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Spin defects in atomically thin two-dimensional (2D) materials such as hexagonal boron nitride (hBN) attract significant attention for their potential quantum applications. The layered host materials not only facilitate seamless integration with optoelectronic devices but also enable the formation of heterostructures with on-demand functionality. Furthermore, their atomic thickness renders them particularly suitable for sensing applications. However, the short coherence times of the spin defects in hBN limit them in quantum applications that require extended coherence time. One primary reason is that both boron and nitrogen atoms have non-zero nuclear spins. Here, we present another 2D material germanium disulfide ($\beta$-GeS$_2$) characterized by a wide bandgap and potential nuclear-spin-free lattice. This makes it as a promising host material for spin defects that possess long-coherence time. Our findings reveal the presence of more than two distinct types of spin defects in single-crystal $\beta$-GeS$_2$. Coherent control of one type defect has been successfully demonstrated at both 5 K and room temperature, and the coherence time $T_2$ can achieve tens of microseconds, 100-folds of that of negatively charged boron vacancy (V$_{\text{B}}^-$) in hBN, satisfying the minimal threshold required for metropolitan quantum networks--one of the important applications of spins. We entatively assign the observed optical signals come from substitution defects. Together with previous theoretical prediction, we believe the coherence time can be further improved with optimized lattice quality, indicating $\beta$-GeS$_2$ as a promising host material for long-coherence-time spins., Comment: 8 pages, 5 figures

This paper describes the development of an on-board data-driven system that can monitor and localize the fault in a quadrotor unmanned aerial vehicle (UAV) and at the same time, evaluate the degree of damage of the fault under real scenarios. To achieve offline training data generation, a hybrid approach is proposed for the development of a virtual data-generative model using a combination of data-driven models as well as well-established dynamic models that describe the kinematics of the UAV. To effectively represent the drop in performance of a faulty propeller, a variation of the deep neural network, a LSTM network is proposed. With the RPM of the propeller as input and based on the fault condition of the propeller, the proposed propeller model estimates the resultant torque and thrust. Then, flight datasets of the UAV under various fault scenarios are generated via simulation using the developed data-generative model. Lastly, a fault classifier using a CNN model is proposed to identify as well as evaluate the degree of damage to the damaged propeller. The scope of this paper focuses on the identification of faulty propellers and classification of the fault level for quadrotor UAVs using RPM as well as flight data. Doing so allows for early minor fault detection to prevent serious faults from occurring if the fault is left unrepaired. To further validate the workability of this approach outside of simulation, a real-flight test is conducted indoors. The real flight data is collected and a simulation to real sim-real test is conducted. Due to the imperfections in the build of our experimental UAV, a slight calibration approach to our simulation model is further proposed and the experimental results obtained show that our trained model can identify the location of propeller fault as well as the degree/type of damage. Currently, the diagnosis accuracy on the testing set is over 80%.

Optically addressable spin defects in wide-bandage semiconductors as promising systems for quantum information and sensing applications have attracted more and more attention recently. Spin defects in two-dimensional materials are supposed to have unique superiority in quantum sensing since their atomatic thickness. Here, we demonstrate that the negatively boron charged vacancy (V$ _\text{B}^{-} $) with good spin properties in hexagonal boron nitride can be generated by ion implantation. We carry out optically detected magnetic resonance measurements at room temperature to characterize the spin properties of V$ _\text{B}^{-} $ defects, showing zero-filed splitting of $ \sim $ 3.47 GHz. We compare the photoluminescence intensity and spin properties of V$ _\text{B}^{-} $ defects generated by different implantation parameters, such as fluence, energy and ion species. With proper parameters, we can create V$ _\text{B}^{-} $ defects successfully with high probability. Our results provide a simple and practicable method to create spin defects in hBN, which is of great significance for integrated hBN-based devices.

Hexagonal boron nitride (hBN) has recently been demonstrated to contain optically polarized and detected electron spins that can be utilized for implementing qubits and quantum sensors in nanolayered-devices. Understanding the coherent dynamics of microwave driven spins in hBN is of crucial importance for advancing these emerging new technologies. Here, we demonstrate and study the Rabi oscillation and related dynamical phenomena of the negatively charged boron vacancy ($\rm V_B^-$) spins in hBN. We report on different dynamics of the $\rm V_B^-$ spins at weak and strong magnetic fields. In the former case the defect behaves like a single electron spin system, while in the latter case it behaves like a multi-spin system exhibiting the multiple-frequency dynamical oscillation like clear beat in Ramsey fringes. We also carry out theoretical simulations for the spin dynamics of $\rm V_B^-$ and reveal that the nuclear spins can be driven via the strong electric-nuclear coupling existing in $\rm V_B^-$ center, which can be modulated by the magnetic field and microwave field., Comment: 9 pages, 5 figures

Two-dimensional hexagonal boron nitride (hBN) has attracted large attentions as platforms for realizations for integrated nanophotonics and collective effort has been focused on the spin defect centers. Here, the temperature dependence of the resonance spectrum in the range of 5-600 K is investigated. The zero-field splitting (ZFS) parameter D is found to decrease monotonicly with increasing temperature and can be described by Varshni empirical equation perfectly, while E almost does not change. We systematically study the differences among different hBN nanopowders and provide an evidence of edge effects on ODMR of VB- defects. Considering the proportional relation between D and reciprocal of lattice volume, the thermal expansion might be the dominant reason for energy-level shifts. We also demonstrate that the VB- defects still exist stably at least at 600 K. Moreover, we propose a scheme for detecting laser intensity using the VB- defects in hBN nanopowders, which is based on the obvious dependence of its D value on laser intensity. Our results are helpful to gain insight into the spin properties of VB- and for the realizations of miniaturized, integrated thermal sensor.

During the last ten years, the studies on non-Markovian open system dynamics has become increasingly popular and having contributions from diverse set of research communities. This interest has arisen due to fundamental problematics how to define and quantify memory effects in the quantum domain, how to exploit and develop applications based on them, and also due to the question what are the ultimate limits for controlling open system dynamics. We give here a simple theoretical introduction to the basic approaches to define and quantify quantum non-Markovianity -- also highlighting their connections and differences. In addition to the importance of the development for open quantum systems studies, we also discuss the implications of the progress for other fields including, e.g., formal studies of stochastic processes and quantum information science, and conclude with possible future directions the recent developments open., Comment: 7 pages. Perspective Article on the theory of quantifying non-Markovianity

Recent developments in practical quantum engineering and control techniques have allowed significant developments for experimental studies of open quantum systems and decoherence engineering. Indeed, it has become possible to test experimentally various theoretical, mathematical, and physical concepts related to non-Markovian quantum dynamics. This includes experimental characterization and quantification of non-Markovian memory effects and proof-of-principle demonstrations how to use them for certain quantum communication and information tasks. We describe here recent experimental advances for open system studies, focussing in particular to non-Markovian dynamics including the applications of memory effects, and discuss the possibilities for ultimate control of decoherence and open system dynamics., Comment: 7 pages. Perspective Article on the experiments of non-Markovian quantum dynamics

LiOsO3 is the first experimentally confirmed polar metal. Previous works suggested that the ground state of LiOsO$_3$ is just close to the critical point of metal-insulator transition. In this work the electronic state of LiOsO$_3$ is tuned by epitaxial biaxial strain, which undergoes the Slater-type metal-insulator transition under tensile strain, i.e., the G-type antiferromagnetism emerges. The underlying mechanism of bandwidth tuning can be extended to its sister compound NaOsO$_3$, which shows an opposite transition from a antiferromagnetic insulator to a nonmagnetic metal under hydrostatic pressure. Our work suggests a feasible route for the manipulation of magnetism and conductivity of polar metal LiOsO$_3$., Comment: 10 pages, 4 figures

LiOsO$_3$ is the first experimentally confirmed polar metal with ferroelectric-like distortion. One puzzling experimental fact is its paramagnetic state down to very low temperature with negligible magnetic moment, which is anomalous considering its $5d^3$ electron configuration since other osmium oxides (e.g. NaOsO$_3$) with $5d^3$ Os ions are magnetic. Here the magnetic and electronic properties of LiOsO$_3$ are re-investigated carefully using the first-principles density functional theory. Our calculations reveal that the magnetic state of LiOsO$_3$ can be completely suppressed by the spin-orbit coupling. The subtle balance between significant spin-orbit coupling and weak Hubbard $U$ of $5d$ electrons can explain both the nonmagnetic LiOsO$_3$ and magnetic NaOsO$_3$. Our work provides a reasonable understanding of the long-standing puzzle of magnetism in some osmium oxides., Comment: 10 pages, 7 figures

Ca$_3$Ti$_2$O$_7$ is an experimentally confirmed hybrid improper ferroelectric material, in which the electric polarization is induced by a combination of the coherent TiO$_6$ octahedral rotation and tilting. In this work, we investigate the tuning of ferroelectricity of Ca$_3$Ti$_2$O$_7$ using iso-valent substitutions on Ca-sites. Due to the size mismatch, larger/smaller alkaline earths prefer $A$'/$A$ sites respectively, allowing the possibility for site-selective substitutions. Without extra carriers, such site-selected iso-valent substitutions can significantly tune the TiO$_6$ octahedral rotation and tilting, and thus change the structure and polarization. Using the first-principles calculations, our study reveals that three substituted cases (Sr, Mg, Sr+Mg) show divergent physical behaviors. In particular, (CaTiO$_3$)$_2$SrO becomes non-polar, which can reasonably explain the suppression of polarization upon Sr substitution observed in experiment. In contrast, the polarization in (MgTiO$_3$)$_2$CaO is almost doubled upon substitutions, while the estimated coercivity for ferroelectric switching does not change. The (MgTiO$_3$)$_2$SrO remains polar but its structural space group changes, with moderate increased polarization and possible different ferroelectric switching paths. Our study reveals the subtle ferroelectricity in the $A_3$Ti$_2$O$_7$ family and suggests one more practical route to tune hybrid improper ferroelectricity, in addition to the strain effect.

We introduce a scheme for remote entanglement generation for the photon polarization. The technique is based on transferring the initial frequency correlations to specific polarization-frequency correlations by local dephasing and their subsequent removal by frequency up-conversion. On fundamental level, our theoretical results show how to create and transfer entanglement, to particles which never interact, by means of local operations. This possibility stems from the multi-path interference and its control in frequency space. For applications, the developed techniques and results allow for the remote generation of entanglement with distant parties without Bell state measurements and opens the perspective to probe frequency-frequency entanglement by measuring the polarization state of the photons., Comment: 8 pages

Recently, a series of different measures quantifying memory effects in the quantum dynamics of open systems has been proposed. Here, we derive a mathematical representation for the non-Markovianity measure based on the exchange of information between the open system and its environment which substantially simplifies its numerical and experimental determination, and fully reveals the locality and universality of non-Markovianity in the quantum state space. We further illustrate the application of this representation by means of an all-optical experiment which allows the measurement of the degree of memory effects in a photonic quantum process with high accuracy., Comment: 5 pages, 5 figures

We construct a linear optics measurement process to determine the entanglement measure, named \emph{I-concurrence}, of a set of $4 \times 4$ dimensional two-photon entangled pure states produced in the optical parametric down conversion process. In our experiment, an \emph{equivalent} symmetric projection for the two-fold copy of single subsystem (presented by L. Aolita and F. Mintert, Phys. Rev. Lett. \textbf{97}, 050501 (2006)) can be realized by observing the one-side two-photon coincidence without any triggering detection on the other subsystem. Here, for the first time, we realize the measurement for entanglement contained in bi-photon pure states by taking advantage of the indistinguishability and the bunching effect of photons. Our method can determine the \emph{I-concurrence} of generic high dimensional bipartite pure states produced in parametric down conversion process., Comment: 4 figures