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When soils available for the construction of liners do not display the characteristics necessary for a good performance, mixtures with other materials can be employed for achieving the desired quality. Several researchers have addressed those mixtures from either a geotechnical or a gas diffusion perspective, emphasizing low hydraulic conductivity. However, in recent years, growing attention has been drawn to the ability of liners to mitigate contamination. The literature lacks studies on the use of amendments for soil liners or cover systems to retain potentially toxic metals, which are important inorganic contaminants. This paper provides a systematic review of the literature considering publications available on Web of Science and SpringerLink databases between January 1st, 2012, and December 5th, 2022. The aim of the review was to identify the types of soils and amendments studied as liners or cover systems for such retention of potentially toxic metals, the methodologies of application of the alternative materials in the soils, and the research gaps and perspectives in the field. Seventeen papers that addressed 31 materials as amendments were retrieved. The most studied amendment was coal fly ash, and 17 amendments were residues or by-products, which indicates concerns over waste destination and sustainability. Among the potentially toxic metals analyzed are Pb, Cu, and Cd. Gaps such as lack of pilot, field-scale, and long-term studies, as well as perspectives for future research (e.g., different liner configurations, concomitant mixtures of two or more materials in the soil, and focus on the sustainability of amendments), were identified., (© 2024. The Author(s), under exclusive licence to Springer Nature Switzerland AG.)

Bioindicators have been widely used to assess the contamination of lead/zinc (Pb/Zn) in smelter areas, mining waste disposal areas and in areas containing slags from Pb ore smelting. In this context, the analysis involving microorganisms has gained prominence as a complementary tool in studies aimed at assessing contaminated sites. Therefore, the objective of this study was to assess the contamination of Pb, Zn and cadmium (Cd) in an area where a PbZn smelter operated, using the integration of geochemical and microbial data. The experimental analysis was conducted to characterize the soil collected at three different sites (samples NS, EW and EP). The analysis conducted was physicochemical, metal concentration, metal speciation and analysis of the microbial community through high-throughput sequencing technique. Through the results it was observed that the high concentrations of metals altered the bacterial community present in the soil. Differences were noted between the microbial communities according to the sampling site, especially in sample EP, collected at the margin of the dirt road, which presented higher metal concentrations and microbial diversity. The main phyla detected in the samples were: Proteobacteria, Bacteroidetes and Acidobacteria. Bacteria tolerant to the presence of potentially toxic metals (PTM), such as Rhodoplanes, Kaistobacter, Sphingomonas and Flavisolibacter were identified in the analyzed samples. The phylogenetic groups identified in the study area are similar to those obtained in other studies in metal contaminated areas. The differences between the bacterial communities in each sample indicate that the concentration of PTM may have influenced the microbial community in the soil. Thus, it is noted the importance of the integration of geochemical and microbial data to evaluate the impact of the improper disposal of high PTM concentrated slags in natural soils., (Copyright © 2019 Elsevier B.V. All rights reserved.)

The inadequate transportation of foundry slags during the construction of a mining waste landfill accounted for the presence of slags in the dirt road that connects the working district of Vila Mota to the city of Adrianópolis. The objectives of this work were to assess the lead (Pb) and zinc (Zn) contamination of the dirt. Three samples separated by 2 km were collected along a dirt road (samples: Adrianópolis, Deposit, and Plant). The conducted assays were physico-chemical parameters, pseudototal concentration, three sequential extraction procedures, and bioaccessibility assay. The laboratory data was used as input in the calculation of contamination indices risk assessment code (RAC) and potential ecological risk (Er i ). The dirt road presented high concentrations of Pb (mean 1426.5 mg kg -1 ) and Zn (mean 4964.8 mg kg -1 ). The BCR SEP (Bureau Community of Reference Sequential Extraction Procedure) method was more adequate in extracting the soluble-exchangeable fraction, and this fraction was correlated with the gastric phase. The bioaccessible fraction is mainly present in the stomach fraction and is transported to the intestinal phase. Using BCR SEP method to calculate the contamination indices, sample Deposit yielded very high risk when calculating RAC and Er i for Pb (72.9% and 639.5, respectively). For Zn, high risk was obtained with RAC and very high risk for Er i (42.5% and 344.2, respectively). The high content of Pb and Zn on the dirt road presents a risk to the population that uses this road, since the soil particles are easily transported, deposited on the dermis, and inhaled.

Improper disposal of mining waste is still considered a global problem, and further details on the contamination by potentially toxic metals are required for a proper assessment. In this context, it is important to have a combined view of the chemical and biological changes in the mining dump area. Thus, the objective of this study was to evaluate the Pb, Zn and Cd contamination in a slag disposal area using the integration of geochemical and microbiological data. Analyses of soil organic matter (SOM), pH, Eh, pseudo-total concentration of metals, sequential extraction and microbial community by polymerase chain reaction-denaturing gradient gel electrophoresis (PCR-DGGE) were conducted. Metal availability was evaluated based on the geoaccumulation index (I geo ), ecological risk ([Formula: see text]), Risk Assessment Code (RAC) and experimental data, and different reference values were tested to assist in the interpretation of the indices. The soil pH was slightly acidic to neutral, the Eh values indicated oxidized conditions and the average SOM content varied from 12.10 to 53.60 g kg -1 . The average pseudo-total concentrations of metals were in the order of Zn > Pb > Cd. Pb and Zn were mainly bound to the residual fraction and Fe-Mn oxides, and a significant proportion of Cd was bound to the exchangeable and carbonate fractions. The topsoil (0-20 cm) is highly contaminated (I geo ) with Cd and has a very high potential ecological risk ([Formula: see text]). Higher bacterial diversity was mainly associated with higher metal concentrations. It is concluded that the integration of geochemical and microbiological data can provide an appropriate evaluation of mining waste-contaminated areas.