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Since the first plasma realized in 2020, a series of key systems on HL-3 (known as HL-2M before) tokamak have been equipped/upgraded, including in-vessel components (the first wall, lower divertor, and toroidal cryogenic/water-cooling/baking/glow discharge systems, etc.), auxiliary heating system of 11 MW, and 28 diagnostic systems (to measure the plasma density electron temperature, radiation, magnetic field, etc.). Magnet field systems were commissioned firstly for divertor plasma discharges. During the 2nd experimental campaign of HL-3 tokamak, several great progresses have been achieved. Firstly, the successful operation with plasma current larger than 1 MA was achieved under a divertor configuration. Secondly, the advanced divertor concept with two distinct snowflake configurations was realized. It is found that the distribution of ion saturation current and heat flux on bottom plate becomes wide due to magnetic surface expansion, demonstrating the advantage of such configuration in the heat flux mitigation. In addition, using the combination of NBI, ECRH and LHCD, the standard sawtoothing high confinement mode of megampere plasma was firstly accessed on the HL-3. The successful commissioning of HL-3 is beneficial for the initial operation of ITER.

Atomically dispersed catalysts have been shown highly active for preferential oxidation of carbon monoxide in the presence of excess hydrogen (PROX). However, their stability has been less than ideal. We show here that the introduction of a structural component to minimize diffusion of the active metal center can greatly improve the stability without compromising the activity. Using an Ir dinuclear heterogeneous catalyst (DHC) as a study platform, we identify two types of oxygen species, interfacial and bridge, that work in concert to enable both activity and stability. The work sheds important light on the synergistic effect between the active metal center and the supporting substrate and may find broad applications for the use of atomically dispersed catalysts.

Abstract Collapse of the edge flow shear as the line-averaged density approaches the Greenwald density limit has been observed as a precursor to the enhanced edge particle flux characteristic of proximity to the density limit regime. Here, we report the use of a biased electrode to sustain the edge shear layer in high density discharges, in which the shear layer would otherwise collapse. A stable increase in line-averaged density is observed along with a strong increase in edge density. These experiments were carried out on the J-TEXT tokamak. The Reynolds stress at the edge is enhanced, and the zonal flow sustained, while density perturbation levels, the flux of turbulence internal energy (i.e., turbulence spreading), and particle and heat flux all decrease significantly. Electron adiabaticity increases, and bias voltage modulation experiments show that an increase in the edge shear leads the increase in adiabaticity. These results suggest that external edge E × B flow shear drive may be of interest for sustaining edge plasma states at high density, and support the hypothesis that collapse of the edge shear layer triggers the onset of the strong transport and turbulence characteristic of the density limit regime.

Recent experimental results about the edge shear flow and poloidal residual stress near the density limit of HL-2A tokamak are reported in this paper. The studies found that the plasma response passes from adiabatic to hydrodynamic response as the plasma density approaches Greenwald density, therefore the residual stress, which is the non-diffusive item in the turbulent Reynolds stress, is reduced. The plasma intrinsic poloidal torque characterized by the divergence of residual stress decreases drastically. The reduction of turbulent generation of edge poloidal flow leads to the decreased edge E×B poloidal flow shearing rate. These experimental results demonstrate the important role of reduced residual stress in the edge poloidal shear layer collapse in the proximity of tokamak density limit.

Enhanced particle transport events are discovered and analyzed as the density limit of the J-TEXT tokamak is approached. Edge shear layer collapse is observed and the ratio of Reynolds power to turbulence production decreases. Simultaneously, the divergence of turbulence internal energy flux (i.e. turbulence spreading) increases, indicating that shear layer collapse triggers an outward spreading event. Studies of correlations show that the enhanced particle transport events are quasi-coherent, and manifested primarily in density fluctuations which exhibit positive skewness. Electron adiabaticity emerges as the critical parameter which signals transport event onset. For α < 0.35 as density approaches the Greenwald density, both turbulence spreading and density fluctuations rise rapidly. Taken together, these results elucidate the connections between edge shear layer, density fluctuations, particle transport events, turbulence spreading and plasma edge cooling as the density limit is approached.

Seawater is the most abundant water source for hydrogen fuel production. Here the authors report a binary photoelectrode of Pt catalyst-GaN semiconductor with promising efficiency, productivity, and stability for seawater hydrogen evolution.

The mission of HL-2A is to explore the key physical topics relevant to ITER and to the advanced tokamak operation (e.g. the operation of future HL-2M), such as the access of H-mode, energetic particle physics, edge-localized mode (ELM) mitigation/suppression and disruption mitigation. Since the 2016 Fusion Energy Conference, the HL-2A team has focused on the investigations on the following areas: (i) pedestal dynamics and L-H transition, (ii) techniques of ELM control, (iii) turbulence and transport, (iv) energetic particle physics. The HL-2A results demonstrated that the increase of mean shear flow plays a key role in triggering L-I and I-H transitions, while the change of flow is mainly induced by the ion pressure gradient. Both mitigation and suppression of ELMs were realized by laser blow-off seeded impurity (Al, Fe, W). The 30% Ne mixture supersonic molecular beam injection seeding also robustly induced ELM mitigation. The ELMs were mitigated by low-hybrid current drive. The stabilization of m/n = 1/1 ion fishbone activities by electron cyclotron resonance heating was found on the HL-2A. A new m/n = 2/1 ion fishbone activity was observed recently, and the modelling indicated that passing fast ions dominantly contribute to the driving of 2/1 fishbone. The non-linear coupling between the toroidal Alfven eigenmode and tearing mode (TM) led to the generation of a high frequency mode with the toroidal mode number n = 0. The turbulence was modulated by TM when the island width exceeds a threshold and the modulation is localized merely in the inner area of the islands. Meanwhile, turbulence radial spread took place across the island region.

Several new results on the physics linking edge poloidal flows to turbulent momentum transport are reported. These are based on experiments on the HL-2A tokamak. Significant deviation from the neoclassical prediction for mean poloidal flow in Ohmic and electron cyclotron resonance heating (ECRH) heated L-mode discharges is derived from direct measurement of the turbulent Reynolds stress. The deviation increases prominently with ECRH power. The turbulent poloidal viscosity is synthesized from fluctuation data, and is found to be comparable to the turbulent particle diffusivity. The intrinsic poloidal torque characterized by the divergence of the non-diffusive residual stress is deduced from synthesis for the first time in a tokamak plasma. Experimental evidence which demonstrates the dynamics of spectral symmetry breaking in drift wave turbulence is in good agreement with the development of the poloidal torque. Taken together, these results elucidate the connections between power injection, turbulence development, pressure gradient and residual stress from symmetry breaking.

Several new results on the physics linking edge poloidal flows to turbulent momentum transport are reported. These are based on experiments on the HL-2A tokamak. Significant deviation from the neoclassical prediction for mean poloidal flow in Ohmic and electron cyclotron resonance heating (ECRH) heated L-mode discharges is derived from direct measurement of the turbulent Reynolds stress. The deviation increases prominently with ECRH power. The turbulent poloidal viscosity is synthesized from fluctuation data, and is found to be comparable to the turbulent particle diffusivity. The intrinsic poloidal torque characterized by the divergence of the non-diffusive residual stress is deduced from synthesis for the first time in a tokamak plasma. Experimental evidence which demonstrates the dynamics of spectral symmetry breaking in drift wave turbulence is in good agreement with the development of the poloidal torque. Taken together, these results elucidate the connections between power injection, turbulence development, pressure gradient and residual stress from symmetry breaking.

ITC27 & APPTC 2018, Gifu, Japan

The conversion of CO2 into liquid fuels, using only sunlight and water, offers a promising path to carbon neutrality. An outstanding challenge is to achieve high efficiency and product selectivity. Here, we introduce a wireless photocatalytic architecture for conversion of CO2 and water into methanol and oxygen. The catalytic material consists of semiconducting nanowires decorated with core-shell nanoparticles, with a copper-rhodium core and a chromium oxide shell. The Rh/CrOOH interface provides a unidirectional channel for proton reduction, enabling hydrogen spillover at the core-shell interface. The vectorial transfer of protons, electrons, and hydrogen atoms allows for switching the mechanism of CO2 reduction from a proton-coupled electron transfer pathway in aqueous solution to hydrogenation of CO2 with a solar-to-methanol efficiency of 0.22%. The reported findings demonstrate a highly efficient, stable, and scalable wireless system for synthesis of methanol from CO2 that could provide a viable path toward carbon neutrality and environmental sustainability. [ABSTRACT FROM AUTHOR]

Heterogeneous catalysts with atomically defined active centers hold great promise for high-performance applications. Among them, catalysts featuring active moieties with more than one metal atom are important for chemical reactions that require synergistic effects but are rarer than single atom catalysts (SACs). The difficulty in synthesizing such catalysts has been a key challenge. Recent progress in preparing dinuclear heterogeneous catalysts (DHCs) from homogeneous molecular precursors has provided an effective route to address this challenge. Nevertheless, only side-on bound DHCs, where both metal atoms are affixed to the supporting substrate, have been reported. The competing end-on binding mode, where only one metal atom is attached to the substrate and the other metal atom is dangling, has been missing. Here, we report the first observation that end-on binding is indeed possible for Ir DHCs supported on WO3. Unambiguous evidence supporting the binding mode was obtained by in situ diffuse reflectance infrared Fourier transform spectroscopy and high-angle annular dark-field scanning transmission electron microscopy. Density functional theory calculations provide additional support for the binding mode, as well as insights into how end-on bound DHCs may be beneficial for solar water oxidation reactions. The results have important implications for future studies of highly effective heterogeneous catalysts for complex chemical reactions.

Atomically dispersed catalysts refer to substrate-supported heterogeneous catalysts featuring one or a few active metal atoms that are separated from one another. They represent an important class of materials ranging from single-atom catalysts (SACs) and nanoparticles (NPs). While SACs and NPs have been extensively reported, catalysts featuring a few atoms with well-defined structures are poorly studied. The difficulty in synthesizing such structures has been a critical challenge. Here we report a facile photochemical method that produces catalytic centers consisting of two Ir metal cations, bridged by O and stably bound to a support. Direct evidence unambiguously supporting the dinuclear nature of the catalysts anchored on α-Fe2O3 is obtained by aberration-corrected scanning transmission electron microscopy (AC-STEM). Experimental and computational results further reveal that the threefold hollow binding sites on the OH-terminated surface of α-Fe2O3 anchor the catalysts to provide outstanding stability against detachment or aggregation. The resulting catalysts exhibit high activities toward H2O photooxidation.

Copper oxides have been of considerable interest as electrocatalysts for CO2 reduction (CO2R) in aqueous electrolytes. However, their role as an active catalyst in reducing the required overpotential and improving the selectivity of reaction compared with that of polycrystalline copper remains controversial. Here, we introduce the use of selected-ion flow tube mass spectrometry, in concert with chronopotentiometry, in situ Raman spectroscopy, and computational modeling, to investigate CO2R on Cu2O nanoneedles, Cu2O nanocrystals, and Cu2O nanoparticles. We show experimentally that the selective formation of gaseous C2 products (i.e., ethylene) in CO2R is preceded by the reduction of the copper oxide (Cu2OR) surface to metallic copper. On the basis of density functional theory modeling, CO2R products are not formed as long as Cu2O is present at the surface because Cu2OR is kinetically and energetically more favorable than CO2R.

Edge shear flow and its effect on regulating turbulent transport have long been suspected to play an important role in plasmas operating near the Greenwald density limit n G. In this study, equilibrium profiles as well as the turbulent particle flux and Reynolds stress across the separatrix in the HL-2A tokamak are examined as is approached in ohmic L-mode discharges. As the normalized line-averaged density n/ngis raised, the shearing rate of the mean poloidal flow ωshdrops, and the turbulent drive for the low-frequency zonal flow (the Reynolds power PRe) collapses. Correspondingly, the turbulent particle transport increases drastically with increasing collision rates. The geodesic acoustic modes (GAMs) gain more energy from the ambient turbulence at higher densities, but have smaller shearing rate than low-frequency zonal flows. The increased density also introduces decreased adiabaticity which not only enhances the particle transport but is also related to reduction in the eddy-tilting and the Reynolds power. Both effects may lead to cooling of edge plasmas and therefore the onset of MHD instabilities that limit the plasma density.

In order to determine the most suitable turbulence model for studying the aerodynamic performance of bus, the effects of different turbulence models on the aerodynamic characteristics of bus were investigated. A comparative analysis was conducted on five turbulence models (IDDES, DDES, DES, LES, URANS). The pressure distribution on the cross section at x=0 and y=0 is also analyzed for each model. The results reveal that IDDES accurately captures the negative pressure at the rear of the bus and predicts the pressure gradients more effectively than other models. IDDES also captures more vortices at the head of the bus and predicts the wake flow more widely than other models. DDES has obvious shedding phenomenon in the wake flow, while IDDES provides a relatively smooth airflow trajectory, but its prediction of airflow trajectory at a distance is less clear. Through quantitative and qualitative analyses of the aerodynamic characteristics of bus under different turbulence models, it can be concluded that IDDES is the most suitable turbulence model to study the aerodynamic characteristics of bus. [ABSTRACT FROM AUTHOR]

Water electrolysis can generate carbon-neutral hydrogen gas from water, yet the required catalysts are often expensive, scarce, and poor at gas release. Here, the authors prepared nitrogen-doped carbon tungstide nanoarrays with high water-splitting activities and bubble-releasing surfaces.

We study the nonlocal phase coupling during turbulence spreading across the magnetic island. It is found that the coherent convective cells (sharing similar features to quasi-coherent mode in experiment) on both sides of the O-point boundary are accumulated during the island formation. The phase entrainment of the convective cells on the turbulence both in the inner and the outer regions of the magnetic island sets up a nonlocal phase coupling channel and leads to a fast spreading of the outer turbulence into the magnetic island by conquering the flow shear at the O-point boundary. This nonlocal coupling mechanism of turbulence spreading is analogous to a turbulence version of the well-known enhanced diffusion of passive scalars in laminar convective flows of neutral fluid system. [ABSTRACT FROM AUTHOR]