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With sizable volatile envelopes but smaller radii than the solar system ice giants, sub-Neptunes have been revealed as one of the most common types of planet in the galaxy. While the spectroscopic characterization of larger sub-Neptunes (2.5-4R$_\oplus$) has revealed hydrogen-dominated atmospheres, smaller sub-Neptunes (1.6--2.5R$_\oplus$) could either host thin, rapidly evaporating hydrogen-rich atmospheres or be stable metal-rich "water worlds" with high mean molecular weight atmospheres and a fundamentally different formation and evolutionary history. Here, we present the 0.6--2.8$\mu$m JWST NIRISS/SOSS transmission spectrum of GJ 9827 d, the smallest (1.98 R$_\oplus$) warm (T$_\mathrm{eq, A_B=0.3} \sim 620$K) sub-Neptune where atmospheric absorbers have been detected to date. Our two transit observations with NIRISS/SOSS, combined with the existing HST/WFC3 spectrum, enable us to break the clouds-metallicity degeneracy. We detect water in a highly metal-enriched "steam world" atmosphere (O/H of $\sim 4$ by mass and H$_2$O found to be the background gas with a volume mixing ratio of >31%). We further show that these results are robust to stellar contamination through the transit light source effect. We do not detect escaping metastable He, which, combined with previous nondetections of escaping He and H, supports the steam atmosphere scenario. In water-rich atmospheres, hydrogen loss driven by water photolysis happens predominantly in the ionized form which eludes observational constraints. We also detect several flares in the NIRISS/SOSS light-curves with far-UV energies of the order of 10$^{30}$ erg, highlighting the active nature of the star. Further atmospheric characterization of GJ 9827 d probing carbon or sulfur species could reveal the origin of its high metal enrichment., Comment: 37 pages, 18 figures, Accepted for publication in ApJL

Kepler-51 is a $\lesssim 1\,\mathrm{Gyr}$-old Sun-like star hosting three transiting planets with radii $\approx 6$-$9\,R_\oplus$ and orbital periods $\approx 45$-$130\,\mathrm{days}$. Transit timing variations (TTVs) measured with past Kepler and Hubble Space Telescope (HST) observations have been successfully modeled by considering gravitational interactions between the three transiting planets, yielding low masses and low mean densities ($\lesssim 0.1\,\mathrm{g/cm^3}$) for all three planets. However, the transit time of the outermost transiting planet Kepler-51d recently measured by the James Webb Space Telescope (JWST) 10 years after the Kepler observations is significantly discrepant from the prediction made by the three-planet TTV model, which we confirmed with ground-based and follow-up HST observations. We show that the departure from the three-planet model is explained by including a fourth outer planet, Kepler-51e, in the TTV model. A wide range of masses ($\lesssim M_\mathrm{Jup}$) and orbital periods ($\lesssim 10\,\mathrm{yr}$) are possible for Kepler-51e. Nevertheless, all the coplanar solutions found from our brute-force search imply masses $\lesssim 10\,M_\oplus$ for the inner transiting planets. Thus their densities remain low, though with larger uncertainties than previously estimated. Unlike other possible solutions, the one in which Kepler-51e is around the $2:1$ mean motion resonance with Kepler-51d implies low orbital eccentricities ($\lesssim 0.05$) and comparable masses ($\sim 5\,M_\oplus$) for all four planets, as is seen in other compact multi-planet systems. This work demonstrates the importance of long-term follow-up of TTV systems for probing longer period planets in a system., Comment: 48 pages, 26 figures, accepted for publication in AJ

High-resolution spectroscopic characterization of young super-Jovian planets enables precise constraints on elemental and isotopic abundances of their atmospheres. As part of the ESO SupJup Survey, we present high-resolution spectral observations of two wide-orbit super-Jupiters in YSES 1 (or TYC 8998-760-1) using the upgraded VLT/CRIRES+ (R~100,000) in K-band. We carry out free atmospheric retrieval analyses to constrain chemical and isotopic abundances, temperature structures, rotation velocities, and radial velocities. We confirm the previous detection of 13CO in YSES 1 b at a higher significance of 12.6{\sigma}, but point to a higher 12CO/13CO ratio of 88+/-13 (1{\sigma} confidence interval), consistent with the primary's isotope ratio 66+/-5. We retrieve a solar-like composition in YSES 1 b with a C/O=0.57+/-0.01, indicating a formation via gravitational instability or core accretion beyond the CO iceline. Additionally, the observations lead to detections of H2O and CO in the outer planet YSES 1 c at 7.3{\sigma} and 5.7{\sigma}, respectively. We constrain the atmospheric C/O ratio of YSES 1 c to be either solar or subsolar (C/O=0.36+/-0.15), indicating the accretion of oxygen-rich solids. The two companions have distinct vsini, 5.34+/-0.14 km/s for YSES 1 b and 11.3+/-2.1 km/s for YSES 1 c, despite their similar natal environments. This may indicate different spin axis inclinations or effective magnetic braking by the long-lived circumplanetary disk around YSES 1 b. YSES 1 represents an intriguing system for comparative studies of super-Jovian companions and linking present atmospheres to formation histories., Comment: 25 pages, 11 figure, accepted for publication in AJ. The extracted CRIRES+ spectra of the YSES-1 system can be found at https://doi.org/10.5281/zenodo.13664032

TOI-1266 is a benchmark system of two temperate ($<$ 450 K) sub-Neptune-sized planets orbiting a nearby M dwarf exhibiting a rare inverted architecture with a larger interior planet. In this study, we characterize transit timing variations (TTVs) in the TOI-1266 system using high-precision ground-based follow-up and new TESS data. We confirm the presence of a third exterior non-transiting planet, TOI-1266 d (P = 32.5 d, $M_d$ = 3.68$^{+1.05}_{-1.11} M_{\oplus}$), and combine the TTVs with archival radial velocity (RV) measurements to improve our knowledge of the planetary masses and radii. We find that, consistent with previous studies, TOI-1266 b ($R_b$ = 2.52 $\pm$ 0.08 $R_{\oplus}$, $M_b$ = 4.46 $\pm$ 0.69 $M_{\oplus}$) has a low bulk density requiring the presence of a hydrogen-rich envelope, while TOI-1266 c ($R_c$ = 1.98 $\pm$ 0.10 $R_{\oplus}$, $M_c$ = 3.17 $\pm$ 0.76 $M_{\oplus}$) has a higher bulk density that can be matched by either a hydrogen-rich or water-rich envelope. Our new dynamical model reveals that this system is arranged in a rare configuration with the inner and outer planets located near the 3:1 period ratio with a non-resonant planet in between them. Our dynamical fits indicate that the inner and outer planet have significantly nonzero eccentricities ($e_b + e_d = 0.076^{+0.029}_{-0.019}$), suggesting that TOI-1266 b may have an inflated envelope due to tidal heating. Finally, we explore the corresponding implications for the formation and long-term evolution of the system, which contains two of the most favorable cool ($<$ 500 K) sub-Neptunes for atmospheric characterization with JWST., Comment: 36 pages, 19 figures, 5 tables, submitted to The Astronomical Journal

Recent mid-infrared observations with JWST/MIRI have resulted in the first direct detections of absorption features from silicate clouds in the transmission spectra of two transiting exoplanets, WASP-17 b and WASP-107 b. In this paper, we measure the mid-infrared ($5-12$ $\mu$m) dayside emission spectrum of the benchmark hot Jupiter HD 189733 b with MIRI LRS by combining data from two secondary eclipse observations. We confirm the previous detection of H$_2$O absorption at 6.5 $\mu$m from Spitzer/IRS and additionally detect H$_2$S as well as an absorption feature at 8.7 $\mu$m in both secondary eclipse observations. The excess absorption at 8.7 $\mu$m can be explained by the presence of small ($\sim$0.01 $\mu$m) grains of SiO$_2$[s] in the uppermost layers of HD 189733 b's dayside atmosphere. This is the first direct detection of silicate clouds in HD 189733 b's atmosphere, and the first detection of a distinct absorption feature from silicate clouds on the day side of any hot Jupiter. We find that models including SiO$_2$[s] are preferred by $6-7\sigma$ over clear models and those with other potential cloud species. The high altitude location of these silicate particles is best explained by formation in the hottest regions of HD 189733 b's dayside atmosphere near the substellar point. We additionally find that HD 189733 b's emission spectrum longward of 9 $\mu$m displays residual features not well captured by our current atmospheric models. When combined with other JWST observations of HD 189733 b's transmission and emission spectrum at shorter wavelengths, these observations will provide us with the most detailed picture to date of the atmospheric composition and cloud properties of this benchmark hot Jupiter., Comment: 21 pages, 7 Figures, 3 Tables, Accepted to ApJL

TOI-836 is a $\sim2-3$ Gyr K dwarf with an inner super Earth ($R=1.7\,R_\oplus$, $P=3.8\,d$) and an outer mini Neptune ($R=2.6\,R_\oplus$, $P=8.6\,d$). Recent JWST/NIRSpec 2.8--5.2 $\mu$m observations have revealed flat transmission spectra for both planets. We present Keck/NIRSPEC observations of escaping helium from this system. While planet b shows no absorption in the 1083 nm line to deep limits ($<0.2$\%), 836c shows strong (0.7\%) absorption in both visits. These results demonstrate that the inner super-Earth has lost its primordial atmosphere while the outer mini-Neptune has not. Self-consistent 1D radiative-hydrodynamic models of c using pyTPCI, an updated version of The PLUTO-CLOUDY Interface, reveal that the helium signal is highly sensitive to metallicity: its equivalent width collapses by a factor of 13 as metallicity increases from 10x to 100x solar, and by a further factor of 12 as it increases to 200x solar. The observed equivalent width is 88\% of the model prediction for 100x metallicity, suggesting that c may have an atmospheric metallicity close to 100x solar. This is similar to K2-18b and TOI-270d, the first two mini-Neptunes with detected absorption features in JWST transmission spectra. We highlight the helium triplet as a potentially powerful probe of atmospheric composition, with complementary strengths and weaknesses to atmospheric retrievals. The main strength is its extreme sensitivity to metallicity in the scientifically significant range of 10--200x solar, and the main weakness is the enormous model uncertainties in outflow suppression and confinement mechanisms, such as magnetic fields and stellar winds., Comment: Submitted to AJ

Recent Atacama Large Millimeter/submillimeter Array (ALMA) observations of protoplanetary disks in the millimeter continuum have shown a variety of radial gaps, cavities, and spiral features. These substructures may be signposts for ongoing planet formation, and therefore these systems are promising targets for direct imaging planet searches in the near-infrared. To this end, we present results from a deep imaging survey in the $L'$-band (3.8 $\mu$m) with the Keck/NIRC2 vortex coronagraph to search for young planets in 43 disks with resolved features in the millimeter continuum or evidence for gaps/central cavities from their spectral energy distributions. Although we do not detect any new point sources, using the vortex coronagraph allows for high sensitivity to faint sources at small angular separations (down to ${\sim}$0$^{\prime\prime}$.1), allowing us to place strong upper limits on the masses of potential gas giant planets. We compare our mass sensitivities to the masses of planets derived using ALMA observations, and while we are sensitive to $\sim$1 M$_{Jup}$ planets in the gaps in some of our systems, we are generally not sensitive to planets of the masses expected from the ALMA observations. In addition to placing upper limits on the masses of gas giant planets that could be interacting with the dust in the disks to form the observed millimeter substructures, we are also able to map the micron-sized dust as seen in scattered light for 8 of these systems. Our large sample of systems also allows us to investigate limits on planetary accretion rates and disk viscosities., Comment: 23 pages, 14 figures, 3 tables, accepted for publication in AJ

Asteroseismology of dwarf stars cooler than the Sun is very challenging due to the low amplitudes and rapid timescales of oscillations. Here, we present the asteroseismic detection of solar-like oscillations at 4-minute timescales ($\nu_{\mathrm{max}}\sim4300\mu$Hz) in the nearby K-dwarf $\sigma$ Draconis using extreme precision Doppler velocity observations from the Keck Planet Finder and 20-second cadence photometry from NASA's Transiting Exoplanet Survey Satellite. The star is the coolest dwarf star to date with both velocity and luminosity observations of solar-like oscillations, having amplitudes of $5.9\pm0.8\,$cm$\,\text{s}^{-1}$ and $0.8\pm0.2$ ppm, respectively. These measured values are in excellent agreement with established luminosity-velocity amplitude relations for oscillations and provide further evidence that mode amplitudes for stars with $T_{\mathrm{eff}}<\,5500\,$K diminish in scale following a $(L/M)^{1.5}$ relation. By modeling the star's oscillation frequencies from photometric data, we measure an asteroseismic age of $4.5\pm0.9\,\rm{(ran)} \pm 1.2\,\rm{(sys)}$ Gyr. The observations demonstrate the capability of next-generation spectrographs and precise space-based photometry to extend observational asteroseismology to nearby cool dwarfs, which are benchmarks for stellar astrophysics and prime targets for directly imaging planets using future space-based telescopes., Comment: Accepted for publication in The Astrophysical Journal

TOI-6255~b (GJ 4256) is an Earth-sized planet (1.079$\pm0.065$ $R_\oplus$) with an orbital period of only 5.7 hours. With the newly commissioned Keck Planet Finder (KPF) and CARMENES spectrographs, we determined the planet's mass to be 1.44$\pm$0.14 $M_{\oplus}$. The planet is just outside the Roche limit, with $P_{\rm orb}/P_{\rm Roche}$ = 1.13 $\pm0.10$. The strong tidal force likely deforms the planet into a triaxial ellipsoid with a long axis that is $\sim$10\% longer than the short axis. Assuming a reduced stellar tidal quality factor $Q_\star^\prime \approx10^7$, we predict that tidal orbital decay will cause TOI-6255 to reach the Roche limit in roughly 400 Myr. Such tidal disruptions may produce the possible signatures of planet engulfment that have been on stars with anomalously high refractory elemental abundances compared to its conatal binary companion. TOI-6255 b is also a favorable target for searching for star-planet magnetic interactions, which might cause interior melting and hasten orbital decay. TOI-6255 b is a top target (Emission Spectroscopy Metric of about 24) for phase curve observations with the James Webb Space Telescope., Comment: 18 pages, 7 figures, 5 tables, accepted to AAS Journals. The first RV mass measurement from the Keck Planet Finder

Young, self-luminous super-Jovian companions discovered by direct imaging provide a challenging test of planet formation and evolution theories. By spectroscopically characterizing the atmospheric compositions of these super-Jupiters, we can constrain their formation histories. Here we present studies of the recently discovered HIP 99770 b, a 16 MJup high-contrast companion on a 17 au orbit, using the fiber-fed high-resolution spectrograph KPIC (R~35,000) on the Keck II telescope. Our K-band observations led to detections of H2O and CO in the atmosphere of HIP 99770 b. We carried out free retrieval analyses using petitRADTRANS to measure its chemical abundances, including the metallicity and C/O ratio, projected rotation velocity (vsini), and radial velocity (RV). We found that the companion's atmosphere has C/O=0.55(-0.04/+0.06) and [M/H]=0.26(-0.23/+0.24) (1{\sigma} confidence intervals), values consistent with those of the Sun and with a companion formation via gravitational instability or core accretion. The projected rotation velocity < 7.8 km/s is small relative to other directly imaged companions with similar masses and ages. This may imply a near pole-on orientation or effective magnetic braking by a circumplanetary disk. In addition, we added the companion-to-primary relative RV measurement to the orbital fitting and obtained updated constraints on orbital parameters. Detailed characterization of super-Jovian companions within 20 au like HIP 99770 b is critical for understanding the formation histories of this population., Comment: 18 pages, 5 figures, accepted to AJ

We report the discovery and characterization of a small planet, TOI-1408 c, on a 2.2-day orbit located interior to a previously known hot Jupiter, TOI-1408 b ($P=4.42$ d, $M=1.86\pm0.02\,M_\mathrm{Jup}$, $R=2.4\pm0.5\,R_\mathrm{Jup}$) that exhibits grazing transits. The two planets are near 2:1 period commensurability, resulting in significant transit timing variations (TTVs) for both planets and transit duration variations (TDVs) for the inner planet. The TTV amplitude for TOI-1408 c is 15% of the planet's orbital period, marking the largest TTV amplitude relative to the orbital period measured to date. Photodynamical modeling of ground-based radial velocity (RV) observations and transit light curves obtained with the Transiting Exoplanet Survey Satellite (TESS) and ground-based facilities leads to an inner planet radius of $2.22\pm0.06\,R_\oplus$ and mass of $7.6\pm0.2\,M_\oplus$ that locates the planet into the Sub-Neptune regime. The proximity to the 2:1 period commensurability leads to the libration of the resonant argument of the inner planet. The RV measurements support the existence of a third body with an orbital period of several thousand days. This discovery places the system among the rare systems featuring a hot Jupiter accompanied by an inner low-mass planet., Comment: Accepted to ApJL, 17 pages, 6 figures, 4 tables

As the closest transiting hot Jupiter to Earth, HD 189733b has been the benchmark planet for atmospheric characterization. It has also been the anchor point for much of our theoretical understanding of exoplanet atmospheres from composition, chemistry, aerosols to atmospheric dynamics, escape, and modeling techniques. Prior studies of HD 189733b have detected carbon and oxygen-bearing molecules H2O and CO in the atmosphere. The presence of CO2 and CH4 has been claimed but later disputed. The inferred metallicity based on these measurements, a key parameter in tracing planet formation locations, varies from depletion to enhancement, hindered by limited wavelength coverage and precision of the observations. Here we report detections of H2O (13.4 sigma), CO2 (11.2 sigma), CO (5 sigma), and H2S (4.5 sigma) in the transmission spectrum (2.4-5 micron) of HD 189733b. With an equilibrium temperature of ~1200K, H2O, CO, and H2S are the main reservoirs for oxygen, carbon, and sulfur. Based on the measured abundances of these three major volatile elements, we infer an atmospheric metallicity of 3-5 times stellar. The upper limit on the methane abundance at 5 sigma is 0.1 ppm which indicates a low carbon-to-oxygen ratio (<0.2), suggesting formation through the accretion of water-rich icy planetesimals. The low oxygen-to-sulfur and carbon-to-sulfur ratios also support the planetesimal accretion formation pathway., Comment: Published online in Nature on July 8th, 2024

Aeronomy, the study of Earth's upper atmosphere and its interaction with the local space environment, has long traced changes in the thermospheres of Earth and other solar system planets to solar variability in the X-ray and extreme ultraviolet (collectively, "XUV") bands. Extending comparative aeronomy to the short-period extrasolar planets may illuminate whether stellar XUV irradiation powers atmospheric outflows that change planetary radii on astronomical timescales. In recent years, near-infrared transit spectroscopy of metastable HeI has been a prolific tracer of high-altitude planetary gas. We present a case study of exoplanet aeronomy using metastable HeI transit observations from Palomar/WIRC and follow-up high-energy data from the Neil Gehrels Swift Observatory that were taken within one month of the WASP-69 system, a K-type main sequence star with a well-studied hot Jupiter companion. Supplemented by archival data, we find that WASP-69's X-ray flux in 2023 was less than 50% of what was recorded in 2016 and that the metastable HeI absorption from WASP-69b was lower in 2023 versus past epochs from 2017-2019. Via atmospheric modeling, we show that this time-variable metastable HeI signal is in the expected direction given the observed change in stellar XUV, possibly stemming from WASP-69's magnetic activity cycle. Our results underscore the ability of multi-epoch, multi-wavelength observations to paint a cohesive picture of the interaction between an exoplanet's atmosphere and its host star., Comment: 25 pages, 15 figures, 6 tables, accepted to The Astronomical Journal

Using Keck Planet Imager and Characterizer (KPIC) high-resolution ($R$~35000) spectroscopy from 2.29-2.49 $\mu$m, we present uniform atmospheric retrievals for eight young substellar companions with masses of ~10-30 $M_\textrm{Jup}$, orbital separations spanning ~50-360 au, and $T_\textrm{eff}$ between ~1500-2600 K. We find that all companions have solar C/O ratios, and metallicities, to within the 1-2$\sigma$ level, with the measurements clustered around solar composition. Stars in the same stellar associations as our systems have near-solar abundances, so these results indicate that this population of companions is consistent with formation via direct gravitational collapse. Alternatively, core accretion outside the CO snowline would be compatible with our measurements, though the high mass ratios of most systems would require rapid core assembly and gas accretion in massive disks. On a population level, our findings can be contrasted with abundance measurements for directly imaged planets with m<10 $M_\textrm{Jup}$, which show tentative atmospheric metal enrichment. In addition, the atmospheric compositions of our sample of companions are distinct from those of hot Jupiters, which most likely form via core accretion. For two companions with $T_\textrm{eff}$~1700-2000 K (kap And b and GSC 6214-210 b), our best-fit models prefer a non-gray cloud model with >3$\sigma$ significance. The cloudy models yield 2-3$\sigma$ lower $T_\textrm{eff}$ for these companions, though the C/O and [C/H] still agree between cloudy and clear models at the $1\sigma$ level. Finally, we constrain 12CO/13CO for three companions with the highest S/N data (GQ Lup b, HIP 79098 b, and DH Tau b), and report $v$sin($i$) and radial velocities for all companions., Comment: Accepted to ApJ, 52 pages, 20 figures

Characterizing rocky exoplanets is a central endeavor of astronomy, and yet the search for atmospheres on rocky exoplanets has hitherto resulted in either tight upper limits on the atmospheric mass or inconclusive results. The 1.95-REarth and 8.8-MEarth planet 55 Cnc e, with a predominantly rocky composition and an equilibrium temperature of ~2000 K, may have a volatile envelope (containing molecules made from a combination of C, H, O, N, S, and P elements) that accounts for up to a few percent of its radius. The planet has been observed extensively with transmission spectroscopy, and its thermal emission has been measured in broad photometric bands. These observations disfavor a primordial H2/He-dominated atmosphere but cannot conclusively determine whether the planet has a secondary atmosphere. Here we report a thermal emission spectrum of the planet obtained by JWST's NIRCam and MIRI instruments from 4 to 12 {\mu}m. The measurements rule out the scenario where the planet is a lava world shrouded by a tenuous atmosphere made of vaporized rock, and indicate a bona fide volatile atmosphere likely rich in CO2 or CO. This atmosphere can be outgassed from and sustained by a magma ocean., Comment: Published online in Nature on May 8, 2024. https://www.nature.com/articles/s41586-024-07432-x. Authors' preprint

The field of exoplanet atmospheric characterization has recently made considerable advances with the advent of high-resolution spectroscopy from large ground-based telescopes and the commissioning of the James Webb Space Telescope (JWST). We have entered an era in which atmospheric compositions, aerosol properties, thermal structures, mass loss, and three-dimensional effects can be reliably constrained. While the challenges of remote sensing techniques imply that individual exoplanet atmospheres will likely never be characterized to the degree of detail that is possible for solar system bodies, exoplanets present an exciting opportunity to characterize a diverse array of worlds with properties that are not represented in our solar system. This review article summarizes the current state of exoplanet atmospheric studies for transiting planets. We focus on how observational results inform our understanding of exoplanet properties and ultimately address broad questions about planetary formation, evolution, and diversity. This review is meant to provide an overview of the exoplanet atmospheres field for planetary- and geo-scientists without astronomy backgrounds, and exoplanet specialists, alike. We give special attention to the first year of JWST data and recent results in high-resolution spectroscopy that have not been summarized by previous review articles., Comment: Chapter 12 accepted for publication in the Reviews in Mineralogy and Geochemistry (RiMG) Volume 90 on "Exoplanets: Compositions, Mineralogy, and Evolution" edited by Natalie Hinkel, Keith Putirka, and Siyi Xu; 62 pages, 15 figures, and 5 equations

The lack of close-in Neptune-mass exoplanets evident in transit surveys has largely been attributed either to photoevaporative mass loss or high-eccentricity migration. To distinguish between these two possibilities, we investigate the origins of TOI-1259 A b, a Saturn-mass (0.4 M$_J$, 1.0 R$_J$) exoplanet lying along the upper edge of the Neptune desert. TOI-1259 A b's close-in ($P$ = 3.48 days) orbit and low bulk density make the planet particularly vulnerable to photoevaporation. Using transits observed in the 1083 nm metastable helium line, we probe the upper atmosphere of TOI-1259 A b with the Hale Telescope at Palomar Observatory and the Near-Infrared Spectrograph on Keck II. We report an excess absorption of $0.395\pm{0.072}\%$ with Palomar and a blueshifted absorption of $2.4\pm0.52\%$ with Keck, consistent with an extended escaping atmosphere. Fitting this signal with a Parker wind model, we determine a corresponding atmospheric mass loss rate of log($\dot{M}$) = $10.33\pm 0.13$ g/s for a thermosphere temperature of $8400^{+1200}_{-1000}$ K based on the Palomar absorption and log($\dot{M}$) = $10.0\pm 0.1$ g/s for a thermosphere temperature of $8200^{+1000}_{-900}$ K based on the Keck absorption. This relatively low rate suggests that this planet would not have been significantly altered by mass loss even if it formed in-situ. However, the presence of a white dwarf companion, TOI-1259 B, hints that this planet may not have formed close-in, but rather migrated inward relatively late. Given the estimated parameters of the proto-white dwarf companion, we find that high-eccentricity migration is possible for the system., Comment: Submitted to the Astronomical Journal (13 pages, 6 figures)

Super-puffs are planets with exceptionally low densities ($\rho \lesssim 0.1$~g~cm$^{-3}$) and core masses ($M_c \lesssim 5 M_\oplus$). Many lower-mass ($M_p\lesssim10M_\oplus$) super-puffs are expected to be unstable to catastrophic mass loss via photoevaporation and/or boil-off, whereas the larger gravitational potentials of higher-mass ($M_p\gtrsim10M_\oplus$) super-puffs should make them more stable to these processes. We test this expectation by studying atmospheric loss in the warm, higher-mass super-puff TOI-1420b ($M = 25.1M_\oplus$, $R = 11.9R_\oplus$, $\rho = 0.08$~g~cm$^{-3}$, $T_\mathrm{eq} = 960$~K). We observed one full transit and one partial transit of this planet using the metastable helium filter on Palomar/WIRC and found that the helium transits were $0.671\pm0.079\%$ (8.5$\sigma$) deeper than the TESS transits, indicating an outflowing atmosphere. We modeled the excess helium absorption using a self-consistent 1D hydrodynamics code to constrain the thermal structure of the outflow given different assumptions for the stellar XUV spectrum. These calculations then informed a 3D simulation which provided a good match to the observations with a modest planetary mass-loss rate of $10^{10.82}$~g~s$^{-1}$ ($M_p/\dot{M}\approx70$~Gyr). Super-puffs with $M_p\gtrsim10M_\oplus$, like TOI-1420b and WASP-107b, appear perfectly capable of retaining atmospheres over long timescales; therefore, these planets may have formed with the unusually large envelope mass fractions they appear to possess today. Alternatively, tidal circularization could have plausibly heated and inflated these planets, which would bring their envelope mass fractions into better agreement with expectations from core-nucleated accretion., Comment: 18 pages, 8 figures, accepted to AJ

Even though sub-Neptunes likely represent the most common outcome of planet formation, their natures remain poorly understood. In particular, planets near 1.5-2.5$\,R_\oplus$ often have bulk densities that can be explained equally well with widely different compositions and interior structures, resulting in grossly divergent implications for their formation. Here, we present the full 0.6-5.2$\,\mu \mathrm{m}$ JWST NIRISS/SOSS+NIRSpec/G395H transmission spectrum of the 2.2$\,R_\oplus$ TOI-270d ($4.78\,M_\oplus$, $T_\mathrm{eq}$=350-380 K), delivering unprecedented sensitivity for atmospheric characterization in the sub-Neptune regime. We detect five vibrational bands of CH$_4$ at 1.15, 1.4, 1.7, 2.3, and 3.3$\,\mu$m (9.4$\sigma$), the signature of CO$_2$ at 4.3$\,\mu$m (4.8$\sigma$), water vapor (2.5$\sigma$), and potential signatures of SO$_2$ at 4.0$\,\mu \mathrm{m}$ and CS$_2$ at 4.6$\,\mu\mathrm{m}$. Intriguingly, we find an overall highly metal-rich atmosphere, with a mean molecular weight of $5.47_{-1.14}^{+1.25}$. We infer an atmospheric metal mass fraction of $58_{-12}^{+8}\%$ and a C/O of $0.47_{-0.19}^{+0.16}$, indicating that approximately half the mass of the outer envelope is in high-molecular-weight volatiles (H$_2$O, CH$_4$, CO, CO$_2$) rather than H$_2$/He. We introduce a sub-Neptune classification scheme and identify TOI-270d as a "miscible-envelope sub-Neptune" in which H$_2$/He is well-mixed with the high-molecular-weight volatiles in a miscible supercritical metal-rich envelope. For a fully miscible envelope, we conclude that TOI-270d's interior is $90_{-4}^{+3}\,$wt$\,\%$ rock/iron, indicating that it formed as a rocky planet that accreted a few wt % of H$_2$/He, with the overall envelope metal content explained by magma-ocean/envelope reactions without the need for significant ice accretion. TOI-270d may well be an archetype of the overall population of sub-Neptunes., Comment: 25 pages, 12 figures

Previous attempts have been made to characterize the atmospheres of directly imaged planets at low-resolution (R$\sim$10s-100s), but the presence of clouds has often led to degeneracies in the retrieved atmospheric abundances with cloud opacity and temperature structure that bias retrieved compositions. In this study, we perform retrievals on the ultra-young ($\lesssim$ 5 Myr) directly imaged planet ROXs 42B b with both a downsampled low-resolution $JHK$-band spectrum from Gemini/NIFS and Keck/OSIRIS, and a high-resolution $K$-band spectrum from pre-upgrade Keck/NIRSPAO. Using the atmospheric retrieval framework of petitRADTRANS, we analyze both data sets individually and combined. We additionally fit for the stellar abundances and other physical properties of the host stars, a young M spectral type binary, using the SPHINX model grid. We find that the measured C/O, $0.50\pm0.05$, and metallicity, [Fe/H] = $-0.67\pm0.35$, for ROXs 42B b from our high-resolution spectrum agree with that of its host stars within 1$\sigma$. The retrieved parameters from the high-resolution spectrum are also independent of our choice of cloud model. In contrast, the retrieved parameters from the low-resolution spectrum show strong degeneracies between the clouds and the retrieved metallicity and temperature structure. When we retrieve on both data sets together, we find that these degeneracies are reduced but not eliminated, and the final results remain highly sensitive to cloud modeling choices. We conclude that high-resolution spectroscopy offers the most promising path for reliably determining atmospheric compositions of directly imaged companions independent of their cloud properties., Comment: Accepted to the Astronomical Journal, 25 pages, 12 figures, 3 tables

We present the mid-infrared (5-12 $\mu$m) phase curve of GJ 367b observed by the Mid-Infrared Instrument (MIRI) on the James Webb Space Telescope (JWST). GJ 367b is a hot (T_eq=1370 K), extremely dense (10.2 +- 1.3 g/cm^3) sub-Earth orbiting a M dwarf on a 0.32 d orbit. We measure an eclipse depth of 79 +- 4 ppm, a nightside planet-to-star flux ratio of 4 +- 8 ppm, and a relative phase amplitude of 0.97 +- 0.10 -- all fully consistent with a zero-albedo planet with no heat recirculation. Su ch a scenario is also consistent with the phase offset of 11 +- 5 degrees East to within 2.2$\sigma$. The emission spectrum is likewise consistent with a blackbody with no heat redistribution and a low albedo of A_B ~ 0.1, with the exception of one anomalous wavelength bin that we attribute to unexplained systematics. The emission spectrum puts few constraints on the surface composition, but rules out a CO2 atmosphere >~ 1 bar, an outgassed atmosphere >~10 mbar (under heavily reducing conditions), or an outgassed atmosphere >~0.01 mbar (under heavily oxidizing conditions). The lack of day-night heat recirculation implies that 1 bar atmospheres are ruled out for a wide range of compositions, while 0.1 bar atmospheres are consistent with the data. Taken together with the fact that most of the dayside should be molten, our JWST observations suggest the planet must have lost the vast majority of its initial inventory of volatiles., Comment: Published by ApJL

M dwarfs are common host stars to exoplanets but often lack atmospheric abundance measurements. Late-M dwarfs are also good analogs to the youngest substellar companions, which share similar $T_{\rm eff}\sim2300-2800~K$. We present atmospheric analyses for the M7.5 companion HIP 55507 B and its K6V primary star with Keck/KPIC high-resolution ($R\sim35,000$) $K$ band spectroscopy. First, by including KPIC relative radial velocities between the primary and secondary in the orbit fit, we improve the dynamical mass precision by 60% and find $M_B=88.0_{-3.2}^{+3.4}$ $M_{\rm Jup}$, putting HIP 55507 B above the stellar-substellar boundary. We also find that HIP 55507 B orbits its K6V primary star with $a=38^{+4}_{-3}$ AU and $e=0.40\pm0.04$. From atmospheric retrievals of HIP 55507 B, we measure $\rm [C/H]=0.24\pm0.13$, $\rm [O/H]=0.15\pm0.13$, and $\rm C/O=0.67\pm0.04$. Moreover, we strongly detect $\rm ^{13}CO$ ($7.8\sigma$ significance) and tentatively detect $\rm H_2^{18}O$ ($3.7\sigma$ significance) in companion's atmosphere, and measure $\rm ^{12}CO/^{13}CO=98_{-22}^{+28}$ and $\rm H_2^{16}O/H_2^{18}O=240_{-80}^{+145}$ after accounting for systematic errors. From a simplified retrieval analysis of HIP 55507 A, we measure $\rm ^{12}CO/^{13}CO=79_{-16}^{+21}$ and $\rm C^{16}O/C^{18}O=288_{-70}^{+125}$ for the primary star. These results demonstrate that HIP 55507 A and B have consistent $\rm ^{12} C/^{13}C$ and $\rm ^{16}O/^{18}O$ to the $<1\sigma$ level, as expected for a chemically homogeneous binary system. Given the similar flux ratios and separations between HIP 55507 AB and systems with young, substellar companions, our results open the door to systematically measuring $\rm ^{13}CO$ and $\rm H_2^{18}O$ abundances in the atmospheres of substellar or even planetary-mass companions with similar spectral types., Comment: Accepted to ApJ, 28 pages, 14 figures

Is the population of close-in planets orbiting M dwarfs sculpted by thermally driven escape or is it a direct outcome of the planet formation process? A number of recent empirical results strongly suggest the latter. However, the unique architecture of the TOI-1266 system presents a challenge to models of planet formation and atmospheric escape given its seemingly "inverted" architecture of a large sub-Neptune ($P_b=10.9$ days, $R_{p,b}=2.62\pm 0.11\, \mathrm{R}_{\oplus}$) orbiting interior to that of the system's smaller planet ($P_c=18.8$ days, $R_{p,c}=2.13\pm 0.12\, \mathrm{R}_{\oplus}$). Here we present revised planetary radii based on new TESS and diffuser-assisted ground-based transit observations, and characterize both planetary masses using a set of 145 radial velocity measurements from HARPS-N ($M_{p,b}=4.23\pm 0.69\, \mathrm{M}_{\oplus}, M_{p,c}=2.88\pm 0.80\, \mathrm{M}_{\oplus}$). Our analysis also reveals a third planet candidate ($P_d=32.3$ days, $M_{p,d}\sin{i} = 4.59^{+0.96}_{-0.94}\, \mathrm{M}_{\oplus}$), which if real, would form a chain of near 5:3 period ratios, although the system is likely not in a mean motion resonance. Our results indicate that TOI-1266 b and c are among the lowest density sub-Neptunes around M dwarfs and likely exhibit distinct bulk compositions of a gas-enveloped terrestrial ($X_{\mathrm{env},b}=5.5\pm 0.7$%) and a water-rich world (WMF$_c=59\pm 14$%), which is supported by hydrodynamic escape models. If distinct bulk compositions are confirmed through atmospheric characterization, the system's unique architecture would represent an interesting test case of inside-out sub-Neptune formation at pebble traps., Comment: Accepted for publication in MNRAS. 21 pages. Our spectroscopic time series are included in the arXiv source files as table6.csv

We compare systems with single giant planets to systems with multiple giant planets using a catalog of planets from a high-precision radial velocity survey of FGKM stars. Our comparison focuses on orbital properties, planet masses, and host star properties. We use hierarchical methods to model the orbital eccentricity distributions of giant singles and giant multis, and find that the distributions are distinct. The multiple giant planets typically have moderate eccentricities and their eccentricity distribution extends to $e=0.47$ (90th percentile), while the single giant planets have a pile-up of nearly circular orbits and a long tail that extends to $e=0.77$. We determine that stellar hosts of multiple giants are distinctly more metal-rich than hosts of solitary giants, with respective mean metallicities $0.228\pm0.027$ vs. $0.129\pm0.019$ dex. We measure the distinct occurrence distributions of single and multiple giants with respect to orbital separation, and find that single gas giants have a $\sim$2.3$\sigma$ significant hot ($a<0.06$) Jupiter pile-up not seen among multi giant systems. We find that the median mass ($\msini$ ) of giants in multiples is nearly double that of single giants (1.71 $\mjup$ vs. 0.92 $\mjup$ ). We find that giant planets in the same system have correlated masses, analogous to the `peas in a pod' effect seen among less massive planets.

Over the last decade, precise exoplanet transmission spectroscopy has revealed the atmospheres of dozens of exoplanets, driven largely by observatories like the Hubble Space Telescope. One major discovery has been the ubiquity of atmospheric aerosols, often blocking access to exoplanet chemical inventories. Tentative trends have been identified, showing that the clarity of planetary atmospheres may depend on equilibrium temperature. Previous work has often grouped dissimilar planets together in order to increase the statistical power of any trends, but it remains unclear from observed transmission spectra whether these planets exhibit the same atmospheric physics and chemistry. We present a re-analysis of a smaller, more physically similar sample of 15 exo-Neptune transmission spectra across a wide range of temperatures (200-1000 K). Using condensation cloud and hydrocarbon haze models, we find that the exo-Neptune population is best described by low cloud sedimentation efficiency ($\mathrm{f_{sed}}\sim0.1$) and high metallicity ($100\times$ Solar). There is an intrinsic scatter of $\sim0.5$ scale height, perhaps evidence of stochasticity in these planets' formation processes. Observers should expect significant attenuation in transmission spectra of Neptune-size exoplanets, up to 6 scale heights for equilibrium temperatures between 500 and 800 K. With JWST's greater wavelength sensitivity, colder (<500 K) planets should be high-priority targets given their clearer atmospheres, and the need to distinguish between the "super-puffs" and more typical gas-dominated planets., Comment: Published in ApJL. 11 pages, 3 figures, 4 tables

HISPEC is a new, high-resolution near-infrared spectrograph being designed for the W.M. Keck II telescope. By offering single-shot, R=100,000 between 0.98 - 2.5 um, HISPEC will enable spectroscopy of transiting and non-transiting exoplanets in close orbits, direct high-contrast detection and spectroscopy of spatially separated substellar companions, and exoplanet dynamical mass and orbit measurements using precision radial velocity monitoring calibrated with a suite of state-of-the-art absolute and relative wavelength references. MODHIS is the counterpart to HISPEC for the Thirty Meter Telescope and is being developed in parallel with similar scientific goals. In this proceeding, we provide a brief overview of the current design of both instruments, and the requirements for the two spectrographs as guided by the scientific goals for each. We then outline the current science case for HISPEC and MODHIS, with focuses on the science enabled for exoplanet discovery and characterization. We also provide updated sensitivity curves for both instruments, in terms of both signal-to-noise ratio and predicted radial velocity precision., Comment: 25 pages, 9 figures. To appear in the Proceedings of SPIE: Techniques and Instrumentation for Detection of Exoplanets XI, vol. 12680 (2023)

We announce the detection of escaping helium from TOI 2134b, a mini-Neptune a few Gyr old. The average in-transit absorption spectrum shows a peak of 0.37 +- 0.05% and an equivalent width of $W_{\rm avg}=3.3 \pm 0.3$ m$\r{A}$. Among all planets with helium detections, TOI 2134b is the only mature mini-Neptune, has the smallest helium signal, and experiences the lowest XUV flux. Putting TOI 2134b in the context of all other helium detections, we report the detection of a strong (p=3.0e-5) and theoretically expected correlation between $F_{\rm XUV}/\rho_{\rm XUV}$ (proportional to the energy-limited mass loss rate) and $R_* W_{\rm avg}$ (roughly proportional to the observationally inferred mass loss rate). Here, $W_{\rm avg}$ is the equivalent width of the helium absorption and $\rho_{\rm XUV}$ is the density of the planet within the XUV photosphere, but the correlation is similarly strong if we use the optical photosphere. TOI 2134b anchors the relation, having the lowest value on both axes. We encourage further observations to fill in missing regions of this parameter space and improve estimates of $F_{\rm XUV}$., Comment: Accepted by ApJL

Photoevaporative mass-loss rates are expected to be highest when planets are young and the host star is more active, but to date there have been relatively few measurements of mass-loss rates for young gas giant exoplanets. In this study we measure the present-day atmospheric mass-loss rate of TOI-1268b, a young (110 - 380 Myr) and low density (0.71$^{+0.17}_{-0.13}$~g~cm$^{-3}$) hot Saturn located near the upper edge of the Neptune desert. We use Palomar/WIRC to search for excess absorption in the 1083~nm helium triplet during two transits of TOI-1268b. We find that it has a larger transit depth ($0.285_{-0.050}^{+0.048}\%$ excess) in the helium bandpass than in the TESS observations, and convert this excess absorption into a mass-loss rate by modeling the outflow as a Parker wind. Our results indicate that this planet is losing mass at a rate of $\log \dot{M} = 10.2 \pm 0.3$~g~s$^{-1}$ and has a thermosphere temperature of 6900$^{+1800}_{-1200}$~K. This corresponds to a predicted atmospheric lifetime much larger than 10 Gyr. Our result suggests that photoevaporation is weak in gas giant exoplanets even at early ages., Comment: Published at The Astronomical Journal (9 pages, 4 figures)

Extremely low-density exoplanets are tantalizing targets for atmospheric characterization because of their promisingly large signals in transmission spectroscopy. We present the first analysis of the atmosphere of the lowest-density gas giant currently known, HAT-P-67 b. This inflated Saturn-mass exoplanet sits at the boundary between hot and ultrahot gas giants, where thermal dissociation of molecules begins to dominate atmospheric composition. We observed a transit of HAT-P-67 b at high spectral resolution with CARMENES and searched for atomic and molecular species using cross-correlation and likelihood mapping. Furthermore, we explored potential atmospheric escape by targeting H$\alpha$ and the metastable helium line. We detect Ca II and Na I with significances of 13.2$\sigma$ and 4.6$\sigma$, respectively. Unlike in several ultrahot Jupiters, we do not measure a day-to-night wind. The large line depths of Ca II suggest that the upper atmosphere may be more ionized than models predict. We detect strong variability in H$\alpha$ and the helium triplet during the observations. These signals suggest the possible presence of an extended planetary outflow that causes an early ingress and late egress. In the averaged transmission spectrum, we measure redshifted absorption at the $\sim 3.8\%$ and $\sim 4.5\%$ level in the H$\alpha$ and He I triplet lines, respectively. From an isothermal Parker wind model, we derive a mass loss rate of $\dot{M} \sim 10^{13}~\rm{g/s}$ and an outflow temperature of $T \sim 9900~\rm{K}$. However, due to the lack of a longer out-of-transit baseline in our data, additional observations are needed to rule out stellar variability as the source of the H$\alpha$ and He signals., Comment: The Astronomical Journal, in press. 17 pages, 9 figures

Mass, radius, and age measurements of young (<100 Myr) planets have the power to shape our understanding of planet formation. However, young stars tend to be extremely variable in both photometry and radial velocity, which makes constraining these properties challenging. The V1298 Tau system of four ~0.5 Rjup planets transiting a pre-main sequence star presents an important, if stress-inducing, opportunity to directly observe and measure the properties of infant planets. Su\'arez-Mascare\~no et al. (2021) published radial-velocity-derived masses for two of the V1298 Tau planets using a state-of-the-art Gaussian Process regression framework. The planetary densities computed from these masses were surprisingly high, implying extremely rapid contraction after formation in tension with most existing planet formation theories. In an effort to further constrain the masses of the V1298 Tau planets, we obtained 36 RVs using Keck/HIRES, and analyzed them in concert with published RVs and photometry. Through performing a suite of cross validation tests, we found evidence that the preferred model of SM21 suffers from overfitting, defined as the inability to predict unseen data, rendering the masses unreliable. We detail several potential causes of this overfitting, many of which may be important for other RV analyses of other active stars, and recommend that additional time and resources be allocated to understanding and mitigating activity in active young stars such as V1298 Tau., Comment: 26 pages, 12 figures; published in AJ

We study the emergent spectral fluxes of transiting hot Jupiters, using secondary eclipses from Spitzer. To achieve a large and uniform sample, we have re-analyzed all secondary eclipses for all hot Jupiters observed by Spitzer at 3.6- and/or 4.5 microns. Our sample comprises 457 eclipses of 122 planets, including eclipses of 13 planets not previously published. We use these eclipse depths to calculate the spectral fluxes emergent from the exoplanetary atmospheres, and thereby infer temperature and spectral properties of hot Jupiters. We find that an abrupt rise in brightness temperature, similar to a phase change, occurs on the day side atmospheres of the population at an equilibrium temperature between 1714K and 1818K (99-percent confidence limits). The amplitude of the rise is 291 +/-49 Kelvins, and two viable causes are the onset of magnetic drag that inhibits longitudinal heat redistribution, and/or the rapid dissipation of day side clouds. We also study hot Jupiter spectral properties with respect to metallicity and temperature inversions. Models exhibiting 4.5 micron emission from temperature inversions reproduce our fluxes statistically for the hottest planets, but the transition to emission is gradual, not abrupt. The Spitzer fluxes are sensitive to metallicity for planets cooler than approximately 1200 Kelvins, and most of the hot Jupiter population falls between model tracks having solar to 30X-solar metallicity., Comment: 29 pages, 12 figures, 4 tables (3 are MR), accepted for the Astronomical Journal

We present evidence of tidally-driven inspiral in the Kepler-1658 (KOI-4) system, which consists of a giant planet (1.1$R_\mathrm{J}$, 5.9$M_\mathrm{J}$) orbiting an evolved host star (2.9$R_\odot$, 1.5$M_\odot$). Using transit timing measurements from Kepler, Palomar/WIRC, and TESS, we show that the orbital period of Kepler-1658b appears to be decreasing at a rate $\dot{P} = 131_{-22}^{+20}$~ms~yr$^{-1}$, corresponding to an infall timescale $P/\dot{P}\approx2.5$~Myr. We consider other explanations for the data including line-of-sight acceleration and orbital precession, but find them to be implausible. The observed period derivative implies a tidal quality factor $Q_\star' = 2.50_{-0.62}^{+0.85}\times10^4$, in good agreement with theoretical predictions for inertial wave dissipation in subgiant stars. Additionally, while it probably cannot explain the entire inspiral rate, a small amount of planetary dissipation could naturally explain the deep optical eclipse observed for the planet via enhanced thermal emission. As the first evolved system with detected inspiral, Kepler-1658 is a new benchmark for understanding tidal physics at the end of the planetary life cycle., Comment: 9 pages, 3 figures, 2 tables, published in Astrophysical Journal Letters

The population of planets smaller than approximately $1.7~R_\oplus$ is widely interpreted as consisting of rocky worlds, generally referred to as super-Earths. This picture is largely corroborated by radial-velocity (RV) mass measurements for close-in super-Earths but lacks constraints at lower insolations. Here we present the results of a detailed study of the Kepler-138 system using 13 Hubble and Spitzer transit observations of the warm-temperate $1.51\pm0.04~R_\oplus$ planet Kepler-138 d ($T_{\mathrm{eq, A_B=0.3}}$~350 K) combined with new Keck/HIRES RV measurements of its host star. We find evidence for a volatile-rich "water world" nature of Kepler-138 d, with a large fraction of its mass contained in a thick volatile layer. This finding is independently supported by transit timing variations, RV observations ($M_d=2.1_{-0.7}^{+0.6}~M_\oplus$), as well as the flat optical/IR transmission spectrum. Quantitatively, we infer a composition of $11_{-4}^{+3}$\% volatiles by mass or ~51% by volume, with a 2000 km deep water mantle and atmosphere on top of a core with an Earth-like silicates/iron ratio. Any hypothetical hydrogen layer consistent with the observations ($<0.003~M_\oplus$) would have swiftly been lost on a ~10 Myr timescale. The bulk composition of Kepler-138 d therefore resembles those of the icy moons rather than the terrestrial planets in the solar system. We conclude that not all super-Earth-sized planets are rocky worlds, but that volatile-rich water worlds exist in an overlapping size regime, especially at lower insolations. Finally, our photodynamical analysis also reveals that Kepler-138 c ($R_c=1.51 \pm 0.04~R_\oplus$, $M_c=2.3_{-0.5}^{+0.6}~M_\oplus$) is a slightly warmer twin of Kepler-138 d, i.e., another water world in the same system, and we infer the presence of Kepler-138 e, a likely non-transiting planet at the inner edge of the habitable zone., Comment: Published in Nature Astronomy. 4 main figures, 10 extended data figures, 13 supplementary figures. 4 tables

JWST is here. The early release observation program (ERO) provides us with the first look at the scientific data and the spectral capabilities. One of the targets from ERO is HAT-P-18b, an inflated Saturn-mass planet with an equilibrium temperature of $\sim$850K. We present the NIRISS/SOSS transmission spectrum of HAT-P-18b from 0.6 to 2.8$\mu m$ and reveal the planet in the infrared beyond 1.6$\mu m$ for the first time. From the spectrum, we see clear water and escaping helium tail features in an otherwise very hazy atmosphere. Our free chemistry retrievals with ATMO show moderate Bayesian evidence (3.79) supporting the presence of methane, but the spectrum does not display any clearly identifiable methane absorption features. The retrieved methane abundance is $\sim$2 orders of magnitude lower than that of solar composition. The methane-depleted atmosphere strongly rejects simple equilibrium chemistry forward models with solar metallicity and C/O ratio and disfavors high metallicity (100 times) and low C/O ratio (0.3). This calls for additional physical processes such as vertical mixing and photochemistry which can remove methane from the atmosphere., Comment: Accepted to ApJL, JWST is awesome!

Transmission spectroscopy provides insight into the atmospheric properties and consequently the formation history, physics, and chemistry of transiting exoplanets. However, obtaining precise inferences of atmospheric properties from transmission spectra requires simultaneously measuring the strength and shape of multiple spectral absorption features from a wide range of chemical species. This has been challenging given the precision and wavelength coverage of previous observatories. Here, we present the transmission spectrum of the Saturn-mass exoplanet WASP-39b obtained using the SOSS mode of the NIRISS instrument on the JWST. This spectrum spans $0.6 - 2.8 \mu$m in wavelength and reveals multiple water absorption bands, the potassium resonance doublet, as well as signatures of clouds. The precision and broad wavelength coverage of NIRISS-SOSS allows us to break model degeneracies between cloud properties and the atmospheric composition of WASP-39b, favoring a heavy element enhancement ("metallicity") of $\sim 10 - 30 \times$ the solar value, a sub-solar carbon-to-oxygen (C/O) ratio, and a solar-to-super-solar potassium-to-oxygen (K/O) ratio. The observations are best explained by wavelength-dependent, non-gray clouds with inhomogeneous coverage of the planet's terminator., Comment: 48 pages, 12 figures, 2 tables. Under review at Nature

Measuring the metallicity and carbon-to-oxygen (C/O) ratio in exoplanet atmospheres is a fundamental step towards constraining the dominant chemical processes at work and, if in equilibrium, revealing planet formation histories. Transmission spectroscopy provides the necessary means by constraining the abundances of oxygen- and carbon-bearing species; however, this requires broad wavelength coverage, moderate spectral resolution, and high precision that, together, are not achievable with previous observatories. Now that JWST has commenced science operations, we are able to observe exoplanets at previously uncharted wavelengths and spectral resolutions. Here we report time-series observations of the transiting exoplanet WASP-39b using JWST's Near InfraRed Camera (NIRCam). The long-wavelength spectroscopic and short-wavelength photometric light curves span 2.0 - 4.0 $\mu$m, exhibit minimal systematics, and reveal well-defined molecular absorption features in the planet's spectrum. Specifically, we detect gaseous H$_2$O in the atmosphere and place an upper limit on the abundance of CH$_4$. The otherwise prominent CO$_2$ feature at 2.8 $\mu$m is largely masked by H$_2$O. The best-fit chemical equilibrium models favour an atmospheric metallicity of 1-100$\times$ solar (i.e., an enrichment of elements heavier than helium relative to the Sun) and a sub-stellar carbon-to-oxygen (C/O) ratio. The inferred high metallicity and low C/O ratio may indicate significant accretion of solid materials during planet formation or disequilibrium processes in the upper atmosphere., Comment: 35 pages, 13 figures, 3 tables, Nature, accepted

Measuring the abundances of carbon and oxygen in exoplanet atmospheres is considered a crucial avenue for unlocking the formation and evolution of exoplanetary systems. Access to an exoplanet's chemical inventory requires high-precision observations, often inferred from individual molecular detections with low-resolution space-based and high-resolution ground-based facilities. Here we report the medium-resolution (R$\sim$600) transmission spectrum of an exoplanet atmosphere between 3-5 $\mu$m covering multiple absorption features for the Saturn-mass exoplanet WASP-39b, obtained with JWST NIRSpec G395H. Our observations achieve 1.46x photon precision, providing an average transit depth uncertainty of 221 ppm per spectroscopic bin, and present minimal impacts from systematic effects. We detect significant absorption from CO$_2$ (28.5$\sigma$) and H$_2$O (21.5$\sigma$), and identify SO$_2$ as the source of absorption at 4.1 $\mu$m (4.8$\sigma$). Best-fit atmospheric models range between 3 and 10x solar metallicity, with sub-solar to solar C/O ratios. These results, including the detection of SO$_2$, underscore the importance of characterising the chemistry in exoplanet atmospheres, and showcase NIRSpec G395H as an excellent mode for time series observations over this critical wavelength range., Comment: 44 pages, 11 figures, 3 tables. Resubmitted after revision to Nature

Relating planet formation to atmospheric composition has been a long-standing goal of the planetary science community. So far, most modeling studies have focused on predicting the enrichment of heavy elements and the C/O ratio in giant planet atmospheres. Although this framework provides useful constraints on the potential formation locations of gas giant exoplanets, carbon and oxygen measurements alone are not enough to determine where a given gas giant planet originated. Here, we show that characterizing the abundances of refractory elements (e.g., silicon, iron) can break these degeneracies. Refractory elements are present in the solid phase throughout most of the disk and their atmospheric abundances therefore reflect the solid-to-gas accretion ratio during formation. We introduce a new framework that parameterizes the atmospheric abundances of gas giant exoplanets in the form of three ratios: Si/H, O/Si, and C/Si. Si/H traces the solid-to-gas accretion ratio of a planet and is loosely equivalent to earlier notions of 'metallicity'. For O/Si and C/Si, we present a global picture of their variation with distance and time based on what we know from the solar system meteorites and an updated understanding of the variations of thermal processing within protoplanetary disks. We show that ultra-hot Jupiters are ideal targets for atmospheric characterization studies using this framework, as we can measure the abundances of refractories, oxygen and carbon in the gas phase. Finally, we propose that hot Jupiters with silicate clouds and low water abundances might have accreted their envelopes between the soot line and the water snowline., Comment: accepted to ApJ on Nov 22, 2022. Added DOI and journal ref

Convergent disk migration has long been suspected to be responsible for forming planetary systems with a chain of mean-motion resonances (MMR). Dynamical evolution over time could disrupt the delicate resonant configuration. We present TOI-1136, a 700-Myr-old G star hosting at least 6 transiting planets between $\sim$2 and 5 $R_\oplus$. The orbital period ratios deviate from exact commensurability by only $10^{-4}$, smaller than the $\sim$\,$10^{-2}$ deviations seen in typical Kepler near-resonant systems. A transit-timing analysis measured the masses of the planets (3-8$M_\oplus$) and demonstrated that the planets in TOI-1136 are in true resonances with librating resonant angles. Based on a Rossiter-McLaughlin measurement of planet d, the star's rotation appears to be aligned with the planetary orbital planes. The well-aligned planetary system and the lack of detected binary companion together suggest that TOI-1136's resonant chain formed in an isolated, quiescent disk with no stellar fly-by, disk warp, or significant axial asymmetry. With period ratios near 3:2, 2:1, 3:2, 7:5, and 3:2, TOI-1136 is the first known resonant chain involving a second-order MMR (7:5) between two first-order MMR. The formation of the delicate 7:5 resonance places strong constraints on the system's migration history. Short-scale (starting from $\sim$0.1 AU) Type-I migration with an inner disk edge is most consistent with the formation of TOI-1136. A low disk surface density ($\Sigma_{\rm 1AU}\lesssim10^3$g~cm$^{-2}$; lower than the minimum-mass solar nebula) and the resultant slower migration rate likely facilitated the formation of the 7:5 second-order MMR. TOI-1136's deep resonance suggests that it has not undergone much resonant repulsion during its 700-Myr lifetime. One can rule out rapid tidal dissipation within a rocky planet b or obliquity tides within the largest planets d and f., Comment: 48 pages, 23 figures, 8 tables. Accepted to AAS journals. Comments welcome!

Observations of helium in exoplanet atmospheres may reveal the presence of large gaseous envelopes, and indicate ongoing atmospheric escape. Orell-Miquel et al. (2022) used CARMENES to measure a tentative detection of helium for the sub-Neptune GJ 1214b, with a peak excess absorption reaching over 2% in transit depth at 10830 Angstroms. However, several non-detections of helium had previously been reported for GJ 1214b. One explanation for the discrepancy was contamination of the planetary signal by overlapping telluric absorption- and emission lines. We used Keck/NIRSPEC to observe another transit of GJ 1214b at 10830 Angstroms, at a time of minimal contamination by telluric lines, and did not observe planetary helium absorption. Accounting for correlated noise in our measurement, we place an upper limit on the excess absorption size of 1.22% (95% confidence). We find that the discrepancy between the CARMENES and NIRSPEC observations is unlikely to be caused by using different instruments or stellar activity. It is currently unclear whether the difference is due to correlated noise in the observations, or variability in the planetary atmosphere., Comment: Accepted for publication in ApJL

Carbon dioxide (CO2) is a key chemical species that is found in a wide range of planetary atmospheres. In the context of exoplanets, CO2 is an indicator of the metal enrichment (i.e., elements heavier than helium, also called "metallicity"), and thus formation processes of the primary atmospheres of hot gas giants. It is also one of the most promising species to detect in the secondary atmospheres of terrestrial exoplanets. Previous photometric measurements of transiting planets with the Spitzer Space Telescope have given hints of the presence of CO2 but have not yielded definitive detections due to the lack of unambiguous spectroscopic identification. Here we present the detection of CO2 in the atmosphere of the gas giant exoplanet WASP-39b from transmission spectroscopy observations obtained with JWST as part of the Early Release Science Program (ERS). The data used in this study span 3.0 to 5.5 {\mu}m in wavelength and show a prominent CO2 absorption feature at 4.3 {\mu}m (26{\sigma} significance). The overall spectrum is well matched by one-dimensional, 10x solar metallicity models that assume radiative-convective-thermochemical equilibrium and have moderate cloud opacity. These models predict that the atmosphere should have water, carbon monoxide, and hydrogen sulfide in addition to CO2, but little methane. Furthermore, we also tentatively detect a small absorption feature near 4.0 {\mu}m that is not reproduced by these models., Comment: 27 pages, 6 figures, Accepted for publication in Nature, data and models available at https://doi.10.5281/zenodo.6959427

Direct imaging studies have mainly used low-resolution spectroscopy ($R\sim20-100$) to study the atmospheres of giant exoplanets and brown dwarf companions, but the presence of clouds has often led to degeneracies in the retrieved atmospheric abundances (e.g. C/O, metallicity). This precludes clear insights into the formation mechanisms of these companions. The Keck Planet Imager and Characterizer (KPIC) uses adaptive optics and single-mode fibers to transport light into NIRSPEC ($R\sim35,000$ in $K$ band), and aims to address these challenges with high-resolution spectroscopy. Using an atmospheric retrieval framework based on petitRADTRANS, we analyze KPIC high-resolution spectrum ($2.29-2.49~\mu$m) and archival low-resolution spectrum ($1-2.2~\mu$m) of the benchmark brown dwarf HD 4747 B ($m=67.2\pm1.8~M_{\rm{Jup}}$, $a=10.0\pm0.2$ au, $T_{\rm eff}\approx1400$ K). We find that our measured C/O and metallicity for the companion from the KPIC high-resolution spectrum agree with that of its host star within $1-2\sigma$. The retrieved parameters from the $K$ band high-resolution spectrum are also independent of our choice of cloud model. In contrast, the retrieved parameters from the low-resolution spectrum are highly sensitive to our chosen cloud model. Finally, we detect CO, H$_2$O, and CH$_4$ (volume mixing ratio of log(CH$_4$)=$-4.82\pm0.23$) in this L/T transition companion with the KPIC data. The relative molecular abundances allow us to constrain the degree of chemical disequilibrium in the atmosphere of HD 4747 B, and infer a vertical diffusion coefficient that is at the upper limit predicted from mixing length theory., Comment: 33 pages, 16 figures, Accepted to ApJ

Kepler-289 is a three-planet system containing two sub-Neptunes and one cool giant planet orbiting a young, Sun-like star. All three planets exhibit transit timing variations (TTVs), with both adjacent planet pairs having orbital periods close to the 2:1 orbital resonance. We observe two transits of Kepler-289c with the Wide-field InfraRed Camera (WIRC) on the 200" Hale Telescope at Palomar Observatory, using diffuser-assisted photometry to achieve space-like photometric precision from the ground. These new transit observations extend the original four-year Kepler TTV baseline by an additional 7.5 years. We re-reduce the archival Kepler data with an improved stellar activity correction and carry out a joint fit with the Palomar data to constrain the transit shapes and derive updated transit times. We then model the TTVs to determine the masses of the three planets and constrain their densities and bulk compositions. Our new analysis improves on previous mass and density constraints by a factor of two or more for all three planets, with the innermost planet showing the largest improvement. Our updated atmospheric mass fractions for the inner two planets indicate that they likely have hydrogen-rich envelopes, consistent with their location on the upper side of the radius valley. We also constrain the heavy element composition of the outer saturn-mass planet, Kepler-289c, for the first time, finding that it contains 30.5 $\pm$ 6.9 $M_{\oplus}$ of metals. We use dust evolution models to show that Kepler-289c must have formed beyond 1~au, and likely beyond 3~au, and then migrated inward., Comment: 16 pages, 10 figures, 2 tables. Accepted to the Astronomical Journal

We use Keck/NIRSPEC to survey a sample of of young ($<$1 Gyr), short period mini Neptunes orbiting nearby K dwargs to measure their mass loss via the metastable helium line. We detect helium absorption from all four of the targets in our initial sample. The first detection, around TOI 560b, was announced in a previous paper. We now announce three additional detections around TOI 1430.01, 2076b, and TOI 1683.01. All four planets show an average in-transit excess absorption of 0.7--1.0%. However, the outflows differ in their kinematic properties. TOI 1430b exhibits pre-ingress absorption, while TOI 2076b's outflow is exceptionally optically thick and shows significant post-egress absorption. For all four planets, the width of the measured helium absorption signal is consistent with expectations for a photoevaporative outflow (10--30 km/s, 5000--10,000 K). Unless broadening mechanisms other than thermal velocity and the bulk outflow velocity are significant, our observations disfavor core-powered mass loss models, which predict much slower (1--3 km/s) outflows. We utilize both an isothermal Parker wind model and an order-of-magnitude method to estimate the mass loss timescale, and obtain $\sim$ a few hundred Myr for each planet. We conclude that many, if not all, of these planets will lose their hydrogen-rich envelopes and become super Earths. Our results demonstrate that most mini Neptunes orbiting sun-like stars have primordial atmospheres, and that photoevaporation is an efficient mechanism for stripping these atmospheres and transforming these planets into super Earths., Comment: Final version, accepted by Astronomical Journal

We present a uniform analysis of transit observations from the Hubble Space Telescope and Spitzer Space Telescope of two warm gas giants orbiting K-type stars - WASP-29b and WASP-80b. The transmission spectra, which span 0.4-5.0 $\mu$m, are interpreted using a suite of chemical equilibrium PLATON atmospheric retrievals. Both planets show evidence of significant aerosol opacity along the day-night terminator. The spectrum of WASP-29b is flat throughout the visible and near-infrared, suggesting the presence of condensate clouds extending to low pressures. The lack of spectral features hinders our ability to constrain the atmospheric metallicity and C/O ratio. In contrast, WASP-80b shows a discernible, albeit muted H$_2$O absorption feature at 1.4 $\mu$m, as well as a steep optical spectral slope that is caused by fine-particle aerosols and/or contamination from unocculted spots on the variable host star. WASP-80b joins the small number of gas-giant exoplanets that show evidence for enhanced atmospheric metallicity: the transmission spectrum is consistent with metallicities ranging from $\sim$30-100 times solar in the case of cloudy limbs to a few hundred times solar in the cloud-free scenario. In addition to the detection of water, we infer the presence of CO$_2$ in the atmosphere of WASP-80b based on the enhanced transit depth in the Spitzer 4.5 $\mu$m bandpass. From a complementary analysis of Spitzer secondary eclipses, we find that the dayside emission from WASP-29b and WASP-80b is consistent with brightness temperatures of $937 \pm 48$ and $851 \pm 14$ K, respectively, indicating relatively weak day-night heat transport and low Bond albedo., Comment: Published in AJ, 26 pages, 13 figures. Updated to reflect proof changes

Transit surveys indicate that there is a deficit of Neptune-sized planets on close-in orbits. If this ``Neptune desert' is entirely cleared out by atmospheric mass loss, then planets at its upper edge should only be marginally stable against photoevaporation, exhibiting strong outflow signatures in tracers like the metastable helium triplet. We test this hypothesis by carrying out a 12-night photometric survey of the metastable helium feature with Palomar/WIRC, targeting seven gas-giant planets orbiting K-type host stars. Eight nights of data are analyzed here for the first time along with reanalyses of four previously-published datasets. We strongly detect helium absorption signals for WASP-69b, HAT-P-18b, and HAT-P-26b; tentatively detect signals for WASP-52b and NGTS-5b; and do not detect signals for WASP-177b and WASP-80b. We interpret these measured excess absorption signals using grids of Parker wind models to derive mass-loss rates, which are in good agreement with predictions from the hydrodynamical outflow code ATES for all planets except WASP-52b and WASP-80b, where our data suggest that the outflows are much smaller than predicted. Excluding these two planets, the outflows for the rest of the sample are consistent with a mean energy-limited outflow efficiency of $\varepsilon = 0.41^{+0.16}_{-0.13}$. Even when we make the relatively conservative assumption that gas-giant planets experience energy-limited outflows at this efficiency for their entire lives, photoevaporation would still be too inefficient to carve the upper boundary of the Neptune desert. We conclude that this feature of the exoplanet population is a pristine tracer of giant planet formation and migration mechanisms., Comment: 31 pages, 14 figures, accepted to AJ