864 results on '"Krebs, Carsten"'
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2. Substrate-Triggered Formation of a Peroxo-Fe2(III/III) Intermediate during Fatty Acid Decarboxylation by UndA
3. Optimized Substrate Positioning Enables Switches in the C–H Cleavage Site and Reaction Outcome in the Hydroxylation–Epoxidation Sequence Catalyzed by Hyoscyamine 6β-Hydroxylase.
4. Optimized Substrate Positioning Enables Switches in C–H Cleavage Site and Reaction Outcome in the Hydroxylation-Epoxidation Sequence Catalyzed by Hyoscyamine 6β-Hydroxylase
5. An Unusual Ferryl Intermediate and its Implications for the Mechanism of Oxacyclization by the Loline-Producing Iron(II)- and 2-Oxoglutarate-Dependent Oxygenase, LolO
6. Structural basis for tRNA methylthiolation by the radical SAM enzyme Mia
7. Drop-on-demand sample delivery for studying biocatalysts in action at X-ray free-electron lasers.
8. An Unusual Ferryl Intermediate and Its Implications for the Mechanism of Oxacyclization by the Loline-Producing Iron(II)- and 2‑Oxoglutarate-Dependent Oxygenase, LolO.
9. High-resolution iron X-ray absorption spectroscopic and computational studies of non-heme diiron peroxo intermediates
10. Steric Perturbation of the Grob-like Final Step of Ethylene-Forming Enzyme Enables 3-Hydroxypropionate and Propylene Production
11. Molecular basis for enantioselective herbicide degradation imparted by aryloxyalkanoate dioxygenases in transgenic plants
12. An iron–sulfur cluster in the zinc-binding domain of the SARS-CoV-2 helicase modulates its RNA-binding and -unwinding activities
13. Synergistic Binding of the Halide and Cationic Prime Substrate of l-Lysine 4-Chlorinase, BesD, in Both Ferrous and Ferryl States
14. Metal-free class Ie ribonucleotide reductase from pathogens initiates catalysis with a tyrosine-derived dihydroxyphenylalanine radical
15. The biosynthesis of methanobactin
16. Emerging Structural and Functional Diversity in Proteins With Dioxygen-Reactive Dinuclear Transition Metal Cofactors
17. Heme biosynthesis depends on previously unrecognized acquisition of iron-sulfur cofactors in human amino-levulinic acid dehydratase
18. Synergistic Binding of the Halide and Cationic Prime Substrate of the l-Lysine 4-Chlorinase, BesD, in Both Ferrous and Ferryl States
19. A Short Fe-Fe Distance in Peroxodiferric Ferritin: Control of Fe Substrate versus Cofactor Decay?
20. Capturing a bis-Fe(IV) State in Methylosinus trichosporium OB3b MbnH
21. What Is the Right Level of Activation of a High-Spin {FeNO}7 Complex to Enable Direct N–N Coupling? Mechanistic Insight into Flavodiiron NO Reductases
22. Auswirkungen und Anpassungsregelungen
23. Exkurs: Umsteuern im Verkehrssektor
24. Mit der Ökologischen Steuerreform jetzt beginnen
25. Weiterführende Überlegungen
26. Die Ökologische Steuerreform in Europa
27. Beispiele für die Auswirkungen einer Ökologischen Steuerreform
28. Die häufigsten Einwände gegen eine Ökologische Steuerreform
29. Einleitung
30. Ökologische Steuerreform: das Konzept
31. Literaturverzeichnis
32. Mechanism of the C5 Stereoinversion Reaction in the Biosynthesis of Carbapenem Antibiotics
33. Evidence that the Fosfomycin-Producing Epoxidase, HppE, Is a Non-Heme-Iron Peroxidase
34. Organophosphonate-degrading PhnZ reveals an emerging family of HD domain mixed-valent diiron oxygenases
35. Summary of the 5th Penn State Bioinorganic Workshop
36. Characterization of LipS1 and LipS2 from Thermococcus kodakarensis: Proteins Annotated as Biotin Synthases, which Together Catalyze Formation of the Lipoyl Cofactor
37. In Vitro Demonstration of Human Lipoyl Synthase Catalytic Activity in the Presence of NFU1
38. Use of Noncanonical Tyrosine Analogues to Probe Control of Radical Intermediates during Endoperoxide Installation by Verruculogen Synthase (FtmOx1)
39. Progress Toward Understanding Protein Control of Reaction Outcome in the Diverse Reactivity of Iron(II)‐ and 2‐Oxoglutarate‐dependent Oxygenases
40. Novel approaches for the accumulation of oxygenated intermediates to multi-millimolar concentrations
41. Synthesis and characterization of a model complex for flavodiiron NO reductases that stabilizes a diiron mononitrosyl complex
42. Synthesis of 6,6‐ and 7,7‐difluoro‐1‐acetamidopyrrolizidines and their oxidation catalyzed by the nonheme Fe oxygenase LolO
43. Substrate-Triggered μ-Peroxodiiron(III) Intermediate in the 4-Chloro-l-Lysine-Fragmenting Heme-Oxygenase-like Diiron Oxidase (HDO) BesC: Substrate Dissociation from, and C4 Targeting by, the Intermediate
44. A mixed-valent Fe(II)Fe(III) species converts cysteine to an oxazolone/thioamide pair in methanobactin biosynthesis
45. Use of Non-canonical Tyrosine Analogs to Probe Control of Radical Intermediates during Endoperoxide Installation by Verruculogen Synthase (FtmOx1)
46. A Radically Different Mechanism for S-Adenosylmethionine—Dependent Methyltransferases
47. Four-electron oxidation of p-hydroxylaminobenzoate to p-nitrobenzoate by a peroxodiferric complex in AurF from Streptomyces thioluteus
48. Substrate Positioning Controls the Partition between Halogenation and Hydroxylation in the Aliphatic Halogenase, SyrB2
49. A Catalytic Di-Heme bis-Fe(IV) Intermediate, Alternative to an Fe(IV)=O Porphyrin Radical
50. Cyanobacterial alkane biosynthesis further expands the catalytic repertoire of the ferritin-like ‘di-iron-carboxylate’ proteins
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