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Cold cores are an early step of star formation, characterized by densities > 10$^4$ cm$^{-3}$, low temperatures (< 15 K), and very low external UV radiation. We investigate the physico-chemical processes at play to tracing the origin of molecules that are predominantly formed via reactions on dust grain surfaces. We observed the cold core LDN 429-C with the NOEMA interferometer and the IRAM 30m single dish telescope in order to obtain the gas-phase abundances of key species, including CO and CH$_3$OH. Comparing the observed gas phase of methanol to its solid phase previously observed with Spitzer allows us to put quantitative constraints on the efficiency of the non-thermal desorption of this species. With physical parameters determined from available Herschel data, we computed abundance maps of 11 detected molecules with a non-local thermal equilibrium radiative transfer model. These observations allowed us to probe the molecular abundances as a function of density and visual extinction, with the variation in temperature being restrained between 12 and 18 K. We then compared the observed abundances to the predictions of the Nautilus astrochemical model. We find that all molecules have lower abundances at high densities and visual extinctions with respect to lower density regions, except for methanol. Comparing these observations with a grid of chemical models based on the local physical conditions, we were able to reproduce these observations, allowing only the parameter time to vary. Comparing the observed gas-phase abundance of methanol with previous measurements of the methanol ice, we estimate a non-thermal desorption efficiency between 0.002% and 0.09%, increasing with density. The apparent increase in the desorption efficiency cannot be reproduced by our model unless the yield of cosmic-ray sputtering is altered due to the ice composition varying as a function of density.

We present new, ice species-specific New Horizons/Alice upper gas coma production limits from the 01 Jan 2019 MU69/Arrokoth flyby of Gladstone et al. (2021) and use them to make predictions about the rarity of majority hypervolatile (CO, N$_2$, CH$_4$) ices in KBOs and Oort Cloud comets. These predictions have a number of important implications for the study of the Oort Cloud, including: determination of hypervolatile rich comets as the first objects emplaced into the Oort Cloud; measurement of CO/N$_2$/CH$_4$ abundance ratios in the proto-planetary disk from hypervolatile rich comets; and population statistical constraints on early (< 20 Myr) planetary aggregation driven versus later (> 50 Myr) planetary migration driven emplacement of objects into the Oort Cloud. They imply that the phenomenon of ultra-distant active comets like C/2017K2 (Jewitt et al. 2017, Hui et al. 2018) should be rare, and thus not a general characteristic of all comets. They also suggest that interstellar object 2I/Borisov did not originate in a planetary system that was inordinately CO rich (Bodewits et al. 2020), but rather could have been ejected onto an interstellar trajectory very early in its natal system's history., Comment: 16 Pages, 2 Figures, 1 Table; accepted for Publication in PSJ 14-Mar-2022

A near surface thermal model for Arrokoth is developed based on the recently released $10^5$ facet model of the body. This thermal solution takes into account Arrokoth's surface re-radiation back onto itself. The solution method exploits Arrokoth's periodic orbital character to develop a thermal response using a time-asymptotic solution method, which involves a Fourier transform solution of the heat equation, an approach recently used by others. We display detailed thermal solutions assuming that Arrokoth's near surface material's thermal inertia ${\cal I} = $ 2.5 W/m$^{-2}$K$^{-1}$s$^{1/2}$. We predict that at New Horizons' encounter with Arrokoth its encounter hemisphere surface temperatures were $\sim$ 57-59 K in its polar regions, 30-40 K on its equatorial zones, and 11-13 K for its winter hemisphere. Arrokoth's orbitally averaged temperatures are around 30-35 K in its polar regions, and closer to 40 K near its equatorial zones. Thermal reradiation from the surrounding surface amounts to less than 5\% of the total energy budget, while the total energy ensconced into and exhumed out Arrokoth's interior via thermal conduction over one orbit is about 0.5\% of the total energy budget. As a generalized application of this thermal modeling together with other KBO origins considerations, we favor the interpretation that New Horizons' REX instrument's $29 \pm 5$K brightness temperature measurement is consistent with Arrokoth's near surface material's being made of sub-to-few mm sized tholin-coated amorphous \water ice grains with 1 W/m$^{-2}$K$^{-1}$s$^{1/2}$ $< {\cal I} < $10-20 W/m$^{-2}$K$^{-1}$s$^{1/2}$, and which are characterized by an X-band emissivity in the range 0.9 and 1., Comment: Accepted on Feb. 21, 2022 for publication in Planetary Science Journal (PSJ)

We present new photometric and spectroscopic observations of SN 2019yvq, a Type Ia supernova (SN Ia) exhibiting several peculiar properties including an excess of UV/optical flux within days of explosion, a high SiII velocity, and a low peak luminosity. Photometry near the time of first light places new constraints on the rapid rise of the UV/optical flux excess. A near-infrared spectrum at $+173$ days after maximum light places strict limits on the presence of H or He emission, effectively excluding the presence of a nearby non-degenerate star at the time of explosion. New optical spectra, acquired at +128 and +150 days after maximum light, confirm the presence of CaII$\lambda 7300~$\r{A} and persistent CaII NIR triplet emission as SN 2019yvq transitions into the nebular phase. The lack of [OI]$\lambda 6300~$\r{A} emission disfavors the violent merger of two C/O white dwarfs (WDs) but the merger of a C/O WD with a He WD cannot be excluded. We compare our findings with several models in the literature postulated to explain the early flux excess including double-detonation explosions, $^{56}$Ni mixing into the outer ejecta during ignition, and interaction with H- and He-deficient circumstellar material. Each model may be able to explain both the early flux excess and the nebular [CaII] emission, but none of the models can reconcile the high photospheric velocities with the low peak luminosity without introducing new discrepancies., Comment: 19 pages, 10 figures, and 2 tables. Accepted by ApJ

We discuss in a thermodynamic, geologically empirical way the long-term nature of the stable majority ices that could be present in Kuiper Belt Object 2014 MU69 after its 4.6 Gyr residence in the EKB as a cold classical object. Considering the stability versus sublimation into vacuum for the suite of ices commonly found on comets, Centaurs, and KBOs at the average ~40K sunlit surface temperature of MU69 over Myr to Gyr, we find only 3 common ices that are truly refractory: HCN, CH3OH, and H2O (in order of increasing stability). NH3 and H2CO ices are marginally stable and may be removed by any positive temperature excursions in the EKB, as produced every 1e8 - 1e9 yrs by nearby supernovae and passing O/B stars. To date the NH team has reported the presence of abundant CH3OH and evidence for H2O on MU69s surface (Lisse et al. 2017, Grundy et al. 2020). NH3 has been searched for, but not found. We predict that future absorption feature detections will be due to an HCN or poly-H2CO based species. Consideration of the conditions present in the EKB region during the formation era of MU69 lead us to infer that it formed "in the dark", in an optically thick mid-plane, unable to see the nascent, variable, highly luminous Young Stellar Object-TTauri Sun, and that KBOs contain HCN and CH3OH ice phases in addition to the H2O ice phases found in their Short Period comet descendants. Finally, when we apply our ice thermal stability analysis to bodies/populations related to MU69, we find that methanol ice may be ubiquitous in the outer solar system; that if Pluto is not a fully differentiated body, then it must have gained its hypervolatile ices from proto-planetary disk sources in the first few Myr of the solar systems existence; and that hypervolatile rich, highly primordial comet C/2016 R2 was placed onto an Oort Cloud orbit on a similar timescale., Comment: 34 Pages, 5 Figures, 2 SOM Tables

The Kuiper Belt is a distant region of the Solar System. On 1 January 2019, the New Horizons spacecraft flew close to (486958) 2014 MU69, a Cold Classical Kuiper Belt Object, a class of objects that have never been heated by the Sun and are therefore well preserved since their formation. Here we describe initial results from these encounter observations. MU69 is a bi-lobed contact binary with a flattened shape, discrete geological units, and noticeable albedo heterogeneity. However, there is little surface color and compositional heterogeneity. No evidence for satellites, ring or dust structures, gas coma, or solar wind interactions was detected. By origin MU69 appears consistent with pebble cloud collapse followed by a low velocity merger of its two lobes., Comment: 43 pages, 8 figure

The Cold Classical Kuiper Belt, a class of small bodies in undisturbed orbits beyond Neptune, are primitive objects preserving information about Solar System formation. The New Horizons spacecraft flew past one of these objects, the 36 km long contact binary (486958) Arrokoth (2014 MU69), in January 2019. Images from the flyby show that Arrokoth has no detectable rings, and no satellites (larger than 180 meters diameter) within a radius of 8000 km, and has a lightly-cratered smooth surface with complex geological features, unlike those on previously visited Solar System bodies. The density of impact craters indicates the surface dates from the formation of the Solar System. The two lobes of the contact binary have closely aligned poles and equators, constraining their accretion mechanism.

The New Horizons spacecraft's encounter with the cold classical Kuiper belt object (486958) Arrokoth (formerly 2014 MU69) revealed a contact-binary planetesimal. We investigate how it formed, finding it is the product of a gentle, low-speed merger in the early Solar System. Its two lenticular lobes suggest low-velocity accumulation of numerous smaller planetesimals within a gravitationally collapsing, solid particle cloud. The geometric alignment of the lobes indicates the lobes were a co-orbiting binary that experienced angular momentum loss and subsequent merger, possibly due to dynamical friction and collisions within the cloud or later gas drag. Arrokoth's contact-binary shape was preserved by the benign dynamical and collisional environment of the cold classical Kuiper belt, and so informs the accretion processes that operated in the early Solar System., Comment: Published in Science 28 Feb 2020 (First release 13 Feb 2020)

The outer Solar System object (486958) Arrokoth (provisional designation 2014 MU$_{69}$) has been largely undisturbed since its formation. We study its surface composition using data collected by the New Horizons spacecraft. Methanol ice is present along with organic material, which may have formed through radiation of simple molecules. Water ice was not detected. This composition indicates hydrogenation of carbon monoxide-rich ice and/ or energetic processing of methane condensed on water ice grains in the cold, outer edge of the early Solar System. There are only small regional variations in color and spectra across the surface, suggesting Arrokoth formed from a homogeneous or well-mixed reservoir of solids. Microwave thermal emission from the winter night side is consistent with a mean brightness temperature of 29$\pm$5 K., Comment: 31 pages, 8 figures

The discovery of the first active interstellar object 2I/Borisov provides an unprecedented opportunity to study planetary formation processes in another planetary system. In particular, spectroscopic observations of 2I allow us to constrain the composition of its nuclear ices. We obtained optical spectra of 2I with the 4.2 m William Herschel and 2.5 m Isaac Newton telescopes between 2019 September 30 and October 13, when the comet was between 2.5 au and 2.4 au from the Sun. We also imaged the comet with broadband filters on 15 nights from September 11 to October 17, as well as with a CN narrow-band filter on October 18 and 20, with the TRAPPIST-North telescope. Broadband imaging confirms that the dust coma colours (B-V=0.82$\pm$0.02, V-R=0.46$\pm$0.03, R-I=0.44$\pm$0.03, B-R=1.28$\pm$0.03) are the same as for Solar System comets. We detect CN emission in all spectra and in the TRAPPIST narrow-band images with production rates between 1.6$\times10^{24}$ and 2.1$\times10^{24}$ molec/s. No other species are detected. We determine three-sigma upper limits for C$_2$, C$_3$, and OH production rates of 6$\times10^{23}$ molec/s, 3$\times10^{23}$ molec/s and 2$\times10^{27}$ molec/s, respectively, on October 02. There is no significant increase of the CN production rate or A(0)f$\rho$ during our observing period. Finally, we place a three-sigma upper limit on the Q(C$_2$)/Q(CN) ratio of 0.3 (on October 13). From this, we conclude that 2I is highly depleted in C$_2$, and may have a composition similar to Solar System carbon-chain depleted comets., Comment: Revised version, Accepted for publication in A&A Letters

The New Horizons spacecraft provided near global observations of Pluto that far exceed the resolution of Earth-based data sets. Most Pluto New Horizons analysis hitherto has focused on the encounter hemisphere of Pluto (i.e., the antiCharon hemisphere containing Sputnik Planitia). In this work, we summarize and interpret data on the far side (i.e., the non-encounter hemisphere), providing the first integrated New Horizons overview of the far side terrains. We find strong evidence for widespread bladed deposits, evidence for an impact crater about as large as any on the near side hemisphere, evidence for complex lineations approximately antipodal to Sputnik Planitia that may be causally related, and evidence that the far side maculae are smaller and more structured than the encounter hemisphere maculae., Comment: 45 pages 12 figures

We present a summary of the campaign of remote observations that supported the European Space Agency's Rosetta mission. Telescopes across the globe (and in space) followed comet 67P/Churyumov-Gerasimenko from before Rosetta's arrival until nearly the end of mission in September 2016. These provided essential data for mission planning, large-scale context information for the coma and tails beyond the spacecraft, and a way to directly compare 67P with other comets. The observations revealed 67P to be a relatively `well behaved' comet, typical of Jupiter family comets and with activity patterns that repeat from orbit-to-orbit. Comparison between this large collection of telescopic observations and the in situ results from Rosetta will allow us to better understand comet coma chemistry and structure. This work is just beginning as the mission ends -- in this paper we present a summary of the ground-based observations and early results, and point to many questions that will be addressed in future studies., Comment: Author prepared version; final published version available at journal. 22 pages

Using Keck/HIRES spectra {\Delta}v ~ 7 km/s, we analyze forbidden lines of [O I] 6300 {\AA}, [O I] 5577 {\AA} and [S II] 6731 {\AA} from 33 T Tauri stars covering a range of disk evolutionary stages. After removing a high velocity component (HVC) associated with microjets, we study the properties of the low velocity component (LVC). The LVC can be attributed to slow disk winds that could be magnetically (MHD) or thermally (photoevaporative) driven. Both of these winds play an important role in the evolution and dispersal of protoplanetary material. LVC emission is seen in all 30 stars with detected [O I] but only in 2 out of eight with detected [S II] , so our analysis is largely based on the properties of the [O I] LVC. The LVC itself is resolved into broad (BC) and narrow (NC) kinematic components. Both components are found over a wide range of accretion rates and their luminosity is correlated with the accretion luminosity, but the NC is proportionately stronger than the BC in transition disks. The FWHM of both the BC and NC correlates with disk inclination, consistent with Keplerian broadening from radii of 0.05 to 0.5 AU and 0.5 to 5 AU, respectively. The velocity centroids of the BC suggest formation in an MHD disk wind, with the largest blueshifts found in sources with closer to face-on orientations. The velocity centroids of the NC however, show no dependence on disk inclination. The origin of this component is less clear and the evidence for photoevaporation is not conclusive.

IRAS 19312+1950 is a peculiar object that has eluded firm characterization since its discovery, with combined maser properties similar to an evolved star and a young stellar object (YSO). To help determine its true nature, we obtained infrared spectra of IRAS 19312+1950 in the range 5-550 $\mu$m using the Herschel and Spitzer space observatories. The Herschel PACS maps exhibit a compact, slightly asymmetric continuum source at 170 $\mu$m, indicative of a large, dusty circumstellar envelope. The far-IR CO emission line spectrum reveals two gas temperature components: $\approx0.22M_{\odot}$ of material at $280\pm18$ K, and $\approx1.6M_{\odot}$ of material at $157\pm3$ K. The OI 63 $\mu$m line is detected on-source but no significant emission from atomic ions was found. The HIFI observations display shocked, high-velocity gas with outflow speeds up to 90 km s$^{-1}$ along the line of sight. From Spitzer spectroscopy, we identify ice absorption bands due to H$_2$O at 5.8 $\mu$m and CO$_2$ at 15 $\mu$m. The spectral energy distribution is consistent with a massive, luminous ($\sim2\times10^4L_{\odot}$) central source surrounded by a dense, warm circumstellar disk and envelope of total mass $\sim500$-$700M_{\odot}$, with large bipolar outflow cavities. The combination of distinctive far-IR spectral features suggest that IRAS 19312+1950 should be classified as an accreting high-mass YSO rather than an evolved star. In light of this reclassification, IRAS 19312+1950 becomes only the 5th high-mass protostar known to exhibit SiO maser activity, and demonstrates that 18 cm OH maser line ratios may not be reliable observational discriminators between evolved stars and YSOs., Comment: 16 pages. Accepted for publication in ApJ

Transitional disks are protoplanetary disks characterized by reduced near- and mid-infrared emission with respect to full disks. This characteristic spectral energy distribution indicates the presence of an optically thin inner cavity within the dust disk believed to mark the disappearance of the primordial massive disk. We present new Herschel Space Observatory PACS spectra of [OI] 63 micron for 21 transitional disks. Our survey complements the larger Herschel GASPS program "Gas in Protoplanetary Systems" (Dent et al. 2013) by quadrupling the number of transitional disks observed with PACS at this wavelength. [OI] 63 micron traces material in the outer regions of the disk, beyond the inner cavity of most transitional disks. We find that transitional disks have [OI] 63 micron line luminosities two times fainter than their full disk counterparts. We self consistently determine various stellar properties (e.g. bolometric luminosity, FUV excess, etc.) and disk properties (e.g. disk dust mass, etc.) that could influence the [OI] 63 micron line luminosity and we find no correlations that can explain the lower [OI] 63 micron line luminosities in transitional disks. Using a grid of thermo-chemical protoplanetary disk models, we conclude that either transitional disks are less flared than full disks or they possess lower gas-to-dust ratios due to a depletion of gas mass. This result suggests that transitional disks are more evolved than their full disk counterparts, possibly even at large radii., Comment: Accepted for publication in ApJ; 52 pages, 16 figures, 8 tables

Dynamically new comet C/2011 L4 (PanSTARRS) is one of the brightest comets since the great comet C/1995 O1 (Hale-Bopp). Here, we present our multi-wavelength observations of C/2011 L4 during its in-bound passage to the inner Solar system. A strong absorption band of water ice at 2.0 $\mu$m was detected in the near infrared spectra, taken with the 8-m Gemini-North and 3-m IRTF telescopes. The companion 1.5 $\mu$m band of water ice, however, was not observed. Spectral modeling show that the absence of the 1.5 $\mu$m feature can be explained by the presence of sub-micron-sized fine ice grains. No gas lines (i.e. CN, HCN or CO) were observed pre-perihelion either in the optical or in the sub-millimeter. 3-$\sigma$ upper limits to the CN and CO production rates were derived. The comet exhibited a very strong continuum in the optical and its slope seemed to become redder as the comet approached the Sun. Our observations suggest that C/2011 L4 is an unusually dust-rich comet with a dust-to-gas mass ratio $>$ 4., Comment: 8 pages, 3 figures, accepted to be published by ApJ

We present spectral and spatial information for major volatile species in Comet 10P/Tempel 2, based on high-dispersion infrared spectra acquired on UT 2010 July 26 (heliocentric distance Rh = 1.44 AU) and September 18 (Rh = 1.62 AU), following the comet's perihelion passage on UT 2010 July 04. The total production rate for water on July 26 was (1.90 +/- 0.12) x 10^28 molecules s-1, and abundances of six trace gases (relative to water) were: CH3OH (1.58% +/- 0.23), C2H6 (0.39% +/- 0.04), NH3 (0.83% +/- 0.20), and HCN (0.13% +/- 0.02). A detailed analysis of intensities for water emission lines provided a rotational temperature of 35 +/- 3 K. The mean OPR is consistent with nuclear spin populations in statistical equilibrium (OPR = 3.01 +/- 0.18), and the (1-sigma) lower bound corresponds to a spin temperature > 38 K. Our measurements were contemporaneous with a jet-like feature observed at optical wavelengths. The spatial profiles of four primary volatiles display strong enhancements in the jet direction, which favors release from a localized vent on the nucleus. The measured IR continuum is much more sharply peaked and is consistent with a dominant contribution from the nucleus itself. The peak intensities for H2O, CH3OH, and C2H6 are offset by ~200 km in the jet direction, suggesting the possible existence of a distributed source, such as the release of icy grains that subsequently sublimed in the coma. On UT September 18, no obvious emission lines were present in our spectra, nevertheless we obtained a 3-sigma upper limit Q(H2O) < 2.86 x 10^27 molecules s-1.

We report measurements of eight primary volatiles (H2O, HCN, CH4, C2H6, CH3OH, C2H2, H2CO, and NH3) and two product species (OH and NH2) in comet 103P/Hartley-2 using high dispersion infrared spectroscopy. We quantified the long- and short-term behavior of volatile release over a three-month interval that encompassed the comet's close approach to Earth, its perihelion passage, and flyby of the comet by the Deep Impact spacecraft during the EPOXI mission. We present production rates for individual species, their mixing ratios relative to water, and their spatial distributions in the coma on multiple dates. The production rates for water, ethane, HCN, and methanol vary in a manner consistent with independent measures of nucleus rotation, but mixing ratios for HCN, C2H6, & CH3OH are independent of rotational phase. Our results demonstrate that the ensemble average composition of gas released from the nucleus is well defined, and relatively constant over the three-month interval (September 18 through December 17). If individual vents vary in composition, enough diverse vents must be active simultaneously to approximate (in sum) the bulk composition of the nucleus. The released primary volatiles exhibit diverse spatial properties which favor the presence of separate polar and apolar ice phases in the nucleus, establish dust and gas release from icy clumps (and also, directly from the nucleus), and provide insights into the driver for the cyanogen (CN) polar jet. The spatial distributions of C2H6 & HCN along the near-polar jet (UT 19.5 October) and nearly orthogonal to it (UT 22.5 October) are discussed relative to the origin of CN. The ortho-para ratio (OPR) of water was 2.85 \pm 0.20; the lower bound (2.65) defines Tspin > 32 K. These values are consistent with results returned from ISO in 1997., Comment: 18 pages, 3 figures, to be published in: Astrophysical Journal Letters

This paper presents spectra in the 2 to 20 micron range of quiescent cloud material located in the IC 5146 cloud complex. The spectra were obtained with NASA's Infrared Telescope Facility (IRTF) SpeX instrument and the Spitzer Space Telescope's Infrared Spectrometer. We use these spectra to investigate dust and ice absorption features in pristine regions of the cloud that are unaltered by embedded stars. We find that the H2O-ice threshold extinction is 4.03+/-0.05 mag. Once foreground extinction is taken into account, however, the threshold drops to 3.2 mag, equivalent to that found for the Taurus dark cloud, generally assumed to be the touchstone quiescent cloud against which all other dense cloud and embedded young stellar object observations are compared. Substructure in the trough of the silicate band for two sources is attributed to CH3OH and NH3 in the ices, present at the ~2% and ~5% levels, respectively, relative to H2O-ice. The correlation of the silicate feature with the E(J-K) color excess is found to follow a much shallower slope relative to lines of sight that probe diffuse clouds, supporting the previous results by Chiar et al. (2007)., Comment: 13 pages, 13 figures with multiple parts, accepted for publication in Astrophysical Journal, Feb. 2011

We report on our first results from a mid-infrared spectroscopic study of ISM features in a sample of deeply obscured ULIRG nuclei using the InfraRed Spectrograph (IRS) on the Spitzer Space Telescope. The spectra are extremely rich and complex, revealing absorption features of both amorphous and crystalline silicates, aliphatic hydrocarbons, water ice and gas phase bands of hot CO and warm C_2H_2, HCN and CO_2. PAH emission bands were found to be generally weak and in some cases absent. The features are probing a dense and warm environment in which crystalline silicates and water ice are able to survive but volatile ices, commonly detected in Galactic dense molecular clouds, cannot. If powered largely by star formation, the stellar density and conditions of the gas and dust have to be extreme not to give rise to the commonly detected emission features associated with starburst., Comment: 10 pages, 7 figures, invited paper for the proceedings of IAU symposium 231 "Astrochemistry: Recent Successes and Current Challenges", D.C. Lis, G.A. Blake & E. Herbst, eds

We report the detection of strong absorption and weak emission features in the 4--27 micron Spitzer-IRS spectrum of the distant ultraluminous infrared galaxy (ULIRG) IRAS F00183--7111 (z=0.327). The absorption features of CO2 and CO gas, water ice, hydrocarbons and silicates are indicative of a strongly obscured (A[9.6]>=5.4; A[V]>=90) and complex line of sight through both hot diffuse ISM and shielded cold molecular clouds towards the nuclear power source. From the profile of the 4.67 micron CO fundamental vibration mode we deduce that the absorbing gas is dense (n~10^6 cm^-3) and warm (720 K) and has a CO column density of ~10^19.5 cm^-2, equivalent to N[H]~10^23.5 cm^-2. The high temperature and density, as well as the small infered size (<0.03pc), locates this absorbing gas close to the power source of this region. Weak emission features of molecular hydrogen, PAHs and Ne+, likely associated with star formation, are detected against the 9.7 micron silicate feature, indicating an origin away from the absorbing region. Based on the 11.2 micron PAH flux, we estimate the star formation component to be responsible for up to 30% of the IR luminosity of the system. While our mid-infrared spectrum shows no tell-tale signs of AGN activity, the similarities to the mid-infrared spectra of deeply obscured sources (e.g. NGC4418) and AGN hot dust (e.g. NGC1068), as well as evidence from other wavelength regions, suggest that the power source hiding behind the optically thick dust screen may well be a buried AGN., Comment: 5 pages, 3 figures. Accepted for publication in ApJS Spitzer Special Issue. Also available at http://isc.astro.cornell.edu/~spoon/publications.html

The 4.62 micron absorption band, observed along the line-of-sight towards various young stellar objects, is generally used as a qualitative indicator for energetic processing of interstellar ice mantles. This interpretation is based on the excellent fit with OCN-, which is readily formed by ultraviolet (UV) or ion-irradiation of ices containing H2O, CO and NH3. However, the assignment requires both qualitative and quantitative agreement in terms of the efficiency of formation as well as the formation of additional products. Here, we present the first quantitative results on the efficiency of laboratory formation of OCN- from ices composed of different combinations of H2O, CO, CH3OH, HNCO and NH3 by UV- and thermally-mediated solid state chemistry. Our results show large implications for the use of the 4.62 micron feature as a diagnostic for energetic ice-processing. UV-mediated formation of OCN- from H2O/CO/NH3 ice matrices falls short in reproducing the highest observed interstellar abundances. In this case, at most 2.7% OCN- is formed with respect to H2O under conditions that no longer apply to a molecular cloud environment. On the other hand, photoprocessing and in particular thermal processing of solid HNCO in the presence of NH3 are very efficient OCN- formation mechanisms, converting 60%--85% and ~100%, respectively of the original HNCO. We propose that OCN- is most likely formed thermally from HNCO given the ease and efficiency of this mechanism. Upper limits on solid HNCO and the inferred interstellar ice temperatures are in agreement with this scenario., Comment: 13 pages, 13 figures, to be published in A&A

We have re-analyzed the 6-12 micron ISO spectrum of the ultra-luminous infrared galaxy Arp220 with the conclusion that it is not consistent with that of a scaled up version of a typical starburst. Instead, both template fitting with spectra of the galaxies NGC4418 and M83 and with dust models suggest that it is best represented by combinations of a typical starburst component, exhibiting PAH emission features, and a heavily absorbed dust continuum which contributes ~40% of the 6-12 micron flux and likely dominates the luminosity. Of particular significance relative to previous studies of Arp220 is the fact that the emission feature at 7.7 micron comprises both PAH emission and a broader component resulting from ice and silicate absorption against a heavily absorbed continuum. Extinction to the PAH emitting source, however, appears to be relatively low. We tentatively associate the PAH emitting and heavily dust/ice absorbed components with the diffuse emission region and the two compact nuclei respectively identified by Soifer et al. (2002) in their higher spatial resolution 10 micron study. Both the similarity of the absorbed continuum with that of the embedded Galactic protostars and results of the dust models imply that the embedded source(s) in Arp220 could be powered by, albeit extremely dense, starburst activity. Due to the high extinction, it is not possible with the available data to exclude that AGN(s) also contribute some or all of the observed luminosity. In this case, however, the upper limit measured for its hard X-ray emission would require Arp220 to be the most highly obscured AGN known., Comment: 11 pages, 9 figures. Accepted for publication in A&A. Also available at http://www.astro.rug.nl/~spoon/publications.html

Mid infrared spectra provide a powerful probe of the conditions in dusty galactic nuclei. They variously contain emission features associated with star forming regions and absorptions by circumnuclear silicate dust plus ices in cold molecular cloud material. Here we report the detection of 6-8um water ice absorption in 18 galaxies observed by ISO. While the mid-IR spectra of some of these galaxies show a strong resemblance to the heavily absorbed spectrum of NGC 4418, other galaxies in this sample also show weak to strong PAH emission. The 18 ice galaxies are part of a sample of 103 galaxies with good S/N mid-IR ISO spectra. Based on our sample we find that ice is present in most of the ULIRGs, whereas it is weak or absent in the large majority of Seyferts and starburst galaxies. This result is consistent with the presence of larger quantities of molecular material in ULIRGs as opposed to other galaxy types. Like NGC 4418, several of our ice galaxy spectra show a maximum near 8um that is not or only partly due to PAH emission. While this affects only a small part of the galaxy population studied by ISO, it stresses the need for high S/N data and refined diagnostic methods, to properly discriminate spectra dominated by PAH emission and spectra dominated by heavy obscuration. The spectral variation from PAH emission to absorbed continuum emission near 8um shows strong similarities with Galactic star forming clouds. This leads us to believe that our classification of ice galaxy spectra might reflect an evolutionary sequence from strongly obscured beginnings of star formation (and AGN activity) to a less enshrouded stage of advanced star formation (and AGN activity), as the PAHs get stronger and the broad 8um feature weakens., Comment: 22 pages, 15 figures, Astronomy & Astrophysics, accepted

The first results from a VLT-ISAAC program on L- and M-band infrared spectroscopy of deeply-embedded young stellar objects are presented. The advent of 8-m class telescopes allows high S/N spectra of low-luminosity sources to be obtained. In our first observing run, low- and medium-resolution spectra have been measured toward a dozen objects, mostly in the Vela and Chamaeleon molecular clouds. The spectra show strong absorption of H2O and CO ice, as well as weak features at `3.47' and 4.62 mu. No significant solid CH3OH feature at 3.54 mu is found, indicating that the CH3OH/H2O ice abundance is lower than toward some massive protostars. Various evolutionary diagnostics are investigated for a set of sources in Vela., Comment: 8 pages, 4 figures, to appear in The Origins of Stars and Planets: the VLT View, eds. J. Alves, M. McCaughrean (Springer Verlag)

We report the detection of absorption features in the 6-8 micron region superimposed on a featureless mid-infrared continuum in NGC 4418. For several of these features this is the first detection in an external galaxy. We compare the absorption spectrum of NGC 4418 to that of embedded massive protostars and the Galactic centre, and attribute the absorption features to ice grains and to hydrogenated amorphous carbon grains. From the depth of the ice features, the powerful central source responsible for the mid-infrared emission must be deeply enshrouded. Since this emission is warm and originates in a compact region, an AGN must be hiding in the nucleus of NGC 4418., Comment: 4 pages, 3 figures, accepted for publication in Astronomy & Astrophysics Letters

We have obtained the full 1-200 um spectrum of the low luminosity (36 Lsun) Class I protostar Elias 29 in the Rho Ophiuchi molecular cloud. It provides a unique opportunity to study the origin and evolution of interstellar ice and the interrelationship of interstellar ice and hot core gases around low mass protostars. We see abundant hot CO and H2O gas, as well as the absorption bands of CO, CO2, H2O and ``6.85 um'' ices. We compare the abundances and physical conditions of the gas and ices toward Elias 29 with the conditions around several well studied luminous, high mass protostars. The high gas temperature and gas/solid ratios resemble those of relatively evolved high mass objects (e.g. GL 2591). However, none of the ice band profiles shows evidence for significant thermal processing, and in this respect Elias 29 resembles the least evolved luminous protostars, such as NGC 7538 : IRS9. Thus we conclude that the heating of the envelope of the low mass object Elias 29 is qualitatively different from that of high mass protostars. This is possibly related to a different density gradient of the envelope or shielding of the ices in a circumstellar disk. This result is important for our understanding of the evolution of interstellar ices, and their relation to cometary ices., Comment: 18 pages and 14 figures, accepted for publication in A&A