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Pro gradu -tutkielmani aihe on Pohjoiskalotti-komitean tekemä työ matkailun edistämiseksi Pohjoiskalotin alueella vuosina 1967–1995. Keskityn työssäni komitean alaiseen matkailutoimintaan, jota vertaan Pohjoismaiden matkailun kehitykseen sekä muuhun matkailun edistämistyöhön Lapin läänissä. Lähteinäni ovat Pohjoiskalotin neuvoston säilynyt asiakirja-aineisto Oulun maakunta-arkistossa ja Pohjoiskalotti-komitean tiedotuslehti Pohjoiskalotti-Uutiset. Saadakseni kokonaiskuvan matkailun kehittämisestä Lapissa, käytän lähteenäni myös Lapin matkailun markkinointimateriaalia sekä kehittämissuunnitelmia, joita vertailen komitean tekemään matkailutyöhön. Tutkimuksessani hyödynnän niin kvalitatiivisia että kvantitatiivia tutkimusmenetelmiä sekä vertailua. Tämän tutkimuksen perusteella matkailun merkitys niin alueen elinkeinoelämässä että Pohjoiskalotti-komitean kokonaistoiminnassa voimistui tutkimusajanjaksolla. Matkailusta tuli jopa aluekehityksen väline Pohjoiskalotilla. Komitea perusti matkailualalle alaisuuteensa kaksi pysyvää matkailutoimielintä, joista ensimmäinen, matkailutyöryhmä, toimi vuosina 1977–1987 ja jälkimmäinen, matkailuneuvosto, vuosina 1987–1997. Pohjoiskalotti-komitea teki läheistä yhteistyötä alueen läänien kanssa, minkä seurauksena niiden matkailun kehittämissuunnitelmat sekä -kohteet olivat suurilta osin yhteneväisiä komitean vastaaviin. Komitean tekemä matkailutyö keskittyi vahvasti erilaisiin markkinointikampanjoihin ja matkailujulkaisuihin. Matkakohteena Pohjoiskalotti pysyi pääosin muuttumattomana 1960–1990-luvuilla, ja sen tärkeimpinä matkailun vetovoimatekijöitä olivat Pohjoiskalotti-komitean mielestä luonto ja kulttuuri. Yhteiskunnalliset ja kansainväliset muutokset kuitenkin vaikuttivat Pohjoiskalotin matkailun kehittämiseen tutkimusajanjaksona. Alueen matkailu kansainvälistyi 1990-luvulle tultaessa ja sen matkailumarkkinoinnin kohdealueeksi profiloitui yhä vahvemmin Eurooppa. Tämän seurauksena komitea pyrki yhdistämään matkailutoimintaansa niin Euroopan ja Venäjän kanssa. Lopulta Pohjoiskalotti-komitean matkailutyö integroitui Euroopan unionin matkailuohjelmiin komitean jäädessä lähinnä hankkeiden toteuttamisen alueelliseksi valvojaksi.

Graphitised carbon nanofibres (G‐CNFs) show superior thermal stability and corrosion resistance in PEM fuel cell environment over traditional carbon black (CB) and carbon nanotube catalyst supports. However, G‐CNFs have an inert surface with only very limited amount of surface defects for the anchorage of Pt catalyst nanoparticles. Modification of the fibre surface is therefore needed. In this study Pt nanoparticles have been deposited onto as‐received and surface‐modified G‐CNFs. The surface modifications of the fibres comprise acid treatment and nitrogen doping by pyrolysis of a polyaniline (PANI) precursor. The modified surfaces were studied by FTIR and XPS and the electrochemical characterization, including long‐term Pt stability tests, was performed using a low‐temperature PEMFC single cell. The performance and stability of the G‐CNF supported catalysts were compared with a CB supported catalyst and the effects of the different surface treatments were discussed. On the basis of these results, new membrane electrode assemblies (MEAs) were manufactured and tested also for carbon corrosion by in situ FTIR analysis of the cathode exhaust gases. It was observed that the G‐CNFs showed 5 times lower carbon corrosion compared to CB based catalyst when potential reached 1.5 V versus RHE in simulated start/stop cycling.

Induction nucleation is a very well suited technique for large scale synthesis of various nanomaterials (Auvinen et. al, 2010) Using induction materials can efficiently be heated to a very high temperature thus enabling high production rates. At the same time the gas flow can be kept cool, which induces extremely high temperature gradients needed for formation of nanoparticles. The synthesis can be carried out at normal pressure, which significantly decreases the facility costs as well as the pumping power. At the outlet of the furnace also the temperature of the inert gas flow is close to ambient enabling the use of common structural materials, rubber seals and inexpensive bag filters. Typically the precursors can be relatively low-cost and yet high purity bulk materials. Induction nucleation process is also environmentally sound as it uses no water, produces no liquid waste and releases only filtered nitrogen from the reactor. The induction nucleation method was initially developed for production of metallic nanoparticles. The source materials are vaporised from tungsten or graphite crucibles to nitrogen or argon carrier gas flow. Graphite felt insulation separates the hot carrier gas from cool nitrogen flow. When the gas flows are mixed turbulently, rapid cooling induces formation of nanoparticles. In this work the same method was applied for production of SiO nanoparticles applied in Li-ion battery anodes. SiO is well suited for material for induction nucleation synthesis as it has significantly higher vapour pressure than either Si or SiO2. It is also far less reactive in high temperatures than pure silicon. SiO particles were produced by heating silicon in contact with oxides in temperature varying between 1 600°C to 1 790°C. The highest mass concentration reached in the tests was 2 600mg/m3 at 1 790°C. The produced particles were amorphous with primary diameter of about 15 nm. In the gas phase the primary particles formed larger agglomerates with mobility diameter of about 150 nm. Also production of SiO-Cu composite particles was tested by placing the source materials either in the same or in separate crucibles. With single crucible set-up the copper content of the produced powder ranged from 2 wt-% to 4 wt-% depending on the test parameters. A two-crucible set-up allowed more freedom in tuning the copper content of the particles. This study belongs to Active Nanocomposite Materials project funded by Tekes under Functional Materials Program.

This article reports the use of the scanning electrochemical microscope (SECM) to investigate the electronic properties of Langmuir monolayers of alkane thiol protected gold nanocrystals (NCs). A substantial increase in monolayer conductivity upon mechanical compression of the Au NC monolayer is reported for the first time. This may be the room temperature signature of the insulator to metal transition previously reported for comparable silver NC monolayers. Factors influencing the conductivity of the monolayer NC array are discussed.

Deposit formation and corrosion of recovery boiler superheater tubes are known to be interrelated with boiler chemistry and the design, as well as the operation conditions in an extremely complex way. After a short review of typical superheater corrosion conditions in the past, a brief summary is given about the work on particulate formation and agglomeration in the flue gas path. Deposit formation mechanisms, deposition fluxes, transformation processes, deposit heat conductivity and heat transfer, as well as transport of deleterious species in the deposits is illuminated by model calculations. Corrosion processes and materials performance is discussed with reference to the results of materials exposures in industrial recovery boilers, and in laboratory corrosion tests. As a conclusion, current needs and likely future trends in the materials technology of superheaters of modern recovery boilers typically operating firing high solids liquors and with low sulphur emissions are summarised.