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2. Dicalcium phosphate dehydrate DCPD as a highly efficient and reusable catalyst for Knoevenagel condensation

Author

Said Boukhris, Brahim Lakhrissi, Zakaria Benzekri, Khalid El Mejdoubi, Brahim Sallek, and Abdelaziz Souizi

Subjects
010405 organic chemistry, Organic Chemistry, Dicalcium phosphate dihydrate, chemistry.chemical_element, Calcium, 010402 general chemistry, Condensation reaction, Heterogeneous catalysis, 01 natural sciences, 0104 chemical sciences, Catalysis, chemistry.chemical_compound, chemistry, Organic chemistry, Knoevenagel condensation, Methylene, Malononitrile
Abstract

We have described the catalytic activities of dicalcium phosphate dihydrate (DCPD) in the condensation reaction of various substituted benzaldehydes with active methylene compound malononitrile. The influences of reaction conditions on the corresponding catalytic behavior have been investigated. The results showed that the DCPD exhibited high catalytic activity and versatility and that it can be recycled without significant loss of its activity for the condensation reactions, which shows the material is a promising new type of heterogeneous catalyst for the condensation reactions. Meanwhile, the catalytic results of DCPD compared favorably with those of other materials for Knoevenagel reactions reported previously.

Published
2016

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