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Herein we described a catalytic epoxidation of α,β-enone with peroxide in situ generated via a predominant single electron transfer and a minor energy transfer pathways using inexpensive natural vitamin B2...

Oxygen-vacancy-induced topotactic phase transformation between the ABO

Light-field shaping technology plays an important role in optics and nanophotonics. For instance, the spatially structured light field, which exhibits characteristic features in complex phases, light intensity, and polarization, is crucial to understanding new physical phenomena and exploring practical applications. Herein, we propose and demonstrate a new class of tunable circular Pearcey beams (TCPBs) by imposing the annular spiral-zone phase (ASZP). Through experiments, we used a spatial light modulator to generate TCPBs based on their spiral phase distribution, and numerically analyzed the generation and control of the beams with unusual autofocusing and self-rotating dynamics. ASZP is a general term for complex phases composed of the spiral phase, equiphase, and radial phase. TCPB typically exhibits dynamical properties, including abrupt autofocusing, automatic generation of optical bottles, and self-rotation of the beam pattern, during propagation. Besides, the number of generated optical bottles can be modulated by the superposition mode of ASZP and the number of subphases. We found that an inappropriate superposition mode leads to distortion, and we analyzed the underlying mechanism. Potential applications of TCPBs in optical manipulation are also discussed, presenting an exemplary role desired for light-field manipulation.

We derive analytical solutions that describe the one-dimensional displaced and chirped symmetric Pearcey Gaussian beam in a uniformly moving parabolic potential. The multiple effective manipulations of the beam, which are originated from the diverse configurations of the dynamic parabolic potential, are demonstrated. On the whole, the accelerating trajectory can transform into a linear superposition form of the oblique straight line and the simple harmonic motion. Meanwhile, we discuss the further modulation of the accelerating trajectory characteristics such as slope, amplitude and phase shift. Additionally, the extension into a two-dimensional scenario is also proposed. Our results theoretically improve the practical value of the Pearcey beam, and lead to potential applications in trajectory manipulation and particle manipulation.

In this Letter, a new, to the best of our knowledge, type of autofocusing and symmetric beam arisen from two quartic spectral phases is introduced in theory and experiment. The symmetric Pearcey Gaussian beam (SPGB), formed with a Gaussian term and two multiplying Pearcey integrals, processes a focusing intensity approximately 1.32 times stronger than the intensity of the symmetric Airy beam. Its four off-axis main lobes split into four bending trajectories symmetrically after focusing. The rectangular intensity distribution and the focal length of the SPGB can be adjusted by two kinds of distribution factors. Additionally, the vortex-guiding property of the beam is demonstrated by embedding an off-axis vortex into the SPGB, which can be applied in particle guiding.

The development of Internet of vehicle (IOV) and autopilot technology indicates the coming of smart traffic and automatic unmanned era. The promotion of networking and intelligence not only provides a rich source for urban traffic data, but also provides an efficient and direct way to solve urban traffic problems. With the help of deep learning and reinforcement learning technology, we propose a model to mine the urban traffic rule from the travel history of urban travelers, and utilize it achieving better allocation of traffic resources by providing a traffic guidance service, finally realize the system optimal traffic travel.

This work reported a simulation study on the optimal diameter (D) and wall thickness (H) of hollow Fe3O4 microspheres to improve the magnetorheological (MR) effect. Modified formulae for the magnetic dipolar force, van der Waals force, and hydrodynamic drag force were employed in the simulation model. Typical evolution of shear stress and microstructures in steady shear flow was obtained. The shear stress-strain curve was divided into linear, fluctuant, and homeostasis regions, which were related to the inclination of particle chains and the lateral aggregation. For hollow Fe3O4 microspheres with different diameters and wall thicknesses, the shear stress curves collapsed onto a quadratic master curve. The best wall thickness was H = 0.39D for a 20 wt% MR fluid and H = 0.35D for a 40 wt% MR fluid, while the optimal diameter was D = 1000 nm and D = 100 nm, respectively. The maximum shear stress of the 40 wt% MR fluid was twice that of the 20 wt% MR fluid. The change of shear stress was due to the competition that results among the magnetic interaction, number of neighbors, tightness, and orientation of the particle chains. Simulated dimensionless viscosity data as a function of Mason number for various diameters, wall thicknesses, and weight fractions collapsed onto a single master curve. The simulated shear stress under both a magnetic field and shear rate sweep matched well with experiments.

Oxygen-vacancy-induced topotactic phase transformation between the ABO2.5 brownmillerite structure and the ABO3 perovskite structure attracts ever-increasing attention due to the perspective applications in catalysis, clean energy field, and memristors. However, a detailed investigation of the electronic-structure evolution during the topotactic phase transformation for understanding the underlying mechanism is highly desired. In this work, multiple analytical methods were used to explore evolution of the electronic structure of SrFeO3−x thin films during the topotactic phase transformation. The results indicate that the increase in oxygen content induces a new unoccupied state of O 2p character near the Fermi energy, inducing the insulator-to-metal transition. More importantly, the hole states are more likely constrained to the dx 2–y 2 orbital than to the d3z 2–r 2 orbital. Our results reveal an unambiguous evolution of the electronic structure of SrFeO3–x films during topotactic phase transformation, which is crucial not only for fundamental understanding but also for perspective applications such as solid-state oxide fuel cells, catalysts, and memristor devices.

A new kind of structured open-ends optical bottle (OB) beam generated by the second order chirped ring symmetric Airy vortex beam (CRSAVB) is derived. The optical vortices (OVs) and the chirped factor on the CRSAVB play a significant role on controlling the sizes, quantities and locations of open-ends OBs. The OVs also play an important role on the rotation of the lobe. Additionally, due to the self-healing property of the CRSAVB, this beam has a certain anti-interference. These results bring more potential on improving the application of multi particles manipulation and expand the generation method of multi open-ends OBs.

Predicting traffic conditions for road segments is the prelude of working on intelligent transportation. Many existing methods can be used for short-term or long-term traffic prediction, but they focus more on regions than on road segments. The lack of fine-grained traffic predicting approach hinders the development of ITS. Therefore, MapLSTM, a spatio-temporal long short-term memory network preluded by map-matching, is proposed in this paper to predict fine-grained traffic conditions. MapLSTM first obtains the historical and real-time traffic conditions of road segments via map-matching. Then LSTM is used to predict the conditions of the corresponding road segments in the future. Breaking the single-index forecasting, MapLSTM can predict the vehicle speed, traffic volume, and the travel time in different directions of road segments simultaneously. Experiments confirmed MapLSTM can not only achieve prediction for road segments based a large scale of GPS trajectories effectively but also have higher predicting accuracy than GPR and ConvLSTM. Moreover, we demonstrate that MapLSTM can serve various applications in a lightweight way, such as cognizing driving preferences, learning navigation, and inferring traffic emissions.

A new type of Pearcey-like vortex beam, generated by the appropriate phase modulation of the optical wavefront, which propagates along a predesigned parabolic trajectory in the free space, is presented. This kind of beam forms several oval closed rings with uneven intensity and focuses along the trajectory. It forms a bending optical bottle (OB) and an off-axis focus. Through setting appropriate parameters, we can adjust the size of the OB and the focus position. Besides, the self-healing property outlines the antijam of the beam. This beam can be appropriately utilized on the optical trapping and the laser energy focusing in a certain degree.

In our study, an analytical expression of the second order chirped Pearcey Gaussian vortex beam (CPGVB) in a medium with a parabolic refractive index is derived. We demonstrate its propagation behaviors as well as the effects of the parameters on the propagation properties. Expectedly, the CPGVB performs periodically automatic Fourier transform in the specific positions, but unexpectedly the off-axis autofocusing position can be generated and controlled without changing the laser incident angle. Furthermore, we investigate the radiation forces of the CPGVB, and thus notice that trapping positions form in the beam-propagation direction.

We propose a new class of abruptly autofocusing beams, the chirped annular Bessel Gaussian beams (CABGBs), which are based on the radial Bessel profile. By using the Rayleigh–Sommerfeld diffraction formula, the nonparaxial propagation of the CABGBs is investigated. We find that the initial chirp with negative value tends to intensify the abruptly autofocusing property by shortening the focal length, shrinking the focal spot size, and increasing the peak intensity contrast. The optical trapping effect of the CABGBs acting on a Rayleigh particle is analyzed, and we find that the particle can be stably trapped in three dimensions if the parameters of the CABGBs are appropriate. If the absolute value of the negative chirp increases, the trapping position is shifted toward the input plane, and both the longitudinal and transverse trapping forces rise. A higher magnitude of the radiation forces can be reached if the incident power increases.

In this paper, an analytical expression with a triple sum of the Hermite–Gaussian vortex beam (HGVB) propagating in a medium with a parabolic transverse spatial distribution of the refractive index is carried out. The intensity, phase, Poynting vector, and angular momentum of the HGVB are demonstrated analytically. The parabolic parameter, orders of the HGVB, and vortex topological charge affect the propagation properties, respectively. Also, the Poynting vector and angular momentum of the HGVB are shown so that we can further discover the properties. Furthermore, radiation forces are used to demonstrate the optical trapping ability of the HGVB, and several trapping positions are formed by the beam during propagation.

We introduce numerically a new polycyclic tornado ring Airy beam (PTRAB) induced by annular spiral zone phases with the second order chirped factor. The PTRAB has such properties of controllable multi focuses, the multi optical bottles and rotation. By choosing appropriate parameters, we can control the times of the multi autofocus and the autofocusing distance, the size and the number of the OBs, the quantity of the spots and the location where the rotary direction changes from counterclockwise to clockwise. We believe our results have potential applications in laser energy focusing, optical tweezers, optical spanners and manufacturing tunable chiral meta-materials.

This work reported a simulation study on the optimal diameter (D) and wall thickness (H) of hollow Fe3O4 microspheres to improve the magnetorheological (MR) effect. Modified formulae for the magnetic dipolar force, van der Waals force, and hydrodynamic drag force were employed in the simulation model. Typical evolution of shear stress and microstructures in steady shear flow was obtained. The shear stress-strain curve was divided into linear, fluctuant, and homeostasis regions, which were related to the inclination of particle chains and the lateral aggregation. For hollow Fe3O4 microspheres with different diameters and wall thicknesses, the shear stress curves collapsed onto a quadratic master curve. The best wall thickness was H = 0.39D for a 20 wt% MR fluid and H = 0.35D for a 40 wt% MR fluid, while the optimal diameter was D = 1000 nm and D = 100 nm, respectively. The maximum shear stress of the 40 wt% MR fluid was twice that of the 20 wt% MR fluid. The change of shear stress was due to the competition that results among the magnetic interaction, number of neighbors, tightness, and orientation of the particle chains. Simulated dimensionless viscosity data as a function of Mason number for various diameters, wall thicknesses, and weight fractions collapsed onto a single master curve. The simulated shear stress under both a magnetic field and shear rate sweep matched well with experiments.

To investigate the microstructural evolution dependency on the apparent viscosity in shear-thickening fluids (STFs), a hybrid mesoscale model combined with stochastic rotation dynamics (SRD) and molecular dynamics (MD) is used. Muller-Plathe reverse perturbation method is adopted to analyze the viscosities of STFs in a two-dimensional model. The characteristic of microstructural evolution of the colloidal suspensions under different shear rate is studied. The effect of diameter of colloidal particles and the phase volume fraction on the shear thickening behavior is investigated. Under low shear rate, the two-atom structure is formed, because of the strong particle attractions in adjacent layers. At higher shear rate, the synergetic pair structure extends to layered structure along flow direction because of the increasing hydrodynamics action. As the shear rate rises continuously, the layered structure rotates and collides with other particles, then turned to be individual particles under extension or curve string structure under compression. Finally, at the highest shear rate, the strings curve more severely and get into two-dimensional cluster. The apparent viscosity of the system changes from shear-thinning behavior to the shear-thickening behavior. This work presents valuable information for further understanding the shear thickening mechanism.

The composite foundation of glass concrete can not only reuse the large number of waste glass, but also improve the bearing capacity of weak foundation and soil with special properties. In this paper, the engineering properties of glass concrete composite foundation are studied based on the development situation of glass concrete and the technology of composite foundation.