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[Display omitted] The Sudokwon landfill (SL) in the Seoul metropolitan area, South Korea, is among the world's largest landfills, striving to curtail landfill gas (LFG) emissions and achieve carbon neutrality by 2050. Since 2005, the SL Management Corporation (SLC) has measured LFG emissions (i.e., methane (CH 4) and carbon dioxide (CO 2)) using a dynamic flux chamber proposed by the US EPA. However, uncertainty prevails in validating the reduction of LFG emissions due to the limited spatiotemporal data coverage. In 2020, an eddy covariance (EC) system was installed to enhance measurements, revealing highly fluctuating LFG emissions driven by waste layer LFG production, LFG collection, and atmospheric pressure changes. During the study period, the annual CH 4 emission increased slightly from 465.0 ± 4.2 to 485.5 ± 6.4 g C m−2, while that of CO 2 decreased by 2/3 (from 408.7 ± 16.5 to 270.6 ± 18.8 g C m−2), primarily due to the doubled CO 2 uptake by the vegetated topsoil. Our first long-term (March 2020 to February 2022) quasi-continuous monitoring using EC (with a gap-filling and partitioning technique based on Random Forest) emphasizes the difficulty of temporal upscaling of discontinuously observed surface emissions to quantify the LFG inventory and the need for continuous observations or suitable proxies (e.g., atmospheric CH 4 concentration). [ABSTRACT FROM AUTHOR]

[Display omitted] • PMOB is an economical solution to reduce landfill CH 4 emissions. • Both single- and two-phase flow models are used for calculating LUGM. • LUGM doesn't reflect gas flow rate into MOL. • A novel PMOB design is proposed with a trapezoidal MOL-GDL interface. • Trapezoidal MOL-GDL interface enhances total gas flow rate into MOL. Passive methane oxidation biosystems (PMOBs) are developed as an innovative and cost-effective solution to reduce methane (CH 4) emissions from municipal solid waste landfills. A PMOB consists of a methane oxidation layer (MOL) and an underlying gas distribution layer (GDL). The length of unrestricted gas migration (LUGM) has been recently proposed as the design criterion for PMOBs where the LUGM is calculated as the horizontal length along the MOL-GDL interface with the volumetric gas content (θ a) exceeding the threshold volumetric gas content (θ a,occ). This paper examined water and gas migration within three PMOBs with different MOL-GDL interfaces subject to precipitation and evaporation using verified numerical models. The results show that the use of a single-phase flow model underestimates the LUGM values of the PMOB for heavy precipitation events, and a two-phase flow model should be used to calculate both the LUGM and the total gas mass flow rate into the MOL when designing PMOBs. Both zig-zag and trapezoidal MOL-GDL interfaces can redistribute the gas mass flow rate at the MOL-GDL interface, while the trapezoidal MOL-GDL interface slightly outperforms the zig-zag MOL-GDL interface for enhancing the total gas mass flow rate into the MOL when comparing with the planar MOL-GDL interface. The zig-zag and trapezoidal MOL-GDL interfaces allow gas migration in the upper part of each PMOB segment even when the lower part of each PMOB segment was filled with water, and thus have a potential to minimize hotspot formation. [ABSTRACT FROM AUTHOR]

• Estimates of modeled CH 4 emission (E) data for 1,325 U.S. landfills were reviewed. • Operators use two methods to estimate E from landfills with a gas collection system. • First-order decay (FOD) method shows increasing emissions. • Collection efficiency assumption method shows decreasing emissions. • FOD method shows some agreement to remotely sensed national estimates. As part of its commitment to the United Nations Framework Convention on Climate Change, the U.S. annually develops a national estimate of methane emissions from municipal solid waste (MSW) landfills by aggregating activity data from each facility. Since 2010, the U.S. has reported a 20 % decrease in MSW landfill emissions despite a 21 % increase in tons disposed. Operator-submitted data were investigated to understand the causes of this decline. In the U.S., operators of landfills with a gas collection and control system (GCCS) calculate their facility's emissions via two separate approaches – (1) first-order decay (FOD) and (2) collection efficiency assumption (CEA) − and select either result to feed into the annual inventory. The FOD model predicts methane generation proportional to waste disposal and that approach calculated a 19 % increase in total methane generated from 2010 to 2022, whereas generation via the CEA approach decreased by 8.9 %. The amount of measured methane collected has increased 7.5 % for the same years. Discrepancies between the two models' generated methane, assumed gas collection efficiencies, and oxidized methane compound into substantive differences in national estimates. Operators more frequently select the CEA method, which results in decreased national estimates. If only the FOD method was used, U.S. MSW landfill emissions would be 1.3-1.7 times greater than current estimates which is similar to recent extrapolations from remote sensing campaigns in the U.S. Both models contain parameters with large inherent uncertainty. Without measurement methods that continuously quantify both point-source and diffuse emissions, an assessment of either equation's accuracy cannot be made. [ABSTRACT FROM AUTHOR]

• Demonstration of a whole-site flushing technique in an MSW landfill. • Use of bromide and water as tracers in landfill. • Verification of dual-porosity behaviour of MSW. • in situ field-scale estimates of block diffusion time. • Examination of different fill-and-draw flushing scenarios. A fill-and-draw flushing test on a landfill cell containing MSW waste was carried out to examine the operational viability of this method for accelerating the flushing of contaminants and landfill stabilisation. During the fill cycle, 800 m3 of water containing the tracer bromide was pumped into the base of a 0.44 ha landfill cell, resulting in the estimated saturation of 9,400 m3 of waste. Abstraction took place in two phases, during which 1,100 m3 of tracer/leachate was recovered. Samples of leachate were analysed for the tracer, electrical conductivity and indigenous solutes chloride and ammonia. Tracer recovery was between 63 and 72 % for bromide. An estimated 227 kg of ammonia and 575 kg of chloride were removed. Test data was used to calibrate a 1D, dual-porosity model involving advection in a mobile zone, and diffusion into 'blocks' of a less mobile zone. The model fitted well to the early time data, whereas later data appears to have been affected by recharge. The results of this trial demonstrate the possibilities of the 'fill-and-draw' concept using the basal leachate drainage system of landfills as a potential accelerated landfill remediation technique. However, modelling results suggest low contaminant removal efficiency. Including a pause between the fill and the draw cycles improves mass removal. [ABSTRACT FROM AUTHOR]

Highlights Environmental hazards caused by the ever‐increasing end‐of‐life (EoL) glass fiber reinforced polymer (GFRPs) composite waste is of major concern for the sustainable development of the industry. Compared to land filling or incineration, pyrolysis is one of the most promising environmentally friendly methods of disposal of EoL GFRPs. Pyrolysis not only results in recovery of clean glass fibers but other valuable products, such as oils. However, long processing time at elevated temperature leads to aggravation of already existed surface flaws along with the structural changes. Therefore, thermal conditioning of glass fibers results in severe deterioration of the strength in recovered fibers and hence limiting the use of recovered fibers to low end‐products. In this study, a new strategy was adopted where instead of complete cleaning of the fibers at pyrolysis stage, the fibers were partially oxidized and the complete removal of char from the surface of glass was done during hot alkaline etching. This strategy was opted to enhance the quality of the required fibers while reducing the processing time. The results showed ~200% increase in strength of fibers after the combined treatment of pyrolysis and post etching compared to the just pyrolyzed samples with etching time of just 1 min. End‐of‐life panels of GFRPs were pyrolyzed under inert environment of Argon. Residual char was partially removed through post oxidation under flowing air. Hot alkaline etching resulted in complete removal of char and surface defects. Partial oxidation and short etching cycles resulted in improved strength of recovered glass fibers. [ABSTRACT FROM AUTHOR]

This paper introduces a new retaining structure, multi-step cantilever retaining walls pulled locally with geogrids, which has advantages of light weight, quick installation and good applicability for high fill earthworks. Considering log-spiral rotation failure mechanism passing by the heel of the lowest wall members as well as pull-out failure and tensile rupture of the flexible reinforcements, an analytical procedure for seismic overall stability of the retained embankment is proposed based on the upper-bound limit analysis method combined with pseudo static approach. Analysis results of a practical example show that the proposed safety factor and critical slip surface are identical with those by numerical simulation method via FLAC3D. The safety factor increases approximately linearly with the ultimate tension force and the number of reinforcements and nonlinearly with the length of reinforcements within a certain range. Horizontal seismic force has noticeable effect on the slope stability, and vertical seismic effect becomes significant under high horizontal acceleration coefficient. The safety factor is decreasing and the critical slip surface develops obviously towards the embankment exterior as the total number of vertical wall members increases. Besides, the distribution width and setback distance from the walls of the strip surcharge have certain effects on the retained slope stability. [ABSTRACT FROM AUTHOR]

Waste generation has seen a significant surge in the last decade, presenting an urgent need for efficient and sustainable waste management strategies. The mounting piles of landfill waste underscore the criticality of segregating recyclable from non-recyclable waste, a measure that could alleviate numerous global environmental challenges. The increasing necessity to differentiate waste into specific categories such as paper, plastic, and metal is becoming evident; these categories demand distinct disposal and recycling methods. Addressing this automatic detection and segregation issue calls for an automated garbage classification system, achievable through computer vision. This paper introduces a deep learning and computer vision-based Smart Ensembled Framework for Waste Management (SEFWaM) to categorize garbage into various classes for improved waste management. This innovative model employs a fusion of transfer learning—a deep learning technique and boosting to devise an ensembled approach for efficient waste classification. Our proposed approach, trained on the Trashnet 2.0 dataset, has demonstrated superior performance over competing algorithms in terms of Weighted Macro Precision (WMP), Weighted Macro Recall (WMR), Weighted Macro F1-Score (WMF), and test accuracy. The proposed SEFWaM model achieves an accuracy of 94.2% for the considered dataset, proving its superior efficiency over other deep learning-based models. This research thereby contributes to a pressing environmental issue by offering an automated, efficient solution for waste management. [ABSTRACT FROM AUTHOR]

A new landfill cover system, biochar-methanotrophs-clay (BMC) cover is recommended for reducing methane emissions at landfills. It also contributes to decreasing soil permeability and improving soil water retention in a long time, due to highly porous structure of biochar and the growth metabolism of methanotrophs. To determine the effects of biochar content, oxidation aging times and methane-filled days on hydraulic properties, a total of 60 groups of experiments were conducted. The saturated hydraulic conductivity (ksat) was obtained by flexible wall permeameter with controllable hydraulic head pressure. The results showed that the ksat of BMC increased with increasing biochar content and oxidation aging times, while decreased with adding methane-filled days. The soil-water characteristic curves (SWCCs) were obtained with soil suction measured by the filter paper method. The results indicated the water retention capacity of MBC reduced with increasing oxidation aging times but increased with adding methane-filled days. Detected by mercury intrusion porosimetry (MIP), fourier transform infrared spectroscopy (FTIR) and scanning electron microscope (SEM), the differences displayed the changes of pore structures and extracellular polymeric substances (EPS). The oxidation aging of biochar increased the volume of pores, resulting in the increased ksat and the decreased water retention capacity. However, the growing of methanotrophs decreased the volume of pores, resulting in the ksat decreased and the water retention capacity increased due to EPS. No matter how many times the oxidation aging process was experienced, the BMC with longer methane-filled days exhibited relatively lower ksat and better water retention capacity. This implied a more stable barrier capacity to reduce water infiltration in the long term. By combing a series of macro and micro experiments, this paper provides theoretical guidance for the application of biocharmethanotroph- clay mixture to landfill covers. [ABSTRACT FROM AUTHOR]

Phosphate tailings are usually used as backfill material in order to recycle tailings resources. This study considers the effect of the mix proportions of clinker-free binders on the fluidity, compressive strength and other key performances of cementitious backfill materials based on phosphate tailings. In particular, three solid wastes, phosphogypsum (PG), semi-aqueous phosphogypsum (HPG) and calcium carbide slag (CS), were selected to activate wet ground granulated blast furnace slag (WGGBS) and three different phosphate tailings backfill materials were prepared. Fluidity, rheology, settling ratio, compressive strength, water resistance and ion leaching behavior of backfill materials were determined. According to the results, when either PG or HPG is used as the sole activator, the fluidity properties of the materials are enhanced. Phosphate tailings backfill material activated with PG present the largest fluidity and the lowest yield stress. Furthermore, the backfill material's compressive strength is considerably increased to 2.9 MPa at 28 days after WGGBS activation using a mix of HPG and CS, all with a settling ratio of only 1.15 percent. Additionally, all the three ratios of binder have obvious solidification effects on heavy metal ions Cu and Zn, and P in phosphate tailings. Graphic Abstract [ABSTRACT FROM AUTHOR]

Located in Douala V (Cameroon), Makepé Missoké is a lowland area that is influenced by the Tongo Bassa and Ngongué rivers. The site has a closed dumpsite, that operated from the 1975's to 2003 for the disposal and storage of domestic waste produced in Douala. Geoelectric profiling (ERT) coupled with seismo-electric imaging was used to characterize the shallow aquifer of the Douala subbasin and map subsurface pollution. Fourteen geoelectrical profiles were deployed between June and August 2018 and March 2019. Along these lines, 49 sets of seismo-electric point data were collected in December 2021. A total of 118 wells drilled (2018) were used to obtain water level and topographic data. The aquifer geometry, hydraulic characteristics, permeability, lithology and leachate plume extent were determined. This survey enables us to visualize waste infiltration and migration within Makepé. The drilled wells indicate that the main lithologies observed are clay, sandy clay, sand, clayey sand and gravel. The leachate plume observed after processing the electric profiles had a resistivity signature of < 10 Ωιτι, and high electrical conductivity are observed in some wells. The leachate migrates within the subsurface along a northwest-southwest trend, where ground water pollution is observed due to leachate infiltration. This infiltration resulted in poor water quality indices in some collected samples. Such pollution is common in unconfined aquifers (< 50 m) due to the absence of a confining layer at the landfill. An increase in resistivity values with depth toward the northeast direction indicates progressive vertical dilution during leachate mineralization. This study integrated geoelectric and seismo-electric tomography with basic water chemistry analysis to effectively characterize the groundwater within the phreatic Quaternary/Mio-Pliocene aquifers of the Douala basin. [ABSTRACT FROM AUTHOR]

Introduction: Methane oxidation biosystems (MOBs) are cost effective engineered systems capable of catalyzing the transformation of CH4 into CO2 biotically, thereby mitigating emissions from landfills. Method: In this study we validate how accurately one can predict the hydraulic behaviour of a MOB using numerical modeling. More precisely how one can identify the length of unrestricted gas migration (LUGM), a critical design criterion for effective methane abatement biosystems. Laboratory experiments were conducted to obtain the material properties for a compost mixed with plastic pellets, and sand. With the water retention curve and air permeability function, we predicted the hydraulic performance of a MOB using Hydrus-2D. We then designed and constructed a MOB and monitored several key parameters for 12 months. The validation of the design methodology was conducted using field measurements, while actual climatic data was used as input in numerical modeling. Results: The air permeability function was an appropriate activation function for determining LUGM. Accordingly, the predicted hydraulic behaviour matched the measured hydraulic behaviour reasonably well, validating the proposed procedure. [ABSTRACT FROM AUTHOR]

To elucidate the time-dependent swelling behavior of landfill sand-bentonite mixture liners under the effect of organic pollutants, an no loading swelling ratio test was conducted on mixtures with varying sand and diesel content. The evolution characteristics of the swelling time curve morphology were investigated. The micro-mechanisms underlying the swelling time effect evolution were explored. The results indicated that the sand-diesel interaction significantly altered the swelling time curve morphological characteristics of the mixture. As the sand content increased, the swelling coefficient at the stable state decreased. However, during the rapid swell phase, dieselcontaminated mixed soil does not exhibit the increase-then-decrease pattern in swell coefficient seen in unpolluted mixed soil. The duration of both the slow swelling phase and the time to reach a stable state were longer. Mechanistic analysis revealed that cation exchange capacity is insufficient to effectively analyze the evolution characteristics of the swelling time curve. Instead, the initial swelling potential of bentonite is the true indicator of the mixture’s swelling properties. The particle size distribution influences the changes in the swelling coefficient during the rapid swelling phase, but diesel alters the particle size distribution, mitigating its impact. The oil sealing effect within intra-aggregate and inter-aggregate pores not only weakened the swelling characteristics of the mixture at all stages but also increased the permeability resistance, thereby reducing the duration of the rapid swelling phase and extending the slow swelling and stable swelling phases. [ABSTRACT FROM AUTHOR]

The effect of applied stress (20, 60, and 150 kPa) on the diffusion of perfluorooctanoic acid (PFOA) and perfluorooctane sulfonate (PFOS) through a geosynthetic clay liner (GCL) is examined. The diffusion coefficients deduced from GCL diffusion tests for PFOA and PFOS decrease linearly with decreasing final bulk GCL void ratio (increasing applied stresses). The different components of the same GCL are also tested for PFOA and PFOS sorption. No statistically significant sorption of PFOA is observed for any of the components of the GCL. However, some sorption of PFOS onto the cover and carrier geotextiles of the GCL is observed with in an average distribution coefficient, K d ∼2.22 ml/g for the GCL. Permeants containing different PFAS compounds are tested to assess their impact on the Geomembrane (GMB) - GCL interface transmissivity in composite liners. Results show PFAS concentrations up to 20 ppm had negligible impact on the GMB-GCL interface transmissivity. Lastly, the GCL specimens extracted from the diffusion tests are tested for hydraulic conductivity. No impact of PFAS is seen on the hydraulic conductivity of GCLs subjected to high applied loads, but a small increase is seen on the GCLs subjected to relatively low applied stresses. • First diffusion test and parameters on PFAS migrating through a GCL and evaluation of a diffusion coefficient for PFOS and PFOA. • First interface transmissivity test with a PFAS-contaminated solution and assessment of the effect of PFAS on interface transmissivity and evaluation of the effect of PFAS on the hydraulic conductivity of GCL used in transmissivity tests. • Use of a diffusion test to independently verify batch test results for partitioning of PFOS and PFOA to a GCL. [ABSTRACT FROM AUTHOR]

1,4‐Dioxane is a probable human carcinogen and a persistent aquatic contaminant. Cometabolic biodegradation of 1,4‐dioxane is a promising low‐cost and effective treatment technology; however, further demonstration is needed for treating landfill leachate. This technology was tested in two full‐scale moving bed biofilm reactors (MBBRs) treating raw landfill leachate with tetrahydrofuran selected as the cometabolite. The raw leachate contained on average 82 μg/L of 1,4‐dioxane and before testing the MBBRs removed an average of 38% and 42% of 1,4‐dioxane, respectively. First, tetrahydrofuran was added to MBBR 1, and 1,4‐dioxane removal was improved to an average of 73%, with the control MBBR removing an average of 37% of 1,4‐dioxane. During this period, an optimal dose of 2 mg/L of tetrahydrofuran was identified. Tetrahydrofuran was then fed to both MBBRs, where the 1,4‐dioxane removal was on average 73% and 80%. Cometabolic treatment at the landfill significantly reduced the concentration of 1,4‐dioxane received from the landfill at a downstream wastewater treatment and indirect potable reuse facility, reducing the load of 1,4‐dioxane from 44% to 24% after the study. Practitioner Points: Cometabolic degradation of leachate 1,4‐dioxane with THF in MBBRs is a feasible treatment technology and a low‐cost technique when retrofitting existing biological treatment facilities.The MBBRs can be operated at a range of temperatures, require no operational changes beyond THF addition, and operate best at a mass ratio of THF to 1,4‐dioxane of 24.Source control of 1,4‐dioxane significantly reduces the concentration of 1,4‐dioxane in downstream wastewater treatment plants and potable reuse facilities. [ABSTRACT FROM AUTHOR]

Managing waste tires presents a significant challenge globally, particularly in regions experiencing high temperatures and shortage of landfill sites. This issue is affecting countries like Kuwait, where the abundance of waste tires is a major source of environmental and safety risks, particularly during the intensely hot summer months. This extreme heat has sparked numerous fires, leading to substantial air pollution due to thick black smoke. Given the limited disposal options, recycling waste tires and finding practical applications for ground tire rubber (GTR) is essential. To address the challenge, a comprehensive laboratory testing program was conducted, using locally produced rubber aggregates as an additive to Kuwait's local surface sands. Two new variables were examined namely the size and gradation of the GTR, and the density of the compacted mixes. For this purpose, two different sizes of rubber aggregates, fine and coarse produced locally, were utilized, and the impact of relative compaction on the strength and compressibility of the mixtures was investigated by testing samples compacted to the maximum density and to 95% of the maximum density. The results suggest that combining local surface sands with rubber tire additives results in a lighter, more permeable, and compressible material, contributing significantly to sustainable waste management. With 20% rubber additive the maximum dry density decreased by nearly 20%, and the permeability increased by 1.74–3.11 times and the compression index increased by 6.15 and 3.8 times with fine and coarse rubber respectively. The angle of friction remained unchanged at 36° with the addition of coarse rubber and decreased by 3°–4° with fine rubber. The change in behavior although not an increase in the strength and stiffness, offers a range of suitable practical applications in civil engineering and environmental management, including use as a drainage layer, embankment construction on soft ground, earth fill around retaining walls, an additive in asphalt mixes, and in manufacturing compressible tiles for sports facilities. [ABSTRACT FROM AUTHOR]

To reduce uncertainties regarding seismic loading scenarios and numerical modeling limitations, the performance-based fragility curves of two California clayey-core earth fill dams (the Anderson and Lexington dams) were developed for the first time using the results of over 170 finite difference seismic analyses. Permanent deformations were considered as the damage index (DI), and fragility curves were generated based on three intensity measures, including the peak ground acceleration (PGA), specific energy density (SED), and Arias intensity (Ia). The results illustrated that the intensity measure significantly affected damage possibilities, and it was essential to simultaneously use all fragility curves based on various intensity measures for proper assessment of seismic vulnerability. Furthermore, evaluation of SED- and Ia-based fragility curves demonstrated that separation of near- and far-field records was critical to generate correct fragility curves when using energy-based parameters as intensity measures. Besides, SED-based fragility curves had the most conservative results, followed by PGA- and Ia-based ones. [ABSTRACT FROM AUTHOR]

Municipal solid wastes are contained in landfills that occupy large areas over several decades and have a significant environmental footprint. The deformation and flow through properties of these materials are important for infrastructure construction on and leachate migration in municipal landfills. However, these properties are not regularly determined because of material heterogeneity, variable constituents, lengthy testing, and pungent odor. The main contribution of this research is the application of consolidation theory to understand the geotechnical behavior of synthetic municipal solid wastes. For this purpose, a synthetic material was prepared in a large cell and incrementally loaded with hydraulic conductivity measured after each load. Test results indicated that void ratio decreased from 0.90 to 0.78 during consolidation as the applied stress increased from 70 to 1225 kPa. The compression index of 0.20 (similar to degraded municipal solid wastes) bounced back with a swell index of 0.022; both indices fell within the range for silt and clay. Likewise, the measured hydraulic conductivity decreased by two orders of magnitude from 10–6 to 10–8 m/s and closely matched those of fine-grained soils. It is concluded that compression of municipal solid wastes follows the consolidation theory and this property is affected by initial void ratio (arising from composition, saturation, and sample disturbance) and particle rearrangement (due to pore water expulsion of during loading). In contrast, the measured conductivity is marginally affected by compression and is quite different from that estimated using the consolidation theory primarily due to alterations in the pore network. [ABSTRACT FROM AUTHOR]

Drilling muds play the essential role the drilling process as they perform many functions, such as the removing of drill cuttings and controlling well pressure. Water-based drilling muds, through the use of more environmentally friendly additives, can meet increased environmental requirements. Many researchers have studied the effects of different natural materials on drilling mud to find environmentally friendly and effective drilling mud materials. The popularity of using waste materials is mainly due to their cost and favourable environmental impact. Performed literature review showed that the rheological and filtration characteristics of water-based drilling muds are enhanced with the addition of leaves of various plants and trees. This article presents investigations of clay-free drilling mud with the addition of birch and aspen leaf powder. This is relevant in the autumn period, since fallen leaves are solid municipal waste and should be disposed of by removal to landfills. The obtained data indicate the possibility of using leaf powder in the drilling mud composition. Addition of leaf powder to the base mud increases the gel strength and plastic viscosity of the mud. In an extent reduces the yield point and filtration index. Rheological parameters increase by 10-30% and filtration index decreases up to 15-17%. [ABSTRACT FROM AUTHOR]

National strategic documents set ambitious goals for reducing greenhouse gas emissions. This also applies to the solid waste management sector, which is experiencing a steady dynamic growth in emissions. The planned measures within the framework of the National Project "Ecology" will not be sufficient for reducing the volume of solid waste disposal and emissions from waste. Positive changes are only possible with a simultaneous increase in new waste recycling capacity and launching a large-scale process of reclaiming land currently occupied by landfills. Pursuing such a course of action has a pronounced social character while its macroeconomic effectiveness is low. The low-emission transformation of the waste management sector requires significant and continuous government incentives through financial support, setting targets, and monitoring their implementation. [ABSTRACT FROM AUTHOR]

A mathematical model for the transport of heavy metal contaminants (HMCs) in a triple-layer composite liner with defective geomembrane under the non-isothermal condition is developed in this study, where the GMB/GCL/CCL (geomembrane, geosynthetic clay liner and compacted clay liner) composite liner is adopted as an example and the Langmuir adsorption model is incorporated. The proposed model is solved by the finite difference approach, and its correctness is validated by comparison with the experimental results, an existing analytical solution and another numerical method. Later, the transport behaviours of HMCs are explored with the established model. Compared with the isothermal condition, the non-isothermal condition enlarges the transport flux, but also reduces the concentration of HMCs. The relative concentration based on the Langmuir adsorption model is higher than that based on the linear adsorption model, which is related to the decrease of the retardation factor under the Langmuir adsorption model. Furthermore, the parametric study shows that when the leachate head ht is between 1.0 and 3.0 m, the defined breakthrough time tb increases by about 1.57 a with the increase of GCL thickness lg by 1 cm, and the tb increases by about 9.07 a with the increase of CCL thickness lc by 0.1 m. [ABSTRACT FROM AUTHOR]

Morocco faces a growing waste issue due to population growth, economic expansion, and industrialization, leading to environmental concerns, especially regarding leachate. From 1986 to 2022, Casablanca's main landfill produced a total of 800,000 m² of leachate, which was stored in evaporation ponds, posing significant environmental risks. Our research not only concentrates on traditional chemical analyses for leachate assessments but also emphasizes ecosystem interactions. Phytotoxicity tests assess the impact of contaminants, particularly heavy metals, complementing traditional chemical analyses. Our study investigated the accumulation of these contaminants in the soil and their subsequent transfer to plant tissues. This research aimed to examine the accumulation of heavy metals, including Pb, Cd, and Hg, in soils irrigated with varying leachate concentrations (C0: control; C1: 5%; C2: 7%; C3: 10%; and C4: 15%). The experiments involved the cultivation of M. sativa plants under open-field conditions. To assess the transfer of metals from soil to plant tissues, the transfer factor (TF) index was calculated. Our findings revealed that Pb, Cd, and Hg exhibited transfer factor ranges of 0.55-0.93, 0.07 to 0.21, and 0.1 to 0.37, respectively. The accumulation of heavy metals at the different leachate concentrations followed the order Pb > Hg > Cd. [ABSTRACT FROM AUTHOR]

The most acceptable way to prevent and eliminate negative phenomena arising from devastating landscapes is phytomelioration. To assess the suitability of the landfill's surface for phytomelioration measures, it is necessary to determine the species composition, physiological stability, density, and completeness of the tree stand (in case of the tree species development) already developing as a result of natural overgrowth. The present work examines the ecological succession of three large urban landfills within the Western Forest Steppe of Ukraine - Lviv, Ternopil, and Lutsk. It was established that the maximum phytomass is characteristic of the gentle slopes of landfills with relatively stable moisture index, and developed soil, which gives reason to attribute the plant groups to the endoecogenesis stage while there are no garbage dumping processes. Three stages of overgrowth were identified for all landfills - syngenetic succession, initial endoecogenetic succession, and mature endoecogenetic succession. The taxonomic structure of the flora of the urban landfills of the Western Forest Steppe is represented by the divisions Magnoliophyta, Pinophyta, Polypodiophyta, Bryophyta, and the classes Magnoliopsida, Liliopsida, Pinopsida, Equisetopsida, Polytrichopsida. The phytomeliorative efficiency of vegetation at solid waste landfills shows that the surface of landfills in the Western Forest Steppe is dominated by stunted plants and the phytomelioration coefficient is low. Thus, the surface of the landfill is suitable for phytomelioration and reclamation works and landfill decommissioning. The phytomeliorative efficiency of vegetation at solid waste landfills shows that the surface of landfills in the Western Forest Steppe is dominated by stunted plants and the phytomelioration coefficient is low. Thus, the surface of the landfill is suitable for phytomelioration and reclamation works and landfill decommissioning. [ABSTRACT FROM AUTHOR]

Landfills are widely employed as the primary means of solid waste disposal. However, this practice generates landfill gas (LFG) which contains methane (CH4), a potent greenhouse gas, as well as various volatile organic compounds and volatile inorganic compounds. These emissions from landfills contribute to approximately 25% of the total atmospheric CH4, indicating the imperative need to valorize or treat LFG prior to its release into the atmosphere. This review first aims to outline landfills, waste disposal and valorization, conventional gas treatment techniques commonly employed for LFG treatment, such as flares and thermal oxidation. Furthermore, it explores biotechnological approaches as more technically and economically feasible alternatives for mitigating LFG emissions, especially in the case of small and aged landfills where CH4 concentrations are often below 3% v/v. Finally, this review highlights biofilters as the most suitable biotechnological solution for LFG treatment and discusses several advantages and challenges associated with their implementation in the landfill environment. [ABSTRACT FROM AUTHOR]

A major roadblock towards the realisation of a circular economy are the lack of high-value products that can be generated from waste. Black soldier flies (BSF; Hermetia illucens) are gaining traction for their ability to rapidly consume large quantities of organic wastes. However, these are primarily used to produce a small variety of products, such as animal feed ingredients and fertiliser. Using synthetic biology, BSF could be developed into a novel sustainable biomanufacturing platform to valorise a broader variety of organic waste feedstocks into enhanced animal feeds, a large variety of high-value biomolecules including industrial enzymes and lipids, and improved fertiliser. This perspective describes how insects, such as Hermetia illucens, which are already used to process organic wastes at industrial scales, could be developed as a synthetic biology platform for sustainable biomanufacturing and bioremediation. [ABSTRACT FROM AUTHOR]

The commercial recycling of spent FCC catalyst typically focuses on recovering only 1–3 % of rare‐earth elements, with the remaining residues often disposed of in landfills. Here, we present a novel method to close a recycling loop for spent FCC catalyst. The method involves a series of leaching steps: Firstly, the spent catalyst material is leached with HNO3 to remove rare‐earth elements such as La; second, solvothermal leaching with HCl removes most of Al and impurities like Fe, Ni and V; finally, a third leaching with H2SO4 removes Ti. The solid residues are then used to synthesize ZSM‐5 without the addition of any extra silicon or aluminum sources after mild activation. The impurities in the synthesis gel strongly modify the properties of the zeolite, with ZSM‐5 crystals containing higher levels of impurities exhibiting lower crystallinities, surface areas, acidities, cracking activities, as well as larger particle sizes. [ABSTRACT FROM AUTHOR]

• A regional CDW landfill landslide risk assessment method is developed. • Most identified landfills located at city administrative borders. • Nearly 70 % of landfills in Shenzhen are at high landslide risk. • Landfills at city internal administrative junctions typically face high risks. In recent years, construction and demolition waste (CDW) landfills landslide accidents have occurred globally, with consequences varying due to surrounding environmental factors. Risk monitoring is crucial to mitigate these risks effectively. Existing studies mainly focus on improving risk assessment accuracy for individual landfills, lacking the ability to rapidly assess multiple landfills at a regional scale. This study proposes an innovative approach utilizing deep learning models to quickly locate suspected landfills and develop risk assessment models based on surrounding environmental factors. Shenzhen, China, with significant CDW disposal pressure, is chosen as the empirical research area. Empirical findings from this study include: (1) the identification of 52 suspected CDW landfills predominantly located at the administrative boundaries within Shenzhen, specifically in the Longgang, Guangming, and Bao'an districts; (2) landfills at the lower risk of landslides are typically found near the northern borders adjacent to cities like Huizhou and Dongguan; (3) landfills situated at the internal administrative junctions generally exhibit higher landslide risks; (4) about 70 % of these landfills are high-risk, mostly located in densely populated areas with substantial rainfall and complex topographies. This study advances landfill landslide risk assessments by integrating computer vision and environmental analysis, providing a robust method for governments to rapidly evaluate risks at CDW landfills regionally. The adaptable models can be customized for various urban and broadened to general landfills by adjusting specific indicators, enhancing environmental safety protocols and risk management strategies effectively. [ABSTRACT FROM AUTHOR]

[Display omitted] • Hydrolysis and acid production stage are the peak period for the siloxanes release. • Species transformation enhances the siloxanes release with short carbon chain. • MSW degradation and species transformation drive the dynamic release of siloxanes. Simulated landfill bioreactors were established and operated for 635 days to investigate the dynamic release of seven siloxanes in landfill biogas (denoted by octamethyltrisiloxane (L3), decamethyltetrasiloxane (L4), dodecamethylpentasiloxane (L5), hexamethylcyclotrisiloxane (D3), octamethylcyclotetrasiloxane (D4) and decamethylcyclopentasiloxane (D5) and dodecamethylcyclohexasiloxane (D6)). In total, 259.45, 252.73, 233.30, 80.40, 4.35, 1.67 and 1.10 mg of D5, D3, D4, D6, L4, L5 and L3 were discharged from 57 kg of municipal solid waste (MSW). More than 70 % of the siloxanes were released before day 119, indicating that the peak period of siloxane discharge occurred during the hydrolysis and acid production stage. The cyclosiloxanes (D3, D4, D5 and D6) were the dominant siloxane species in the biogas. The mass load of discharged cyclosiloxanes was more than 98 % of that of the total siloxanes. In addition to the variation in the concentration distribution profiles of the different siloxane species in the MSW, transformations among species may have an important effect on the release of siloxanes. The main transformation products were D3 and D4 with high release rates (>20 %) and high measured contents of trimethylsilanol (TMSOH) and functional microorganisms (Pseudomonas) were observed during landfilling. These results suggested that MSW degradation and transformation of siloxanes both drive the dynamic release of siloxanes during long-term landfilling. [ABSTRACT FROM AUTHOR]

[Display omitted] • Non-antibiotic pharmaceuticals have higher risk than antibiotics in landfill leachates. • Population size contributed to the regional differences of pharmaceuticals in leachates. • Solid waste composition and loading affect pharmaceutical concentrations in leachate. • High level of pharmaceuticals was observed in the leachate of residual/food waste. Municipal solid waste (MSW) landfill sites have been identified as a significant source of pharmaceuticals in the environment because unused or expired pharmaceuticals are discarded into MSW, which eventually percolate into leachates. However, the contamination of pharmaceuticals in landfill leachate in China is not comprehensively understood. Previous research into factors influencing pharmaceutical concentrations focused on a limited number and type of target pollutants or restricted study area. In the present study, 66 pharmaceuticals were analyzed (including 45 antibiotic and 21 non-antibiotic pharmaceuticals, also categorized as 59 prescription and 7 non-prescription pharmaceuticals) in leachate samples from landfill sites with various characteristics in different regions of China. The results indicated that non-antibiotic pollutants were present at significantly higher concentrations than antibiotic pollutants, with median concentrations of 1.74 μg/L and 527 ng/L, respectively. Non-antibiotic pollutants also presented a higher environmental risk than antibiotic pollutants, by 2 to 4 orders of magnitude, highlighting that non-antibiotic pharmaceuticals should not be overlooked during the assessment of landfill leachate. Pharmaceutical concentrations in landfill leachate samples exhibited regional differences; the population size served by the landfills was the dominant factor contributing to the observed differences. In addition, landfill characteristics such as the solid waste composition and MSW loading can also affect pharmaceutical concentrations in landfill leachate. Despite the implementation of the classification and disposal policy of MSW in Shanghai, China since July 2019, specifying that unused or expired pharmaceuticals should be discarded as hazardous waste, high levels of pharmaceutical contaminations were detected in leachate from the main components of classified MSW (i.e., residual and food waste). These findings emphasize the importance of pharmaceutical management in solid waste systems. [ABSTRACT FROM AUTHOR]

This study attempts to explore the evolution process and driving factors of waste disposal facilities in China by employing a unique dataset that combines municipal-level data on socioeconomic characteristics with establishment-level information on waste disposal facilities over the years 2003–2020. This research reveals a noticeable transformation in the structure of waste disposal facilities in China, with rapid declines in landfill sites and steady increases in incineration plants and composting plants. Meanwhile, the distribution of waste disposal facilities exhibits an apparent spatial imbalance across regions. Specifically, landfill sites are primarily clustered in the central regions; incineration plants are concentrated in eastern areas; and composting plants are scattered and widely distributed. The results of the dynamic spatial Durbin model further indicate that consumption level and land area are the two main driving factors of the increase in the total number of waste disposal facilities and that of three different types of facilities; for each 1% increase in the two factors, the total number of waste disposal facilities will increase by 0.4551 and 0.1329 units respectively. However, waste generation, population density, land price, industrial structure and policy instruments have rather heterogeneous effects on waste disposal facilities and their different types. This study can provide guidelines for optimizing the distribution pattern of waste disposal facilities to mitigate against the unbalanced and inadequate development of waste disposal facilities in China and other developing countries with similar situations. [ABSTRACT FROM AUTHOR]

Long-term monitoring and treatment of landfill leachate (LFL) and landfill gas (LFG) is required until landfilled municipal solid waste (MSW) is sufficiently stabilized and post-closure care can be terminated. Monitoring data of methane (CH4) emissions in LFG from a marine landfill over 30 years were compared with the IPCC first order decay (FOD) model estimates. The observed changes in CH4 showed a similar attenuation trend to the estimates, but the observed CH4 emissions were only about 30% of the estimate over 30 years; LFL is considered to be another pathway for organic carbon to be released to the environment, but the total organic carbon in discharged LFL was only about 0.2% of CH4 carbon in LFG emission over the same period. The increase in the CO2/CH4 ratio in LFG over time suggests that the discrepancy between estimated and observed emissions is due to methane oxidation in the overlying soil, in addition to the high coefficient values used in the FOD model. Total organic carbon (TOC) in LFL discharged as effluent reached a maximum value in the early stages of the landfill and gradually decreased, but only to about one-third of the maximum value after more than 30 years and a decrease in the amount of effluent. As incineration of MSW is expected to reduce organic carbon and nitrogen, the CH4 reduction effect of incineration of business and household waste and sewage sludge was investigated using FOD model estimates. [ABSTRACT FROM AUTHOR]

Globally, less than 0.5% of postconsumer textile waste is recycled, with the majority incinerated or ending up in landfills. Most postconsumer textiles are mixed fibers, complicating mechanical recycling due to material blends and contaminants. Here, we demonstrate the chemical conversion of postconsumer mixed textile waste using microwave-assisted glycolysis over a ZnO catalyst followed by solvent dissolution. This approach electrifies the process heat while allowing rapid depolymerization of polyester and spandex to their monomers in 15 minutes. A simple solvent dissolution enables the separation of cotton and nylon. We assess the quality of all components through extensive material characterization, discuss their potential for sustainable recycling, and provide a techno-economic analysis of the economic feasibility of the process. [ABSTRACT FROM AUTHOR]

This study investigated seasonal variations in the physico-chemical properties of leachate from the Kupferberg landfill site, examining the influence of landfill age and climatic factors. Data provided by the Windhoek Municipality during the years 2017 to 2022 facilitated the exploration of critical concerns related to groundwater protection and human health. Guided by two research questions and anchored in hypotheses tested at a 95% confidence level, the study employed Statistical Packages for Social Scientists (SPSS) for analysis. Significant temperature variations were observed across years [F (5, 21) = 4.493, p < 0.05], indicating a substantial relationship between landfill age and seasonal variations in leachate physico-chemical properties. Further ANOVA tests revealed temperature trends impacting leachate parameters, such as organic content and pH. While COD displayed a declining trend with landfill age, inorganic components like Cl- and alkalinity exhibited no distinct age-related pattern. Wet seasons demonstrated higher EC and Cl--mean values than dry seasons, correlating with elevated COD levels. The study underscored the incremental rise in parameter values over time and during the rainy season, attributed to solid waste degradation and rainwater percolation. Notably, climatic conditions significantly influenced seasonal variations in leachate physico-chemical properties (p < 0.05). Based on this outcome, null hypothesis 1 was rejected. The second null hypothesis was also rejected because climatic conditions do influence the seasonal variations in physico-chemical properties. These findings are crucial for emphasizing the need for effective leachate management strategies and providing valuable insights for arid regions. Future research can expand on a national scale, employing one-way ANOVA tests on other landfills in Namibia, and engaging local communities for comprehensive data collection on cross-contamination. [ABSTRACT FROM AUTHOR]

Municipal solid wastes (MSWs) disposed in landfills are generally exposed to drying and wetting cycles because of the variation in environmental conditions, decomposition of organics and leachate recirculation. This paper studies the water retention curves (WRCs) of fresh and degraded MSWs under various numbers of drying and wetting cycles with water and leachate exposure. The result indicates that the water retention capacities of MSWs decrease with drying and wetting cycles. The maximum hysteresis between the drying and wetting cycles is observed in the first cycles for all MSW samples. The WRCs of medium to highly decomposed MSWs under drying and wetting cycles are similar to those of soils. The WRCs of fresh MSWs can undergo substantial changes due to the discharge of intra-particle moisture caused by decomposition and compression. For both fresh and decomposed MSWs, the WRCs stabilize after 3 drying and wetting cycles. However, only the MSWs of one initial composition with similar void ratios were investigated. Further research should be conducted to investigate the water retention behavior of MSWs with diverse initial compositions (e.g., food contents) and void ratios. [ABSTRACT FROM AUTHOR]

Partial nitritation (PN) is a novel treatment for nitrogen removal using aerobic ammonium oxidation with reduced oxygen requirements compared to conventional nitrification. This study evaluated the performance of the PN process and the factors influencing nitrogen removal from landfill leachate. During the reactivation of biomass, the results showed 70% ammonium removal, but only 20% total nitrogen removal. Further analysis showed that low nitrite accumulation and high nitrate production promoted the growth of nitrite‐oxidizing bacteria (NOB). The ammonium removal activity after soaking the cultivated biomass in synthetic water and leachate was measured to be 0.57, 0.1, 0.17, and 0.25 g N•g VSS−1•d−1 for synthetic wastewater and leachate soaking for synthetic wastewater, 12 h, 3 days, and 7 days, respectively. The study found abundant ammonium‐oxidizing bacteria (AOB) and NOBs in biomass soaked in synthetic wastewater. However, soaking in leachate promoted AOB growth and inhibited NOB growth making leachate suitable for PN. Practitioner Points: The study found that with a longer leachate‐soaking period for biomass, ammonium removal activity increases, which in turn increases ammonium conversions during the PN process.Ammonium‐oxidizing bacteria (AOB) can acclimate to landfill leachate substrate and grow with a longer soaking period.Nitrite‐oxidizing bacteria (NOB) were inhibited by landfill leachate substrate, which is beneficial for nitrite accumulation.Anabolized DO can convert nitrite to nitrate rapidly, which results in higher nitrate accumulation compared to nitrite accumulation.Hence, the DO level has to be sufficiently low to prevent nitrite oxidation and nitrate accumulation. [ABSTRACT FROM AUTHOR]

This paper offers a survey of progress in utilizing bio-oil from wood and forestry waste for creating eco-friendly asphalt pavements, with a focus on sustainability and future research directions. The substantial yearly production of wood and forestry waste often ends up in landfills. However, using pyrolysis to convert this waste into bio-oil presents an alternative to petroleum-based asphalt binders. Bio-oil shares characteristics with traditional binders used in asphalt, resulting in three main applications: bio-asphalt, bio-rejuvenator, and polyurethane (PU)-modified bio-asphalt. Bio-asphalts, though similar to traditional binders, display vulnerability to aging, experiencing mass loss and volatile component evaporation when aged. Bio-oil incorporation affects high- and low-temperature performance grades adversely, limiting its usage due to susceptibility to aging and impact on high-temperature performance. To tackle these issues, additives like rejuvenators, polymers, nanomaterials, and crumb rubber have been introduced to enhance aging resistance and overall performance of bio-asphalt. Wood-based bio-oil, due to its low viscosity and compatibility with petroleum-based binders, is suitable for rejuvenating aged asphalt. The optimal wood-based bio-rejuvenator percentage is 5–20%, with recommended mixing conditions of 130–145 °C, 1000–3000 rpm, and 10–30 min. Innovatively, polyurethane (PU) modification involves incorporating isocyanate into bio-asphalt to create PU-modified bio-asphalt, yielding improved strength, increased high-temperature viscosity, enhanced elastic recovery, and resistance to low-temperature cracking. [ABSTRACT FROM AUTHOR]

There is a lack of information on the level of microplastic (MP) contamination in leachate, which contains high levels of pollutants and has considerable complexity to treat, originating from landfills. In this review, the sources, abundance, and characteristics (polymer type, size, shape) of MPs in landfill leachates were presented. Subsequently, the limited number of studies on MPs released into the environment from the environment from the leachate of uncontrolled landfills were summarised. In the next section, possible remediation approaches (physical treatment processes, chemical treatment processes, biological treatment processes, and constructed wetlands) for MPs in landfill leachate were discussed. Finally, research gaps and recommendations for future studies on MPs in landfill leachates were presented. As a result of the review, it was determined that there is an urgent need for a standardized MP analysis method. Furthermore, the necessity for an increased number of studies on the removal of MPs from landfill leachate with high efficiency and low cost was highlighted. It was emphasized that reducing the amount of plastic waste in landfills and reducing the amount of MP in landfill leachate can be achieved by taking and implementing urgent measures through public policies. [ABSTRACT FROM AUTHOR]

Borehole samples were collected from a municipal solid waste (MSW) landfill in Xi'an, China, and subjected to a series of basic geotechnical and compression tests. This study aims to investigate the influence of composition, dry unit weight, moisture content, organic content, and landfill age on the compressibility of MSW. The results show that with increasing landfill age, the compressible components and organic content exhibit a decreasing trend while the dry unit weight increases. The moisture content does not vary significantly. There is also a linear trend between the logarithm of the primary compression strain and vertical stress. In addition, with an increase in compressible components content, moisture content, and organic content, the modified primary compression index (Cc') shows an increasing trend, whereas with an increase in dry unit weight and landfill age, Cc' shows a decreasing trend. Furthermore, regarding the 34 sets of data, authors only selected five data points for a detailed comparative analysis, this decision was made on the basis that these data points are representative. A modified primary compression index prediction model that considers the dry unit weight, moisture content, and landfill age of the MSW as influencing factors results in a fitting coefficient of 0.797. The Cc' values in this study are within the range of 0.12 to 0.36. These findings provide a reference for the vertical expansion design of existing landfills. [ABSTRACT FROM AUTHOR]

Organophosphate esters (OPEs) used as flame retardants and plasticizers are additives in building and construction materials, decorations, furniture, electronic equipment, among other applications. The presence of materials containing these substances in construction and demolition waste (CDW) from weak waste management practices can result in environmental contamination. In this study, OPEs' presence in soil samples collected from a CDW landfill in Brazil was evaluated. Soil samples were collected in areas adjacent to CDW from an inert landfill, and the samples were analysed by gas chromatography coupled to mass spectrometry. The OPEs were detected in all soil samples at quantifiable concentrations ranging from 21 to 251 ng g−1, and detected compounds were tris(phenyl) phosphate, tris(2-butoxyethyl) phosphate, tris(1,3-dichloroisopropyl) phosphate, tris(2-chloroisopropyl) phosphate and 2-ethylhexyl diphenyl phosphate. The presence of these compounds in a CDW landfill is probably due to the lack of control of the materials sent to and deposited in the landfill, which, results in part from the lack of sampling and screening systems that can help identify the presence of contaminants in the CDW waste stream. This is partially due to OPEs not being considered controlled compounds under current regulations, thus screening or separation for handling of OPEs at construction and demolition work sites is rare to non-existent. The data generated in this study reveals the need for improving CDW management to minimize, if not eliminate, environmental contamination by OPEs. [ABSTRACT FROM AUTHOR]