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Integrating sulfion‐rich wastewater purification with photo‐charging Zn‐Air batteries enables dual benefits for solar energy storage and environmental protection. However, photo‐charging efficiency is hindered by charge transfer issues. Here, the study synthesizes a CdS@CdIn2S4 core–shell photoelectrode and uses Kelvin Probe Force Microscopy (KPFM) to probe surface potential changes and photo‐charge transfer under illumination. The outer shell (CdIn2S4) exhibits upward band bending and a Conduction Band (CB) more negative than bulk CdS, leading to the accumulation of photoelectrons on the surface, which is detrimental to sulfion oxidation. Vacancy engineering aligns the Fermi energy of two materials, creating an optimal type‐II configuration that accumulates holes on the surface, thereby boosting the photo‐charging current density in Zn‐Air/Sulfion hybrid batteries by 18‐fold. A benchmark photo‐charging current density of 1.26 mA cm−2 is therefore achieved for Zn‐Air/Sulfion hybrid batteries. This work demonstrates the effectiveness of regulating charge transfer pathways in photo‐charging Zn‐Air/Sulfion hybrid batteries, showing potential applications in various photo‐assisted batteries. [ABSTRACT FROM AUTHOR]

Procapra picticaudata is an ungulate endemic to the Tibetan Plateau and is widely distributed in the Three-River-Source region. Predicting the seasonal variations in habitat suitability and understanding the effects of environmental variables on habitat use by this species will help formulate effective conservation strategies and clarify its niche characteristics. Based on point records of the occurrence collected during repeated field surveys in winter (January 2019) and summer (August 2019), we used MaxEnt model to predict the differences in habitat suitability and the distribution pattern of the P. picticaudata in the Three-River-Source region using eight preselected environmental variables. We further explored the influence of those variables on the P. picticaudata' distribution pattern using environmental response curves. The results showed that the average area under the receiving operator curve values in winter and summer was 0.901 ±0.023 and 0.882±0.024, respectively, with a good accuracy of fitness. The total area of suitable habitat for P. picticaudata in winter and summer was 6. 83 X 104 and 9. 78 X 104 km2, respectively. The area of suitable habitats in summer increased significantly compared with winter. There was a tendency for P. picticaudata to spread to the south of the Yangtze River Source Park and the Yellow River Source Park in summer. The spatial patterns of habitat suitability in both winter and summer took Three-River-Source National Park as the high-value center and decreased around it. The seasonal average temperature, altitude, population density, and slope were the main environmental variables affecting the distribution of P. picticaudata both in winter and summer. The higher temperatures in summer allowed the suitable P. picticaudata habitats to extend into areas above 5000 m in altitude, and to areas with slopes of less than 25°, compared with winter. The expansion of human activities in summer encroached on the suitable habitat of P. picticaudata. [ABSTRACT FROM AUTHOR]

Understanding the spatiotemporal distribution of multiple ecosystem services (ESs) and their complex internal relationships is crucial for regional collaborative sustainable development. The lack of research on the temporal dynamics of multiple ESs and their internal relationships limits the effective management of ecosystem services. Based on spatial patterns and temporal dynamics, we mapped the changes in five key ESs and assessed the internal relationships over 1324 counties in northern China from 2000 to 2018. The spatial differences in ES relationships were clustered into four distinct ES bundles, and we quantified the driving force of spatiotemporal pattern changes in ES bundles. Our results showed that the relationships among ESs changed with time. From 2000 to 2018, the ES bundle pattern changed mainly in the east. The relationship of some counties changed from the trade-off between provisioning and regulating ESs to synergy, while the others changed from low synergy to high synergy. The identification of impact factors of the service cluster pattern showed that the dominant force factor for improving ecosystem service synergy in northern China is the initial condition, and the contribution of human land management and economic development is approximately 11.0% in the high-level synergy bundles and greater than 20.0% in other bundles. By addressing the spatiotemporal change in ES bundles, we clearly identified the direction and strength of the ES response to ecosystem management and provided a basis for large-scale land management evaluation and effective information for future policy making in northern China and other areas with similar natural conditions. Graphical Abstract [ABSTRACT FROM AUTHOR]