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Conforming materials to rigid substrates with Gaussian curvature --- positive for spheres and negative for saddles --- has proven a versatile tool to guide the self-assembly of defects such as scars, pleats, folds, blisters, and liquid crystal ripples. Here, we show how curvature can likewise be used to control material failure and guide the paths of cracks. In our experiments, and unlike in previous studies on cracked plates and shells, we constrained flat elastic sheets to adopt fixed curvature profiles. This constraint provides a geometric tool for controlling fracture behavior: curvature can stimulate or suppress the growth of cracks, and steer or arrest their propagation. A simple analytical model captures crack behavior at the onset of propagation, while a two-dimensional phase-field model with an added curvature term successfully captures the crack's path. Because the curvature-induced stresses are independent of material parameters for isotropic, brittle media, our results apply across scales., Comment: Published in Nature Materials, 22 August 2016; updated to reflect changes since submission

We present a theoretical study of the energetics of thin nematic shells with two charge one-half defects and one charge-one defect. We determine the optimal arrangement: the defects are located on a great circle at the vertices of an isosceles triangle with angles of 66 degrees at the charge one-half defects and a distinct angle of 48 degrees, consistent with experimental findings. We also analyse thermal fluctuations around this ground state and estimate the energy as a function of thickness. We find that the energy of the three-defect shell is close to the energy of other known configurations having two charge-one and four charge one-half defects. This finding, together with the large energy barriers separating one configuration from the others, explains their observation in experiments as well as their long-time stability., Comment: 8 pages, 7 figures

This review introduces the elasticity theory of two-dimensional crystals and nematic liquid crystals on curved surfaces, the energetics of topological defects (disclinations, dislocations and pleats) in these ordered phases, and the interaction of defects with the underlying curvature. This chapter concludes with two cases of three-dimensional nematic phases confined to spaces with curved boundaries, namely a torus and a spherical shell., Comment: Book chapter. 30 pages, 11 figures

We present a theoretical study of director fields in toroidal geometries with degenerate planar boundary conditions. We find spontaneous chirality: despite the achiral nature of nematics the director configuration show a handedness if the toroid is thick enough. In the chiral state the director field displays a double twist, whereas in the achiral state there is only bend deformation. The critical thickness increases as the difference between the twist and saddle-splay moduli grows. A positive saddle-splay modulus prefers alignment along the short circle of the bounding torus, and hence stimulates promotes a chiral configuration. The chiral-achiral transition mimics the order-disorder transition of the mean-field Ising model. The role of the magnetisation in the Ising model is played by the degree of twist. The role of the temperature is played by the aspect ratio of the torus. Remarkably, an external field does not break the chiral symmetry explicitly, but shifts the transition. In the case of toroidal cholesterics, we do find a preference for one chirality over the other -- the molecular chirality acts as a field in the Ising analogy., Comment: 7 pages, 6 figures, 1 table

Conforming materials to rigid substrates with Gaussian curvature-positive for spheres and negative for saddles-has proven a versatile tool to guide the self-assembly of defects such as scars, pleats, folds, blisters, and liquid crystal ripples. Here, we show how curvature can likewise be used to control material failure and guide the paths of cracks. In our experiments, and unlike in previous studies on cracked plates and shells, we constrained flat elastic sheets to adopt fixed curvature profiles. This constraint provides a geometric tool for controlling fracture behaviour: curvature can stimulate or suppress the growth of cracks and steer or arrest their propagation. A simple analytical model captures crack behaviour at the onset of propagation, while a two-dimensional phase-field model with an added curvature term successfully captures the crack's path. Because the curvature-induced stresses are independent of material parameters for isotropic, brittle media, our results apply across scales.