal equation of state of h‐type non‐magnetic Fe7(C,N)3 is determinedThe density profile and seismic features of a planetary core could be altered across the spin transition, which may affect core dynamics [ABSTRACT FROM AUTHOR]

The rapid advancement and deployment of Artificial Intelligence (AI) poses significant regulatory challenges for societies. While it has the potential to bring many benefits, the risks of commercial exploitation or unknown technological dangers have led many jurisdictions to seek a legal response before measurable harm occurs. However, the lack of technical capabilities to regulate this sector despite the urgency to do so resulted in regulatory inertia. Given the borderless nature of this issue, an internationally coordinated response is necessary. This article focuses on the theoretical framework being established in relation to the development of international law applicable to AI and the regulatory authority to create and monitor enforcement of said law. The authors argue that the road ahead remains full of obstacles that must be tackled before the above-mentioned elements see the light despite the attempts being made currently to that end. [ABSTRACT FROM AUTHOR]

Using simulations is considered an effective tool in training and instructional processes. At the core of the process is the ‘scenario’. The objective of the current research was to shed light on the elements that affect the development of the scenario topic and all that relate to its operation during a simulation. With a mixed method based on grounded theory, we analysed the characteristics of 74 simulation workshops and 150 scenarios between the years 2019–2020 carried out in our college’s simulation centre. Findings point to a need to construct clear criteria and rules for preparing scenarios for simulation training. Issues such as the active simulation participants’ selection process, the scenario writer’s identity, the time of exposure to the scenario before arriving at the simulation centre, and how the scenario is mediated may also contribute to the simulation’s effectiveness. [ABSTRACT FROM AUTHOR]

Lithium is one of the lightest elements on Earth and it has been in the environment since the formation of the galaxy. While a common element, it has not been found to be an essential element in biological processes, ranging from single cell organisms to Homo sapiens. Instead, at an early stage of evolution, organisms committed to a range of elements such as sodium, potassium, calcium, magnesium, zinc, and iron to serve essential functions. Such ions serve critical functions in ion channels, as co-factors in enzymes, as a cofactor in oxygen transport, in DNA replication, as a storage molecule in bone and liver, and in a variety of other roles in biological processes. While seemingly excluded from a major essential role in such processes, lithium ions appear to be able to modulate a variety of biological processes and "correct" deviation from normal activity, as a deficiency of lithium can have biological consequences. Lithium salts are found in low levels in many foods and water supplies, but the effectiveness of Li salts to affect biological systems came to recent prominence with the work of Cade, who reported that administrating Li salts calmed guinea pigs and was subsequently effective at relatively high doses to "normalize" a subset of patients with bipolar disorders. Because of its ability to modulate many biological pathways and processes (e.g., cyclic AMP, GSK-3beta, inositol metabolism, NaK ATPases, neuro processes and centers, immune-related events, respectively) both in vitro and in vivo and during development and adult life, Li salts have become both a useful tool to better understand the molecular regulation of such processes and to also provide insights into altered biological processes in vivo during aging and in disease states. While the range of targets for lithium action supports its possible role as a modulator of biological dysregulation, it presents a conundrum for researchers attempting to elucidate its specific primary target in different tissues in vivo. This review will discuss aspects of the state of knowledge regarding some of the systems that can be influenced, focusing on those involving neural and autoimmunity as examples, some of the mechanisms involved, examples of how Li salts can be used to study model systems, as well as suggesting areas where the use of Li salts could lead to additional insights into both disease mechanisms and natural processes at the molecular and cell levels. In addition, caveats regarding lithium doses used, the strengths and weaknesses of rodent models, the background genetics of the strain of mice or rats employed, and the sex of the animals or the cells used, are discussed. Low-dose lithium may have excellent potential, alone or in combination with other interventions to prevent or alleviate aging-associated conditions and disease progression. [ABSTRACT FROM AUTHOR]

Local Authorities in England are rarely able to find a school place for newly arrived unaccompanied sanctuary seekers when the young person arrives in their locality aged 15–16. Criticisms regarding this exclusionary practice are plentiful; that said, it has been argued the dominance of debate regarding access to mainstream education for pupils aged 15–16 obfuscates critical analysis of the educational needs of this group. Focussed on a bespoke Local Authority educational offer for fewer than twenty newly arrived unaccompanied sanctuary seekers aged 15–16, this paper analyses the essence of this offer in relation to social inclusion. Analysed in relation to the category, structure and level/function of the young people's social inclusion, this paper draws on interview and focus group data to shine a light on the efficacious elements of the offer which point to ways forward for mainstream schools. [ABSTRACT FROM AUTHOR]

Recent seismological studies of the Martian core revealed its relatively low density, suggesting the presence of large amounts of light elements including oxygen and carbon in addition to sulfur. In order to reveal crystallizing solids in the light-element-rich core of Mars, we performed high-pressure melting experiments on Fe-S-O-C alloys at 26–49 GPa using a laser-heated diamond-anvil cell. The liquidus phase relations in the Fe-S-O-C system were determined based on textural and chemical characterizations of recovered samples. The results show that Fe-S-O-C liquids crystallize FeO or Fe 3 C in the presence of small amounts of O or C in liquids. Accordingly the liquidus fields of Fe 3 S and Fe 2 S are small, and the quaternary eutectic point is found to be close to the Fe-Fe 3 S binary eutectic point. Under Martian core conditions, S-rich liquids have low liquidus temperatures to crystallize FeO or Fe 3 C compared to S-poor liquids. The pressure dependence of liquidus temperatures suggests that crystallization of Mars' core starts at the center upon cooling. According to the FeO-Fe 3 C cotectic surfaces and their liquidus temperatures, an FeO and/or Fe 3 C inner core is predicted unless the Martian core remains entirely liquid. [ABSTRACT FROM AUTHOR]

Himalayan leucogranite is an excellent target for understanding the orogenic process of the India–Asia collision, but its origin and tectonic significance are still under debate. An integrated study of geochronology, geochemistry, and in situ Sr-Nd-Hf isotopes was conducted for a tourmaline-bearing leucogranite in the eastern Tethyan Himalaya using LA-ICP-MS, X-ray fluorescence spectroscopy, and ICP-MS and LA-MC-ICP-MS, respectively. LA-ICP-MS U-Pb dating of zircon and monazite showed that it was emplaced at ~19 Ma. The leucogranite had high SiO2 and Al2O3 contents ranging from 73.16 to 73.99 wt.% and 15.05 to 15.24 wt.%, respectively. It was characterized by a high aluminum saturation index (1.14–1.19) and Rb/Sr ratio (3.58–6.35), which is characteristic of S-type granite. The leucogranite was enriched in light rare-earth elements (LREEs; e.g., La and Ce) and large ion lithophile elements (LILEs; e.g., Rb, K, and Pb) and depleted in heavy rare-earth elements (e.g., Tm, Yb, and Lu) and high field strength elements (HFSEs; e.g., Nb, Zr, and Ti). It was characterized by high I Sr (t) (0.7268–0.7281) and low ε Nd (t) (−14.6 to −13.2) and ε Hf (t) (−12.6 to −9.47), which was consistent with the isotopic characteristics of the Higher Himalayan Sequence. Petrogenetically, the origin of the leucogranite is best explained by the decompression-induced muscovite dehydration melting of an ancient metapelitic source within the Higher Himalayan Sequence during regional extension due to the movement of the South Tibetan Detachment System (STDS). The significantly high lithium and beryllium contents of the leucogranite and associated pegmatite suggest that Himalayan leucogranites possess huge potential for lithium and beryllium exploration. [ABSTRACT FROM AUTHOR]

Flowering time and maturity are crucial agronomic traits that affect the regional adaptability of soybean plants. The development of soybean cultivars with early maturity adapted to longer days and colder climates of high latitudes is very important for ensuring normal ripening before frost begins. FUL belongs to the MADS‐box transcription factor family and has several duplicated members in soybeans. In this study, we observed that overexpression of GmFULc in the Dongnong 50 cultivar promoted soybean maturity, while GmFULc knockout mutants exhibited late maturity. Chromatin immunoprecipitation sequencing (ChIP‐seq) and RNA sequencing (RNA‐seq) revealed that GmFULc could bind to the CArG, bHLH and homeobox motifs. Further investigation revealed that GmFULc could directly bind to the CArG motif in the promoters of the GmZTL3 and GmZTL4 genes. Overexpression of GmZTL4 promoted soybean maturity, whereas the ztl4 mutants exhibited delayed maturity. Moreover, we found that the cis element box 4 motif of the GmZTL4 promoter, a motif of light response elements, played an important role in controlling the growth period. Deletion of this motif shortened the growth period by increasing the expression levels of GmZTL4. Functional investigations revealed that short‐day treatment promoted the binding of GmFULc to the promoter of GmZTL4 and inhibited the expression of E1 and E1Lb, ultimately resulting in the promotion of flowering and early maturation. Taken together, these findings suggest a novel photoperiod regulatory pathway in which GmFULc directly activates GmZTL4 to promote earlier maturity in soybean. [ABSTRACT FROM AUTHOR]

Samples from asteroid Ryugu, brought back by asteroid explorer Hayabusa2, are important for investigating the origin and evolution of the solar system. Here, we report the elemental compositions of a 123‐mg Ryugu sample determined with a nondestructive muon elemental analysis method. This method is a powerful tool for determining bulk chemical composition, including light elements such as C, N, and O. From the muonic x‐ray spectra with three carbonaceous chondrites, the relationship between the elemental composition and muonic x‐ray intensity was determined for each element. Calibration curves showed linearity, and the elemental composition of Ryugu was quantitatively determined. The results reflect the average bulk elemental composition of asteroid Ryugu owing to the large amount of samples. Ryugu has an elemental composition similar to that of Orgueil (CI1) and should be classified as CI1. However, the O/Si ratio of Ryugu is 25% lower than that of Orgueil, indicating that Orgueil may have been seriously contaminated by terrestrial materials after its fall to Earth. These results indicate that the Ryugu sample is more representative than the CI chondrites as a solid material of the solar system. [ABSTRACT FROM AUTHOR]

The light homogenizing element is a crucial component of the illumination system of the lithography machine. Its primary purpose is to realize the uniform distribution of energy. However, it suffers from a common issue, which is angular spectrum discreteness, which significantly impacts light uniformity. To address this, we design and fabricate random micro-cylindrical lens arrays to obtain a small-angle Gaussian optical field, which can compensate for the angular spectrum discreteness. By adjusting the pitches and curvature radii of the micro-cylindrical lenses separately, we are able to manipulate the divergence angle of the emitted sub-beams, enabling precise angular spectrum modulation. By using mask-moving technology, the angular spectrum modulator is fabricated to generate a Gaussian illumination field. The surface profile is measured and determined with a structural roughness below 10 nm. Furthermore, optical test experiments on the modulator have been conducted, achieving an angle error of less than 0.02° and a balance better than 0.5%. [ABSTRACT FROM AUTHOR]

Copyright of Industrial Water Treatment is the property of CNOOC Tianjin Chemical Research & Design Institute and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)

N6-methyladenosine (m6A), a well-characterized RNA modification, is involved in regulating multiple biological processes; however, genome-wide identification and functional characterization of the m6A modification in legume plants, including soybean (Glycine max (L.) Merr.), remains lacking. In this study, we utilized bioinformatics tools to perform comprehensive analyses of molecular writer candidates associated with the RNA m6A modification in soybean, characterizing their conserved domains, motifs, gene structures, promoters, and spatial expression patterns. Thirteen m6A writer complex genes in soybean were identified, which were assigned to four families: MT-A70, WTAP, VIR, and HAKAI. It also can be identified that multiple cis elements in the promoters of these genes, which were classified into five distinct groups, including elements responsive to light, phytohormone regulation, environmental stress, development, and others, suggesting that these genes may modulate various cellular and physiological processes in plants. Importantly, the enzymatic activities of two identified m6A writers, GmMTA1 and GmMTA2, were confirmed in vitro. Furthermore, we analyzed the expression patterns of the GmMTAs and GmMTBs under different abiotic stresses, revealing their potential involvement in stress tolerance, especially in the response to alkalinity or darkness. Overexpressing GmMTA2 and GmMTB1 in soybean altered the tolerance of the plants to alkalinity and long-term darkness, further confirming their effect on the stress response. Collectively, our findings identified the RNA m6A writer candidates in leguminous plants and highlighted the potential roles of GmMTAs and GmMTBs in the response to abiotic stress in soybean. [ABSTRACT FROM AUTHOR]

Context. The production of neutron-rich elements at neutron densities intermediate to those of the s- and r-processes, the so-called i-process, has been identified as possibly being responsible for the observed abundance pattern found in certain carbon-enhanced metal-poor (CEMP) stars. The production site may be low-metallicity stars on the asymptotic giant branch (AGB) where the physical processes during the thermal pulses are not well known. Aims. We investigate the impact of overshoot from various convective boundaries during the AGB phase on proton ingestion events (PIEs) and the neutron densities as a necessary precondition for the i-process as well as on the structure and continued evolution of the models. Methods. We therefore analyzed models of a 1.2 M⊙, Z = 5 × 10−5 star. A fiducial model without overshoot on the AGB (overshoot was applied during the pre-AGB evolution) serves as a reference. The same model was then run with various overshoot values and the resulting models were compared to one another. Light element nucleosynthesis is also discussed. Additionally, we introduce a new timescale argument to predict PIE occurrence to discriminate between a physical and a numerical reason for a nonoccurrence. A comparison to observations as well as previous studies was conducted before finally presenting the most promising choice of overshoot parameters for the occurrence of the i-process in low-mass, low-metallicity models. Results. The fiducial model reveals high neutron densities and a persistent split of the pulse-driven convection zone (PDCZ). Overshoot from the PDCZ results in either temporary or permanent remerging of the split PDCZ, influencing the star's structure and evolution. While both overshoot and non-overshoot models exhibit PIEs generating neutron densities suitable for the i-process, they lead to varied C/O and N/O ratios and notable Li enhancements. Comparison with previous studies and observations of CEMP-r/s stars suggests that while surface enhancements in our models may be exaggerated, abundance ratios align well. Though, for high values of overshoot from the PDCZ the agreement becomes worse. [ABSTRACT FROM AUTHOR]

Positional and multicolor photometric observations of near-Earth asteroids were carried out using the SBG telescope of the Kourovka Astronomical Observatory of Ural Federal University and the Zeiss-1000 telescope of the Simeiz Observatory of INASAN in 2022–2023. Based on the results of positional observations with the SBG telescope, improved orbital elements were obtained for seven asteroids. The periods of axial rotation of seven asteroids were estimated from photometric observations. Based on the results of photometric observations in the B, V, R, I filters, color indices were obtained for six asteroids. [ABSTRACT FROM AUTHOR]

A semiempirical molecular-orbital approach has been developed to calculate the dissociation energies of 57 second-row neutral and charged diatomic molecules. One-electron energies and wave functions were used. The 2s and 2p electrons have separate energies and separate values of Z2S and Z2P. Calculations were made with a CNDO/INDO FORTRAN programme modified to a level of approximation that is more similar to extended Hückel calculations than to either CNDO or INDO. The correlation between calculated and experimental dissociation energies was favourable with a relative standard deviation of 15%. Additionally, dipole moments for the molecules were calculated concurrently with the same parameters. The correlation between calculated and experimental dipole moments was favourable for seventeen molecules with a relative standard deviation of 19%. The correlation between calculated and experimental ionisation potentials for fourteen molecules was also favourable with a relative standard deviation of 11%. Also, a repulsion work function was formulated and used in this work between pairs of atoms. For 90% of the molecules studied, the maximum calculated dissociation energy occurred within ±0.1 Å of the experimental bond distance. The semiempirical methods used in the present work could be used for future studies of larger molecules, including organic molecules. [ABSTRACT FROM AUTHOR]

This paper offers a critical analysis of Law 20.393, which regulates the criminal liability of legal persons in Chile, with special emphasis on those aspects in which the national legislator was innovative in relation to the Italian legislation used as the main inspiring model, weighing the sense of each of them in the light of the discussion on these elements in comparative law. In this sense, the reflections are especially focused on the weighting of the relevance and scope of three important modifications: the unification of the regime of attribution of liability whether a subject acts in a superior position or one in a subordinate position; the omission of the inclusion of the requirement of fraudulent circumvention of the preventive rule; and the certification as a mechanism of preventive suitability of the model recognized by international regulations as useful for the accreditation of a serious and efficient self-regulation. [ABSTRACT FROM AUTHOR]

Fe-Mn carbonate is the dominant mineral in the Erdaokan Ag deposit, which represents the first large independent silver deposit during the Late Triassic Period in the Duobaoshan Cu-Mo-Au mineralization concentrated area of Heilongjiang Province, NE China. The Fe-Mn carbonates in the deposit frequently co-exist with Ag minerals. Thus, the presence of Fe-Mn carbonates plays a crucial role in the ore-formation process, making their analysis essential for obtaining valuable metallogenic information about the Erdaokan deposit. Through microexamination, SEM and EDS analysis, a clear relationship between Fe-Mn carbonate minerals and Ag minerals was established. Furthermore, electron probe microanalysis, LA-ICP-MS, and Sr-Nd isotope tests were conducted to analyze Fe-Mn carbonates for significant metallogenic insights. The distribution pattern of trace elements and rare-earth elements in Fe-Mn carbonates is similar, characterized by Zr depletion (below 0.131 ppm), enrichment of light rare-earth elements, a noticeable deficit of Eu (δEu = 0.06–0.63), and an average Y/Ho value of 34.29, indicating the involvement of upper mantle-derived deep magma in the formation of ore-forming materials. The samples had a Sm-Nd isochron age of 233.7 ± 1.2 Ma, suggesting that the Erdaokan Ag deposit was formed during the Late Triassic Period. This study highlights the significance of Fe-Mn carbonate as a valuable mineral indicator for regional silver prospecting purposes, and confirms the Late Triassic Period as another important metallogenic stage in the Duobaoshan Cu-Mo-Au mineralization concentrated area. [ABSTRACT FROM AUTHOR]

Maize is an important crop used for food, feed, and fuel. Abiotic stress is an important factor affecting maize yield. The EPF/EPFL gene family encodes class-specific secretory proteins that play an important role in the response to abiotic stress in plants. In order to explore and utilize the EPF/EPFL family in maize, the family members were systematically identified, and their chromosomal localization, physicochemical properties, cis-acting element prediction in promoters, phylogenetic tree construction, and expression pattern analysis were carried out using bioinformatics techniques. A total of 18 ZmEPF/EPFL proteins were identified in maize, which are mostly alkaline and a small portion acidic. Subcellular localization results showed that ZmEPF6, ZmEPF12, and ZmEPFL2 are localized in the nucleus and cytoplasm. Analysis of cis-acting elements revealed that members of the ZmEPF/EPFL family contain regulatory elements such as light response, anoxic, low temperature, and hormone response regulatory elements. RT-qPCR results showed that these family members are indeed responding to cold stress and hormone treatments. These results of this study provide a theoretical basis for improving the abiotic stress resistance of maize in future research. [ABSTRACT FROM AUTHOR]

A novel nondestructive light element analysis method for bulk materials using muon beams was demonstrated. This method is based on the lifetime measurement of muons in a material and performed by measuring muon-decay electrons and identifying elements using the atomic number based on muon lifetimes. Muon irradiation on pure iron and two steel samples with known carbon contents was conducted to prepare a calibration curve for the quantitative analysis. We also performed a muon lifetime measurement for a Japanese sword and successfully determined its carbon content as 0.51 wt% using the calibration curve, without sample destruction. [ABSTRACT FROM AUTHOR]

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Electride possesses electrons localized at interstitial sites without attracting nuclei. It brings outstanding material properties not only originating from its own loosely bounded characteristics but also serving as a quasiatom, which even chemically interacts with other elemental ions. In elemental metals, electride transitions have been reported in alkali metals where valence electrons can easily gain enough kinetic energy to escape nuclei. However, there are few studies on transition metals. Especially iron, the key element of human technology and geophysics, has not been studied in respect of electride formation. In this study, it is demonstrated that electride formation drives the superionic state in iron hydride under high‐pressure conditions of the earth's inner core. The electride stabilizes the iron lattice and provides a pathway for hydrogen diffusion by severing the direct interaction between the metal and the volatile element. The coupling between lattice stability and superionicity is triggered near 100 GPa and enhanced at higher pressures. It is shown that the electride‐driven superionicity can also be generalized for metal electrides and other rocky planetary cores by providing a fundamental interaction between the electride of the parent metal and doped light elements. [ABSTRACT FROM AUTHOR]

Doping light elements in Pt‐group metals is an effective approach toward improving their catalytic properties for oxygen reduction reaction (ORR). However, it is challenging to control dopant sites and to establish the correlation between the doping site and the catalytic property. In this paper, this success is demonstrated in controlling N doping sites in Pd metallene to manipulate electrocatalytic properties toward ORR. A Pd metallene sample with N dopant predominantly located at the atomic vacancy site (V‐N‐Pd metallene) exhibits two times higher mass activity in ORR than a Pd metallene sample with N dopant mainly occupied the interstitial site (I‐N‐Pd metallene). However, the I‐N‐Pd metallene shows improved durability than the V‐N‐Pd metallene, with only a 4 mV decay in half‐wave potential after 20 000 cycles. Computational calculation results reveal that the significantly enhanced ORR activity of V‐N‐Pd metallene arises from the atomic vacancy‐doped N, which modulates the electronic structure of Pd metallene to weaken the adsorption energy of intermediate O* species. This work provides guidelines for manipulating catalytic properties by controlling the doping sites of light elements in metal nanostructures. [ABSTRACT FROM AUTHOR]

The GRAS gene family, responsible for encoding transcription factors, serves pivotal functions in plant development, growth, and responses to stress. The exploration of the GRAS gene family within the Orchidaceae has been comparatively limited, despite its identification and functional description in various plant species. This study aimed to conduct a thorough examination of the GRAS gene family in Cymbidum goeringii, focusing on its physicochemical attributes, phylogenetic associations, gene structure, cis-acting elements, and expression profiles under heat stress. The results show that a total of 54 CgGRASs were pinpointed from the genome repository and categorized into ten subfamilies via phylogenetic associations. Assessment of gene sequence and structure disclosed the prevalent existence of the VHIID domain in most CgGRASs, with around 57.41% (31/54) CgGRASs lacking introns. The Ka/Ks ratios of all CgGRASs were below one, indicating purifying selection across all CgGRASs. Examination of cis-acting elements unveiled the presence of numerous elements linked to light response, plant hormone signaling, and stress responsiveness. Furthermore, CgGRAS5 contained the highest quantity of cis-acting elements linked to stress response. Experimental results from RT-qPCR demonstrated notable variations in the expression levels of eight CgGRASs after heat stress conditions, particularly within the LAS, HAM, and SCL4/7 subfamilies. In conclusion, this study revealed the expression pattern of CgGRASs under heat stress, providing reference for further exploration into the roles of CgGRAS transcription factors in stress adaptation. [ABSTRACT FROM AUTHOR]

Reflective LCDs have a great advantage of low power consumption, but the brightness is not consistently sufficient because ambient light is used as a light source. To increase light efficiency, we combined reflective LCDs and the Pancharatnam‐Berry deflector (PBD), a diffractive optical element that controls the propagation of incident light. We confirmed that on‐axis brightness is increased by 2.2 times against the incident collimated light from a polar angle of 30° when compared to a reflective LCD without PBD. [ABSTRACT FROM AUTHOR]

Film and TV video scenes contain rich art and design elements such as light and shadow, color, composition, and complex affects. To recognize the fine-grained affects of the art carrier, this paper proposes a multitask affective value prediction model based on an attention mechanism. After comparing the characteristics of different models, a multitask prediction framework based on the improved progressive layered extraction (PLE) architecture (multi-headed attention and factor correlation-based PLE), incorporating a multi-headed self-attention mechanism and correlation analysis of affective factors, is constructed. Both the dynamic and static features of a video are chosen as fusion input, while the regression of fine-grained affects and classification of whether a character exists in a video are designed as different training tasks. Considering the correlation between different affects, we propose a loss function based on association constraints, which effectively solves the problem of training balance within tasks. Experimental results on a self-built video dataset show that the algorithm can give full play to the complementary advantages of different features and improve the accuracy of prediction, which is more suitable for fine-grained affect mining of film and TV scenes. [ABSTRACT FROM AUTHOR]

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Our Compton profile measurements of Ti and TiH2 using readily available hard X-ray radiation at 27.5 keV, detected by both a Hitachi Vortex silicon-drift detector and a high-resolution superconducting transition-edge sensor array, are found to be in excellent accord with state-of-the-art density functional theory based calculations. The spherically averaged difference between the Compton profiles of TiH2 and Ti is well described by an inverted parabola, supporting an itinerant behavior of the electron gas screening the protons in the Ti matrix. Our experimental approach, validated by two different detectors, extends the applicability of Compton scattering technique to the readily accessible hard x-ray regime (below 30 keV). Our study suggests possibilities for experiments at low-flux bending magnet synchrotron beamlines and paves the way for the development of tabletop Compton experiments with x-ray tubes. [ABSTRACT FROM AUTHOR]

The elucidation of novel bonding situations at heavy p-block elements has greatly advanced recent efforts to access useful reactivity at earth-abundant main-group elements. Molecules with unsaturated bonds between heavier, electropositive elements and lighter, electronegative elements are often highly polarized and competent in small-molecule activations, but the reactivity of these molecules may be quenched by self-association of monomers to form oligomeric species where the polar, unsaturated groups are assembled in a head-to-tail fashion. In this Frontier, we discuss the synthetic strategies employed to isolate monomeric σ2,λ3-stibinidene chalcogenides (RSbCh) and monomeric σ4,λ5-stibine chalcogenides (R3SbCh). These classes of molecules each feature polarized antimony–chalcogenide bonds (Sb = Ch/Sb+–Ch−). We highlight how the synthesis and isolation of these molecules has led to the discovery of novel reactivity and has shed light on fundamental aspects of inorganic structure and bonding. Despite these advances, there are critical aspects of this chemistry that remain underdeveloped and we provide our perspective on yet-unrealized synthetic targets that may be achieved with the continued development of the strategies described herein. [ABSTRACT FROM AUTHOR]

This paper introduces a facile method to develop core-shell nanocomposite Cu/(Cu 2 O/CuO) through gradually oxidation on Cu nanocomposite precursors. As-prepared catalyst exhibited excellent catalytic activity in the reaction of water oxidation reaction (WOR). Comparing with the reported catalyst, Cu/(Cu 2 O/CuO) posed one of the highest O 2 evolution around 7700 μmol g-1·h-1. By analyzing the composition of catalysts in each reaction stages, the evolution pathway of Cu towards Cu 2 O/CuO and the different roles of each component in catalytic water oxidation reactions were deeply studied. In presence of high conductive Cu element and excellent light absorption Cu 2 O, the photo generated electron and holes can be effectively separated and greatly improve the efficiency of the catalyst. The evolution process and synergistic effects of the three components play a crucial role in improving photocatalytic efficiency, which promoting the nanocomposite to be a highly efficient core-shell catalyst for WOR. This paper presents the evolution of a highly active photocatalytic water oxidation catalyst with no photosensitizers. [Display omitted] • Cu/(Cu 2 O/CuO) core-shell nanocomposite exhibits a a high oxygen production rate of 7700 μmol·g-1·h-1. • The relationship between the evolution of Cu to Cu 2 O/CuO and the photocatalytic efficiency was explored. • Cu/Cu 2 O core-shell plays a crucial role in charge separation and dramatically increasing the catalytic efficiency. [ABSTRACT FROM AUTHOR]

Generally, particle-induced X-ray emission (PIXE) analysis is performed using protons as the incident projectiles. In this study, helium ions were used for inducing X-ray emission to improve the detection limit for the characterization of light elements in the PM2.5 fine fraction. The sampling was conducted for 24 h using a Gent stacked filter unit sampler at an industrial site in Surabaya, Indonesia. The samples were analyzed by PIXE using a 4-MV Van de Graaff accelerator at Kyoto University. Both helium and protons were used in the analysis to obtain optimal results, and 21 elements were detected in the samples. Notably, the use of helium particle-induced X-ray emission was more suitable for Na, Mg, Al, and Si than protons. Moreover, the sensitivity and limit of detection for these elements were enhanced using helium ions. Validation was performed using standard reference material NIST 2783 air particulates on filter media, and the results were in good agreement. Using both He-PIXE and H-PIXE, heavy metals, crustal elements, and other elements were identified that exhibited the characteristics of PM2.5 collected in Surabaya, Indonesia. Further statistical analysis and receptor modeling are required to identify the possible pollutant sources of PM2.5. [ABSTRACT FROM AUTHOR]

Crystalline porous organic polymers (CPPs) or covalent organic frameworks (COFs), are composed by light elements linked by covalent bonds. Despite the remarkable progress attained, there are still bottlenecks limiting further development, some of them related to the presence of defects during their synthesis as well as in‐depth understanding of structure of active centers and/or details of the reaction mechanism. Indeed, very often the proposed structures are far from reality because defects and disorders have not been considered. The present review provides an illustrative overview of "defects and disorder in COFs". These defects include those not only generated during the synthesis and manipulation of COFs, but also lack of crystallinity, stacking disorder and network vacancies. The review starts giving general remarks on organic COFs and their synthetic methods, followed by different methods to play and manage defects, how to minimize them or how to take advantage of them to gain new properties and applications. Selected characterization techniques to quantify defective structures and active sites in COFs are also presented. Finally, the challenges and future opportunities in the field have been summarized in the last section. [ABSTRACT FROM AUTHOR]

Due to the BCS theory, hydrogen, the lightest element, would be the prospect of room-temperature superconductor after metallization, but because of the difficulty of the hydrogen metallization, the theory about hydrogen pre-compression was proposed that the hydrogen-rich compounds could be a great option for the high Tc superconductors. The superior properties of TmH6, YbH6 and LuH6 indicated the magnificent potential of heavy rare earth elements for low-pressure stability. Here, we designed XTmH12 (X = Y, Yb, Lu, and La) to obtain higher Tc while maintaining low pressure stability. Most prominently, YbTmH12 can stabilize at a pressure of 60 GPa. Compared with binary TmH6 hydride, its Tc was increased to 48 K. The results provide an effective method for the rational design of moderate pressure stabilized hydride superconductors. [ABSTRACT FROM AUTHOR]

Very metal-poor (VMP) stars record the signatures of early accreted galaxies, making them essential tools for unraveling the early stages of Galaxy formation. Understanding the origin of VMP stars requires comprehensive studies of their chemical compositions and kinematics, which are currently lacking. Hence, we conduct a chemodynamical analysis of 352 VMP stars selected from one of the largest uniform high-resolution VMP star samples, jointly obtained from LAMOST and Subaru. We apply a friends-of-friends clustering algorithm to the master catalog of this high-resolution sample, which consists of 5778 VMP stars. It results in 131 dynamically tagged groups with 89 associated with known substructures in the Milky Way, including Gaia-Sausage-Enceladus (GSE), Thamnos, Helmi streams, Sequoia, Wukong, Pontus, and the very metal-poor disk (VMPD). Our findings are: (i) the VMPD shows lower Zn abundances than the rest, which indicates that it could be a relic of small stellar systems; (ii) Sequoia shows moderately high r -process abundances; (iii) Helmi streams show deficiencies in carbon and light neutron-capture elements; (iv) the fraction of carbon-enhanced metal-poor stars with no enhancement in heavy elements (CEMP-no stars) seems low in the VMPD and the Helmi streams; and (v) a subgroup in GSE exhibits a very high fraction of r -process enhanced stars, with four out of five showing [Eu/Fe]> +1.0. The abundance patterns of other elements in VMP substructures largely match the whole VMP sample. We also study large-scale correlations between abundance ratios and kinematics without classifying stars into substructures, but it does not yield significant correlations once the overall chemical evolution is considered for most elements. [ABSTRACT FROM AUTHOR]

Spin–orbit torque (SOT) in the heavy elements with a large spin–orbit coupling (SOC) has been frequently used to manipulate the magnetic states in spintronic devices. Recent theoretical works have predicted that the surface oxidized light elements with a negligible SOC can yield a sizable orbit torque (OT), which plays an important role in switching the magnetization. Here, we report anomalous-Hall-resistance and harmonic-Hall-voltage measurements on perpendicularly magnetized Ta/Cu/[Ni/Co]5/Cu-CuOx multilayers. Both torque efficiency and spin-Hall angle of these multilayers are largely enhanced by introducing a naturally oxidized Cu-CuOx layer, where the SOC is negligible. Such an enhancement is mainly due to the collaborative driven of the SOT from the Ta layer and the OT from the Cu/CuOx interface and can be tuned by controlling the thickness of Cu-CuOx layer. Compared to the Cu-CuOx-free multilayers, the maximum torque efficiency and spin-Hall angle were enhanced by a factor of ten, larger than most of the reported values in the other heterostructures. [ABSTRACT FROM AUTHOR]