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The electronic excitation spectrum of lithium atoms residing on the surface of helium nanodroplets is presented and analyzed employing a Rydberg-Ritz approach. Utilizing resonant two-photon ionization spectroscopy, two different Rydberg series have been identified: one assigned to the nS(Σ) series and the other with predominantly nP(Π) character. For high Rydberg states, which have been resolved up to n = 13, the surrounding helium effectively screens the valence electron from the Li ion core, as indicated by the apparent red-shift of Li transitions and lowered quantum defects on the droplet with respect to their free atom counterparts. For low n states, the screening effect is weakened and the prevailing repulsive interaction gives rise to strongly broadened and blue-shifted transitions. The red-shifts originate from the polarization of nearby He atoms by the positive Li ion core. As a consequence of this effect, the ionization threshold is lowered by 116 ± 10 cm -1 for Li on helium droplets with a radius of about 40 Å. Upon single-photon ionization, heavy complexes corresponding to Li ions attached to intact helium droplets are detected. We conclude that ionization close to the on-droplet ionization threshold triggers a dynamic process in which the Li ion core undergoes a transition from a surface site into the droplet.

We present a thorough theoretical and experimental study of the electronic structure of RbCa. The mixed alkali-alkaline earth molecule RbCa was formed on superfluid helium nanodroplets. Excited states of the molecule in the range of 13 000-23 000 cm -1 were recorded by resonance enhanced multi-photon ionization time-of-flight spectroscopy. The experiment is accompanied by high level ab initio calculations of ground and excited state properties, utilizing a multireference configuration interaction method based on multiconfigurational self consistent field calculations. With this approach the potential energy curves and permanent electric dipole moments of 24 electronic states were calculated. In addition we computed the transition dipole moments for transitions from the ground into excited states. The combination of experiment and theory allowed the assignment of features in the recorded spectrum to the excited [Formula: see text], [Formula: see text], [Formula: see text], [Formula: see text], [Formula: see text], [Formula: see text], [Formula: see text], and [Formula: see text] states, where the experiment allowed to benchmark the calculation. This is the first experimental work giving insight into the previously unknown RbCa molecule, which offers great prospects in ultracold molecular physics due to its magnetic and electronic dipole moment in the [Formula: see text] ground state.

Excited states and the ground state of the diatomic molecule RbSr were calculated by post Hartree-Fock molecular orbital theory up to 22 000 cm(-1). We applied a multireference configuration interaction calculation based on multiconfigurational self-consistent field wave functions. Both methods made use of effective core potentials and core polarization potentials. Potential energy curves, transition dipole moments, and permanent electric dipole moments were determined for RbSr and could be compared with other recent calculations. We found a good agreement with experimental spectra, which have been obtained recently by helium nanodroplet isolation spectroscopy. For the lowest two asymptotes (Rb (5s (2)S) + Sr (5s4d (3)P°) and Rb (5p (2)P°) + Sr (5s(2) (1)S)), which exhibit a significant spin-orbit coupling, we included relativistic effects by two approaches, one applying the Breit-Pauli Hamiltonian to the multireference configuration interaction wave functions, the other combining a spin-orbit Hamiltonian and multireference configuration interaction potential energy curves. Using the results for the relativistic potential energy curves that correspond to the Rb (5s (2)S) + Sr (5s4d (3)P°) asymptote, we have simulated dispersed fluorescence spectra as they were recently measured in our lab. The comparison with experimental data allows to benchmark both methods and demonstrate that spin-orbit coupling has to be included for the lowest states of RbSr.

We report an experimental investigation of RbSr molecules attached to helium nanodroplets. The molecules are prepared on the surface of helium droplets by utilizing a sequential pickup scheme. We provide a detailed analysis of the excitation spectrum in the wavelength range 11,600-23,000 cm(-1). The spectrum has been recorded by resonance enhanced multi-photon ionization time-of-flight spectroscopy. The inherent mass sensitivity of the method allows for an unraveling of the RbSr spectrum, which is influenced by Rb and Sr dimer contributions, because of the proximity of their respective isotopologues. In addition, the vibrationally resolved 4(2)Σ(+) band was investigated using laser induced fluorescence spectroscopy. The vibronic transitions exhibit a lambda-shaped peak form, which is characteristic of excitations on helium droplets and indicative of strong coupling of the molecule to the superfluid helium environment. Furthermore, the vibrationally resolved 4(2)Σ(+) state enables the determination of molecular parameters, which are in excellent agreement with previously measured dispersed fluorescence spectra, originating from bare RbSr molecules. The assignment of recorded transitions is based on calculated transition dipole moments and potential energy curves. The theoretical results allow for the identification of transitions from the vibronic X(2)Σ(+) ground state to the 2(2)Π, 3(2)Σ(+), 4(2)Σ(+), 3(2)Π, 4(2)Π and 6(2)Σ(+) states. The detailed investigation of RbSr on helium droplets provides a solid basis for further high resolution gas phase studies of this diatomic molecule that holds promise in the area of cold molecular physics.

We present a combined experimental and theoretical study of the RbSr molecule. The experimental approach is based on the formation of RbSr molecules on helium nanodroplets. Utilizing two-photon ionization spectroscopy, an excitation spectrum ranging from 11,600 up to 23,000 cm(-1) was recorded. High level ab initio calculations of potential energy curves and transition dipole moments accompany the experiment and facilitate an assignment of transitions. We show that RbSr molecules desorb from the helium droplets upon excitation, which enables dispersed fluorescence spectroscopy of free RbSr. These spectra elucidate X(2)Σ(+) ground and excited state properties. Emission spectra originating from states corresponding to the Rb(5s(2)S) + Sr(5s5p(3)P) asymptote were recorded; spin-orbit coupling was included for the simulation. The results should provide a good basis for achieving the formation of this molecule in cold collisions, thus offering intriguing prospects for ultracold molecular physics.

We report on the formation of mixed alkali-alkaline earth molecules (LiCa) on helium nanodroplets and present a comprehensive experimental and theoretical study of the ground and excited states of LiCa. Resonance enhanced multiphoton ionization time-of-flight (REMPI-TOF) spectroscopy and laser induced fluorescence (LIF) spectroscopy were used for the experimental investigation of LiCa from 15000 to 25500 cm(-1). The 4(2)Σ(+) and 3(2)Π states show a vibrational structure accompanied by distinct phonon wings, which allows us to determine molecular parameters as well as to study the interaction of the molecule with the helium droplet. Higher excited states (4(2)Π, 5(2)Σ(+), 5(2)Π, and 6(2)Σ(+)) are not vibrationally resolved and vibronic transitions start to overlap. The experimental spectrum is well reproduced by high-level ab initio calculations. By using a multireference configuration interaction (MRCI) approach, we calculated the 19 lowest lying potential energy curves (PECs) of the LiCa molecule. On the basis of these calculations, we could identify previously unobserved transitions. Our results demonstrate that the helium droplet isolation approach is a powerful method for the characterization of tailor-made alkali-alkaline earth molecules. In this way, important contributions can be made to the search for optimal pathways toward the creation of ultracold alkali-alkaline earth ground state molecules from the corresponding atomic species. Furthermore, a test for PECs calculated by ab initio methods is provided.

We report on the spectroscopic investigation of lithium atoms and lithium dimers in their triplet manifold on the surface of helium nanodroplets (He(N)). We present the excitation spectrum of the 3p ← 2s and 3d ← 2s two-photon transitions for single Li atoms on He(N). The atoms are excited from the 2S(Σ) ground state into Δ, Π, and Σ pseudodiatomic molecular substates. Excitation spectra are recorded by resonance enhanced multiphoton ionization time-of-flight (REMPI-TOF) mass spectroscopy, which allows an investigation of the exciplex (Li*–He(m), m = 1–3) formation process in the Li–He(N) system. Electronic states are shifted and broadened with respect to free atom states, which is explained within the pseudodiatomic model. The assignment is assisted by theoretical calculations, which are based on the Orsay–Trento density functional where the interaction between the helium droplet and the lithium atom is introduced by a pairwise additive approach. When a droplet is doped with more than one alkali atom, the fragility of the alkali–He(N) systems leads preferably to the formation of high-spin molecules on the droplets. We use this property of helium nanodroplets for the preparation of Li dimers in their triplet ground state (13Σu(+)). The excitation spectrum of the 23Πg(ν′ = 0–11) ← 13Σu(+)(ν″ = 0) transition is presented. The interaction between the molecule and the droplet manifests in a broadening of the transitions with a characteristic asymmetric form. The broadening extends to the blue side of each vibronic level, which is caused by the simultaneous excitation of the molecule and vibrations of the droplet (phonons). The two isotopes of Li form 6Li2 and 7Li2 as well as isotope mixed 6Li7Li molecules on the droplet surface. By using REMPI-TOF mass spectroscopy, isotope-dependent effects could be studied.

Rubidium atom Rydberg states perturbed by helium droplets of different sizes provide insight into the role of a nanosized dielectric on the Coulomb potential. The observation of droplet size-dependent shifts of excited states with respect to bare atom states is explained by a decreased quantum defect and a lowered ionization threshold. Within the scope of a Rydberg model, we demonstrate that quantum defects and ionization potentials are constant for each specific Rydberg series, which confirms the Rydberg character of excited Rubidium states on helium droplets. A set of six Rydberg series could be identified. Individual Rydberg states are observed with effective principal quantum numbers up to n* ≈ 19 and l ≤ 3, for which the expectation value of the electron orbital radius is about 10 times larger than the droplet radius.