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1. Comparison of interfacial electron transfer through carboxylate and phosphate anchoring groups

Author

She, Chunxing, Guo, Jianching, Irle, Stephan, Morokuma, Keiji, Lian, Tianquna, Mohler, Debra L., Zabri, Herve, Odobel, Fabrice, Kyoun-Ta Youm, Fang Liu, and Hupp, Joseph T.

Subjects
Phosphonates -- Chemical properties, Carboxylic acids -- Chemical properties, Pyridine -- Chemical properties, Dielectric films -- Structure, Dielectric films -- Chemical properties, Thin films -- Structure, Thin films -- Chemical properties, Chemicals, plastics and rubber industries
Abstract

The effects of anchoring groups on electron injection from adsorbate to nanocrystalline thin films were investigated by comparisons injection kinetics through carboxylate versus phosphonate groups to Ti[O.sub.2] and Sn[O.sub.2]. The anchoring groups were shown to have negligible effects on the energetics of relevant orbitals in the Re complexes.

Published
2007

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