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The problem of selection between sequencing and dispatching as a scheduling approach in a job-shop setting is investigated. Makespan performance using the two different approaches is compared through simulation experiments, under such dynamic manufacturing environments as machine breakdowns, specification changes and rush jobs. Based upon the experimental results, a new approach that switches sequencing to dispatching according to the manufacturing situation is proposed, to make the best use of both sequencing and dispatching approaches. [ABSTRACT FROM AUTHOR]

The article proposes a systematic and practical algorithm for the problem of load smoothing of transformers and feeders in large-scale distribution systems. The system of power distribution in urban areas in Japan is discussed, as well as the main strategies for deciding open positions of sectionalizing switches for real systems in their normal state and the requirements for an open loop distribution system.

We investigated the previously unexplored domain of water vapor/gas separation using graphene oxide (GO) membranes, expecting future applications, including gas dehumidifiers and superior humidity controllers. While the importance of manipulation of GO nanosheet size and surface chemistry in traditional water purification and gas separation has been acknowledged, their potential impact on water vapor/gas separation remained unexplored until now. We applied sonication and hydrogen peroxide treatments to GO water dispersions and systematically evaluated the size and surface chemistry of each GO nanosheet. Both treatments reduced the GO nanosheet size to shorten the diffusion length, which improved water permeance. In addition, hydrogen peroxide treatment improved the hydrophilicity of the nanosheet. Our novel findings demonstrate that optimization of GO nanosheet size and the increase in their hydrophilicity via hydrogen peroxide treatments for 5 h significantly enhance water permeance, leading to a remarkable water vapor permeance of 4.6 × 10 -6 mol/(m 2 s Pa) at 80 °C, a 3.1-fold improvement over original GO membranes, while maintaining a water vapor/nitrogen permeance ratio exceeding 10,000. These results not only provide important insights into the nature of water vapor/gas separation but also suggest innovative methods for optimizing the GO membrane structure.

A 40 cm length Bis(triethoxysilyl)ethane (BTESE) membrane having different pore sizes was successfully prepared by changing the number of coating times for gas permeation (GP) and organic solvent reverse osmosis (OSRO) separation study. It was found that BTESE-6 membranes prepared through six-time coating consisted of small-sized pores in the range 0.56 to 0.64 nm estimated using modified Gas Translation (mGT) method and 0.59 to 0.67 nm estimated by nanopermporometry (NPP) method, respectively. These membranes demonstrated a high DMF rejection, R DMF > 5 kg m J v total > 5 kg m -2 h -1 at operating condition feed pressure, P f : 8 MPa; feed temperature, T f : 50 °C; and feed flowrate, Q O separation, our BTESE-6 membranes still exhibited high flux in the range of 3-6 kg m f : 30 mL/min; and they exhibited a high degree selectivity of He/SF 6 in the range of ~ 260-3400 at a permeation temperature 200 °C. On the other hand, the larger pore sizes of the BTESE-4 membranes (pore size estimates > 0.76 nm to 1.02 nm) exhibited low DMF rejection and a low degree selectivity of He/SF 6 around ~30% and 25, respectively, at the same operating condition as BTESE-6. Both GT and NPP methods can be considered as an indicator of the measurement membrane pore size. From this study, it was found that He and SF 6 gases can be some of the potential predictors for water and DMF permeance. Furthermore, by comparing our OSRO membrane with other PV membranes for DMF/H 2 O separation, our BTESE-6 membranes still exhibited high flux in the range of 3-6 kg m -2 h -1 with a separation factor H 2 O/DMF in the range of 80-120.

Steam recovery from the spent gases from flues could be a key step in addressing the water shortage issue while additionally benefiting energy saving. Herein, we propose a system that uses organosilica membranes consisting of a developed layered structure to recover steam and latent heat from waste. Proof-of-concept testing is conducted in a running incinerator plant. The proposed system eliminates the need for a water supply while simultaneously recovering latent heat from the waste stream. First, the long-term stability of an organosilica membrane is confirmed over the course of six months on a laboratory-scale under a simulated waste stream. Second, steam recovery is demonstrated in a running waste incinerator plant (bench-scale), which confirms the steady operation of this steam recovery system with a steam recovery rate comparable to that recorded in the laboratory-scale test. Third, process simulation reveals that this system enables water-self-reliance with energy recovery that approximates 70% of waste combustion energy., (© 2023. The Author(s).)

Graphene oxide (GO) has attracted attention as an excellent membrane material for water treatment and desalination owing to its high mechanical strength, hydrophilicity, and permeability. In this study, composite membranes were prepared by coating GO on various polymeric porous substrates (polyethersulfone, cellulose ester, and polytetrafluoroethylene) using suction filtration and casting methods. The composite membranes were used for dehumidification, that is, water vapor separation in the gas phase. GO layers were successfully prepared via filtration rather than casting, irrespective of the type of polymeric substrate used. The dehumidification composite membranes with a GO layer thickness of less than 100 nm showed a water permeance greater than 1.0 × 10 -6 mol/(m 2 s Pa) and a H 2 O/N 2 separation factor higher than 10 4 at 25 °C and 90-100% humidity. The GO composite membranes were fabricated in a reproducible manner and showed stable performance as a function of time. Furthermore, the membranes maintained high permeance and selectivity at 80°C, indicating that it is useful as a water vapor separation membrane.

This review presents a concise conceptual overview of membranes derived from organic chelating ligands as studied in several works. The authors' approach is from the viewpoint of the classification of membranes by matrix composition. The first part presents composite matrix membranes as a key class of membranes and makes a case for the importance of organic chelating ligands in the formation of inorganic-organic composites. Organic chelating ligands, categorized into network-modifying and network-forming types, are explored in detail in the second part. Four key structural elements, of which organic chelating ligands (as organic modifiers) are one and which also include siloxane networks, transition-metal oxide networks and the polymerization/crosslinking of organic modifiers, form the building blocks of organic chelating ligand-derived inorganic-organic composites. Three and four parts explore microstructural engineering in membranes derived from network-modifying and network-forming ligands, respectively. The final part reviews robust carbon-ceramic composite membranes as important derivatives of inorganic-organic hybrid polymers for selective gas separation under hydrothermal conditions when the proper organic chelating ligand and crosslinking conditions are chosen. This review can serve as inspiration for taking advantage of the wide range of possibilities presented by organic chelating ligands.

This work investigated the long-term hydrothermal performance of composite carbon-SiO 2 -ZrO 2 membranes. A carbon-SiO 2 -ZrO 2 composite was formed from the inert pyrolysis of SiO 2 -ZrO 2 -polybenzoxazine resin. The carbon-SiO 2 -ZrO 2 composites prepared at 550 and 750 °C had different surface and microstructural properties. A carbon-SiO 2 -ZrO 2 membrane fabricated at 750 °C exhibited H 2 selectivity over CO 2 , N 2 , and CH 4 of 27, 139, and 1026, respectively, that were higher than those of a membrane fabricated at 550 °C (5, 12, and 11, respectively). In addition to maintaining high H 2 permeance and selectivity, the carbon-SiO 2 -ZrO 2 membrane fabricated at 750 °C also showed better stability under hydrothermal conditions at steam partial pressures of 90 (30 mol%) and 150 kPa (50 mol%) compared with the membrane fabricated at 500 °C. This was attributed to the complete pyrolytic and ceramic transformation of the microstructure after pyrolysis at 750 °C. This work thus demonstrates the promise of carbon-SiO 2 -ZrO 2 membranes for H 2 separation under severe hydrothermal conditions.

A series of pendant-type alkoxysilane structures with various carbon numbers (C 1 -C 8 ) were used to fabricate sol-gel derived organosilica membranes to evaluate the effects of the C/Si ratio and fluorine doping. Initially, this investigation was focused on the effect that carbon-linking (pendant-type) units exert on a microporous structure and how this affects the gas-permeation properties of pendant-type organosilica membranes. Gas permeation results were compared with those of bridged-type organosilica membranes (C 1 -C 8 ). Network pore size evaluation was conducted based on the selectivity of H 2 /N 2 and the activation energy ( E p ) of H 2 permeation. Consequently, E p (H 2 ) was increased as the C/Si ratio increased from C 1 to C 8 , which could have been due to the aggregation of pendant side chains that occupied the available micropore channel space and resulted in the reduced pore size. By comparison, these permeation results indicate that pendant-type organosilica membranes showed a somewhat loose network structure in comparison with bridged-type organosilica membranes by following the lower values of activation energies ( E p ). Subsequently, we also evaluated the effect that fluorine doping (NH 4 F) exerts on pendant-type [methytriethoxysilane (MTES), propyltrimethoxysilane (PTMS)] and bridged-type [1,2-bis(triethoxysilyl)methane (BTESM) bis(triethoxysilyl)propane (BTESP)] organosilica structures with similar carbon numbers (C 1 and C 3 ). The gas-permeation properties of F-doped pendant network structures revealed values for pore size, H 2 /N 2 selectivity, and E p (H 2 ) that were comparable to those of pristine organosilica membranes. This could be ascribed to the pendant side chains, which might have hindered the effectiveness of fluorine in pendant-type organosilica structures. The F-doped bridged-type organosilica (BTESM and BTESP) membranes, on the other hand, exhibited a looser network formation as the fluorine concentration increased.

In this study, nickel-doped aminosilica membranes containing pendant groups were prepared with 3-aminopropyltriethoxysilane (APTES), trimethoxy[3-(methylamino)propyl]silane (MAPTS), 3 N , N -dimethyl aminopropyltrimethoxysilane (DAPTMS), N -[3-(trimethoxysilylpropyl]ethylene diamine (TMSPED), and 1-[3-(trimethoxysilyl)propyl] urea (TMSPU). Differences in the structures of terminal amine ligands significantly contributed to the formation of a coordinated structural assembly. Ultraviolet-visible spectroscopy (UV-vis), Fourier transform infrared spectroscopy (FT-IR), X-ray diffraction (XRD), and N 2 adsorption isotherms revealed that short and rigid pendant amino groups successfully coordinated with nickel to produce subnanopores in the membranes, while an ion-exchange interaction was suggested for longer and sterically hindered aminosilica precursors. Moreover, the basicity of amine precursors affected the affinity of ligands for the development of a coordinated network. A pristine aminosilica membrane showed low levels of H 2 permeance that range from 0.1 to 0.5 × 10 -6 mol m -2 s -1 Pa -1 with a H 2 /N 2 permeance ratio that ranges from 15 to 100. On the contrary, nickel coordination increased the H 2 permeance to 0.1-3.0 × 10 -6 mol m -2 s -1 Pa -1 with H 2 /N 2 permeance ratios that range from 10 to 68, which indicates the formation of a microporous structure and enlargement of pore sizes. The strong level of coordination affinity between nickel ions and amine groups induced rearrangement of the flexible pendant chain into a more rigid structure.

Organosilica membranes are a promising candidate for pervaporation dehydration owing to their tunable molecular sieving characteristics and excellent hydrothermal stability. Herein, we report a facile modification using an atmospheric-pressure water vapor plasma to enhance the pervaporation performance of organosilica membranes. The surface of methyl-terminated organosilica membranes was treated by water vapor plasma to develop an ultrathin separation active layer suitable for pervaporation dehydration. The surface hydrophilicity was increased by water vapor plasma due to oxidative decomposition of methyl groups to form silanol groups. The plasma-modified layer had a thickness of several nanometers and had a silica-like structure due to the condensation of silanol groups. The plasma-modified organosilica membranes exhibited an improved molecular sieving property owing to the formation of highly cross-linked siloxane networks with a pore size of approximately 0.4 nm. The membranes also exhibited an excellent permselectivity in the dehydration of alcohols due to the nanometer-thick separation active layer with controlled pore size and increased hydrophilicity. The plasma-modified membranes showed high H 2 O permeance exceeding 10 -6 mol m -2 s -1 Pa -1 with permeance ratios for H 2 O/EtOH and H 2 O/IPA of 517-3050 and >10 000, respectively, in the dehydration of 90 wt % aqueous solutions at 50 °C, which is among the highest permselectivities for silica-based membranes. Furthermore, the plasma-modified membranes displayed highly efficient dehydration performance for a H 2 O/MeOH mixture. The H 2 O permeance and H 2 O/MeOH permeance ratio in the dehydration of a 90 wt % MeOH aqueous solution at 50 °C were (2.3-3.0) × 10 -6 mol m -2 s -1 Pa -1 and 31-143, respectively, which exceeded the permeance-selectivity trade-off of conventional membranes including polymeric, silica-based, and zeolite membranes. The results indicate that the proposed plasma-assisted approach can enhance the pervaporation performance of organosilica membranes via the modification under atmospheric pressure and at room temperature.

Copolymerization of bis[3-(triethoxysilyl)propyl]amine (BTESPA) and N -(2-hydroxyethyl)- N '-[3-(triethoxysilyl)propyl]urea (HETESPU) provided highly permeable robust reverse osmosis (RO) membranes that have an organically bridged polysilsesquioxane (PSQ) structure. The RO experiments with NaCl aqueous solution (2000 ppm) indicated that the introduction of hydroxyethylurea groups markedly improved the permeability of water (1.86 × 10 -12 m 3 /m 2 sPa) to approximately 19 times higher than that of a membrane prepared via the BTESPA homopolymerization, with NaCl rejection remaining nearly unchanged (96%). This is the highest water permeability obtained so far for PSQ-based membranes that show higher than 90% NaCl rejection. The improvement of water permeability is likely due to aggregation through hydrogen bonding in the PSQ layer, which can be regarded as a hydrophilic water channel.

Organosilica membranes have recently attracted much attention due to excellent hydrothermal stability which enables their use in the presence of water. In particular, during humid-gas separations at moderate-to-high temperatures, these membranes have shown excellent water permeance and moderate water selectivity, which has been a breakthrough in separation performance. In the present work, we found that aluminum doping into the bis(triethoxysilyl)ethane (BTESE)-derived organosilica structure further improves water selectivity (H 2 O/N 2 , H 2 O/H 2 ) while maintaining a level of water permeance that reaches as high as several 10 -6 mol (m -2 s -1 Pa -1 ). Single-gas permeation and nitrogen adsorption experiments have revealed that aluminum doping promotes densification of the pore structure and improves molecular sieving. In addition, water adsorption and desorption experiments have revealed that aluminum doping enhances water adsorption onto the pore walls, which blocks permeation by other gasses and significantly improves water permeation selectivity during the separation of humid gases. Our results provide a strategy for the fabrication of a membrane that provides both a high level of water permeance and enhanced water selectivity., Competing Interests: The authors declare that they have no competing interests., (This journal is © The Royal Society of Chemistry.)

The nickel-doped bis [3-(trimethoxysilyl) propyl] amine (BTPA) derived membrane has a microporous coordinated network that has high potential to be an ideal separation barrier for methanol-toluene azeotropic mixtures via the pervaporation process. Ni-BTPA membranes were modified by employing a nickel dopant over amine groups in mole ratios (mol/mol) that ranged from 0.125 to 0.50. The incorporation of different amounts of nickel dopant into flexible amine-rich organosilica precursors of BTPA increased the rigidity and resulted in a porous structure with a large specific surface area (increased from 2.36 up to 282 m 2 g -1 ) and a high pore volume (from 0.024 up to 0.184 cm 3 g -1 ). Methanol-toluene separation performance by the nickel-doped BTPA (Ni-BTPA) membranes was increased with increases in the nickel concentration. Ni-BTPA 0.50 showed separation performance that was superior to other types of membranes, along with a high-level of flux at 2.8 kg m -2 h -1 and a separation factor higher than 900 in a 10 wt % methanol feed solution at 50 °C. These results suggest that the balance between the microporosity induced by amine-nickel coordination and an excessive amount of nickel-ion facilitates high levels of flux and separation of methanol.

The similar physico-chemical properties of propylene and propane molecules have made the separation process of propylene/propane challenging. Membrane separation techniques show substantial prospects in propylene/propane separation due to their low energy consumption and investment costs, and they have been proposed to replace or to be combined with the conventional cryogenic distillation process. Over the past decade, organosilica membranes have attracted considerable attention due to their significant features, such as their good molecular sieving properties and high hydrothermal stability. In the present review, holistic insight is provided to summarize the recent progress in propylene/propane separation using polymeric, inorganic, and hybrid membranes, and a particular inspection of organosilica membranes is conducted. The importance of the pore subnano-environment of organosilica membranes is highlighted, and future directions and perspectives for propylene/propane separation are also provided.

A new polyhedral oligomeric silsesquioxane (POSS) designed with eight -(CH 2 ) 3 -NH-(CH 2 ) 2 -NH 2 groups (PNEN) at its apexes was used as nanocomposite uploading into 1,2-bis(triethoxysilyl)ethane (BTESE)-derived organosilica to prepare mixed matrix membranes (MMMs) for gas separation. The mixtures of BTESE-PNEN were uniform with particle size of around 31 nm, which is larger than that of pure BTESE sols. The characterization of thermogravimetric (TG) and gas permeance indicates good thermal stability. A similar amine-contained material of 3-aminopropyltriethoxysilane (APTES) was doped into BTESE to prepare hybrid membranes through a copolymerized strategy as comparison. The pore size of the BTESE-PNEN membrane evaluated through a modified gas-translation model was larger than that of the BTESE-APTES hybrid membrane at the same concentration of additions, which resulted in different separation performance. The low values of E p (CO 2 )-E p (N 2 ) and E p (N 2 ) for the BTESE-PNEN membrane at a low concentration of PNEN were close to those of copolymerized BTESE-APTES-related hybrid membranes, which illustrates a potential CO 2 separation performance by using a mixed matrix membrane strategy with multiple amine POSS as particles.

Microporous silica membranes have shown promise as potential candidates for energy-efficient chemical separation. Herein, we report the ultrafast synthesis of silica membranes, on the order of minutes, in atmospheric-pressure, low-temperature plasma. Direct deposition in the discharge region of atmospheric-pressure plasma enables the immediate formation of a thin silica layer on a porous substrate. The plasma-deposited layer had a thickness of ∼13 nm and was confined to the immediate surface of the substrate. With an increase in deposition temperature, we observed an increase in the inorganic nature of the plasma-deposited layer and simultaneous improvement in the membrane performance. Consequently, the resulting membranes exhibited outstanding permeance for small-sized gas molecules, such as H 2 (>10 -6 mol m -2 s -1 Pa -1 ), with a high H 2 /SF 6 permeance ratio of ∼6300, providing a nonthermal alternative for the fabrication of silica-based membranes.