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Radiative cooling by molecules is a crucial process for hydrodynamic escape, as it can efficiently remove the thermal energy driving the outflow, acquired through X-ray and extreme UV absorption. Carbon oxides, such as CO and CO2, and their photochemical products are anticipated to serve as vital radiative cooling sources not only in atmospheres dominated by carbon oxides but also in H2-rich atmospheres. However, their specific effects on the hydrodynamic escape, especially in H2-rich atmospheres, have been inadequately investigated. In this study, we conduct 1-D hydrodynamic escape simulations for H2-rich atmospheres incorporating CO, CO2, and their chemical products on an Earth-mass planet. We consider detailed radiative cooling processes and chemical networks related to carbon oxides to elucidate their impacts on the hydrodynamic escape. In the escape outflow, CO2 undergoes rapid photolysis, producing CO and atomic oxygen, while CO exhibits photochemical stability compared to CO2. The H2 oxidation by atomic oxygen results in the production of OH and H2O. Consequently, the hydrodynamic escape is significantly suppressed by the radiative cooling effects of CO, H2O, OH, and H3+ even when the basal mixing fraction of CO and CO2 is lower than ~0.01. These mechanisms extend the lifetime of H2-rich atmospheres by about one order of magnitude compared to the case of pure hydrogen atmospheres on early Earth, which also results in negligible escape of heavier carbon- and nitrogen-bearing molecules and noble gases., Comment: 47 pages, 9 figures

Earth is expected to have acquired a reduced proto-atmosphere enriched in H2 and CH4 through the accretion of building blocks that contain metallic Fe and/or the gravitational trapping of surrounding nebula gas. Such an early, wet, reduced atmosphere that covers a proto-ocean would then ultimately evolve toward oxidized chemical compositions through photochemical processes that involve reactions with H2O-derived oxidant radicals and the selective escape of hydrogen to space. During this time, atmospheric CH4 could be photochemically reprocessed to generate not only C-bearing oxides but also organics. However, the branching ratio between organic matter formation and oxidation remains unknown despite its significance on the abiotic chemical evolution of early Earth. Here, we show via numerical analyses that UV absorptions by gaseous hydrocarbons such as C2H2 and C3H4 significantly suppress H2O photolysis subsequent CH4 oxidation during the photochemical evolution of a wet proto-atmosphere enriched in H2 and CH4. As a result, nearly half of the initial CH4 converted to heavier organics along with the deposition of prebiotically essential molecules such as HCN and H2CO on the surface of a primordial ocean for a geological timescale order of 10-100 Myr. Our results suggest that the accumulation of organics and prebiotically important molecules in the proto-ocean could produce a soup enriched in various organics, which might have eventually led to the emergence of living organisms., Comment: 35 pages, 12 figures

Context. Ch-type asteroids are distinctive among other dark asteroids in that they exhibit deep negative polarization branches (NPBs). Nevertheless, the physical and compositional properties that cause their polarimetric distinctiveness are less investigated. Aims. We aim to investigate the polarimetric uniqueness of Ch-type asteroids by making databases of various observational quantities (i.e., spectroscopic and photometric properties as well as polarimetric ones) of dark asteroids.Methods. We conducted an intensive polarimetric survey of 52 dark asteroids (including 31 Ch-type asteroids) in the R$_\mathrm{C}$-band to increase the size of polarimetric samples. The observed data are compiled with previous polarimetric, spectroscopic, and photometric archival data to find their correlations. Results. We find remarkable correlations between these observed quantities, particularly the depth of NPBs and their spectroscopic features associated with the hydrated minerals. The amplitude of the opposition effect in photometric properties also shows correlations with polarimetric and spectral properties. However, these observed quantities do not show noticeable correlations with the geometric albedo, thermal inertia, and diameter of asteroids. Conclusions. Based on the observational evidence, we arrive at our conclusion that the submicrometer-sized structures (fibrous or flaky puff pastry-like structures in phyllosilicates) in the regolith particles could contribute to the distinctive NPBs of hydrated asteroids., Comment: 25 pages, 10 figures (Accepted for the publication of Astronomy and Astrophysics on May 30, 2024)

Terrestrial planets currently in the habitable zones around M dwarfs likely experienced a long-term runaway greenhouse condition because of a slow decline in host-stellar luminosity in its pre-main sequence phase. Accordingly, they might have lost significant portions of their atmospheres including water vapor at high concentration by hydrodynamic escape induced by the strong stellar XUV irradiation. However, the atmospheric escape rates remain highly uncertain due partly to a lack of understanding of the effect of radiative cooling in the escape outflows. Here we carry out 1-D hydrodynamic escape simulations for an H$_{2}$-H$_{2}$O atmosphere on a planet with mass of $1M_{\oplus}$ considering radiative and chemical processes to estimate the atmospheric escape rate and follow the atmospheric evolution during the early runaway greenhouse phase. We find that the atmospheric escape rate decreases with the basal H$_{2}$O/H$_{2}$ ratio due to the energy loss by the radiative cooling of H$_{2}$O and chemical products such as OH and H$_{3}^{+}$: the escape rate of H$_{2}$ becomes one order of magnitude smaller when the basal H$_{2}$O/H$_{2}=0.1$ than that of the pure hydrogen atmosphere. The timescale for H$_{2}$ escape exceeds the duration of the early runaway greenhouse phase, depending on the initial atmospheric amount and composition, indicating that H$_{2}$ and H$_{2}$O could be left behind after the end of the runaway greenhouse phase. Our results suggest that temperate and reducing environments with oceans could be formed on some terrestrial planets around M dwarfs., Comment: 15 pages, 7 figures

The investigation of asteroids near the Sun is important for understanding the final evolutionary stage of primitive solar system objects. A near-Sun asteroid, (155140) 2005 UD, has orbital elements similar to those of (3200) Phaethon (the target asteroid for the JAXA's $DESTINY^+$ mission). We conducted photometric and polarimetric observations of 2005 UD and found that this asteroid exhibits a polarization phase curve similar to that of Phaethon over a wide range of observed solar phase angles ($ \alpha = 20 - 105^\circ $) but different from those of (101955) Bennu and (162173) Ryugu (asteroids composed of hydrated carbonaceous materials). At a low phase angle ($\alpha \lesssim 30^\circ$), the polarimetric properties of these near-Sun asteroids (2005 UD and Phaethon) are consistent with anhydrous carbonaceous chondrites, while the properties of Bennu are consistent with hydrous carbonaceous chondrites. We derived the geometric albedo, $ p_\mathrm{V} \sim 0.1 $ (in the range of 0.088-0.109); mean $ V $-band absolute magnitude, $ H_\mathrm{V} = 17.54 \pm 0.02 $; synodic rotational period, $ T_\mathrm{rot} = 5.2388 \pm 0.0022 $ hours (the two-peaked solution is assumed); and effective mean diameter, $ D_\mathrm{eff} = 1.32 \pm 0.06 $ km. At large phase angles ($ \alpha \gtrsim 80^\circ$), the polarization phase curve are likely explained by the dominance of large grains and the paucity of small micron-sized grains. We conclude that the polarimetric similarity of these near-Sun asteroids can be attributed to the intense solar heating of carbonaceous materials around their perihelia, where large anhydrous particles with small porosity could be produced by sintering., Comment: 15 pages, 9 figures, accepted for publication in Monthly Notices of Royal Astronomical Society (MNRAS)

Context. Asteroids in comet-like orbits (ACOs) consist of asteroids and dormant comets. Due to their similar appearance, it is challenging to distinguish dormant comets from ACOs via general telescopic observations. Surveys for discriminating dormant comets from the ACO population have been conducted via spectroscopy or optical and mid-infrared photometry. However, they have not been conducted through polarimetry. Aims. We conducted the first polarimetric research of ACOs. Methods. We conducted a linear polarimetric pilot survey for three ACOs: (944) Hidalgo, (3552) Don Quixote, and (331471) 1984 QY1. These objects are unambiguously classified into ACOs in terms of their orbital elements (i.e., the Tisserand parameters with respect to Jupiter $T_\mathrm{J}$ significantly less than 3). Three ACOs were observed by the 1.6 m Pirka Telescope from UT 2016 May 25 to UT 2019 July 22 (13 nights). Results. We found that Don Quixote and Hidalgo have polarimetric properties similar to comet nuclei and D-type asteroids (optical analogs of comet nuclei). However, 1984 QY1 exhibited a polarimetric property consistent with S-type asteroids. We conducted a backward orbital integration to determine the origin of 1984 QY1, and found that this object was transported from the main belt into the current comet-like orbit via the 3:1 mean motion resonance with Jupiter. Conclusions. We conclude that the origins of ACOs can be more reliably identified by adding polarimetric data to the color and spectral information. This study would be valuable for investigating how the ice-bearing small bodies distribute in the inner Solar System., Comment: 12 pages, 6 figures, accepted for publication in Astronomy and Astrophysics (A&A)

The asteroid exploration project "Hayabusa2" has successfully returned samples from the asteroid (162173) Ryugu. In this study, we measured the linear polarization degrees of Ryugu using four ground-based telescopes from 2020 September 27 to December 25, covering a wide-phase angle (Sun-target-observer's angle) range from 28$^\circ$ to 104$^\circ$. We found that the polarization degree of Ryugu reached 53$\%$ around a phase angle of 100$^\circ$, the highest value among all asteroids and comets thus far reported. The high polarization degree of Ryugu can be attributed to the scattering properties of its surface layers, in particular the relatively small contribution of multiply-scattered light. Our polarimetric results indicate that Ryugu's surface is covered with large grains. On the basis of a comparison with polarimetric measurements of pulverized meteorites, we can infer the presence of submillimeter-sized grains on the surface layer of Ryugu. We also conjecture that this size boundary represents the grains that compose the aggregate. It is likely that a very brittle structure has been lost in the recovered samples, although they may hold a record of its evolution. Our data will be invaluable for future experiments aimed at reproducing the surface structure of Ryugu., Comment: 8 pages, 3 figures, 2 tables, Accepted for publication in ApJ Letters

The existence of liquid water within an oxidized environment on early Mars has been inferred by the Mn-rich rocks found during recent explorations on Mars. The oxidized atmosphere implied by the Mn-rich rocks would basically be comprised of CO$_2$ and H$_2$O without any reduced greenhouse gases such as H$_2$ and CH$_4$. So far, however, it has been thought that early Mars could not have been warm enough to sustain water in liquid form without the presence of reduced greenhouse gases. Here, we propose that H$_2$O$_2$ could have been the gas responsible for warming the surface of the oxidized early Mars. Our one-dimensional atmospheric model shows that only 1 ppm of H$_2$O$_2$ is enough to warm the planetary surface because of its strong absorption at far-infrared wavelengths, in which the surface temperature could have reached over 273~K for a CO$_2$ atmosphere with a pressure of 3~bar. A wet and oxidized atmosphere is expected to maintain sufficient quantities of H$_2$O$_2$ gas in its upper atmosphere due to its rapid photochemical production in slow condensation conditions. Our results demonstrate that a warm and wet environment could have been maintained on an oxidized early Mars, thereby suggesting that there may be connections between its ancient atmospheric redox state and possible aqueous environment., Comment: 8 pages, 7 figures, published in ApJ

Direct-imaging techniques of exoplanets have made significant progress recently, and will eventually enable to monitor photometric and spectroscopic signals of earth-like habitable planets in the future. The presence of clouds, however, would remain as one of the most uncertain components in deciphering such direct-imaged signals of planets. We attempt to examine how the planetary obliquity produce different cloud patterns by performing a series of GCM (General Circulation Model) simulation runs using a set of parameters relevant for our Earth. Then we use the simulated photometric lightcurves to compute their frequency modulation due to the planetary spin-orbit coupling over an entire orbital period, and attempt to see to what extent one can estimate the obliquity of an Earth-twin. We find that it is possible to estimate the obliquity of an Earth-twin within the uncertainty of several degrees with a dedicated 4 m space telescope at 10 pc away from the system if the stellar flux is completely blocked. While our conclusion is based on several idealized assumptions, a frequency modulation of a directly-imaged earth-like planet offers a unique methodology to determine its obliquity., Comment: 29 pages, 18 figures, accepted for publication in ApJ

Laser altimetry is a powerful tool for addressing the major objectives of planetary physics and geodesy, and have been applied in planetary explorations of the Moon, Mars, Mercury, and the asteroids Eros, and Itokawa. The JUpiter Icy Moons Explorer (JUICE), led by European Space Agency (ESA), has started development to explore the emergence of habitable worlds around gas giants. The Ganymede Laser Altimeter (GALA) will be the first laser altimeter for icy bodies, and will measure the shape and topography of the large icy moons of Jupiter, (globally for Ganymede, and using flyby ground-tracks for Europa and Callisto). Such information is crucial for understanding the formation of surface features and can tremendously improve our understanding of the icy tectonics. In addition, the GALA will infer the presence or absence of a subsurface ocean by measuring the tidal and rotational responses. Furthermore, it also improves the accuracy of gravity field measurements reflecting the interior structure, collaborating with the radio science experiment. In addition to range measurements, the signal strength and the waveform of the laser pulses reflected from the moon's surface contain information about surface reflectance at the laser wavelength and small scale roughness. Therefore we can infer the degrees of chemical and physical alterations, e.g., erosion, space weathering, compaction and deposition of exogenous materials, through GALA measurements without being affected by illumination conditions. JUICE spacecraft carries ten science payloads including GALA. They work closely together in a synergistic way with GALA being one of the key instruments for understanding the evolution of the icy satellites Ganymede, Europa, and Callisto., Comment: 10 pages, 6 figures, accepted for publication in Trans. JSASS Aerospace Tech. Japan

We present a unique and significant polarimetric result regarding the near-Earth asteroid (152679) 1998 KU$_\mathrm{2}$ , which has a very low geometric albedo. From our observations, we find that the linear polarization degrees of 1998 KU$_\mathrm{2}$ are 44.6 $\pm$ 0.5\% in the R$_\mathrm{C}$ band and 44.0 $\pm$ 0.6\% in the V band at a solar phase angle of 81.0\degr. These values are the highest of any known airless body in the solar system (i.e., high-polarization comets, asteroids, and planetary satellites) at similar phase angles. This polarimetric observation is not only the first for primitive asteroids at large phase angles, but also for low-albedo (< 0.1) airless bodies. Based on spectroscopic similarities and polarimetric measurements of materials that have been sorted by size in previous studies, we conjecture that 1998 KU$_\mathrm{2}$ has a highly microporous regolith structure comprising nano-sized carbon grains on the surface., Comment: 9 pages, 5 figures, and 3 tables, accepted for publication in A&A

We conducted a polarimetric observation of the fast-rotating near-Earth asteroid (1566) Icarus at large phase (Sun-asteroid-observer's) angles $\alpha$= 57 deg--141deg around the 2015 summer solstice. We found that the maximum values of the linear polarization degree are $P_\mathrm{max}$=7.32$\pm$0.25 % at phase angles of $\alpha_\mathrm{max}$=124$\pm$8 deg in the $V$-band and $P_\mathrm{max}$=7.04$\pm$0.21 % at $\alpha_\mathrm{max}$=124$\pm$6 deg in the $R_\mathrm{C}$-band. Applying the polarimetric slope-albedo empirical law, we derived a geometric albedo of $p_\mathrm{V}$=0.25$\pm$0.02, which is in agreement with that of Q-type taxonomic asteroids. $\alpha_\mathrm{max}$ is unambiguously larger than that of Mercury, the Moon, and another near-Earth S-type asteroid (4179) Toutatis but consistent with laboratory samples with hundreds of microns in size. The combination of the maximum polarization degree and the geometric albedo is in accordance with terrestrial rocks with a diameter of several hundreds of micrometers. The photometric function indicates a large macroscopic roughness. We hypothesize that the unique environment (i.e., the small perihelion distance $q$=0.187 au and a short rotational period of $T_\mathrm{rot}$=2.27 hours) may be attributed to the paucity of small grains on the surface, as indicated on (3200) Phaethon., Comment: 32 pages, 6 figures, accepted for publication in AJ